| Код ТН ВЭД | 705479 |
| Polymer Type | Metallocene Linear Low Density Polyethylene (mLLDPE) |
| Density | 0.915 g/cm3 |
| Melt Index | 1.0 g/10 min |
| Melt Flow Ratio | 16 |
| Tensile Strength At Yield Md | 1200 psi |
| Tensile Strength At Yield Td | 1100 psi |
| Tensile Strength At Break Md | 4500 psi |
| Tensile Strength At Break Td | 4000 psi |
| Elongation At Break Md | 500% |
| Elongation At Break Td | 600% |
| Dart Drop Impact | 300 g |
| Elmendorf Tear Strength Md | 200 g |
| Elmendorf Tear Strength Td | 300 g |
| Haze | 7% |
| Gloss 45 | 75% |
| Vicat Softening Point | 95 °C |
| Melting Point | 120 °C |
Как аккредитованный завод Bamberger Polymers Bapolene mLLDPE 615FP, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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Blown film converters running vertical form-fill-seal (VFFS) lines for frozen vegetable and IQF seafood packaging compound Bamberger Polymers Bapolene mLLDPE 615FP at 70–90 wt% with 10–30 wt% of a high-pressure LDPE having a melt index of 0.25–0.5 g/10 min. Supplier datasheet values for the 615FP grade typically cite a melt index of 1.0 g/10 min per ISO 1133-1:2022 and a density of 0.916 g/cm³. The sealant layer is processed on a coextruded three-layer line with a 30:1 L/D single-screw extruder, 1.8 mm die gap, blow-up ratio 2.2:1–3.0:1, and frost line height maintained at 4–6 die diameters. Compliance for direct food contact in the United States is governed by FDA 21 CFR 177.1520, and for the European Union by EU Regulation 10/2011 with an overall migration limit of 10 mg/dm². Terminal product types produced under these conditions include frozen vegetable bags, individually quick-frozen seafood pouches, and ice cream pouches requiring hot-tack strength above 2.0 N/25 mm at 110 °C when tested by ASTM F1921. Low-temperature dart impact at -20 °C is assessed by ASTM D1709 Method A, and failures typically occur at the seal transition zone rather than in the film body.
A production-scale bottleneck appears when the 615FP addition exceeds 80 wt% and the LDPE let-down falls below 15 wt%: melt fracture initiates at the die lip, producing longitudinal shark-skin defects on the sealant surface. Operators respond by raising the lower die lip temperature to 180–190 °C and increasing the frost line height to 5–6 die diameters, which reduces shear stress at the die exit. Specific output is limited to 0.8 kg/h/die-mm on a 300 mm die; exceeding this threshold without increasing the LDPE fraction causes thickness variation greater than ±5%. Pre-drying is not routinely required unless a hygroscopic slip or antiblock masterbatch is incorporated at levels above 3 wt% and ambient relative humidity exceeds 60%.
Heavy-duty sack lines targeting 50 kg load-bearing industrial packaging blend Bapolene mLLDPE 615FP at 30–60 wt% with a bimodal HDPE or a fractional-melt LDPE to improve tear propagation resistance and dart impact over monolayer HDPE. The governing test standards are ASTM D1709 for dart impact, ASTM D1922 for Elmendorf tear, and ISO 527-3 for tensile properties of films. Compliance with transport packaging requirements for non-hazardous goods can be verified using ISO 21898:2004, while dangerous goods packaging may require UN certification tests. On a high-stalk blown film line with 2.0 mm die gap, 3.0:1–4.0:1 blow-up ratio, and stalk height of 8–10 die diameters, the blend is processed at melt temperatures of 190–210 °C. Terminal products include FIBC liners, fertilizer sacks, mineral bulk bags, and polymer resin shipment sacks.
A process conflict arises when 615FP content exceeds 60 wt%: the lower melt viscosity of mLLDPE relative to bimodal HDPE destabilizes the bubble, leading to oscillation in frost line position and film thickness variation exceeding ±5%. To mitigate, converters raise screw speed to maintain 0.6–0.9 kg/h/die-mm specific output and reduce die lip temperature by 5–10 °C. Bubble stability failure is most pronounced on lines with die diameters below 250 mm, where the dimensionless process time is insufficient for stress relaxation; larger dies of 350–400 mm permit higher 615FP loadings without flutter. The incompatibility with unmodified high-density polyethylene at ratios above 60 wt% in the same melt stream arises from a viscosity mismatch of more than 500 Pa·s at 190 °C and 100 s⁻¹, causing interfacial instability and pinhole formation at the melt web.
Pinhole formation in filled sacks during drop tests correlates with low TD tear strength. Converter production logs show that replacing 30 wt% HDPE with 615FP raises Elmendorf tear TD by 20–40% without sacrificing stackability, because the resin’s narrow comonomer distribution reduces crystalline tie-molecule defects. Table 1 reports blend-gradient ranges from production trials at 100 µm gauge and 3.0:1 BUR.
| 615FP addition (wt%) | Dart impact (ASTM D1709, g) | Elmendorf tear MD (ASTM D1922, g) | Elmendorf tear TD (ASTM D1922, g) |
|---|---|---|---|
| 0 | 120–180 | 150–200 | 150–220 |
| 30 | 180–250 | 200–280 | 180–260 |
| 50 | 250–320 | 250–350 | 220–320 |
| 70 | 300–380 | 300–420 | 250–380 |
On cast film lines dedicated to pallet unitization, addition of 20–40 wt% Bapolene mLLDPE 615FP to a Ziegler-Natta LLDPE base resin (melt index 2.0–3.5 g/10 min) modifies neck-in and final cling force. The process is a single-screw cast film extrusion line with a 150 mm chill roll, vacuum box, and line speeds of 300–600 m/min. Compliance with cling and puncture performance is verified by ASTM D5458-12 (cling stretch wrap) and ASTM D5748-95 (puncture resistance). At 30 wt% 615FP, pre-stretch ratios of 200–250% are attainable without film break on high-speed turntable wrappers, but exceeding 40 wt% reduces melt drawability and increases edge trim waste because the lower molecular weight distribution of mLLDPE accelerates neck-in at the die lip. Terminal product types include machine stretch film, hand stretch film, and pre-stretched film supplied on 3-inch cores.
A line limitation is that cast film lines without a vacuum edge pinning system show increased gauge variation above 500 m/min, typically exceeding ±2.5% thickness deviation. The neck-in reduction at 20–40 wt% addition is measurable as a decrease in final film width from 635 mm to 610 mm at 450 m/min, which converters compensate for by increasing die width or adjusting the vacuum box position. Cling force measured by ASTM D5458-12 typically rises with 615FP content up to 30 wt% due to lower crystallinity, then plateaus; further addition beyond 40 wt% creates excessive unwind noise and film blocking at storage temperatures above 35 °C.
Agricultural silage covers and bale wrap manufactured with Bapolene mLLDPE 615FP at 60–100 wt% rely on the resin’s low-temperature puncture resistance and controlled oxygen transmission. Compliance for agricultural thermoplastic films in the European market falls under EN 13206:2017, while tensile properties are verified by ISO 527-3 and puncture resistance by ASTM D5748-95. A common formulation adds 5–8 wt% of a UV-stabilized masterbatch, which raises film opacity and requires pre-drying when the masterbatch is hygroscopic and ambient relative humidity exceeds 60%. The downstream process is blown film extrusion with a 2.2 mm die gap, blow-up ratio 2.5:1–3.5:1, and melt temperature 180–200 °C. Terminal products include silage covers, silage stretch film, and greenhouse films.
A processing boundary appears when 615FP content falls below 60 wt%: the oxygen transmission rate rises above 2,500 cm³/m²/day·atm at 25 µm thickness, reducing silage fermentation quality. Published data for this specific UV-stabilized configuration is limited to supplier technical bulletins rather than peer-reviewed sources. Amine-based stabilizers are avoided in silage formulations because they can react with acidic fermentation volatiles, accelerating oxidative degradation at the film surface. On production-scale lines, the primary failure mode is puncture at the bale wrap overlap during high-pressure round baling; films with dart impact below 150 g by ASTM D1709 are generally considered unsuitable for dense-silage baling systems.
Coextruded sealant webs for stand-up pouches and lidding films frequently employ Bapolene mLLDPE 615FP as the heat-seal layer at 20–30 wt% of the total multilayer structure, or 80–100% of the sealant layer itself. The governing food-contact standards are FDA 21 CFR 177.1520 and EU Regulation 10/2011, with specific migration limits for antioxidants and processing aids. The downstream process is three-layer coextrusion with a laminating adhesive tie layer, followed by solventless lamination to polyester or oriented polyamide. Seal initiation temperature for the 615FP sealant layer ranges from 85–95 °C, allowing hermetic seal formation at dwell times of 0.5–1.0 s on rotary pouch machines. Terminal product types include stand-up pouches, lidding films, and liquid pouch sealant webs.
A limitation is that seal strength measured by ASTM F88 typically plateaus at 12–15 N/25 mm, and further dwell-time increases do not improve hermeticity because the seal failure mode shifts to delamination at the adhesive tie layer. On production-scale pouch lines, excessive seal bar temperature above 120 °C causes the 615FP layer to flow out of the seal area, reducing seal width below 1.0 mm and creating leakers. The resin is incompatible with high-viscosity HDPE in the same sealant layer at ratios above 60 wt% due to melt fracture at the die exit.
Collation shrink film lines process Bapolene mLLDPE 615FP at 50–100 wt% to achieve controlled transverse direction (TD) shrinkage for bottle multipacks and can overwrap. Compliance with shrink force measurement is specified in ISO 14616:1997, while free-shrink characteristics are tested by ASTM D2732. The film is produced on a high-stalk blown film line with a 1.6 mm die gap and blow-up ratio 3.0:1–4.5:1, followed by orientation through a heated shrink frame. At 100% 615FP, TD free shrink reaches 60–70% at 120 °C, but published data for this specific resin in high-stalk orientation is limited; converter production logs indicate that adding 20–30 wt% LDPE reduces TD shrink to 45–55% while improving bubble stability. Terminal products include six-pack bottle collation film, can shrink wrap, and industrial overwrap.
The critical processing parameter is the stalk temperature profile: if the stalk cools below 100 °C before orientation, frozen-in stress causes gauge variation and uneven shrink force, creating loose bottle multipacks. On a 400 mm die, the maximum specific output is approximately 0.7 kg/h/die-mm before bubble flutter occurs. Shrink force measured by ISO 14616:1997 for 50 µm film typically ranges from 2.0–3.5 N/15 mm in the TD, sufficient to hold 6×0.5 L PET bottle multipacks without distortion of the bottle labels.
Table 2 summarizes primary compliance anchors and acceptance thresholds commonly referenced across these downstream application segments. Thresholds vary by end-user specification and package configuration.
| Application segment | Primary standard | Test method | Typical acceptance threshold |
|---|---|---|---|
| Frozen food VFFS | FDA 21 CFR 177.1520 | ASTM F1921 | Hot-tack > 2.0 N/25 mm at 110 °C |
| Heavy-duty sack | ISO 21898:2004 | ASTM D1709 | Dart impact > 250 g |
| Pallet stretch | ASTM D5458-12 | ASTM D5748-95 | Puncture resistance > 3.5 J |
| Silage film | EN 13206:2017 | ISO 527-3 | Tensile strength > 25 MPa MD |
| Collation shrink | ISO 14616:1997 | ASTM D2732 | TD free shrink 60–70% at 120 °C |
| Bag-in-box | FDA 21 CFR 175.300 | ASTM F392 | Flex-crack > 500 cycles at -20 °C |
Bag-in-box liners for wine, dairy, and syrup transport employ Bapolene mLLDPE 615FP at 80–100 wt% to resist flex-crack generation during distribution. Compliance for liquid food contact in the United States falls under FDA 21 CFR 175.300 for resinous and polymeric coatings, and EU Regulation 10/2011 in Europe. The downstream process is a monolayer blown film extrusion line with 2.0 mm die gap, blow-up ratio 2.0:1–3.0:1, and melt temperature 180–200 °C. Flex-crack resistance is quantified by ASTM F392, with acceptable liners surviving 500–1,000 flex cycles without leakage when tested at -20 °C. Terminal products include bag-in-box liners for wine, dairy syrups, and institutional liquid concentrates.
The primary limitation is oxygen permeability: at 50 µm thickness, the oxygen transmission rate is approximately 1,500–2,000 cm³/m²/day·atm, making the resin suitable only for ambient or refrigerated liquid transport with short shelf life, not for oxygen-sensitive products without additional barrier layers. Pre-drying is required at relative humidity above 60% if a calcium carbonate or slip masterbatch exceeds 3 wt%. On production lines, fold lines at the bag corner exhibit stress whitening after 1,500 flex cycles, but this does not necessarily correlate with leakage unless the film gauge falls below 40 µm.
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