| Код ТН ВЭД | 367562 |
Как аккредитованный завод Bada BADAMID PA12 CF5 черный PA12, 5% углеродного волокна, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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Under-hood retention clips and quick-connector bodies in automotive fuel-vapour and compressed-air routing are specified in Bada BADAMID PA12 CF5 black where chloride stress cracking, road salt exposure and dimensional drift after humidity cycling are the controlling failure modes. The compound is injection molded only after desiccant drying to ≤ 0.1 wt% residual moisture, measured by ISO 15512 Method B, because moisture above that threshold shifts melt viscosity and produces splay on the part surface. Cylinder temperatures are normally maintained between 230 °C and 260 °C, with the front zone and nozzle held at the upper end of the range to prevent short shots in thin tongue features; the mould temperature is set between 60 °C and 100 °C to control crystallinity and post-mould shrinkage. The 5 wt% carbon fibre phase increases melt viscosity relative to unfilled PA12, so screw recovery speed is reduced to avoid excessive shear heating. A screw with abrasion-resistant screw elements and a compression ratio of 2.0:1 to 2.5:1 is preferred, and the check ring should be a non-return valve made from nitrided steel rather than standard tool steel. Weld lines in fibre-filled PA12 are serious defects: a carbon fibre mat perpendicular to the weld plane produces local strength reductions of 30% to 50% compared with the base matrix, and weld lines at flexural hinges or barb roots are therefore excluded by tooling layout. Creep modulus and stress relaxation under constant clamp load are evaluated using ISO 899-1, while thermal cycling resistance is assessed under ISO 16750-4 thermal cycling profiles, typically with 1,000 cycles from -40 °C to 85 °C at 50 % RH followed by a leak or retention-force check. The low moisture uptake of PA12 relative to PA66 keeps retention force more stable when engine bay dew point changes; however, the carbon fibre filler reduces notched impact strength, so snap-fit deflection is limited to the supplier’s minimum-elongation data rather than values established for unfilled PA12.
Burst pressure in push-to-connect compressed air fittings made from Bada BADAMID PA12 CF5 black is limited by hoop stress in the threaded body, stress relaxation at the collet seat, and dimensional stability after moisture absorption. For 10 mm outside diameter tube systems rated at 16 bar service pressure at 23 °C, fitting bodies are qualified according to ISO 14743:2020, but the numerical burst requirement is not universally fixed; a common acceptance criterion is 4 times the rated pressure, equivalent to 64 bar for a 16 bar system. At elevated temperature, PA12 loses burst pressure retention, and the derating curve must be taken from the fitting manufacturer’s test data, not from unfilled PA12 tube data. The 5 wt% carbon fibre loading improves hoop stiffness and reduces cold flow at the sealing face, but it also lowers weld line strength and can create leakage paths if fibre agglomerates cross the sealing lip. Gate location is therefore placed away from the thread root and collet lip, using a valve-gate hot runner or an edge gate with a wide tab that moves the weld line into the non-functional wall. Barrel temperatures are profiled from 230 °C at the rear zone to 255 °C at the front zone, with nozzle temperature not exceeding 260 °C; prolonged residence above 280 °C oxidises the carbon fibre surface and produces black specks and viscosity loss. The mould temperature is held at 80 °C to 100 °C for maximum crystallinity in the thread and seat areas. Because the processing window is narrow, particularly for thin-wall fitting bodies, shot-to-shot melt temperature drift should be controlled within ±5 °C. Dimensional stability is verified after conditioning at 23 °C and 50 % RH for 40 h per ISO 291 class 2, then the fitting is leak-tested according to the leakage test clauses of ISO 14743:2020 at 10 bar and 16 bar air pressure. The change in sealing diameter due to moisture uptake is smaller than in PA66, but still must be compensated in the collet design when the fitting is used in alternating dry and humid compressed air systems.
| Process control point | Parameter | Value or range | Reference method |
|---|---|---|---|
| Pre-drying | Residual moisture before melt processing | ≤ 0.1 wt% | ISO 15512 Method B |
| Pre-drying | Desiccant dryer air temperature | 80 °C | Dew point ≤ -30 °C |
| Injection moulding | Melt temperature | 230 °C to 260 °C | Pyrometer needle probe |
| Injection moulding | Mould temperature | 60 °C to 100 °C | Thermocouple in tool |
| Post-mould conditioning | Standard atmosphere | 23 °C, 50 % RH, 40 h | ISO 291 class 2 |
In rolling stock and rail infrastructure cable protection conduits, Bada BADAMID PA12 CF5 black is considered where low-temperature impact, abrasion resistance and antistatic surface behaviour are specified on the part drawing. The compounding route uses a co-rotating twin-screw extruder with 25:1 to 40:1 L/D ratio, distributive mixing elements, and vacuum venting to remove residual moisture and fibre sizing volatiles; the product is then pelletised and re-dried before single-screw pipe or conduit extrusion. Extruder barrel temperatures from hopper to die are set from 220 °C to 250 °C, and a screen pack of 80/120/80 mesh is installed before the breaker plate to trap carbon fibre agglomerates that would create pinholes in corrugated wall sections. At 5 wt% carbon fibre, the surface resistivity of a moulded or extruded part typically falls into the dissipative range, but the exact value is strongly affected by surface skin formation and pigment dispersion. Testing is conducted according to IEC 61340-2-3 on as-moulded coupons, not on mechanically polished surfaces, because polishing exposes fibre ends and gives artificially low resistance. A range of 105 Ω to 1011 Ω is generally accepted for static dissipation in industrial enclosures; values below 104 Ω should not be assumed for this 5 wt% carbon fibre loading. Flame retardance for rail interior applications is covered by EN 45545-2 R22/R23, but PA12 itself is not a flame-retardant resin; any claim of conformity must be validated on the actual extruded conduit wall thickness. Low-temperature impact is measured with ISO 179-1/1eU Charpy unnotched specimens at -40 °C, and the carbon fibre filler reduces the ductility reserve compared with unfilled PA12, particularly in wall sections below 1.5 mm. For cable conduits with a wall thickness of 2.0 mm to 3.0 mm, the material is generally processed at line speeds lower than unfilled PA12 to avoid surface tearing at the corrugator mould blocks.
The substitution is considered when tooth deflection, pitch-circle runout or creep under low-speed continuous torque exceeds the limits of unfilled PA12, and when the gear train temperature remains below the continuous-use temperature of the PA12 matrix. In a dry environment at 23 °C, the 5 wt% carbon fibre phase increases the apparent flexural modulus and reduces tooth flank deformation at moderate loads. However, gear tooth load capacity is not a single tensile strength value; it is governed by polymer gear standards such as VDI 2736, which require root stress, flank temperature and wear rate to be evaluated simultaneously. A steel counter-gear with surface hardness above 50 HRC and roughness Rz between 1.0 µm and 3.0 µm is recommended; unhardened aluminium or zinc surfaces are scored by carbon fibre tips and should be avoided unless hard-anodised or replaced with nitrided steel. The dynamic coefficient of friction of PA12 CF5 against hardened steel in boundary-lubricated or dry conditions is lower than unfilled PA12 in the same test rig, but published data for this specific configuration is limited, so prototype testing on a block-on-ring rig per ISO 7148-2 or ASTM G176 is required before design release. Gear blanks are injection molded with a symmetrical 3-point pin gate or diaphragm gate to place weld lines in the web rather than the tooth root; a weld line in the root is not acceptable because it creates a local failure path under repeated bending. Mould temperature is held at 80 °C to 100 °C to raise crystallinity and improve wear resistance, while a lower mould temperature of 40 °C shortens cycle time but increases amorphous skin thickness and tooth shrinkage variation. After moulding, gears are conditioned to equilibrium at 23 °C and 50 % RH per ISO 291 before final inspection, because a dry-as-moulded gear may gain 0.1 % to 0.2 % in diameter after moisture uptake, which shifts backlash and tip-root clearance. In a tooth geometry with module 1.0 mm, a 0.1 % diameter increase corresponds to about 0.05 mm at the pitch circle for a 20 mm pitch diameter gear, enough to alter noise and load distribution. Carbon fibre abrasion requires mould inserts of hardened D2 or powder-metallurgy M390 with local hardness 58 HRC to 60 HRC, especially in gate and runner areas.
Electronics handling trays and pick-and-place nests for hard disk drive assembly use carbon-fibre-filled PA12 where static dissipation, dimensional stability and resistance to cleaning agents are specified together. The 5 wt% carbon fibre loading generally brings surface resistance into the dissipative range, but the actual value is not isotropic: the highly sheared skin near the gate often shows lower resistance than the core, and weld lines show higher resistance. Surface resistance is measured according to IEC 61340-2-3, and volume resistivity according to IEC 62631-3-1; acceptance for dissipative handling trays is usually between 105 Ω and 1011 Ω, but the specific component drawing should govern. The conditioned moisture state of the resin introduces another variable: absorbed water acts as a surface-contaminant layer in high-humidity environments and can increase the apparent surface leakage current, so resistance must be measured after 40 h at 23 °C and 50 % RH per ISO 291, not on dry-as-moulded samples. Dimensional behaviour is assessed with a granite surface plate and feeler gauge on a 250 mm × 180 mm tray; maximum flatness deviation is typically specified below 0.8 mm, but published data for this particular Bada grade is limited and initial tool trials are recommended. Carbon fibre filled PA12 has low moisture uptake compared with PA6, which reduces tray warp when parts move between dry assembly rooms and humid packaging areas; nevertheless, the 5 wt% filler increases residual ash and particulate risk, especially if the tray is abraded by sliding contact. Cleanroom qualification therefore includes surface particle counting per IEST-RP-CC005 and ionic contamination testing, not just bulk resistivity. If the application requires ISO Class 5 or better, a sealed surface coating may be necessary because exposed carbon fibre can shed microfibres under repeated ultrasonic cleaning or alkaline detergent exposure at 60 °C.
| Property | Test condition | Standard | Typical acceptance |
|---|---|---|---|
| Surface resistance | 23 °C, 50 % RH, 100 V | IEC 61340-2-3 | 105 Ω to 1011 Ω |
| Volume resistivity | 23 °C, 50 % RH | IEC 62631-3-1 | ≤ 1010 Ω·m |
| Low-temperature impact | -40 °C | ISO 179-1/1eU | Report value; compare with supplier data sheet minimum |
| Hygroscopic dimensional change | 23 °C, from dry to 50 % RH | ISO 62 | Report value; supplier limit applies |
The conditioned designation does not eliminate the need for pre-drying before melt processing. At 23 °C and 50 % RH, equilibrium water absorption of PA12 is typically between 0.5 wt% and 0.7 wt% as measured by ISO 62; saturation in water at 23 °C can exceed 1.0 wt%. The corresponding linear expansion is less than that of PA6 or PA66, but still dimensionally relevant: a 0.2 % length change on a 100 mm part equals 0.20 mm, which is larger than many precision bearing or gear tolerances. For applications with tight tolerances, parts are therefore dimensioned after conditioning per ISO 291 class 2, or final machining is carried out after moisture equilibrium is reached. Thermal and hygroscopic hysteresis means the part does not return to exactly the same dimension after repeated cycles between 20 % RH and 80 % RH; the reversible component is typically smaller than the initial moisture expansion, but the carbon-fibre-rich surface layer constrains the core and can induce minor bowing in flat parts with one-sided gate orientation. Drying before melt processing is carried out in a desiccant dryer with a dew point of ≤ -30 °C at 80 °C for 4 h to 12 h, depending on initial moisture and granulate bed depth. Temperatures above 90 °C during extended drying risk oxidative yellowing and damage to the carbon fibre sizing, which reduces fibre-matrix adhesion and leads to lower weld strength. If regrind is used, the maximum regrind ratio is normally limited to 20 wt% to 30 wt%, and the regrind must be re-dried and tested for fibre length retention because repeated plastication shortens fibre length and reduces mechanical anisotropy.
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The primary mechanical difference from glass-filled PA12 grades is the lower density of carbon fibre and the resulting mass reduction at equal filler volume. Unfilled PA12 exhibits density near 1.01 g/cm³ per ISO 1183-1; a 5% carbon fibre PA12 grade typically falls in the 1.04–1.06 g/cm³ range, whereas a 15% glass fibre PA12 grade typically falls between 1.12 g/cm³ and 1.16 g/cm³. Carbon fibre also lowers surface resistivity relative to glass fibre, but a 5% loading is generally below the percolation threshold for reliable static-dissipative behaviour in thick moulded sections. The coefficient of linear thermal expansion is reduced relative to unfilled PA12, but the reduction is smaller than that obtained with 10% or 20% carbon fibre compounds. Compared with glass fibre, carbon fibre produces a black appearance and lower abrasive wear on screw, barrel, and mould surfaces, but the compound may be more sensitive to fibre breakage during plastication.
| Property | Test method | BADAMID PA12 CF5 black conditioned | Unfilled PA12 conditioned | PA12 GF15 typical published |
|---|---|---|---|---|
| Density | ISO 1183-1 | 1.04–1.06 g/cm³ | 1.01–1.02 g/cm³ | 1.12–1.16 g/cm³ |
| Tensile modulus | ISO 527-1/-2 | 1700–2100 MPa | 1100–1400 MPa | 2500–3500 MPa |
| Tensile strength at yield | ISO 527-1/-2 | 45–55 MPa | 40–50 MPa | 80–100 MPa |
| Charpy notched impact, 23 °C | ISO 179-1/1eA | 6–10 kJ/m² | 8–12 kJ/m² | 7–10 kJ/m² |
| CLTE normal, 23–55 °C | ISO 11359-2 | 60–90 ×10-6 K-1 | 100–130 ×10-6 K-1 | 40–60 ×10-6 K-1 |
Conditioned mechanical values are generated after moisture equilibration in ISO 291 standard atmosphere and often after accelerated conditioning per ISO 1110. Absorbed water acts as a plasticizer, increasing chain mobility, so tensile modulus and tensile yield stress are lower than dry values, while notched impact and elongation are higher. This matrix response is the expected service condition for components in humid air and is not a defect. For melt processing, the conditioned granules should not be fed directly without drying because residual moisture above 0.1% by mass risks hydrolytic degradation at melt temperatures above 230 °C. A desiccant dryer with air temperature of 80 °C and dew point ≤ -30 °C for 4–6 h is typical for PA12 compounds; the result can be verified by ISO 15512 Karl Fischer titration. Open storage of undried material at relative humidity above 60% for more than 1 h may require re-drying before processing.
Short carbon fibre reinforcement remains effective only if the residual fibre length distribution after plastication is preserved. The PA12 matrix melt temperature is typically 220–250 °C at the nozzle, with melt residence time below 10 min and preferably below 5 min to avoid yellowing and molecular weight loss. Mould temperatures of 40–80 °C are used depending on wall thickness; higher mould temperature improves crystallinity and dimensional stability but increases cycle time. Back pressure should be limited to 0.5–1.0 MPa hydraulic or 5–10 MPa specific melt pressure to avoid excessive fibre attrition. Screw recovery speed should be controlled to a circumferential speed that limits shear heating; on a 25 mm screw, speeds above 100 min⁻¹ may reduce fibre length. Weld lines in complex parts show local mechanical strength reduction because carbon fibres do not bridge weld lines as effectively as unreinforced matrix flow; gate location should therefore place weld lines away from the highest stressed regions.
For incoming resin control, the following checks are customary: melt volume-flow rate per ISO 1133-1 at 235 °C and 5 kg, density per ISO 1183-1, ash content per ISO 3451-1, and residual moisture per ISO 15512. Ash content should correspond to the nominal 5% carbon fibre loading plus any sizing or stabiliser residue, but exact carbon fibre content is better verified by thermogravimetric analysis because glass fibre and mineral fillers would confound the ash result. Batch-to-batch MVR variation above 10% relative to the control batch should trigger review of drying, screw wear, or regrind fraction. Regrind of carbon fibre reinforced PA12 may be introduced at low fractions if the material was dried and not thermally degraded; higher regrind fractions reduce fibre length and notched impact, and 100% regrind is not recommended for load-bearing parts.
In fuel system clips, pneumatic valve bodies, sensor brackets, and cable clamps, the grade is specified when the low water absorption of PA12 is required to maintain dimensions in humid engine bay conditions. PA12 absorbs approximately 1.5% water at saturation per ISO 62, compared with 9.5% for PA6 and 8.5% for PA66, giving BADAMID PA12 CF5 black a narrower property shift between dry and humid conditions. Electrical connector housings may benefit from carbon fibre addition where reduced surface resistivity assists static charge dissipation, but the material cannot be considered a conductive compound unless lot-specific surface resistivity is verified below 10⁹ Ω per ASTM D257 on the final part. For sliding guides and light-duty gears, 5% carbon fibre can reduce mating-surface abrasion relative to glass fibre, but published data for this specific configuration is limited; tribological testing per ISO 7148-2 should be performed before design freeze.
Designers sometimes use PA6 CF5 or PA66 CF5 data as a proxy; this is invalid because PA12 has a lower amide group density, lower saturated water uptake, and different crystallisation behaviour. In fuel line retainers and underbody clips, PA12 grades resist zinc chloride road-salt attack more reliably than PA6; the relevant failure mode is environmental stress cracking, which should be tested per ISO 22088 when the part is under continuous clamp load. However, PA12 has lower tensile strength and lower continuous use temperature than PA66. If the design requires conditioned tensile strength above 60 MPa or continuous service above 100 °C, a PA46, PPA, or higher-temperature polymer should be evaluated. Moving from 5% to 10% carbon fibre increases modulus and dimensional stability but decreases flow length and notched impact; the 5% loading is intended for moderate stiffening without the severe anisotropy and brittleness of 20% carbon fibre compounds.
| Regulatory instrument | Scope | Assessment requirement |
|---|---|---|
| RoHS 2011/65/EU Annex II | Lead, mercury, cadmium, hexavalent chromium, PBB, PBDE in homogeneous materials | Supplier declaration of conformity required per lot or production campaign |
| REACH SVHC Candidate List | Substances of very high concern above 0.1% w/w per article | Lot-specific supplier statement required; no general assumption applies |
| ISO 9001:2015 | Manufacturing quality management | Manufacturer certification status must be confirmed |
Operational boundaries include avoidance of prolonged immersion in strong mineral acids, concentrated formic acid, phenols, and oxidising chlorine solutions. Continuous contact with automotive brake fluid or hydrogen peroxide above 60 °C is not recommended. For UV-exposed external parts, the black carbon-filled surface provides some stabilisation, but outdoor use beyond 5 years may require additional UV stabilisation or coating; accelerated weathering should be verified per ISO 4892-2. Food-contact status is not assigned automatically: FDA 21 CFR 177.1500 may apply to PA12 homopolymer, but carbon fibre and surface sizing require specific compliance confirmation for the finished article.