| Код ТН ВЭД | 354076 |
Как аккредитованный завод Braskem PP Homopolymer F006EC2, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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When Wall Thicknesses Drop Below **400 Microns** Braskem PP homopolymer F006EC2 delivers a melt flow index of **6.0 g/10 min** (**ASTM D1238**, **230 °C**/**2.16 kg**) and a tensile yield strength of **34 MPa** (**ASTM D638**, **50 mm/min**). These values position the grade for thin-wall injection molding of food-contact containers with nominal wall stock from **0.35 mm** to **0.80 mm**. On toggle-clamp or hydraulic machines with clamping forces of **1,200–2,500 kN**, the recommended melt temperature window is **210–250 °C** and mold surface temperature is held at **20–50 °C**. Injection speeds above **200 mm/s** prevent premature freeze-off in pin-gated multi-cavity tools producing dairy tubs, margarine basins, and delicatessen trays. The European Food Contact Regulation **EU No. 10/2011** and **FDA 21 CFR 177.1520(c)** cover the neat homopolymer; converters must validate overall migration limits below **10 mg/dm²** for aqueous, acidic, and fatty simulants. Shrinkage anisotropy of **1.2–1.6 %** parallel to flow and **1.0–1.4 %** perpendicular (**ISO 294-4**) necessitates mold dimension compensation, especially for lids requiring lip-seal integrity after hot-fill exposure at **85–95 °C**. Process-stabilization packages supplied in the pellet eliminate the need for drying below **60 %** ambient relative humidity; only in saturated environments prior to molding is a **2-hour** desiccant drying cycle at **80 °C** advised. Extruded tape yarn production from Braskem PP F006EC2 begins with melt pumping through a slit die into a water quench bath maintained at **30–40 °C**. Barrel zones are profiled from **190 °C** at the feed throat to **240 °C** at the die head, ensuring a homogeneous melt without gel inclusions that would cause fiber breakage during the stretching phase. The solidified tape, typically **1.5–3.0 mm** wide and **50–100 µm** thick, passes through a hot-air oven or over heated godet rolls at **110–140 °C** where a draw ratio of **1:5.5** to **1:8.0** is applied. The molecular orientation induced in this step lifts tensile strength at break to **250–350 MPa** in the machine direction and reduces elongation at break below **20 %**. Circular or box looms interlace the tapes into heavy-duty woven sacks for fertilizers, cement, resins, and pet-food granules; International Standard **ISO 21898:2004** governs sack-drop and seam-strength testing for such packaging. For UV-stabilized variants intended for outdoor storage, converters compound **0.15–0.30 wt%** hindered amine light stabilizer (HALS) masterbatch on-line, which extends the useful life of the fabric to approximately **6–12 months** under direct tropical sunlight, measured by tensile strength retention after accelerated weathering per **ASTM G154 Cycle 1**. A critical processing boundary appears when the quench-bath temperature drifts above **45 °C**: crystallinity drops too low, and the subsequent oven-stretching step produces frequent tape fibrillation and width variation exceeding **±8 %** of nominal. What Controls Melt Curtain Stability in Monolayer Cast Film Extrusion? The cast film process relies on an air-knife system to pin a molten curtain exiting a T-slot die against a chill roll cooled to **18–30 °C**. For F006EC2 extruded at **220–260 °C** through a die gap of **0.5–0.8 mm**, the melt curtain must traverse an air gap of **100–180 mm** without neck-in exceeding **15 %** and without edge-bead build-up that disturbs winding tension. Chill-roll surface roughness of **Ra 0.2–0.4 µm** imparts a gloss level of **80–90 GU** at **60°** (**ASTM D2457**), suitable for bread bags, textile over-wrap, and photo-album lamination film. The film gauge normally ranges from **25 µm** to **60 µm**, controlled via gravimetric extruder output and line speeds of **80–200 m/min**. Polypropylene film in these thicknesses meets **EU Directive 94/62/EC** for packaging waste reduction and, when used in direct food contact, the specific migration limits of **EU No. 10/2011 Annex II**. Corona treatment applied on-line to a surface energy of **42–48 mN/m** (**ASTM D2578**) ensures adhesion of water-based flexographic inks and polyurethane laminating adhesives. A documented processing limit is the onset of surging at screw speeds above **120 rpm** in a **75 mm** single-screw extruder with an **L/D 30** when back-pressure exceeds **28 MPa**, leading to gauge bands visible at **±2 µm** amplitude every **5–8 m** of wound roll. Thermoforming sheet gauges between **0.8 mm** and **2.0 mm** require a narrow melt temperature window to avoid sag in the clamping frame of a continuous roll-fed thermoformer. F006EC2 resin is extruded through a coat-hanger sheet die at **215–245 °C** onto a three-roll polishing stack with roll temperatures set to **30–55 °C**, producing amorphous or lightly crystalline sheet with a degree of crystallinity below **45 %**. The sheet is re-heated in a quartz or ceramic infrared oven to **155–170 °C** surface temperature before plug-assisted positive forming into dairy cups, drink tumblers, and portion packs. Forming pressures range from **0.4–0.7 MPa**, and aluminum temperature-controlled molds operating at **50–70 °C** shorten cycle times while preserving rim dimensional accuracy. Compliance with the U.S. Food and Drug Administration **21 CFR 177.1520** olefin polymer regulation is unconditional because no plasticizers or high levels of extractable catalyst residues are present; the grade carries a Braskem food-contact statement aligned with **FDA FCN 399** and **EU Regulation (EU) 10/2011**. The axial stretching during forming reduces the sheet thickness non-uniformly, necessitating a starting gauge **15–20 %** above the final base thickness. One documented failure mode is the appearance of translucent stress-whitening in container corners when the core sheet temperature at forming drops below **148 °C** — this brittle response can be eliminated by extending the oven dwell by **1.0–1.5 seconds** or raising the upper heater bank by **8–12 °C**. When Spunbond Line Speeds Exceed **3,500 m/min**, Fiber Diameter Uniformity Depends on Melt Filtration In spunbond nonwoven manufacturing, the polymer melt is extruded through a spinneret with capillaries of **0.3–0.6 mm** diameter at **230–260 °C**, and the filaments are drawn by high-velocity air streams at **3,000–5,000 m/min** onto a moving collection belt. Braskem F006EC2 with a narrow molecular weight distribution (**Mz/Mw ~ 3.5–4.2**, measured by high-temperature GPC) yields minimal oligomer fuming at the die face, which is critical for continuous production runs of **12–18 hours** between spinneret cleaning cycles. The as-spun filaments develop a degree of orientation that boosts tensile tenacity to **2.8–3.5 cN/dtex** without a separate drawing step. Fabric basis weights typically lie between **10 g/m²** and **50 g/m²** for hygiene top-sheet, medical gown, and furniture scrim applications. Medical-grade nonwovens must comply with **ISO 10993-5** (cytotoxicity) and **ISO 10993-10** (skin irritation) when the fabric is the body-contact layer; raw-material lot-to-lot traceability and a certificate of analysis showing heavy-metal content below **1 ppm** each are standard procurement specifications. Process data indicates that the critical shear rate at the spinneret hole entry must stay below **300,000 s⁻¹** to avoid melt fracture; for a typical hole diameter of **0.4 mm**, this imposes a maximum throughput per hole of **0.6 g/hole/min**. When throughput exceeds this ceiling, fiber diameter variability measured on-line by a laser micrometer rises above **±8 %CV**, compromising cover factor and hydrostatic head measured per **AATCC 127**. Additionally, the nonwoven fabric’s thermal bonding window is constrained: the bonding embossing roll must be maintained at **150–160 °C** to create discrete bond points without compacting the entire web, and the resulting tensile strength in machine direction reaches **20–35 N/5 cm** at a bonding area of **12–20 %**. Dimensional Fidelity in Appliance Components Molded to Tight Tolerances Polypropylene homopolymer F006EC2 is specified for small appliance housings, structural brackets, and pump components where continuous service temperatures reach **90–105 °C** under zero mechanical load. Injection molding conditions in hot-runner tools with sequential valve gating employ a melt temperature of **220–240 °C** and mold temperature of **40–60 °C** to achieve a crystallinity level that balances impact resistance and shrinkage control. The heat deflection temperature under **0.455 MPa** (**ASTM D648**) is **105 °C**, and the Vicat softening point (**ISO 306, A50**) is **153 °C**, defining the upper working limit for parts near heating elements or in enclosed electronic enclosures. Compliance with flammability standard **UL 94 HB** at **1.5 mm** thickness is inherent for the unfilled homopolymer; thicker sections up to **3.0 mm** can also meet **IEC 60695-11-10** glow-wire ignition requirements for unattended appliance circuits. Long-term thermal aging data generated at **120 °C** in accordance with **UL 746B** indicates a Relative Thermal Index (RTI) of **110 °C** for mechanical impact and **115 °C** for electrical properties, placing it within the accepted range for coffee-machine frames, toaster side panels, and refrigerator door liners. When components are assembled with self-tapping screws, the resin’s flexural modulus of **1,450 MPa** (**ISO 178**) provides sufficient thread-holding strength, with pull-out forces of **120–180 N** in a **2.5 mm** boss diameter; however, insert molding with brass fittings requires a minimum boss diameter of **6 mm** to prevent hoop-stress cracking during thermal cycling between **-20 °C** and **80 °C**. Processors report that short-shot occurrences in multi-cavity molds decrease when the cushion distance is maintained at **4–6 mm** and the decompression after charge is limited to **2 mm**, preserving a uniform shot weight of **±0.15 %** across **32-cavity** arrangements. The absence of antistatic additives in the base grade should be noted for applications involving moving air streams, where surface resistivity above **10¹⁶ Ω/sq** (**IEC 62631-3-2**) promotes dust accumulation; inline addition of **0.5–1.5 %** ethoxylated amine concentrate during molding is permissible provided the final compound complies with **RoHS Directive 2011/65/EU** for electronic equipment. When hot-stamping or in-mold labeling is employed, the label adhesion must survive **85 °C** in a **95 %** relative humidity environment for **500 hours** without delamination, verified by cross-hatch peel testing according to **ISO 2409**.
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| Property | F006EC2 (Homopolymer) | Impact Copolymer (~MFR 3.0) | Standard |
|---|---|---|---|
| Flexural modulus (1% secant) | 1450–1550 MPa | 1050–1200 MPa | ASTM D790A |
| Notched Izod impact (23 °C) | 25–35 J/m | 90–120 J/m | ASTM D256 |
| Tensile yield strength | 34–36 MPa | 26–28 MPa | ASTM D638 |
| Heat deflection temperature (0.455 MPa) | 100–105 °C | 85–90 °C | ASTM D648 |
| Regulation / Standard | Applicability | Limiting Condition |
|---|---|---|
| FDA 21 CFR §177.1520(c) Item 1.1a | All food types (no alcoholic content above 8%) | Use temperature not exceeding 100 °C |
| EU Regulation 10/2011 (as amended) | Specific migration limit for overall migration | 10 mg/dm² per Annex I |
| REACH (EC 1907/2006) | Monomer and additive substances registered | No SVHC content above 0.1% w/w |
| CONEG (Model Toxics in Packaging) | Sum of Pb, Cd, Hg, Cr(VI) below 100 ppm | Compliance certified by supplier |