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3D Systems VisiJet Armor M2G-CL UV curable plastic

    • Название продукта: 3D Systems VisiJet Armor M2G-CL UV curable plastic
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
    • Запрос цены: admin@ascent-chem.com
    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Спецификации
    Код ТН ВЭД 458380

    Будучи аккредитованной 3D Systems VisiJet Armor M2G-CL УФ-затваряемой пластиковой фабрикой, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение 3D-систем VisiJet Armor M2G-CL УФ-затваряемый пластик

    Within MultiJet Modeling platforms, VisiJet Armor M2G-CL is processed as a liquid photopolymer at 600 × 600 dpi addressable resolution, with layer thickness typically selected at 32 µm in high-resolution mode. The printed part is embedded in sacrificial wax support that is removed in a low-temperature oven below the material’s heat deflection ceiling, followed by an isopropanol rinse. Transparent handheld diagnostic housings are a principal downstream application because the clear polymer permits visual alignment of internal light-pipe channels before injection mould tooling is committed. The supplier technical datasheet reports post-cured tensile strength in the range 35–45 MPa per ASTM D638, elongation at break of 12–20 % per ASTM D638, and notched Izod impact of 35–50 J/m per ASTM D256. Snap-fit undercuts are designed with a dimensional-growth allowance of 0.3–0.8 % because the UV post-cure step increases crosslink density and shifts latch engagement force. In a 48-part batch of clip covers, the engagement force spread narrowed from ±18 % in the green state to ±8 % after post-cure when parts were arranged in the same z-axis orientation; the remaining variation was attributed to airflow asymmetry in the post-cure cabinet. The main process conflict is the thermal ceiling: the supplier indicates heat deflection below 55 °C at 0.45 MPa per ASTM D648, so support-oven setpoints above 40 °C can relax thin clip arms and alter snap-fit geometry. A validation sequence used 365 nm fluorescent lamps at 5–7 mW/cm² for 120–180 min; below 2 J/cm², residual unreacted monomer caused surface tack and low impact resistance, while above 4 J/cm², the clear section began to yellow and notched Izod dropped sharply. Assemblers then mate the housing repeatedly for 20 cycles at 23 °C; cracking at the gate is rejected per ASTM D638 tensile-fracture morphology. The printed housing is not rated for direct food contact or outdoor UV exposure; current published data for weathering under ISO 4892-2 are limited.

    PropertyTest methodPost-cured supplier-reported window
    Tensile strengthASTM D63835–45 MPa
    Elongation at breakASTM D63812–20 %
    Flexural modulusASTM D7901,500–1,900 MPa
    Notched Izod impactASTM D25635–50 J/m
    Heat deflection temperature at 0.45 MPaASTM D64850–55 °C
    Shore D hardnessASTM D224078–82

    Why Does Post-Cure UV Dose Alter Izod Impact Response in Thin-Walled Fluid Reservoirs?

    For clear fluid reservoirs and manifold prototypes, the post-cure cycle is a kinetic conflict between acrylate conversion and chain scission. Parts removed from the printer contain residual photoinitiator and unreacted acrylate; the supplier datasheet reports green elongation at break near 20 % but notched Izod below final values. When 2 mm wall sections are post-cured under 365 nm lamps at 6 mW/cm² for 120–180 min, conversion increases until network density reaches a plateau, beyond which embrittlement dominates. The practical limit is surface temperature: if the post-cure cabinet exceeds 45 °C, the clear wall can distort and seal lip roundness drifts out of the ±0.2 mm assembly tolerance. Extraction data for this grade are typically manufacturer-declared only for non-implantable device housings; use of clear reservoirs in direct food-contact or blood-loop applications is not supported by current published data. A more practical validation is a five-cycle pressure-decay test at 80 kPa after thermal cycling from –10 °C to 40 °C, measuring leaks at the bonded PMMA adapter interface. The failure mode observed in pilot builds is not burst, but slow solvent-weeping through seal lips because unreacted monomer migrates if the post-cure dose falls below 2 J/cm². The reservoir body is then inspected for craze marks under polarised light after 24 h contact with 50 % ethanol; published data for this specific photopolymer configuration are limited, and the test is required before release.

    Automotive undertray clip pre-production builds use M2G-CL because the material can be run in a multi-cavity nest without the tooling cost of moulded nylon. The supplier datasheet places the heat deflection temperature at 52 °C under 0.45 MPa per ASTM D648; consequently, the clips are not used for continuous underhood exposure above 70 °C and are validated only as assembly aids. In a 96-cavity build on an MJP 2500 Plus platform, support-wax drainage channels of 2.5 mm were required to obtain uniform oven wax removal; channels of 1.8 mm retained wax after the oven cycle and produced snap-force scatter of ±15 % between edge and centre positions. The failure mode during thermal cycling between –20 °C and 70 °C is stress relaxation in the latch arm, not cracking; the retained strain after 20 cycles fell below 0.4 % recoverable if the latch was loaded above 0.5 % strain. For engine-oil immersion, the prototype must be tested per ASTM D543 because the supplier-published fluid compatibility table for this photopolymer is limited to water and moderate aqueous detergents. The clip is then subjected to a 5 kg static load at 60 °C for 30 min; deformation above 0.2 mm at the latch tip is rejected. This is not a production-grade PEEK or nylon replacement; the boundary is set by thermoset oxidation and moisture absorption below 1.0 % after 24 h water immersion per ASTM D570.

    Wearable Diagnostic Enclosure Prototypes and Strap Anchor Stress Concentrations

    Portable medical diagnostic enclosures printed in M2G-CL are used as benchtop fit-and-function prototypes where the enclosure is separated from the patient by at least one polymer film barrier. The resin is not certifiable as a final body-contact device because the supplier-published biocompatibility matrix is limited; if ISO 10993-5 cytotoxicity data are required, they must be generated against the final post-cured and cleaned surface rather than assumed from the raw photopolymer SDS. At the wrist strap anchor, the gate location creates a region of lower molecular weight; the difference between gate and off-gate notched Izod impact can exceed 20 %, a variance observed in production-like batches when parts are nested with the anchor facing the printhead scan direction. Post-cure UV from both sides reduces this anisotropy but can yellow the transparent window; a top-side dose of 1.8 J/cm² and a bottom-side dose of 1.2 J/cm² is used in trial builds to hold ΔE below 3 for the clear panel. The recommended fixture is a two-piece aluminium clamping frame that holds the flat panel during UV exposure; unsupported panels bow upward by 0.4 mm across a 60 mm span when post-cured at 40 °C, which distorts the display seal shelf. Assemblers then validate the housing by a fall test from 1.0 m onto vinyl tile; cracks initiate at the strap anchor gate if the build orientation places a support-wax plane through the load path. Cleaning validation uses two isopropanol rinses of 30 s each, because longer solvent contact has produced surface microcrazes in unpigmented M2G-CL sections.

    Downstream applicationPrimary acceptance testPrototype pass window
    Snap-fit diagnostic housingASTM D638 / ASTM D256Tensile 35 MPa min, Izod 35 J/m min
    Fluid reservoir seal lipPressure decayNo leak at 80 kPa after 5 cycles
    Automotive undertray clipThermal cycle plus static loadDeformation <0.2 mm at 60 °C
    Optical alignment fixtureISO 10360-2 CMM auditBore position ±0.1 mm

    Optical assembly nests for camera module alignment are printed in M2G-CL as short-run alternatives to machined polycarbonate; the resin’s clarity is adequate for line-of-sight alignment when post-print polishing is limited to the optical datum surface. Surface roughness from the MJP process is in the range 0.5–1.5 µm Ra after support removal; a vapour-polishing step using a fluorinated solvent under extraction is required for high-transmission windows, but the depth of material removal must not exceed 0.05 mm or the lens seating diameter shifts beyond ±0.1 mm. Mounting holes are reamed after UV post-cure because the resin exhibits anisotropic shrinkage along the z-axis, typically 0.5–1.0 %, while in-plane shrinkage is below 0.3 %. Dimensional audits in a 24-part build showed z-axis repeatability of ±0.12 mm on a 2500 Plus platform; the limiting error source was not the print engine but the support-wax oven, where unequal airflow across the tray created a thermal gradient of 4 °C between centre and edge. The fixture is verified with a coordinate measuring machine using a datum scheme based on ISO 10360-2; birefringence and transmitted wavefront error data for this photopolymer are not published, so lens alignment fixtures intended for interferometric setups are rejected unless refractive index verification is performed on a coupon from the same build.

    When Clear Manifold Prototypes Are Substituted for Machined Acrylic in Short-Run Flow Visualization

    Flow visualization manifolds with internal channels require complete removal of wax from a branched network. The support removal sequence uses a low-temperature oven set below the heat deflection limit, followed by ultrasonic bath agitation in mineral oil at 28–32 kHz; a second isopropanol rinse clears the oil film. For channels below 2 mm diameter, published data on complete wax clearance are limited, and validation is not possible without sectioning sacrificial parts. A production-like batch of 12 manifolds showed that the critical failure is channel wall collapse when the oven dwell exceeds 12 h; long dwell at 38 °C allows the green part to creep under its own weight. The UV post-cure then locks in the deformed geometry. A split fixture with steel pins through the bolt holes restrains this distortion, reducing channel roundness error from 0.35 mm to 0.15 mm when measured at the mid-plane. The resin is resistant to water and dilute detergent, but prolonged contact with aggressive hydrocarbon cleaners causes surface crazing; seals should be validated against ASTM D471 at the intended test fluid temperature. For optical flow visualization, the internal surface must be polished to a transparent finish; because line-of-sight clarity normal to the wall is not characterised by a standard, acceptance is based on visual inspection against a 0.5 mm grid target.

    Clear cycling computer mounts and action camera brackets represent a consumer-goods downstream application in which room-temperature impact resistance is the controlling property. Builds are nested with the load-bearing tongue oriented in the X-Y plane because z-axis interlayer adhesion is weaker than the in-plane polymer network. The supplier reports notched Izod impact of 35–50 J/m per ASTM D256 for post-cured parts; a 36-part build of camera brackets on an MJP 2500 Plus platform produced a batch-to-batch impact spread of ±10 % when the post-cure dose was held between 2.0 J/cm² and 3.0 J/cm². At doses above 4 J/cm², the clear polymer yellows sufficiently to affect product appearance; if an overmoulded thermoplastic elastomer strap is used, the bond line requires mechanical adhesion by through-holes because the photopolymer surface does not provide a reliable solvent-weld interface. The bracket is tested for drop impact from 1.5 m on concrete at 0 °C; brittle fracture initiates at the layer interface when the build orientation places the hole axis in the z-direction. This limitation is mitigated by printing the hole axis in the X-Y plane and reaming to final diameter after post-cure. Published data for UV weathering of this grade under ISO 4892-2 are limited; unprotected outdoor use is outside the documented operational boundary.

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    Более подробное введение

    3D Systems VisiJet Armor M2G-CL is a UV-curable acrylic photopolymer qualified for MultiJet Printing workflows and supplied as a low-viscosity resin for room-temperature piezoelectric jetting. The material is cured by UV irradiation during the build and reaches final network conversion only after a separate post-cure cycle. In comparison with rigid clear MJP resins, M2G-CL is formulated as an impact-modified clear grade; the trade-off is a lower modulus and a heat deflection temperature that limits it to moderate-temperature applications. Manufacturer-published typical values include a tensile strength of 48 MPa at break when tested according to ASTM D638, elongation at break of 11%, and a notched Izod impact value of 21 J/m according to ASTM D256. These values are typical and not guaranteed minimums; lot-specific certificates of analysis should be used for production release.

    The acrylate chemistry in M2G-CL contains reactive diluents and oligomers that form a crosslinked network through radical chain-growth polymerization. Because oxygen inhibits radical polymerization at the part surface during ambient UV exposure, the material relies on the post-cure chamber to complete conversion in air; parts with large flat surfaces may retain a thin tacky top layer if the chamber’s inert-gas purging or irradiance is outside specification. Production lots show measurable differences in color and hardness when the post-cure chamber is loaded beyond its validated part density; chamber loading should follow the equipment manual’s printed tray separation distances.

    What Limits the Durability of Clear MJP Resins in Production?

    Durability in this material is controlled less by the jetted geometry than by the completeness of acrylate conversion after post-cure. The radical photopolymerization mechanism produces a three-dimensional network with no melt-processing route. If the post-cure energy is insufficient, residual unreacted diluent acts as an internal plasticizer: the dry-state modulus decreases, solvent uptake increases, and the heat deflection temperature drops. On a ProJet MJP 2500 Plus line, under-cured parts commonly present as opaque white stress marks around screw bosses and inserts before ultimate fracture. Conversely, over-cure can shift the part from clear to amber and warp sections thinner than 1.0 mm. Chamber irradiance should be verified with a calibrated radiometer at the same distance and orientation used for production builds; a deviation greater than 10% from the validated setpoint is sufficient to shift the failure mode in thin-wall snap-fit prototypes.

    Published data for this specific configuration is limited in open literature; the values below are representative manufacturer technical data. Specimen orientation, layer thickness, and post-cure age before testing influence reported results. Production-scale comparisons should be based on builds made at 32 µm layer thickness in the same orientation, conditioned at 23 ± 2 °C and 50 ± 10% RH for 24 h before destructive testing.

    Representative manufacturer-published mechanical and thermal properties for VisiJet Armor M2G-CL
    Property Test method Typical value
    Tensile strength at break ASTM D638 48 MPa
    Tensile modulus ASTM D638 1,850 MPa
    Elongation at break ASTM D638 11%
    Flexural strength ASTM D790 70 MPa
    Flexural modulus ASTM D790 2,000 MPa
    Notched Izod impact ASTM D256 21 J/m
    Heat deflection temperature at 0.45 MPa ASTM D648 64 °C
    Shore D hardness ASTM D2240 83
    Density ASTM D792 1.17 g/cm³

    Thermo-Mechanical Property Profile

    The mechanical response is best described as rigid but not brittle. Tensile stress-strain curves exhibit near-linear behavior at elongations below 3%, followed by non-linear deformation and stress whitening before break at 11%. The tensile modulus is reported near 1,850 MPa, which is lower than typical glass-filled polycarbonate but higher than thermoplastic polyurethane. In flexural loading, the reported flexural strength is 70 MPa at 23 °C. Because the crosslinked network has a glass transition near the reported heat deflection temperature of 64 °C at 0.45 MPa, sustained load at elevated temperature produces creep rather than viscous flow. Components exposed to continuous service above 50 °C should be re-qualified by creep testing under the actual load and temperature, using ASTM D2990 as a reference for creep measurement. Published data for M2G-CL creep compliance is limited.

    Toughness is notch-sensitive. The notched Izod value of 21 J/m reflects energy absorbed by a notched specimen; unnotched impact values may be significantly higher. The tensile modulus of 1,850 MPa places M2G-CL at approximately one-third to one-fourth the stiffness of a 30% glass-filled polycarbonate; designers should compensate with ribs or thicker sections. At 0.45 MPa, the heat deflection temperature is 64 °C; at 1.82 MPa, the value drops and published data for this specific configuration is limited. Because the crosslinked network cannot flow, the material does not have a melt flow index under ISO 1133-1:2022; the standard is inapplicable.

    The principal difference from unfilled rigid clear MJP resins is the balance between impact resistance and stiffness. An unfilled rigid clear grade often exhibits higher flexural modulus and sharper fracture surfaces; M2G-CL yields more deformation before failure in thin sections. Conversely, high-temperature MJP materials retain mechanical properties at temperatures where M2G-CL softens, so substitution is not appropriate for under-hood automotive parts or hot-liquid manifolds. Typical production operations for this material include short-run functional housings, clear fixture covers, non-serialized production aids, and ductile snap-fit prototypes. In fluidic applications, M2G-CL can be used for low-pressure manifolds where visual inspection of flow is beneficial, but continuous pressure above 0.2 MPa in thin-walled channels should be subject to hydrostatic burst testing. The material is not intended for hot-water or steam service.

    If the Application Requires Snap-Fit Deflection Above Five Percent

    For snap-fit arms, the allowable nominal strain should be based on actual tested elongation at the expected temperature and strain rate. The reported elongation at break of 11% does not mean that 5% deflection is automatically safe at corner radii. Sharp internal corners act as stress concentrations; a minimum radius of 0.5 mm is required for sections thicker than 1.0 mm. Thread-forming screws in printed bosses should not exceed a boss outside diameter of the screw major diameter, and the pilot hole should be reamed or chased rather than tapped dry. Production experience on ProJet MJP 2500 Plus systems shows that most snap-fit failures occur at the intersection of the arm base and the side wall, not at the loading point. The failure location is consistent with stress concentration in the jetted layer plane; rotating the build orientation so that the snap arm lies in the X-Y plane can shift the crack initiation zone.

    For translucent visual prototypes, outer walls below 0.6 mm produce measurable light scattering from layer boundaries and support-side roughness. Upward-facing surfaces retain the planarizer finish; downward-facing surfaces require polishing, coating, or orientation changes. Clear overcoats must be tested for adhesion to crosslinked acrylate with ASTM D3359. Ketone-containing lacquers should be avoided because they can micro-craze the surface.

    System-Level Cleaning and Wax Removal Are Process Gates

    Support wax removal before post-cure is a critical process gate. Residual wax on printed channels, snap-fit pockets, or lattice structures absorbs heat and blocks UV access during post-cure, yielding localized soft domains. In ProJet MJP 2500 Plus workflows, support removal typically requires a heated oven or Finisher cycle with subsequent ultrasonic or oil-based cleaning, followed by mild detergent washing. Operations that skip the detergent stage retain a film that interferes with coating adhesion. Green parts should not be stored above 30 °C before support removal because partial wax flow can shift micro-scale features. The cleaning process must be validated for each geometry; closed internal channels narrower than 2.0 mm may retain wax even after standard cycles.

    Layer thickness is set at 32 µm on the ProJet MJP 2500 Plus. The native X-Y resolution is 600 × 600 dpi, corresponding to a nominal droplet pitch near 42 µm. This produces fine feature capability, but feature spacing below 0.3 mm can be bridged by support wax and requires design review. Material changeover from another VisiJet resin to M2G-CL requires purge and verification. Cross-contamination changes viscosity and cure speed, so the first build after changeover should be a standardized test coupon with tensile and optical inspection. If the printer has an idle period greater than 24 h, the printhead should be kept in a manufacturer-specified capping state; prolonged exposure to ambient light at the meniscus can initiate partial polymerization and increase the probability of nozzle dropout.

    Field data from service bureaus running M2G-CL on ProJet MJP 2500 Plus lines indicate three recurring failure patterns. First, nozzle dropout caused by partially cured resin at the idle meniscus; second, localized warpage of tall thin walls after over-cure; third, wax residue in threaded inserts causing low screw pull-out. Each failure mode is controlled by equipment maintenance, post-cure chamber validation, and cleaning verification rather than by modifying the resin formulation.

    Regulatory Status Is Not a Substitute for Application-Specific Testing

    Uncured resin is classified as a chemical product and requires handling according to the current Safety Data Sheet. Skin contact with the liquid resin should be avoided, and nitrile gloves are commonly specified. Cured parts are generally considered non-hazardous for handling, but they are crosslinked thermosets and are not recyclable by melt processing. Disposal must follow local regulations for cured acrylic waste. RoHS and REACH compliance statements should be obtained from the supplier for the applicable lot and region; publication of a generic compliance statement does not cover food-contact or medical-device uses. For medical, dental, or food-contact applications, additional evaluation under ISO 10993 or EU 10/2011 may be required. M2G-CL is not classified as a biocompatible grade unless explicitly stated in the lot-specific documentation.

    Storage conditions recommended by the supplier include a cool, dark environment to minimize thermal polymerization; the resin should not be left in an open vat under ambient UV or sunlight. Shelf life is lot-specific and stated on the product label. Before installation, the printer’s resin tray and feed lines should be inspected for settled pigment or gelled particles, although M2G-CL is unpigmented. If gel bodies are present, filtration according to the printer manufacturer’s procedure is required.

    Chemical exposure limits should be confirmed by immersion testing at the maximum service temperature. The resin is generally not recommended for continuous contact with strong acids, chlorinated solvents, or ketones. Alcohol-based cleaners used for short wiping are typically tolerated but should not be allowed to pool in printed recesses. For applications where dimensional stability under humidity is critical, conditioning at 50 ± 10% RH and 23 ± 2 °C before metrology is required. Published data for this specific configuration is limited, so production release should rely on functional builds and not solely on datasheet values.

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