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Barlog Plastics KEBABLEND M 48/67 PA12 for Plastic Bonded Magnets

    • Название продукта: Barlog Plastics KEBABLEND M 48/67 PA12 for Plastic Bonded Magnets
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
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    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Код ТН ВЭД 291082

    Как аккредитованный завод Barlog Plastics KEBABLEND M 48/67 PA12 для пластиковых магнитов, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение пластиков Barlog KEBABLEND M 48/67 PA12 для пластиковых магнитов

    In antilock braking and stability-control encoder rings, the PA12-bonded ferrite compound is processed as supplied rather than blended with unfilled PA12, because dilution of the magnetizable fraction below the manufacturer’s specified volume loading shifts remanence and coercivity outside the sensor ASIC detection window. Compliance records for this application are aligned to IATF 16949:2016 supplier quality clauses, RoHS Directive 2011/65/EU Annex II, and REACH Regulation (EC) No 1907/2006; material marking follows ISO 11469:2016. The formulation addition ratio is fixed at 100% virgin compound for safety-relevant wheel-speed encoder rings, with regrind from cold-runner and sprue limited to 10 wt% in non-safety validation lots only after secondary drying at 80°C for 6 h to a moisture content below 0.1%. The downstream production route is multi-cavity injection molding in hardened, wear-protected tooling; a reciprocating screw with L/D ratio of 20:1 and non-return valve is used because the ferrite filler accelerates screw and barrel wear. Melt temperature is held at 250–270°C, mold temperature at 60–80°C, and injection speed is kept in the lower half of the machine capability to reduce shear heating at the gate. Hold pressure is set between 600 bar and 900 bar on the hydraulic pressure transducer, and gate freeze is confirmed by shot-weight stabilization across 20 consecutive cycles. After ejection, multipole magnetization is performed on a capacitor-discharge fixture, and pole-pitch verification uses a Hall probe referenced to IEC 60404-8-1:2015. The terminal component is a multipole encoder ring, typically 24 to 96 alternating poles, mounted on a bearing seal or tone wheel for active wheel-speed sensors.

    Why Do Thin-Wall Electric Power Steering Sensor Targets Demand a Compound with Low Water Uptake?

    Thin-wall rotor position sensor targets for column-assist and rack-assist electric power steering systems are subjected to cabin humidity swings and thermal cycling, which generate differential swelling between the overmolded PA12 compound and the steel hub. Water absorption measured per ISO 62:2008 at 23°C saturation for PA12 is approximately 1.5 wt%, while at 50% relative humidity equilibrium moisture uptake is 0.7–0.8 wt%; this is lower than PA66, which absorbs 2.5–3.0 wt% under the same condition. The applicable compliance stack includes IATF 16949:2016, environmental testing per ISO 16750-4:2010, RoHS Directive 2011/65/EU, and REACH Regulation (EC) No 1907/2006. The formulation addition ratio is 100% as-supplied compound; runner regrind is excluded from EPS safety-class targets because viscosity shifts from a second heat history alter thin-wall filling and magnetic filler orientation. External mold release may be applied as a dry, silicone-free agent, but no internal lubricant or impact modifier is added because both reduce tensile strength measured per ISO 527-2:2012 below the value required by the part drawing. The downstream process is thin-wall injection molding on an all-electric machine with clamp force from 800 kN to 1200 kN, a 30 mm screw, and a cold-runner valve-gated tool; wall thickness is below 2.0 mm. Melt temperature is controlled within 255–265°C, mold temperature within 70–85°C, and injection velocity is profiled to maintain a flow-front velocity above 150 mm/s in the thin section. Post-mold magnetization uses a multi-pole fixture matched to the sensor pole count, and magnetic field amplitude is verified against IEC 60404-8-1:2015. The terminal part is an EPS rotor position sensor magnet ring overmolded onto a sintered or machined steel hub.

    Across sealless magnetic couplings for chemical dosing pumps, the PA12-bonded ferrite compound is selected because it avoids eddy-current losses associated with metallic magnetic assemblies and provides sufficient torque transmission in low-speed, positive-displacement pump heads. The applicable compliance framework includes ISO 5199:2002 for chemical process pump construction, Directive 2014/34/EU when the pump is installed in an ATEX-classified zone, RoHS Directive 2011/65/EU, and REACH Regulation (EC) No 1907/2006. The addition ratio is 100% compound without let-down; insert overmolding uses the same feedstock without adhesion-promoting primers, provided the stainless steel hub surface is prepared to Ra 0.8–1.2 µm according to ISO 21920-2:2021 and preheated to 100–120°C immediately before placement in the cavity. Downstream production is insert injection molding with a vertical or horizontal machine, a cold-runner tunnel gate, melt temperature 250–270°C, mold temperature 60–80°C, and injection speed reduced to 20–40 mm/s because high-speed filling of thick coupling rings can trap air at the insert interface and create magnetic voids detected by flux mapping. After molding, the rings are annealed at 80°C for 2 h in a nitrogen-purged oven to relieve molded-in stress before magnetization; multi-pole magnetization is performed on a dedicated fixture with pole count matched to the pump’s drive and driven rotors. The terminal products are inner and outer rotor magnet rings for sealless centrifugal or gear pumps, magnetized as multi-pole rings and assembled into containment shells.

    When Multipole Rings Replace Sintered Ferrite Segments in Electric Oil Pump Rotors

    Plastic-bonded ferrite multipole rings replace sintered ferrite segments in electric oil pump rotors where complex pole geometry and insertion into a rotor stack are combined with a need for corrosion resistance in hot transmission fluid. Compliance is governed by IATF 16949:2016 for automotive service, and environmental testing follows ISO 16750-4:2010 temperature and humidity profiles; material restrictions follow RoHS Directive 2011/65/EU and REACH Regulation (EC) No 1907/2006. The formulation addition ratio is 100% as-supplied compound; regrind reuse is permitted only up to 15 wt% when blended with virgin material, and only after the mixed feed passes melt volume-flow rate retest per ISO 1133-1:2022 Procedure A at 275°C and 5 kg, with a deviation of no more than 10% from virgin. The downstream process is injection molding of ring-shaped rotor magnets in a cold-runner, multi-cavity tool with wear-resistant gate inserts; melt temperature is 250–270°C, mold temperature 60–80°C, and hold pressure is profiled to maintain part weight within ±0.5% of the validated process. Because the compound is an isotropic ferrite-filled PA12 type, anisotropic alignment is not performed; after ejection, the ring is magnetized in a capacitor-discharge fixture to the required pole count, typically 8 or 10 poles for electric oil pump rotors, and flux uniformity is checked by Hall probe mapping against IEC 60404-8-1:2015. The terminal product is a multipole rotor ring bonded or press-fitted into the rotor assembly of a 12V or 24V electric oil pump or coolant pump.

    Linear Position Encoder Targets in High-Humidity Industrial Environments

    Linear position encoder targets for machine tools, packaging lines, and synchronized linear axes require pole-pitch stability under humidity cycling, oil mist, and periodic thermal excursions. The material is processed as single-component feedstock without dilution; no colorant or pigment addition is recommended because non-magnetizable pigments displace the magnetizable fraction and reduce magnetic remanence measured per IEC 60404-8-1:2015. The relevant normative set includes ISO 294-4:2018 for processing shrinkage measurement, ISO 62:2008 for moisture uptake, RoHS Directive 2011/65/EU, REACH Regulation (EC) No 1907/2006, and ISO 11469:2016 for polymer marking. The downstream production route is two-position injection molding of encoder segments onto a pre-machined aluminum carrier; the carrier is preheated to 90–110°C and surface roughened to Ra 1.0–1.6 µm per ISO 21920-2:2021 to create mechanical interlock. Melt temperature is set at 250–265°C, mold temperature at 60–80°C, and injection speed is limited to 40–60 mm/s to minimize filler orientation gradients along the part length. After molding and cooling, the encoder target is magnetized with alternating poles at the pole pitch specified by the encoder sensor, typically 1.0–5.0 mm; flux density is mapped along the full travel length using a Hall array, with acceptance tolerance tied to the sensor datasheet. The terminal component is a linear magnetic encoder scale or target strip used in industrial automation axes.

    Because PA12-bonded ferrite rotor rings maintain dimensional stability better than PA66 equivalents under 80% relative humidity, they are used in appliance and power-tool brushless motor sensor rings where the part must survive condensation after cold storage. Compliance for household appliances is aligned to IEC 60335-1:2020, with material restrictions under RoHS Directive 2011/65/EU and REACH Regulation (EC) No 1907/2006. The compound is used at 100% virgin feedstock for first-production runs; regrind from runners is allowed up to 20 wt% in non-safety commercial parts after validation of melt volume-flow rate per ISO 1133-1:2022 and after drying to below 0.1% moisture. Downstream processing is high-cavitation cold-runner injection molding with melt temperature 250–270°C, mold temperature 60–80°C, and in-line multi-pole magnetization after part ejection. The terminal part is a sensor magnet ring for brushless motor commutation or rotor position feedback in washing machines, dishwashers, power tools, and small appliance drives.

    In automated laboratory pipetting and micro-dosing platforms, published data for this specific KEBABLEND M 48/67 PA12 configuration is limited; however, the material’s PA12 carrier is used for non-fluid-contact magnet carriers where high dimensional reproducibility and low moisture uptake are required. The applicable compliance framework is IEC 61010-1:2010 safety for laboratory equipment, RoHS Directive 2011/65/EU, and REACH Regulation (EC) No 1907/2006; USP Class VI or ISO 10993-1 evaluation is not typically performed for this application because the magnet is isolated from fluid paths. The addition ratio is 100% as-supplied compound; no let-down with lubricated PA12 is approved because internal lubricant reduces mechanical interlock with overmolded polycarbonate or PBT carriers. Production is insert molding or two-shot molding with a cold-runner system, melt temperature 250–265°C, mold temperature 60–80°C, and capacitor-discharge magnetization after ejection. Terminal components are miniature multi-pole magnet rings used in pipettor Z-axis drives, microplate transfer arms, and syringe pump stepper motor feedback assemblies.

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    Более подробное введение

    Barlog Plastics KEBABLEND M 48/67 PA12 is a ready-to-process polyamide 12 compound formulated as a binder system for plastic-bonded permanent magnets. The grade is supplied as granulate and is intended for injection moulding, hot-runner moulding and, in selected configurations, extrusion. The product code M 48/67 identifies the magnetic filler package and binder viscosity within the KEBABLEND M series; numerical values for remanence, coercivity, maximum energy product and density are defined in the current supplier datasheet and are not reproduced here to avoid version conflict. Magnetic characterisation of moulded samples is carried out according to IEC 60404-5, density according to ISO 1183-1 and tensile modulus according to ISO 527-2.

    Plastic-bonded magnets using PA12 are distinguished from PA6 and PPS binder systems by lower water uptake and reduced thermal processing stress. The material is specified where complex net-shape geometries, thin wall sections, low eddy-current losses and moderate continuous operating temperatures are required. For anisotropic magnetic output, magnetisation can be performed after moulding or, where a magnetising field is integrated into the tool, during the moulding cycle. Published data for the anisotropic behaviour of this specific configuration is limited and must be confirmed with the manufacturer’s application engineering documentation.

    Because the magnetic filler dominates volumetric and rheological properties, the density of PA12-bonded ferrite grades generally falls in the range 2.8–3.8 g/cm³, while rare-earth-filled grades fall in the range 5.0–6.0 g/cm³. These values are reference intervals and do not replace the lot certificate. The melt mass-flow rate tested under ISO 1133-1 is controlled by the manufacturer to maintain lot-to-lot processing consistency; a significant increase in MFR relative to the virgin value is an indicator of thermal or hydrolytic degradation. The PA12 matrix exhibits a melting peak near 175–180 °C by differential scanning calorimetry according to ISO 11357-3. This defines the lower processing bound and the practical service ceiling, not the continuous use temperature. The crystallisation temperature of PA12 is approximately 140–150 °C; rapid cooling in cold moulds reduces crystallinity and can affect dimensional stability and magnetic filler orientation.

    Which injection moulding parameters govern process stability for high-filler PA12 magnet compounds?

    Residual moisture control is the first processing constraint. PA12 is hygroscopic enough that pellets exposed to uncontrolled air must be dried in a desiccant dryer at 80 °C for 4–8 h to a target moisture content below 0.10 %. A dew point below -30 °C is recommended. Moulding with residual moisture above 0.15 % can cause splay, gas porosity and a viscosity shift that disturbs magnetic particle orientation. Hopper residence time should be limited; at ambient relative humidity above 60 %, dried pellets regain surface moisture within 30–60 min if left open to air.

    Barrel temperatures for PA12-based magnetic compounds are generally set between 220 °C and 260 °C. The lower limit is dictated by melt viscosity and screw torque; the upper limit is dictated by oxidative chain scission. A measured melt temperature above 270 °C is not recommended for high filler loadings. Persistent operation at 270 °C can produce discolouration, melt strength loss and uncontrolled changes in melt flow that reduce cavity-to-cavity consistency. Mould temperatures from 40 °C to 80 °C are commonly used; higher mould temperatures within this band improve surface replication but extend cycle time. Hot runner nozzles should be set 5–10 °C above the melt temperature but below 270 °C; higher nozzle temperatures can cause local degradation at the gate.

    For injection moulding machines with clamp force between 500 kN and 3,000 kN, low-compression screws with a compression ratio of 1.5:1–2.0:1 and abrasion-resistant non-return valves are preferred. Backpressure should be kept low to avoid mechanical degradation of the magnetic filler and excess shear heating. Cavity pressure sensors and short-shot studies are recommended because the high filler content makes switchover position sensitive. A switchover from filling to holding based on cavity pressure rather than screw position reduces flash and shot-weight variation in multi-cavity tools.

    Comparative selection between M 48/67 PA12 and PA6- or PPS-based magnet compounds begins with water absorption and thermal ageing. Under 23 °C and 50 % relative humidity, unfilled PA12 absorbs approximately 0.7 % water by mass according to ISO 62; PA6 absorbs 2.5–3.0 %, and PPS absorbs <0.1 %. Filled magnetic compounds follow the same ordering. The lower moisture uptake of PA12 reduces dimensional change and demagnetisation drift caused by humidity exposure in sensor and actuator applications.

    Carrier polymer Density (ISO 1183-1) Water absorption at 23 °C/50 % RH (ISO 62) Typical barrel temperature Continuous use ceiling
    PA12 1.01–1.02 g/cm³ 0.6–0.8 % 220–260 °C 80–100 °C
    PA6 1.13–1.15 g/cm³ 2.5–3.0 % 240–270 °C 100–120 °C
    PPS 1.34–1.36 g/cm³ <0.1 % 300–340 °C 180–240 °C

    These values are generic unfilled polymer reference data and must be adjusted for magnetic filler content. Compared with PPS, PA12 offers a lower processing temperature. PPS-based magnet compounds require barrel temperatures above 300 °C and mould temperatures between 130 °C and 150 °C. The PA12 grade processes in the 220–260 °C barrel range, reducing thermal exposure of the magnetic filler. The trade-off is a lower continuous service temperature; PA12-bonded magnets are generally not specified for continuous operation above 100 °C under mechanical load, whereas PPS-bonded magnets can be used at continuous temperatures of 180–240 °C depending on filler stability and design.

    Tooling, Gating and Demagnetisation Risk

    Highly filled PA12 magnet compounds exhibit pronounced pseudoplastic flow and rapid solidification. Gate location, gate thickness and flow length must be designed to minimise free-jet melt fracture and filler orientation instability. Direct pin gates may create jetting and separation of the magnetic filler from the polymer melt; fan gates or edge gates with a thickness not less than 60 % of the part wall improve filling. Moulds should be vented to 0.01–0.02 mm to prevent air entrapment without flash, particularly where multi-cavity tools are used.

    Experience on production-scale injection moulding lines shows that mineral and rare-earth fillers in magnet compounds accelerate screw, barrel and check-ring wear. Bimetallic barrels, nitrided screw surfaces and hardened gate inserts are specified to maintain shot consistency. Mould maintenance intervals are shorter than for unfilled PA12 because the filler acts as an abrasive on moving components. Magnetic orientation coils embedded in the mould must be electrically isolated and thermally protected from mould temperature control circuits.

    Demagnetisation during service is influenced by operating temperature, external opposing fields and mechanical stress. The coercivity HcJ reported per IEC 60404-5 provides the primary selection criterion for resistance to demagnetisation; a higher HcJ is required for parts used near electric motors or in narrow air gaps. Testing at the application-specific temperature is necessary because coercivity can decrease as temperature rises, even if the remanence remains temporarily stable.

    Lot acceptance for KEBABLEND M 48/67 PA12 should be structured around the following test matrix. The table does not repeat supplier-specific numerical limits; it identifies the methods by which the datasheet values are measured and by which incoming-material consistency is verified.

    Property Test method Process or design relevance
    Density ISO 1183-1 Filler loading, voids
    Melt mass-flow rate (MFR) ISO 1133-1 Lot-to-lot processability
    Tensile modulus ISO 527-2 Part stiffness
    Charpy unnotched impact ISO 179-1/1eU Impact resistance
    Water absorption ISO 62, 23 °C/50 % RH Dimensional stability
    Magnetic remanence Br IEC 60404-5 Magnetic output
    Coercivity HcJ IEC 60404-5 Resistance to demagnetisation
    Maximum energy product (BH)max IEC 60404-5 Magnet performance

    When M 48/67 PA12 is processed in humid cleanroom-free environments

    Production halls with ambient relative humidity above 60 % require closed hopper loading or a dry-air blanket. PA12 regains surface moisture quickly after drying; open hoppers can reintroduce moisture within 30–60 min, resulting in splay even when the pellet core remains dry. At 85 % RH, direct dryer-to-throat conveying is recommended because surface moisture adsorption on cold regrind or cold granules is faster than for warm pellets.

    Regrind use should be limited. The presence of magnetic filler makes particle size distribution after regrinding irregular; addition of more than 20 % regrind without revalidation is not recommended because it can shift melt viscosity, reduce magnetic filler alignment and alter mechanical impact behaviour. The compound should not be contaminated with incompatible polymer families; small amounts of polyolefin purge residues can produce delamination in PA12 parts. Avoid exposure to strong acids, phenols or concentrated oxidising media without specific validation because these can hydrolyse or degrade the polyamide matrix.

    Plastic-bonded magnet components produced from PA12-based grades are specified for sensor magnets, encoder wheels, rotor position magnets, pump impeller magnets and actuator magnets, where complex geometry and moderate temperature requirements overlap. For each application, the mechanical load, peak operating temperature, chemical contact and demagnetisation field must be established before material substitution, because no single grade covers every magnet application.

    Because the PA12 melting point is near 175–180 °C, the practical continuous-use ceiling in a magnetised assembly is generally below 100 °C under mechanical load. At temperatures above 80 °C, creep modulus decreases and magnetic remanence may exhibit reversible or irreversible losses depending on the coercivity of the filler. Testing per IEC 60404-5 at the application-specific temperature is therefore required. Chemical exposure to automotive oils and fuels is generally tolerable for PA12, but exposure to strong acids, phenols or concentrated alcohols should be avoided without specific validation because they can plasticise or hydrolyse the matrix.

    Compliance statements for REACH SVHC and RoHS Directive 2011/65/EU annex II restrictions must be requested from the compound supplier; the magnetic filler may contain restricted metallic elements depending on the filler system. The grade is not assumed to meet food-contact requirements under FDA 21 CFR or Regulation (EU) No 10/2011 without explicit supplier confirmation.

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