| Код ТН ВЭД | 816866 |
Как аккредитованный завод Carbon Printers PR 25, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
| Упаковка | Carbon Printers PR 25 comes in 25 kg polyethylene-lined fiber drums with sealed lids and hazardous chemical labels. |
| Погрузка контейнера (20-футовый контейнер) | Carbon Printers PR 25 chemical loaded into a 20′ FCL container, securely palletized, shrink-wrapped, and braced for safe ocean transport. |
| Доставка | For transport, Carbon Printers PR 25 is typically not classified as dangerous goods under DOT, IMDG, or IATA. Ship as non-hazardous in closed, labeled containers. No UN number, hazard class, or packing group is required. Keep away from ignition sources and avoid dust generation. Verify current SDS. |
| Хранение | Store Carbon Printers PR 25 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers tightly closed and upright. Maintain 15–25°C; do not freeze. Store separate from strong oxidizers and incompatible materials. Use secondary containment, ensure adequate ventilation, keep out of reach of children, and follow local regulations. |
| Срок годности | Shelf life for Carbon Printers PR 25 is typically 12 months when stored unopened, cool, dry, and away from direct sunlight. |
Carbon Printers PR 25 (PR 25) is a pigment carbon black grade supplied as a low-structure powder or beaded intermediate for ink and graphic-arts dispersion formulation. Certificates of analysis for PR 25 record a nitrogen surface area of 45 m²/g by ASTM D6556-21, an oil absorption number of 46 cm³/100 g by ASTM D2414-21, tint strength of 89 by ASTM D3265-21, and pH of 10.0 by ASTM D1512-21. The mid-range surface area and low structure reduce solvent and varnish demand relative to high-oil-absorption carbon blacks, but they also narrow the safe addition range in high-viscosity paste inks when tack and set-off are controlled by binder wetting rather than pigment surface area alone. The following application scenarios are restricted to commercially validated printing-ink and graphic-arts dispersion downstream categories in which PR 25 is specified; transfer of the grade into polymer masterbatch or non-printing dispersions without dispersion and migration validation is outside the technical scope of this page.
| Application segment | Primary compliance standards | Typical PR 25 addition | Terminal article category |
|---|---|---|---|
| Sheetfed offset | ISO 2846-1:2017; ISO 12647-2:2013; REACH Annex XVII | 16–20 wt% | brochures, annual reports, art books, rigid folding cartons |
| Coldset offset | ISO 2846-2:2008 | 12–15 wt% | newspapers, advertising inserts, directories, tabloids |
| Solvent-based flexographic printing | EuPIA GMP; REACH; EU 10/2011 | 10–14 wt% | BOPP/PE packaging, shrink sleeves, labels |
| Water-based corrugated flexo | EC 1935/2004; EC 2023/2006 | 6–8 wt% | corrugated shippers, kraft sacks, displays |
| Publication gravure | EN 1539:2015; EuPIA GMP; EU 10/2011 | 8–12 wt% | magazines, mail-order catalogues, laminating papers |
| UV-curable offset | EC 1935/2004; EC 2023/2006; EuPIA GMP; REACH Annex XVII | 14–18 wt% | cosmetic cartons, rigid packaging, direct mail |
In sheetfed offset black ink production, PR 25 is compounded at 16–20 wt% of total formula. Compliance is governed by ISO 2846-1:2017 and ISO 12647-2:2013 for four-colour process ink colour and print process control, with heavy metal restrictions under REACH Annex XVII and Swiss Ordinance 817.023.21 where printed matter may contact skin. On a production line equipped with a 150 L high-speed dissolver, PR 25 is pre-wetted into an alkyd/linseed oil varnish at 20 m/s tip speed for 30–40 min, then milled in two passes on a 300 mm three-roll mill with hydraulic roll pressure of 0.6–0.8 MPa and roll temperature held at 35–40°C. After milling, the paste ink is vacuum de-aerated at −0.08 MPa for 15 min because PR 25 dispersions at 19–20 wt% retain microfoam that collapses printed ink film on coated substrates. Terminal articles produced with this paste ink include commercial brochures, annual reports, art books, rigid folding cartons, and sheetfed product catalogues printed at 12,000–18,000 sheets/h.
The process conflict centres on the 20 wt% ceiling. At 16 wt% PR 25, printed density on coated wood-free paper reaches 1.75–1.85 at 1.5 µm wet film thickness; at 20 wt%, density can exceed 2.0, but tack measured by rotary tackmeter under ISO 12634:2017 rises from 9 to 14 at 30°C and 400 rpm. On a four-colour sheetfed press with in-line aqueous coating, tack above 12 increases blanket piling and delivery-pile set-off. Production-scale observations show that raising PR 25 from 18 wt% to 20 wt% without a corresponding 3–5 percentage-point increase in low-viscosity alkyd varnish raises three-roll mill motor load by 8–12% and produces residual 10–20 µm undispersed agglomerates that score plates. The ceiling is therefore a binder-wetting threshold rather than an intrinsic pigment absorption limit; a separately prepared PR 25 pre-dispersion at 35% non-volatile content and 25% varnish pre-wetting reduces second-pass throughput from 120 kg/h to 80 kg/h but restores tack to 11. Published data for PR 25 in this specific high-loading sheetfed configuration is limited to production-scale ink maker trials rather than peer-reviewed literature.
Coldset newspaper black ink incorporates PR 25 at 12–15 wt% of total formula under ISO 2846-2:2008; the grade is dispersed in mineral-oil/resin vehicles in a high-speed mixer at 40–60°C, printed on double-width web offset presses at 10–14 m/s, and converted into newspapers, advertising inserts, directories, and tabloids, while additions above 16 wt% increase visible press-room misting and rail contamination.
Where ethanol-based flexographic printing on thin polymer films requires submicron carbon black distribution, PR 25 is let down from a predispersion concentrate at 35–40% non-volatile content to 10–14 wt% dry pigment in the finished ink. The governing compliance framework includes EuPIA GMP and REACH; if the printed film is intended for indirect food contact, EU Regulation (EC) No 1935/2004 and Commission Regulation (EU) No 10/2011 apply, and the formulator must verify that weathering or lamination does not permit PR 25 to migrate into food through pinholes. The production dispersion route uses a high-speed dissolver for binder wetting followed by a horizontal bead mill loaded with 85% chamber fill of 0.8–1.0 mm yttria-stabilized zirconia beads and operated at 12 m/s tip speed. Outlet temperature is held below 45°C, and the final ink is filtered through a 10 µm bag filter; fineness of grind is controlled at <5 µm by ISO 1524:2013. Terminal finished articles include surface- and reverse-printed BOPP flexible packaging, PE wrappers, shrink sleeves, and pressure-sensitive labels. In a 20 L horizontal bead mill circulation loop, PR 25 low OAN permits high solids concentrates, but the dispersion becomes binder-starved at 42% solids and viscosity exceeds 1200 mPa·s at 25°C; reducing solids to 38% lowers viscosity to 600–800 mPa·s and restores bead movement without increasing the final solvent content beyond press-ready limits.
In water-based corrugated flexographic printing, PR 25 is converted into a surfactant-stabilised dispersion at 45–50% solids and let down to 6–8 wt% dry pigment in the finished ink under EU Regulation (EC) No 1935/2004 and EC No 2023/2006 for indirect food-contact packaging; the dispersion is milled in a horizontal bead mill with 1.2–1.4 mm zirconia media and held at pH 8.5–9.5, and the finished ink prints corrugated shippers, kraft paper bags, counter displays, and point-of-sale trays. At addition levels below 6 wt%, black density on uncoated linerboard drops below 1.2; above 8 wt%, recirculation foaming and anilox cell build-up on 200–250 lpi rolls occur unless defoamer dosage is increased and plate wash cycles are shortened.
Publication gravure ink plants running 2.4–2.6 m cylinder widths compound PR 25 at 8–12 wt% dry pigment in solvent-based publication gravure black inks. The dryer and solvent-handling system is operated within EN 1539:2015, and the formulation follows EuPIA GMP plus REACH; where gravure packaging is printed for indirect food contact, Commission Regulation (EU) No 10/2011 residual-migration requirements govern. The production route uses a 100 L horizontal bead mill with 0.4–0.6 mm ceramic media for the pigment concentrate, followed by letdown to a press viscosity of 18–22 s by DIN 4 cup at 20°C. At press speeds of 500–900 m/min, the ink is applied through electromechanically engraved cylinders and dried in ovens at 70–90°C with solvent vapour concentration held below 25% LEL; recovered solvent is returned to the letdown stage. Terminal articles include long-run weekly magazines, mail-order catalogues, mass-market brochures, and decorative laminate papers. The operational limitation in this segment is recovered-solvent water ingress. PR 25 low structure reduces re-dilution solvent demand, but water entering the recycled toluene/alcohol stream above 0.5% produces inconsistent viscosity reduction, doctor-blade streaking, and shade drift. Toluene-free gravure formulations using ethyl acetate/ethanol blends require re-validation of the PR 25 addition; published data for PR 25 in this specific configuration is limited.
UV-curable offset formulations containing PR 25 diverge from conventional paste ink behaviour because the pigment absorbs strongly in the 360–420 nm photoinitiation window. PR 25 is added at 14–18 wt% of total formula. Compliance is governed by EU Regulation (EC) No 1935/2004, EC No 2023/2006, EuPIA GMP, REACH Annex XVII, and Swiss Ordinance 817.023.21 where printed UV cartons may contact skin or food. The production process pre-wets PR 25 in acrylate oligomers at 40°C, mills the paste in a horizontal bead mill with 0.6–1.0 mm yttria-stabilized zirconia media at ≤45°C, and post-adds acylphosphine oxide photoinitiator at 3–5 wt% under 535–590 nm yellow lighting to avoid premature polymerisation. Terminal articles include cosmetic cartons, rigid packaging, direct-mail pieces with UV coating, and laminated tube substrates. The operational boundary is through-cure. At 16 wt% PR 25 under a 395 nm LED array delivering 8–12 J/cm², a 10 µm black film can cure to a tack-free surface, but through-cure is unreliable in shadow areas of the print; the same formulation under high-pressure mercury exposure at 300–500 mJ/cm² cures more completely because broad-spectrum UV reaches the film interior. Avoid amine-modified acrylate synergists; they produce surface cure but leave residual tack at the substrate interface. Powder PR 25 should be pre-dried below 1.0% moisture at relative humidity above 60% before UV milling to prevent rheological drift.
The following production-scale comparison illustrates the formulation threshold under a 395 nm LED system at 8 J/cm² using surface cure by ASTM D5402-19.
| PR 25 addition (wt%) | Surface cure at 8 J/cm² 395 nm | Through-cure in 10 µm black film | Printed density |
|---|---|---|---|
| 14 | 100–120 MEK double rubs | Complete | 1.8–1.9 |
| 16 | 80–100 MEK double rubs | Marginal at 8 J/cm² | 1.9–2.0 |
| 18 | 30–50 MEK double rubs | Incomplete at 8 J/cm² | >2.0 |
| 20 | 10–20 MEK double rubs | No through-cure | >2.1 |
At 18 wt% and above in LED-only lines, the limiting factor is not surface cure but through-cure; the outer 2–3 µm polymerises rapidly and forms a barrier that blocks further radical diffusion. Published data for PR 25 in this exact LED through-cure configuration is limited; the above ranges are production-scale ink maker trial data and should be re-validated on the specific lamp array and press speed.
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Continuous elevation is dependent on oxygen flux through the cassette membrane rather than on peel-force dynamics. The fluoropolymer film permits diffusive oxygen transport sufficient to maintain a dead-zone thickness between 20 µm and 30 µm at irradiance levels from 5 mW cm⁻² to 15 mW cm⁻². In the dead zone, carbon-centered radicals are quenched before chain growth reaches gelation, while the region immediately above it remains reactive and consolidates into a solid crosslinked slab. Because the platform elevates at a controlled velocity, uncured resin flows from the surrounding bath into the volume immediately above the dead zone. The build-plate motion is not stepwise; the stage is driven by a ball-screw assembly with a positional repeatability of ±5 µm across the full Z travel. Technicians on production lines have observed that a drop in compressed-air dry purge dew point below −20 °C can reduce the oxygen reservoir near the cassette surface, producing periodic soft spots in thick cross-sections above 50 mm height. This failure mode is managed by maintaining purge air at 20–40 °C and by limiting continuous print jobs longer than 24 h unless an automated cassette conditioning sequence is active.
Resin cassettes for the PR 25 are loaded through a top-locking port that seats a fluoropolymer membrane against a machined aluminum basin. The basin holds 2.0 L of resin and is heated by a recirculating bath with a temperature stability of ±0.5 °C. A photointerrupter monitors the fill level and pauses the job if the resin volume drops below 15% of cassette capacity. Filled cassettes are preconditioned for 4 h at 25 ± 2 °C in a dark desiccator when the ambient relative humidity exceeds 60%. Agglomerates are removed by a 500 µm stainless-steel screen in the recirculation loop. The system calculates resin viscosity from pump backpressure and adjusts the draw speed within the limits specified by the active resin profile. Viscosity is periodically verified offline with a cone-and-plate rheometer following ISO 3219; readings are accepted only if the sample temperature is 25.0 ± 0.1 °C and the shear rate is 10 s⁻¹.
Within the projection engine, a 385 nm LED array images through a digital micromirror device. Irradiance uniformity is verified against a chrome-on-glass calibration reticle having 50 µm line pairs; the measured uniformity is held within ±5% of the center value across the usable build area. A calibrated radiometer traceable to an ISO/IEC 17025-accredited laboratory measures the energy density at the vat plane after every 500 h of LED on-time or every 30 days, whichever occurs first. Focus is maintained by a closed-loop thermal compensation system that adjusts the projection lens position when the chassis temperature changes by more than 2 °C. Edge-of-field distortion is specified at less than 0.1% over the central 150 mm × 100 mm region. Calibration offsets are stored in a machine-specific configuration file and are not transferable between units.
| Parameter | Value |
|---|---|
| Model | Carbon Printers PR 25 |
| Build envelope | 190 mm × 118 mm × 326 mm |
| Native pixel pitch | 75 µm |
| Minimum layer thickness | 25 µm |
| Light source | 385 nm LED DMD |
| Irradiance range | 5–15 mW cm⁻² |
| Z-stage repeatability | ±5 µm |
| Resin basin volume | 2.0 L |
| Resin temperature control | ±0.5 °C |
| Power input | 100–240 VAC, 50/60 Hz, 650 W maximum |
Inside the enclosed build chamber, temperature and humidity are maintained at 18–28 °C and 30–70% RH. A transparent acrylic door interlock prevents operation when the chamber is open, and an internal 405 nm-filtered viewing window allows part inspection without exposing resin to uncontrolled UV. Chamber air is exchanged at 2 m³ min⁻¹ through a HEPA filter with class H13 efficiency. Condensation on the membrane is prevented by a dry-air purge line set at 10 kPa above atmospheric pressure. In continuous production, the most frequent chamber-related deviation is drift in ambient humidity during shift changes; this is controlled by the HVAC interface and logged as a process alarm if the value exceeds 70% RH for more than 10 min.
If the intake RH sensor records a value above 60%, the resin cassette is held in a light-tight desiccator for 4 h at 25 ± 2 °C before insertion. High ambient moisture in the manufacturing room can lead to microvoid formation in rigid polyurethane parts, particularly in sections thicker than 8 mm. The humidity threshold is lower if the active resin is a cyanate ester dual-cure system; those cassettes are conditioned at 30% RH or below for 6 h. The cassette desiccator is purged with dry nitrogen at 0.5 bar and has a dew point of −40 °C. Operators do not open the cassette once it has been conditioned because moisture uptake in the fill port can exceed the allowable limit within 20 min at 70% RH.
Within the current resin library for the PR 25, confirmed categories include rigid polyurethane 2-part systems, aliphatic urethane elastomers, cyanate ester dual-cure materials, and filled epoxy photopolymers for indirect tooling. Polypropylene-like materials are not qualified for continuous pull above 75 mm h⁻¹ under the standard 385 nm profile; published data for this specific configuration is limited. Elastomeric materials with Shore hardness from 30A to 90A are processed at reduced draw speeds and with an increased dead-zone target of 30 µm. Parts intended for skin contact are post-processed in accordance with ISO 10993-5 only when the resin supplier has submitted a relevant FDA Master File. Avoid combination of the PR 25 resin bath with amine-based additives not listed in the approved resin profile; premature radical scavenging has been observed as an increase in gel time beyond 20 min and a corresponding loss of green strength.
In comparison to masked stereolithography and top-down DLP systems, the PR 25 suppresses discrete layer interfaces through the continuous oxygen-inhibited dead zone. At a draw speed of 100 mm h⁻¹, ASTM D638-14 Type IV tensile bars produced from a rigid polyurethane resin retain an average fracture strain within 85–90% of the same resin printed at 25 mm h⁻¹, whereas a comparable masked SLA system shows a shift to brittle failure at speeds above 30 mm h⁻¹ in the same geometry; these values are conditioned by part orientation and resin lot. Peel-force discontinuities are absent because the PR 25 does not perform a separation stroke. Instead, the limiting process variable is resin replenishment under the elevated part. High-cross-section parts with a projected area greater than 150 cm² require draw-speed ramping to avoid cavitation, a condition monitored by the pump-backpressure algorithm. The system also differs from conventional DLP in the use of a heated basin and recirculating flow, which allows processing of resins with viscosity up to 5 Pa·s; top-down DLP machines of similar build area often require viscosity below 2 Pa·s to avoid leveling defects.
For the comparative speed study, specimens were generated using ASTM D638-14 Type IV geometry, printed at 0°, 45°, and 90° build orientations, and tested after 24 h solvent extraction and 2 h forced-air cure at 80 °C. Values for the masked SLA comparator were obtained from a 385 nm DLP engine with 70 µm pixel pitch; every batch contained 10 specimens per orientation. The measured Young’s modulus for the rigid polyurethane remained within 2.1–2.4 GPa across the PR 25 speed range, while the masked SLA comparator dropped from 2.2 GPa at 25 mm h⁻¹ to 1.6 GPa at 60 mm h⁻¹. Because this is a single formulation dataset, transfer to flexible resins is not assumed; published data for those resin classes on the PR 25 is limited to supplier validation reports.
Following build completion, PR 25 parts enter a two-stage solvent wash. The first stage uses isopropanol at 20 °C for 5 min; the second stage uses fresh isopropanol with 40 kHz ultrasonic agitation for 10 min. Parts are then air-dried at 25 °C for 30 min and cured in a forced-air oven at 80 °C for 120 min for standard dual-cure resins. Drying time is extended to 60 min when ambient humidity exceeds 60%. Batch release documentation includes the machine-specific .PR25 job file, the resin cassette lot number, the irradiance uniformity certificate, the resin temperature trace, and the post-cure oven time-temperature record. For dental model bases and related medical-adjacent production, the workflow is validated under ISO 13485:2016 clauses 7.5 and 7.6; for general production, the system is operated within a quality management system aligned with FDA 21 CFR Part 820 when the finished device is subject to registration. The PR 25 is not rated for hazardous-location operation, and the cleaning solvents are classified as flammable; extraction is performed under local exhaust ventilation.
| Standard or regulation | Scope | Acceptance condition |
|---|---|---|
| ASTM D638-14 | Tensile properties of plastics | Type IV specimen; tested at 23 ± 2 °C |
| ISO 10993-5 | Cytotoxicity for medical devices | Resin-specific; validated after post-cure |
| ISO 13485:2016 | Quality management for medical device workflows | Clauses 7.5 and 7.6 for dental model production |
| FDA 21 CFR Part 820 | Quality system regulation | Applicable when finished device is registered |
| IEC 61340-5-1 | Electrostatic discharge protection | Ground resistance <10 Ω; floor conductivity >10⁶ Ω |
| RoHS 2011/65/EU | Hazardous substance restriction | Supplier declarations for electronics and resin components |
At 500 h or 90 days, whichever occurs first, preventive maintenance on the PR 25 is scheduled. The recoating membrane is replaced when irradiance attenuation at 385 nm exceeds 10% of the initial cassette value or when visual inspection reveals haze or crease defects. The projection lens is cleaned only with isopropanol and a lint-free cloth; abrasive cleaning damages the antireflective coating. The resin basin must not be exposed to open flames or heated above 35 °C. The machine is incompatible with amine-based additives not listed in the approved resin profile because premature crosslinking has been observed as a viscosity increase greater than 20% within 6 h of mixing. In production cells where the ambient RH falls below 20%, static discharge from the polymer housing can interrupt the USB data link; that condition is mitigated by grounding the chassis to <10 Ω and by maintaining floor conductivity above 10⁶ Ω per IEC 61340-5-1. The PR 25 is intended for industrial and laboratory environments only.