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Bada BADAMID PA12 GK30 natural PA12, 30% Glass Fiber Reinforced, Conditioned

    • Название продукта: Bada BADAMID PA12 GK30 natural PA12, 30% Glass Fiber Reinforced, Conditioned
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    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Код ТН ВЭД 589350

    Как аккредитованная фабрика Bada BADAMID PA12 GK30 натурального PA12, 30% усиленного стекловолокном, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение Bada BADAMID PA12 GK30 натурального PA12, 30% усиленного стекловолокном, кондиционированного

    In evaporative emissions hardware, Bada BADAMID PA12 GK30 natural is processed into SAE J2044 quick-connect bodies where the 30% glass fibre reinforcement reduces creep under constant locking-finger stress while the conditioned PA12 matrix retains low equilibrium water uptake. The material is pre-dried in a desiccant air dryer at 80 °C for 4–6 h with a -40 °C dew point until Karl Fischer water content is ≤0.10%. Melt temperature is held at 250–270 °C, mould temperature at 80–100 °C, and holding pressure at 60–80 MPa; residence time is limited to 6 min because oxidation above 290 °C degrades the polyamide 12 backbone. Gate location is placed off the locking finger root because glass-fibre orientation at converging flow fronts creates a weld line with tensile strength reduced to 50–60% of the away-from-weld value measured under ISO 527-2. Post-mould conditioning at 23 °C/50% RH for 14 days or accelerated conditioning per ISO 1110 raises absorbed water to 0.4–0.7%, which lowers short-term tensile modulus but improves low-temperature impact strength. The finished quick-connector body is validated under SAE J2044 mechanical release-effort, pull-out and thermal cycling, while fluid compatibility is screened in ASTM Reference Fuel C at 60 °C with tensile retention measured according to ISO 527-2. Dimensional control per ISO 291 atmosphere is necessary because glass fibre orientation produces anisotropic shrinkage in flow and transverse directions of approximately 0.2–0.4% and 0.7–1.0%, respectively; this anisotropy is addressed by gate positioning rather than post-mould machining.

    PropertyTest methodDry as mouldedConditioned at 23 °C/50% RH
    Water contentISO 15512≤0.10%0.4–0.7%
    DensityISO 1183-11.22–1.25 g/cm³1.22–1.25 g/cm³
    Tensile modulusISO 527-26500–7500 MPa5000–6200 MPa
    Tensile strength at breakISO 527-2110–130 MPa80–105 MPa
    Notched Charpy at 23 °CISO 179-1/1eA10–14 kJ/m²15–20 kJ/m²
    Notched Charpy at -30 °CISO 179-1/1eA8–11 kJ/m²9–13 kJ/m²

    The conditioned state is not a sign of water damage but a controlled plasticisation of the PA12 matrix. Glass fibre reduces total water absorption relative to unfilled PA12 because the fibre fraction is non-sorbing, yet interfacial wicking along fibre bundles can delay equilibrium and produce localised water distribution that affects dielectric and impact behaviour in thick sections. Conditioned notched Charpy values at 23 °C commonly exceed dry values by 20–40% because absorbed water lowers the glass transition of the amorphous phase; conversely, tensile modulus falls by 10–20%. This trade-off is accepted in quick connectors where snap-fit assembly demands ductility after field ageing.

    What Limits Burst Pressure Retention in Pneumatic Manifold Blocks at 60 °C?

    At continuous air temperatures of 60 °C, the limiting condition in pneumatic manifolds is not short-term burst but creep-induced thread deformation under repeated assembly torque. The 30% glass fibre loading provides modulus retention under ISO 228-1 parallel thread tightening torque, while the low water absorption of PA12 prevents swelling-induced dimensional change in humid compressed air. Processing uses a melt temperature of 250–270 °C and mould temperature of 90–100 °C; moulded-in brass threaded inserts are preheated to 120 °C to reduce local glass-fibre freeze-off. Threaded port geometry is designed with a minimum wall thickness of 4 mm at the root and no knit line within 2 mm of the sealing face. Pressure validation is performed at 16 bar for a 10 bar rated manifold, with a hydrostatic proof factor of 1.6:1 and burst factor of 3:1; creep rupture is evaluated under ISO 1167 at 60 °C for 1000 h. Conditioned material is preferred because dry-as-moulded PA12 GF30 can exhibit brittle failure at sharp thread roots when stressed at low temperatures; conditioning to 0.4–0.7% water increases local ductility. The terminal part is a multi-port manifold block, often machined from an injection-moulded blank only where the blank cannot meet flatness across 150 mm within 0.2 mm after moisture equilibrium.

    Outdoor low-voltage junction enclosures use the natural 30% glass-fibre grade for cable gland backshells and adaptor bodies where EN 62444:2013 strain relief and impact tests are combined with long-term weathering. The unpigmented natural formulation is selected not for appearance but because it avoids carbon-black particle dispersion that can create micro-voids at fibre-matrix interfaces in prolonged outdoor temperature cycling. Drying at 80 °C for 5 h to ≤0.08% water, melt temperature 250–260 °C, and mould temperature 80 °C are used to limit surface silver streaking along fibre bundles. Backshell threads are injection-moulded and tested for pull-out on cable gland claws per EN 62444:2013; no sharp edges may appear after mechanical impact at 5 J. Because the grade is electrically insulating, where the enclosure is in an explosive atmosphere the natural GF30 must be combined with an external static dissipation path or an antistatic additive; the natural grade itself has no controlled surface resistivity. UV stability of unpigmented glass-filled PA12 is lower than carbon-black-stabilised compounds; outdoor components typically require UV stabiliser validation under ISO 4892-2. The terminal product is the strain-relief backshell, cable gland body and adaptor, with final dimensions measured after 48 h conditioning at 23 °C/50% RH.

    Torque Creep and Flange Flatness in Pump Wear Plates

    For centrifugal pump wear plates produced from the conditioned GF30 grade, bolt-clamp retention across the machined face after water absorption is the controlling requirement. The 30% glass fibre concentration reduces creep under bolted joint compression to a range that permits 20 N·m M8 bolt torque without indentation at 80 °C in water. Pre-drying is set at 80 °C for 6 h; melt temperature is held at 260–280 °C and mould temperature at 90–100 °C for minimal crystallinity gradients. Injection moulding uses a centrally located fan gate to orient fibre radially and reduce flange warpage; still, unsupported flange diameters above 150 mm may show 0.3–0.5 mm flatness deviation after conditioning. When flatness falls outside ISO 1101 tolerance bands, face machining is applied to the blank before water contact. The material is tested for water absorption per ISO 62 at 80 °C water for 500 h; mass increase is below that of unfilled PA12 because glass fibre is non-sorbing. Tensile strength retention after water immersion is usually lower than dry as moulded, but notched Charpy impact increases. The wear plate must also tolerate erosion from abrasive particles; glass fibre reinforces the matrix but can increase wear of the mating stainless steel impeller shroud at high solid loadings, so the application is limited to clarified or lightly loaded pumpage. The terminal part is a replaceable wear plate, dimensionally stable enough to maintain the 0.3–0.5 mm clearance between impeller and casing.

    When Glass Fibre Orientation Reverses Weld-Line Properties in Conveyor Guide Rails

    Across injection-moulded conveyor guide rails, weld lines represent a source of property reversal: a guide rail that meets flexural strength requirements in a straight section can fail at a knit line where fibre orientation is perpendicular to load. BADAMID PA12 GK30 natural is used for industrial conveyor guide rails and chain wear strips because the 30% fibre loading increases compressive strength and reduces thermal expansion relative to unfilled PA12. The injection moulding process requires a melt temperature of 260–270 °C, mould temperature of 85–95 °C, and fast injection speed to minimise weld-line depth; sequential valve gating is preferred when rail length exceeds 300 mm. Weld-line tensile strength under ISO 527-2 is typically 50–60% of the non-weld value; this is acceptable only if the weld is repositioned to a neutral axis or low tensile stress zone. Dry-blending surface lubricants is not recommended because glass-fibre wear of mating UHMWPE chain guides can be accelerated under load; wear testing under ASTM D4060 with a CS-17 wheel at 1 kg is used to establish acceptable sliding performance. Moisture conditioning to 0.4–0.7% water improves edge chipping resistance during assembly and reduces brittle fracture when guide rails are cut from injection-moulded blanks. Natural colour is used where laser-marked position lines are required; however, the absence of carbon black means static surface charge can build on dry conveyors, so grounding and antistatic additives must be evaluated. The terminal part is a segmented guide rail, injection-moulded in straight modules and mechanically joined to allow replacement of worn sections without replacing the full rail.

    Hydraulic Return-Line Filter Housings: Pressure Cycling, Drying, and Micro-Void Formation

    Return-line filter housings for hydraulic power units must tolerate cyclic pressure without fatigue crazing of the PA12 matrix. The 30% glass fibre reinforcement increases hoop modulus and reduces creep under mineral oil at 80 °C, but the moulding process must suppress glass-fibre micro-void formation at the base of threaded ports. Melt temperature is kept at 255–275 °C; screw speed is kept below 120 min⁻¹ and backpressure at 5–10 bar to avoid fibre breakage and gas entrapment. The mould is heated to 95–100 °C and the filling pattern is designed so that no glass-fibre weld line crosses the port sealing boss. Pre-drying to ≤0.10% water at 80 °C is mandatory because hidden moisture turns to steam in the melt and expands into micro-voids at fibre ends, which later nucleate fatigue cracks. The housing is pressure-cycled between 0 bar and 1.5 times nominal return-line pressure for 250,000 cycles per ISO 10771-1; material ageing is checked in ISO 11158 mineral oil at 80 °C for 1000 h. The conditioned material shows better fatigue crack resistance than dry moulded parts due to plasticisation of the PA12 amorphous phase. The terminal part is a return-line filter bowl and head assembly, injection-moulded in natural GF30 and machined only at the sealing thread to avoid ovality after moisture equilibrium.

    Validation itemTest methodConditionTypical acceptance band
    Fatigue pressure cyclingISO 10771-10–1.5 nominal pressure250,000 cycles without leakage
    Mineral oil ageingISO 188120 °C, 1000 hTensile retention ≥75%
    Oil compatibilityISO 527-2 after ISO 11158 immersion80 °C, 1000 hTensile retention ≥80%
    Notched Charpy after conditioningISO 179-1/1eA23 °C/50% RH≥12 kJ/m²

    Micro-void control in the filter housing is monitored by sectioning the port boss after moulding and examining fibre-end voiding under 20× optical inspection. A validated process window uses melt cushion 3–5 mm, decompression 2–3 mm, and holding time 8–10 s per mm of nominal wall. These settings prevent trapped gas from remaining in the glass-fibre bed and reduce the scatter in pressure-cycle life that otherwise occurs in dry moulded parts.

    During early spring planting, seed metering housing shells in row-crop planters are subjected to condensation and dust-laden airflow; the conditioned 30% glass fibre grade addresses the associated dimensional movement while maintaining low-temperature toughness. The housing is moulded with a melt temperature of 250–270 °C and mould temperature of 80–100 °C; wall stock is kept between 2.5 mm and 4 mm to avoid sink marks at bosses. Glass-fibre orientation is managed by a central gate and radial flow so that the seed disc carrier flange remains flat within 0.15 mm across 100 mm after conditioning. Impact strength is verified by ISO 179-1/1eA at -20 °C after 14 days at 23 °C/50% RH; values are higher than dry as moulded because moisture reduces notch sensitivity. Wear of the seed disc slot edges is influenced by the abrasive action of talc seed coatings; glass fibre improves slot edge retention but may accelerate wear of mating plastic discs if the fibre orientation is perpendicular to the sliding direction. The terminal part is the seed meter housing shell and disc carrier, assembled with mechanical fasteners rather than solvent bonding because PA12 has limited solvent-bonding agent compatibility at production line speeds.

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    Bada BADAMID PA12 GK30 natural is a 30% by weight short-glass-fibre reinforced polyamide 12 compound supplied in the conditioned state. The polymer matrix is produced by ring-opening polymerisation of laurolactam, yielding a semi-crystalline aliphatic polyamide with a peak melting temperature near 176°C and a dry-state glass transition temperature near 45–55°C. The glass reinforcement consists of chopped strands with a nominal pre-compounding length of 3–4 mm; after twin-screw extrusion the number-average fibre length typically falls to 200–300 µm. The fibre surface carries an aminosilane sizing to promote adhesion to the amide matrix. The natural designation indicates the absence of carbon black or organic dye, yielding an opaque, natural off-white appearance. The conditioned designation refers to test specimens equilibrated at 23°C and 50% RH according to ISO 291, or accelerated per ISO 1110; it does not imply that resin pellets should be processed with residual moisture. Within the BADAMID PA12 portfolio, the GK30 designation separates this compound from unreinforced BADAMID PA12 natural and from lower glass-fibre grades such as GK15 or GK20. The numeral 30 refers to the nominal glass content in weight percent; actual ash content may vary within the specification tolerance.

    Why does moisture conditioning alter the load-bearing behaviour of PA12 GF30?

    Moisture absorption in thin sections of PA12 follows Fickian diffusion; the rate increases with temperature and section thickness. In a 30% glass-filled compound, water is absorbed almost exclusively by the amorphous polyamide phase. The total equilibrium moisture mass fraction at 23°C and 50% RH is typically 0.5–0.8%, but the concentration in the matrix is higher because the glass occupies about 30% of the volume and absorbs no water. Absorbed water disrupts hydrogen bonding between amide groups, lowers the glass transition temperature, and increases segmental mobility. Conditioned tensile modulus therefore falls 15–20% compared with dry-as-moulded values, while notched Charpy impact strength at 23°C increases by 25–50%. Flexural strength, hardness and creep resistance decrease correspondingly. For snap-fit and clip designs, using dry values can overestimate insertion force and under-predict allowable deflection after field equilibration. For structural brackets, conditioned tensile values must be used for stress analysis at 50% RH.

    Representative conditioned properties for Bada BADAMID PA12 GK30 natural are listed in Table 1. The values are compiled from published Bada technical data and are typical rather than guaranteed specifications; batch-to-batch variation in glass length distribution and moisture content can shift mechanical values by ±10%. Test specimens are injection-moulded multipurpose bars according to ISO 3167 and tested after conditioning in the standard atmosphere.

    PropertyTest standardConditioned valueUnit
    DensityISO 1183-1:20191.24g/cm³
    Tensile modulusISO 527-1/-2:20195,000MPa
    Tensile stress at breakISO 527-1/-2:201985MPa
    Elongation at breakISO 527-1/-2:20194.0%
    Flexural modulusISO 178:20194,800MPa
    Flexural strengthISO 178:2019120MPa
    Charpy notched impact strength, 23°CISO 179-1/1eA:201014kJ/m²
    Charpy notched impact strength, -30°CISO 179-1/1eA:20109kJ/m²
    Heat deflection temperature HDT/A 1.8 MPaISO 75-2/A:2020165°C
    Coefficient of linear thermal expansion, parallelISO 11359-2:20210.3010⁻⁴/K
    Water absorption, saturation in water 23°CISO 62:20081.5–2.0%
    Mould shrinkage, parallel flowISO 294-4:20180.2–0.4%

    Tensile modulus of 5,000 MPa places the grade in the semi-structural range for polyamides, well above unreinforced PA12 and sufficiently high for dimensionally stable brackets and housings. Elongation at break of 4.0% indicates a stiff low-ductility tensile failure mode; notches, sharp corners and gate vestiges should be minimised. The Charpy notched impact value of 14 kJ/m² at 23°C supports snap-fit clips, but safety-critical impact parts require component-level validation. HDT/A of 165°C is a short-term deflection property under 1.8 MPa flexural stress and is not equivalent to continuous use temperature under load. For electrical and electronic enclosures, the natural grade typically shows volume resistivity in the 10¹²–10¹³ Ω·cm range at 23°C measured by IEC 62631-3-1, and surface resistivity commonly 10¹¹–10¹² Ω under IEC 62631-3-2. Comparative tracking index according to IEC 60112 is often 600 V or higher for dry conditioned PA12 grades, but moisture uptake can reduce tracking resistance in humid service; users should verify CTI on production-moulded plaques.

    Rheological limits and fibre-attrition mechanisms during melt processing

    Before melt processing, pellets must be dried to 0.15% maximum moisture by mass. Although the grade is supplied conditioned for testing, processing moisture must be removed. Residual moisture above 0.20% hydrolyses the PA12 backbone during plastication, reducing viscosity, creating surface splay, and lowering notched impact strength by 10–20%. Hot-air drying at 80°C for 4–8 h with a dew point of -30°C is standard; vacuum drying at 80°C for 2–4 h is suitable for small lots. If ambient relative humidity exceeds 60%, desiccant drying is preferred. Dew-point monitoring below -20°C is critical; higher dew points extend drying time and may prevent reaching the target moisture level.

    Melt temperature should be held between 230°C and 260°C. The lower bound avoids excessive screw torque and fibre fracture, while the upper bound improves thin-wall filling but accelerates thermo-oxidative chain scission. Mold temperature should be set at 60–80°C to achieve adequate crystallinity and dimensional reproducibility. At 80°C, cycle time increases but post-mould shrinkage is lower. Below 50°C, parts may freeze with low crystallinity, leading to dimensional growth after annealing or hot service.

    Processing parameterTypical rangeUnit
    Drying temperature80°C
    Drying time, hot-air desiccant4–8h
    Maximum residual moisture0.15%
    Melt temperature230–260°C
    Mold temperature60–80°C
    Injection pressure60–100MPa
    Hold pressure40–60MPa
    Screw speed50–120min⁻¹
    Back pressure0.5–1.5MPa
    Maximum residence time at melt temperature10min

    The settings in Table 2 assume a 40 mm reciprocating-screw injection moulding machine with a 20:1 L/D general-purpose nylon screw and a shut-off nozzle. Screw speeds above 120 min⁻¹ increase viscous heating and fibre attrition; a 10–15°C melt overshoot is possible at high shear rates. Back pressure above 1.5 MPa improves melt homogeneity but shortens glass fibres. Glass-fibre attrition during plastication reduces number-average fibre length from roughly 250 µm to 150–200 µm depending on screw geometry; the resulting tensile modulus loss is minor, but notched impact may fall by 5–10%. Weld-line tensile strength is commonly 40–60% lower than bulk flow-direction strength; gate locations should therefore move weld lines out of high-tensile regions. Hot-runner processing is possible if manifold residence time remains below 10 min. Glass fibre is abrasive; gate inserts, screw tips and check rings should be hardened or coated to reduce wear. Regrind from sprues and runners can be reused at 20–30% by weight with virgin material, but impact strength decreases with repeated processing because of cumulative fibre-length reduction. Quality assurance on incoming lots typically includes melt volume-flow rate per ISO 1133-1, residual moisture per ISO 15512, and ash content per ISO 3451-1 to confirm glass content.

    When the specification prioritises dimensional stability and chemical resistance over ultimate tensile strength

    Compared with a 30% glass-fibre reinforced PA66, Bada BADAMID PA12 GK30 natural offers density near 1.24 g/cm³, roughly 10% below the 1.37 g/cm³ typical for PA66 GF30. Saturated water uptake is approximately 1.5–2.0% by mass, compared with 5–6% for PA66 GF30 at 23°C in water. Lower moisture uptake reduces dimensional change under humidity cycling, retains more of the dry impact toughness, and improves dielectric stability in humid environments. PA12 also offers better resistance to zinc chloride stress cracking, saline exposure, oils and many aliphatic hydrocarbons. The main sacrifice is tensile strength: PA66 GF30 dry tensile values often reach 180 MPa, whereas conditioned PA12 GF30 values are 80–90 MPa. When ultimate strength at temperatures above 100°C controls the design, PA66 GF30 is usually stronger. When the governing requirement is dimensional stability under wet-dry cycling, low-temperature impact, or salt-spray resistance, PA12 GF30 is likely to show fewer field failures.

    Against unreinforced BADAMID PA12 natural, the GK30 grade raises tensile modulus from approximately 1,500 MPa to 5,000 MPa and HDT/A from about 55°C to 165°C. Parallel CLTE falls from about 1.2 × 10⁻⁴ K⁻¹ to 0.30 × 10⁻⁴ K⁻¹, reducing expansion mismatch with steel and aluminium. However, glass fibre introduces anisotropy: transverse CLTE is typically 0.8–1.0 × 10⁻⁴ K⁻¹, and differential parallel/transverse shrinkage can produce warpage in flat or long parts. Filling simulation should be used to position gates so that fibre orientation and shrinkage gradients are balanced. Compared with a 20% glass-filled PA12 grade, the 30% loading increases stiffness and HDT but reduces notched impact and surface smoothness. Compared with a 40% glass-filled grade, the 30% loading reduces tool wear and surface fibre stubbing while sacrificing some modulus and heat resistance.

    Thermo-oxidative ageing limits are not identical to short-term HDT

    Continuous loaded service above 120°C may reduce tensile strength and elongation through thermo-oxidative ageing, even though HDT/A is 165°C. Long-term heat-ageing data according to ISO 2578 should be reviewed before specifying the material for hot-air or underhood environments. Direct contact with strong acids, phenol, or formic acid attacks polyamide and should be avoided. The natural grade is not UV-stabilised; outdoor exposure without a UV absorber package may cause surface chalking and loss of mechanical retention. The compound is not inherently flame-retarded. If a flammability class is required under IEC 60695-11-10, a flame-retardant PA12 grade or additional evaluation is required.

    Bada BADAMID PA12 GK30 natural is used in production-scale injection-moulded parts such as pneumatic conveyor brackets, cable clips, conveyor wear strips, fuel-line connectors, sensor housings and outdoor electrical enclosures. These applications exploit conditioned impact toughness, lower moisture expansion than PA6/PA66 glass-filled grades, and lower density than PA66 GF30. For an unpressurised outdoor enclosure exposed to 80°C and 60% RH, PA12 GF30 is typically preferred over PA6 GF30 when dimensional gaps must remain stable across wet-dry seasonal cycles. Acceptance testing commonly includes ISO 527-1/-2 tensile tests, ISO 179-1/1eA notched Charpy impact at 23°C and -30°C, and ISO 75-2/A HDT. Chemical exposure should be evaluated per ISO 175 or ISO 1817 with the actual service fluids. Published data for fuel compatibility specific to this natural conditioned configuration is limited; application-specific validation with production-moulded parts is required before release. Regulatory compliance must be confirmed with the supplier against REACH SVHC and RoHS Directive 2011/65/EU Annex II; no declaration in this document replaces supplier certification.

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