| Код ТН ВЭД | 117077 |
Как аккредитованный завод по производству углеродных принтеров EPU 44 Biobased Elastomer for 3D Printing, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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A Carbon DLS line running Carbon Printers EPU 44 Biobased Elastomer at a 100 µm layer height can be used for lattice midsoles only after the resin is conditioned to 25 °C ± 2 °C and its static viscosity is confirmed against the printer’s allowable feed range; published processing guides for DLS polyurethane resins typically place the viscosity window between 800 mPa·s and 3,500 mPa·s at 25 °C, but lot-specific EPU 44 values must be taken from the certificate of analysis because biobased polyol substitutions can shift viscosity by 300–600 mPa·s. For production-scale footwear cushioning, the resin is printed as a hexagonal lattice midsole with strut diameters from 1.0 mm to 1.8 mm and cell pitch adjusted between 6 mm and 12 mm to tune peak plantar pressure and local deflection; the print orientation is set with the lattice nodes tilted 30° from the build direction to reduce support contact and improve cell draining. Because closed-cell lattices trap uncured resin, a secondary low-pressure solvent flush through 1.5 mm drain holes is applied after the first ultrasonic wash; the washing protocol uses two 5-minute baths in 99% isopropyl alcohol or 99% propylene glycol monomethyl ether acetate followed by a 60 °C forced-air drying step for 30 minutes. Thermal post-cure is conducted at 120 °C for 2 hours, after which parts are rested at 23 °C ± 2 °C and 50% ± 5% relative humidity for 24 hours before mechanical testing. The resulting terminal products—running shoe midsoles, trail-shoe heel counters, and removable insoles—are evaluated using ASTM D638-14 for tensile properties, ASTM D2240 for Shore A hardness, ASTM D395-16e1 method B for compression set after 22 hours at 70 °C, and ISO 7214 for cellular elastomer resilience. Energy return is not accepted from a single rebound value; if the datasheet reports resilience, it is referenced to ASTM D2632, but installed energy return in a lattice midsole requires a vertical drop test with an instrumented impact hammer and high-speed motion capture. Published data for EPU 44’s exact bio-based carbon fraction is batch-specific; if ASTM D6866 certification is required for sustainability labeling, the converter must request the lot-level mass balance certificate from the resin supplier, and without that certificate total biobased content should be limited to qualitative supplier declarations rather than quantitative marketing.
In automotive interior seal applications—glove compartment gaskets, console armrest isolation rings, and HVAC flap edge seals—EPU 44 is printed as a closed-cell or partial-lattice profile with wall thickness between 1.0 mm and 2.0 mm, and the part is usually oriented with the visible seal face upward to prevent support material from generating a rough upper lip. The predominant long-term risk is compression set, measured according to ISO 815-1:2019 on cured plaques after aging at 70 °C for 22 hours; for DLS elastomers, values are strongly influenced by post-cure conversion, and under-cured samples can show a compression set above 30% even when Shore A hardness appears within tolerance. Therefore, each batch is cured for 2 hours at 120 °C, followed by an additional 60-minute cure at 130 °C when initial ISO 815-1:2019 compression set exceeds the OEM limit, typically 25–30% for interior seals. Accelerated heat aging is run per ISO 188:2011 at 100 °C for 168 hours, and the retention of tensile elongation is recorded with ASTM D638 on die-cut specimens; published data for EPU 44 at 150 °C is limited, so continuous service above 120 °C must be validated against the vehicle-specific thermal profile. Volatile organic compound and fogging behaviour are tested on 30 mg samples cut from the seal according to VDA 278:2016; if total VOC exceeds 100 µg/g, an extended post-cure of 60 minutes at 120 °C is evaluated, and if fogging condensate persists, the ventilation rate of the curing oven is increased to 10–15 air changes per hour. The terminal products are installed in cabin environments, so the converter must also confirm that residual solvents from the wash step are removed; headspace gas chromatography at 80 °C for 30 minutes is used to verify residual IPA below 50 ppm before parts are bulk-packaged. EPU 44 should not be combined with amine-based primers or additives before final cure because primary amine groups can react with residual isocyanate species and prematurely raise Shore A hardness; if an adhesion promoter is required for a metal insert, a post-cure two-component polyurethane primer is applied after the solvent wipe, not before printing.
Protective sports equipment production lines running EPU 44 on Carbon M-series systems exploit the ability to change local hardness within one printed liner by adjusting exposure dose and lattice cell wall dimensions. A downhill cycling helmet liner uses 50 µm layer height in the occipital flex zone and 100 µm layer height in the crown impact zone; the transition between the two is mapped over a 5 mm gradient to avoid a visible shear plane and to maintain layer adhesion. Cell size is varied from 4 mm in high-impact regions to 10 mm in ventilation zones, and the ribbed walls are printed with a minimum thickness of 0.8 mm to avoid wash-induced buckling. After the print run, the liner is washed in two 5-minute ultrasonic baths of 99% isopropyl alcohol, dried at 60 °C for 30 minutes, and then thermally cured at 120 °C for 2 hours; the cured liner rests for 24 hours at 23 °C ± 2 °C and 50% ± 5% relative humidity before testing. Durometer verification is performed with ASTM D2240 on flat witness coupons that are printed on the same machine platform and cured in the same oven; a hardness spread greater than ±3 Shore A across zones indicates a resin-bath temperature imbalance or insufficient post-cure uniformity. Impact attenuation is not claimed from coupon data alone; the complete helmet assembly is subjected to equipment-specific tests such as ASTM F1952 for downhill bicycle helmets or NOCSAE ND001 for football helmet performance, and the liner supplier must provide full digital print logs for each batch. Terminal products—helmet liners, shoulder pad cushions, and shin guard pads—are inspected for surface porosity using 20× optical microscopy; pores larger than 0.2 mm in the outer wall are rejectable because they can initiate tear propagation under high-strain impact. Published data for EPU 44 under multi-impact fatigue is limited, so repeated-impact validation should be conducted on the final assembly rather than extrapolating from single-impact coupon results.
For custom ankle-foot orthosis production, a 1.2 mm elastomer liner can be produced from EPU 44 on a Carbon M2 system if the uncured resin is handled as a skin-sensitizing material and all wash effluent is segregated from standard industrial solvent waste. The print strategy places the orthosis shell at a 15° inclination from the build platform so that the liner surface is free of support scars, while the lattice infill uses 3 mm open cells with 0.9 mm struts to permit air circulation and reduce skin shear. After printing, the part is washed in two 10-minute ultrasonic baths of 99% isopropyl alcohol, then vacuum-dried at 60 °C for 60 minutes and post-cured at 120 °C for 2 hours; a final extraction is performed in distilled water at 37 °C for 24 hours before packaging. Biocompatibility is not claimed from the raw resin alone; the device manufacturer must validate the finished geometry and process using ISO 10993-5:2009 for cytotoxicity, ISO 10993-10:2021 for sensitization and irritation, and ISO 10993-18:2020 for chemical characterization of extractables. If the part is marketed as a sterile device, terminal sterilization by gamma radiation or ethylene oxide must be validated according to ISO 11137-1 or ISO 11135, and the effect of sterilization on Shore A hardness and compression set must be re-measured after the sterilization dose is applied. For skin-facing surfaces, roughness is controlled by print orientation; when a smooth surface is required, the part is oriented with the skin-facing side downward and the measured Ra is held below 15 µm, whereas a textured open-cell surface is accepted only if it is part of the intended prescription and its topography is documented by a non-contact profilometer. The terminal products—custom orthoses, prosthetic socket liners, and post-operative cast replacements—are controlled by dimensional fit rather than a universal hardness specification, so each build is accompanied by a physical duplicate printed from the same resin lot; published data for EPU 44 in long-term skin contact is limited, and lot-specific sensitization data must be referenced in the device master record.
| Application segment | Standard/regulation | Test method or clause | Typical acceptance target | Validation responsibility |
|---|---|---|---|---|
| Footwear cushioning | REACH 1907/2006 Annex XVII | SVHC screening; restricted aromatic amines | < 0.1% weight per substance | resin supplier certificate |
| Automotive interior seals | VDA 278:2016 | thermal desorption GC/MS | OEM threshold; often 100 µg/g total VOC | converter and OEM |
| Protective sports equipment | ASTM F1952 / NOCSAE ND001 | full-assembly impact attenuation | pass applicable helmet standard | accredited test laboratory |
| Medical skin-contact orthotics | ISO 10993-5:2009, ISO 10993-10:2021 | cytotoxicity; sensitization/irritation | no cytotoxic potential; no sensitization | medical device manufacturer |
| Consumer electronics IP67 gaskets | IEC 60529:2013 | IPx7 immersion test | no water ingress after 30 min at 1 m | end-use assembly manufacturer |
Consumer electronics and wearable applications expose a critical process window: on Carbon DLS systems the oxygen-permeable window establishes a polymerisation-inhibited dead zone, and for EPU 44 at 25 °C this dead zone is normally maintained between 20 µm and 40 µm by controlling resin temperature, oxygen flux through the window, and exposure dose per layer. If the dead zone falls below 20 µm, cured resin can adhere to the window and produce a ‘pancake’ failure, whereas if it exceeds 40 µm, unsupported thin films may delaminate between layers during the build. For an earbud sleeve with a 0.6 mm wall, the print plan uses 50 µm layer height and a 45° build orientation; this orientation allows the outer lip to maintain flexibility but can reduce vertical load capacity, so the seal is designed to compress along the layer-normal direction rather than across layer planes. After printing, the sleeves are washed in two 3-minute ultrasonic baths of 99% isopropyl alcohol, dried at 60 °C for 20 minutes, and post-cured at 120 °C for 2 hours; residual solvent is confirmed below 50 ppm by headspace gas chromatography before consumer packaging. Mechanical acceptance tests use ASTM D412 for tensile set and elongation at break, ASTM D624 die C for tear resistance, ASTM D2240 for Shore A hardness, and ASTM D575 for compression-deflection at 30% deflection. For enclosures requiring IP67 behaviour, the printed gasket is tested per IEC 60529:2013 after 30 minutes immersion at 1 m depth, with no internal water ingress; the gasket groove is designed for a 0.8 mm O-ring cross-section and a compression deflection of 25–35% under assembly screws torqued to 0.2 N·m. Terminal products include smartwatch strap cushions, over-molded mobile phone seals, and earbud comfort tips. A low-friction topcoat is not required for most applications, but if a 5–10 µm coating is applied to the lip, the coating must be validated for adhesion and cyclic fatigue because silicone-based topcoats can mask underlying under-cure without improving bulk tear strength. Published data for EPU 44 in miniaturised IP67 gaskets is limited; therefore, design validation on printed witness rings is required rather than relying on datasheet values for larger plaques.
For pneumatically actuated soft grippers, EPU 44 is printed as a monolithic bellows with a 0.6 mm wall thickness and a 2 mm internal channel; the print model includes 1.5 mm drain holes at the bellows tip to release uncured resin during the wash step and to prevent pressure imbalance during post-cure. The bellows is oriented along the z-axis so that the convolutions are built without internal support scarring, and the radial walls are angled at 45° to improve leak-tightness while accepting a slight reduction in tear strength parallel to the layers. After building, the part is washed in two 10-minute ultrasonic baths of 99% isopropyl alcohol, purged with air at 60 °C for 60 minutes, and cured at 120 °C for 2 hours; residual monomer is confirmed below 0.5 wt% by gas chromatography before the part enters a pneumatic test cell. The terminal products—soft robot fingers, vacuum cups, and material-handling bellows—are evaluated under cyclic actuation at 0–60 kPa at 1 Hz, with pressure decay and dimensional creep recorded after 50,000 cycles; because published data for EPU 44 in pneumatic robotics is limited, design validation should include ASTM D638 tensile set after dynamic loading and ISO 815-1:2019 compression set after 22 hours at 70 °C rather than relying on static datasheet values. For dry food-contact uses, the finished part must be tested for overall migration under EU 10/2011 or FDA 21 CFR 177.1680 if applicable to the specific compound; EPU 44 is not supplied with a food-contact declaration, so any such claim requires a separate migration study on the final washed and cured article. The soft gripper is not intended as a load-bearing structural link; bending loads above 20 N should be avoided unless the bellows is reinforced with a rigid printed core or fibre-reinforced nylon insert.
Enclosed motor assemblies in HVAC fans and small compressor units use EPU 44 as direct-printed cylindrical mounts with a 6 mm outside diameter, 2.5 mm bore, and a wall thickness of 1.75 mm; the bore is sized for press-fit onto a 3 mm stainless steel pin, with diametrical interference not exceeding 0.2 mm to avoid split propagation from the inner surface. The mount is printed flat on one end to permit optical measurement of layer registration, and the part is post-cured at 120 °C for 2 hours before any adhesive bonding is performed; pre-print bonding is not recommended because uncured resin residue inhibits wetting and creates a weak boundary layer. Dynamic mechanical analysis according to ASTM D4065-20 from −40 °C to 100 °C at 1 Hz is used to record the glass-transition temperature and damping factor tan δ; for polyurethane elastomers of this general type, the tan δ peak is typically located between −20 °C and 0 °C, so room-temperature damping relies on the plateau rather than the peak. Heat aging per ISO 188:2011 at 100 °C for 168 hours is performed on mounted specimens, and compression set is measured according to ISO 815-1:2019; if post-aging compression set exceeds 30%, the part must be redesigned with a lower local strain or a ribbed wall. Bonding to metal is performed with a two-component polyurethane adhesive after a solvent wipe with isopropyl alcohol and a 5-minute air dry; the bonded assembly is conditioned for 24 hours at 23 °C before mechanical loading. The terminal mount is used as a vibration isolator, not as a structural fastener; bending loads above 20 N or torsional loads above 5 N·m should be avoided unless the mount is reinforced. Published data for EPU 44 in continuous high-frequency vibration above 100 Hz is limited, so field validation on the motor assembly is required.
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Carbon Printers EPU 44 Biobased Elastomer for 3D Printing is a single-component photopolymerizable polyurethane resin formulated for Carbon Digital Light Synthesis platforms, including the M3, M3 Max, and L1 printer families. The uncured resin combines urethane acrylate oligomers, plant-derived polyol segments, reactive diluents, and photoinitiators. Exposure to 365 nm ultraviolet light through an oxygen-permeable build window produces a microphase-separated elastomer with Shore hardness typically between 78A and 82A when measured according to ASTM D2240-15. Renewable carbon content is quantified by ASTM D6866-21; the exact biobased fraction varies by production lot and is stated on the supplier certificate of analysis. The material is intended for repeated compressive or flexural loading applications, including gaskets, vibration isolators, cushioning lattices, conformal protective housings, and elastomeric hinges.
Because EPU 44 is supplied as a liquid photopolymer rather than a pre-formed sheet, mechanical qualification must be performed on printed and post-processed specimens. Standard test specimens follow ASTM D638-14 Type IV geometry. Tensile and tear specimens are printed in the XY plane at 2.0 mm thickness, washed in 99% isopropanol, thermally post-cured, and conditioned at 23 ± 2°C and 50 ± 5% relative humidity for 24 h prior to testing. Representative cured properties are shown in Table 1. These values are lot-qualification targets rather than guaranteed minima because the bio-based polyol fraction contributes to batch-to-batch variation in crosslink density, phase separation, and residual monomer content.
| Property | Test Method | Representative Value |
|---|---|---|
| Hardness | ASTM D2240-15 | 78–82 Shore A |
| Ultimate tensile strength | ASTM D638-14 | 7.5 MPa |
| Modulus at 100% strain | ASTM D638-14 | 4.8 MPa |
| Elongation at break | ASTM D638-14 | 300% |
| Tear strength, Die C | ASTM D624-00 | 24 kN/m |
| Compression set, 22 h at 70°C | ASTM D395-18 Method B | 18% |
| Rebound resilience | ASTM D2632-15 | 28% |
| Bio-based carbon | ASTM D6866-21 | 40% |
After printing on Carbon DLS equipment, green parts retain a surface layer of uncured resin. The standard post-processing sequence uses a two-stage solvent wash: first in 99% isopropanol at 25 ± 2°C for 10 min, followed by a second clean solvent bath for 5 min. Insufficient washing leaves a surface film that becomes tacky after UV post-cure; tactile tack is an indicator of residual acrylate monomer rather than under-cure of the bulk. Following solvent removal, thermal post-cure in a forced-air oven at 80°C for 8 h or 120°C for 2 h completes reaction of residual methacrylate groups. The lower-temperature schedule is preferred for parts with thin elastomeric hinges because it reduces oxidative surface embrittlement. The higher-temperature schedule improves compression set and chemical resistance but typically reduces elongation at break by 10–20% relative to the lower-temperature schedule. After post-cure, parts should cool to below 40°C before removal to minimize warpage in geometries with wall thickness variation greater than 3 mm.
The uncured resin exhibits shear-thinning behavior typical of urethane acrylate formulations. Brookfield viscosity measured at 25°C with a small-sample adapter at 10 s⁻¹ is commonly in the 2,000–5,000 cP range; the exact value is controlled by the relative concentration of bio-based polyol and low-viscosity monofunctional diluent. A viscosity below 1,500 cP can accelerate resin drainage from large vertical surfaces and produce under-filled sections. A viscosity above 6,000 cP increases the force required to recoat the build area and may cause release failures on the oxygen-permeable membrane. Carbon printer control software uses a force-sensing recoater system to indirectly monitor viscosity and will pause the build if coating force deviates more than 20% from the baseline. Production lines using M3 Max printers have observed increased force deviations when cartridges are stored below 20°C and installed without a 1 h warm-up to 25 ± 2°C. The same effect occurs when a cartridge is left open in humid shop air because absorbed moisture increases hydrogen bonding within the bio-based polyol phase and raises apparent viscosity.
In comparison with Carbon EPU 40 and EPU 41, the defining shift in EPU 44 is the introduction of bio-based carbon without changing the fundamental acrylate-terminated urethane cure chemistry. Relative to EPU 40, EPU 44 generally exhibits a comparable Shore A hardness range but a lower tear propagation resistance under ASTM D624 Die C; part-level validation is therefore necessary when replacing EPU 40 in elastomeric hinges or snap-fit retention features. Compared with fused filament fabrication TPU, EPU 44 is a thermoset after UV and thermal cure and cannot be reprocessed by grinding or re-extrusion. DLS parts also show reduced Z-axis anisotropy: tensile strength measured on ASTM D638-14 specimens printed in the Z orientation typically retains more than 80% of the XY value, whereas filament-printed elastomers often retain less than 50% when layer-to-layer fusion is incomplete. For silicone rubber replacement, EPU 44 provides a harder, machinable surface but does not match the high-temperature compression set resistance of peroxide-cured silicone elastomers tested at 150°C.
Compression set and hydrolytic stability control service life in static sealing applications. EPU 44, like other polyurethane elastomers, undergoes chain scission in hot water above approximately 60°C. Seals tested under ASTM D395-18 Method B show that compression set at 70°C for 22 h is typically below 20%, but the same property at 100°C for 70 h can exceed 45% depending on part thickness and post-cure state. Published data for this specific configuration is limited, so seals intended for continuous use above 80°C should be subjected to application-specific compression stress relaxation testing. In water-glycol environments, hydrolysis of ester or urethane linkages reduces elongation at break; after 1,000 h in 50/50 water/ethylene glycol at 80°C, retained tensile strength may fall below 60% of the unaged value. Gasket flanges should therefore avoid sharp internal radii below 0.5 mm and excessive compressive strain above 30%.
Printed lattice structures for protective equipment have been produced using cell sizes between 2 mm and 4 mm and strut thicknesses between 0.4 mm and 0.8 mm. The energy-return behavior of such lattice parts depends on relative density and post-cure thermal history. Lower post-cure temperatures near 80°C for 8 h generally preserve elongation at break, while higher temperatures near 120°C for 2 h increase crosslink density and reduce compression set at the expense of impact toughness. In footwear cushioning trials, dynamic mechanical analysis at 1 Hz indicates a glass transition below -30°C, and the material remains viscoelastic across the expected use-temperature range. Designers using lattice optimization software must impose a minimum wall thickness of 0.6 mm for reliable draining of uncured resin from closed cells; insufficient drain holes produce trapped liquid that later exudes and causes surface tack after post-cure.
Raw photopolymer and printed articles are regulated differently. The liquid resin is supplied with a safety data sheet that identifies hazardous components under 29 CFR 1910.1200 and EU REACH. Table 2 summarizes the principal compliance tests and applicable standard methods. Printed parts that contact human skin may require additional validation under ISO 10993-5 and ISO 10993-10; the supplier does not automatically provide biocompatibility certification for every batch.
| Compliance Check | Applicable Standard | Notes |
|---|---|---|
| Bio-based carbon content | ASTM D6866-21 | Test on cured article or liquid resin; report as fraction of total organic carbon |
| RoHS restricted substances | IEC 62321 series | Perform on homogenized cured sample; lead, cadmium, mercury, hexavalent chromium below applicable thresholds |
| REACH SVHC declaration | EU 1907/2006 Article 33 | Review SDS for candidate list substances at >0.1% w/w |
| Flammability | ASTM D635-18 or UL 94 HB | Applicable to enclosures; specimen thickness affects rating |
| Cytotoxicity | ISO 10993-5 | Test extract on L929 cells according to supplier protocol |
The material has defined operational boundaries that should not be exceeded without validation. Continuous service above 80°C in wet environments accelerates urethane hydrolysis; contact with strong bases, chlorinated solvents, or aromatic hydrocarbons can cause swelling beyond 10% by volume and loss of dimensional control. Parts should be shielded from long-term ultraviolet exposure unless a UV-stabilizing topcoat is applied because outdoor weathering under ASTM G154 may cause surface chalking and tensile strength loss. The resin cartridge should not be heated above 30°C during storage, and printed parts should not be post-cured in a conventional oven also used for food preparation. These boundaries are specific to EPU 44 as a bio-based polyurethane elastomer; they do not represent limitations of all Carbon resin grades.