| Код ТН ВЭД | 484317 |
Как аккредитованный завод Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
| Упаковка | Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament, 1 kg spool, vacuum-sealed in foil with desiccant, in labeled box. |
| Погрузка контейнера (20-футовый контейнер) | 20′ FCL container loading: palletized Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament spools secured, moisture-protected, and evenly distributed. |
| Доставка | Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament ships as a non-hazardous article. Each spool is vacuum-sealed with desiccant, boxed for protection, and transported via standard parcel or freight. No UN number, hazard class, or special handling is required. Store in a cool, dry area. |
| Хранение | Store Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament in a cool, dry, well-ventilated area, away from heat, sparks, open flames, and direct sunlight. Keep in sealed, moisture-barrier packaging or airtight containers with desiccant. Maintain moderate room temperature and low humidity. Avoid contact with strong oxidizers, static discharge, and incompatible materials. Follow manufacturer’s recommendations and local regulations. Store separately from food. |
| Срок годности | Typically 12 months when unopened in original packaging, stored cool and dry, away from moisture, heat, and UV light. |
For automotive wire-harness bracket trials, Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament is dried in a forced-air hopper dryer at 80 °C for 4 h to reduce residual moisture below 0.05 wt%. Deposition on a Cartesian gantry extruder with a 0.4 mm hardened brass nozzle is conducted at a melt setpoint of 240 °C, a glass build plate at 105 °C, and an enclosed chamber at 50–60 °C. Layer height is held at 0.16 mm, perimeter count at 4, and gyroid infill at 85% to stabilise snap-fit bosses and clip retention geometry. Warp-induced dimensional drift in the z-axis becomes measurable above build heights of 25 mm because bulk ABS shrinkage of 0.7–0.9% creates residual tensile stress at the part perimeter; a 10 mm brim and rounded corner radii above 3 mm are specified to suppress corner delamination. Conditioned test coupons printed in the x-y plane typically exhibit tensile yield in the 28–35 MPa range when tested per ASTM D638-14, while z-axis tensile values are commonly reported at 50–60% of in-plane strength; clip retention features are therefore oriented parallel to the build bed. Long-term underhood exposure to distilled water and 50 vol% ethylene glycol at 60 °C can be screened using ASTM D543 immersion for 7 d; published data for this specific Clariant black ABS filament under hot Diesel exhaust gas recirculation condensate is limited. Terminal components include routing clips, relay-box mounting brackets, and strain-relief retainers validated on engine compartment mock-ups before mould tooling release.
CNC job-shop workholding fixtures require a deposition profile that prioritises interlayer fusion over fine surface finish: the filament is run through a 0.6 mm nozzle at 250 °C with a bed temperature of 110 °C, active layer cooling disabled after the first 5 layers, and layer height set to 0.30 mm to accelerate large-body deposition. Infill density is held at 40% cubic, with 5 top and bottom solid layers and 3 perimeters. Printed quench fixtures for a VMC are annealed at 85 °C for 2 h in a convection oven and allowed to cool at 0.5 °C/min to prevent thermal warping during stress relaxation. Locating bores are reamed to H7 tolerance after annealing because as-built ABS bores typically show ±0.10 mm deviation on diameters below 10 mm. The anisotropic strength envelope is the controlling process conflict: published comparative datasets for FDM ABS indicate in-plane tensile strength in the 30–38 MPa range under ISO 527-2:2012, while vertical ligament strength falls to approximately 50% of in-plane values. Clamping force is therefore limited to 1.5 kN per M6 threaded insert, and inserts are installed after annealing with press-fit clearance of 0.05 mm. Final components include drill-jig plates, CMM holding fixtures, and temporary soft-jaw inserts for low-volume lathe turning. Dimensional inspection is referenced to ISO 2768-1 class m for non-critical features, while critical bores are verified against ISO 286-2 limit gauges.
Enclosure bodies for DIN-rail power supplies and IoT gateways are printed as shell-and-lid pairs with 0.2 mm layer height, 3 perimeters, and 30% triangular infill; bosses for snap-fits are filled to 100% local density. Compliance of a standard ABS enclosure is limited to UL 94 HB at 3.0 mm; the black pigmentation does not promote a V-2 rating, and ignition-sensitive components therefore require internal metal sub-panels. Glow-wire testing under IEC 60695-2-11 must be repeated for the specific printed wall thickness, because void architecture at 30% infill changes the heat conduction path relative to solid injection-moulded plaques. For low-temperature service, notched Izod impact of ABS tested under ASTM D256-10 declines with temperature; suppliers frequently cite 200–350 J/m at 23 °C, but published data for this filament at −30 °C is limited. Enclosures are therefore screened against IEC 60068-2-1 operational cold soak at −20 °C before use. The black colour improves optical opacity for light-emitting indicator segregation, but UV stability is not equivalent to ASA; outdoor deployment requires a UV-stable coating or black ASA co-polymer. Terminal products include deadfront operator panels, terminal covers, and sensor-housing bodies for indoor industrial networks.
When a water-glycol pump volute iteration is moved from machined nylon to black ABS printing, the spiral passage is split along the impeller centreline and printed with 0.18 mm layer height, 4 perimeters, and 100% rectilinear infill to reduce internal void communication during pressure testing. The build plate is set to 100 °C, the nozzle to 245 °C, and the part is oriented with the casing face parallel to the xy plane so that hydrostatic test pressure loads the strongest build direction. After machining joining faces flat, acetone vapour smoothing is performed at 45 °C for 3 min in a sealed chamber; radial clearance change after smoothing is typically 0.10–0.20 mm on curved volute walls, so bearing bores and seal counterbores are reamed after surface treatment. Chemical compatibility is narrow: ethylene glycol/water mixtures up to 50 vol% at 60 °C are acceptable for short-duration screening, while aromatic hydrocarbons, ketones, and ester-based bio-lubricants cause stress cracking and must be excluded from the test loop. Final printed prototypes are used for flow visualisation and cavitation onset trials at pressures below 1.0 bar; they are not intended for potable water contact because published migration data for this black ABS formulation under FDA 21 CFR 177.1020 is not established.
Thick-walled black ABS grips for corded power tool housing iterations are built with a 0.6 mm nozzle, 0.25 mm layer height, and variable infill: 80% gyroid in the hand-grip core, 100% triangular infill under M3 screw bosses, and 5 perimeters on all exterior surfaces to prevent breakout during post-print sanding. Bed adhesion at 110 °C and chamber preheat at 45 °C are held for the first 15 min before deposition to reduce curling in the long-axis direction. After support removal, the shell is sealed with a two-part polyurethane primer and wet-sanded with 600-grit abrasive before topcoat. Solvent compatibility is the key downstream risk: some automotive primers contain aromatic hydrocarbons that can induce microcrazing in unstressed ABS bosses; a xylene-free primer is specified, and pull-out strength of inserted brass inserts is checked after 24 h at 23 °C. Compliance for the prototype assembly is assessed under RoHS 2011/65/EU Annex II and REACH 1907/2006 SVHC candidate-list screening; no food-contact or skin-contact claims are attached. Final components are full-scale ergonomic mock-ups for drop, grip-force, and ingress-protection tunnel evaluations before steel tooling sign-off.
Vacuum forming tool cores for low-volume HIPS and PETG packaging prototypes are printed as hollow shells with 6 perimeters, 25% hexagon infill, and 0.2 mm layer height using a nozzle setpoint of 235 °C and bed at 105 °C. The upper forming face is sealed with a two-part epoxy coating to close the inherent 0.2–0.4 vol% interlayer void fraction observed in as-printed ABS. The process-temperature conflict is severe: measured heat deflection temperature for bulk ABS under 0.455 MPa load is approximately 98 °C per ASTM D648-18, while HIPS sheet enters the form box at 160–180 °C. The printed tool can survive short intermittent contact only if the face temperature is pulled back by forced-air jets and aluminium heat-sink rails embedded in the shell; continuous contact exceeds the tool’s dimensional stability envelope and causes creep in the cavity floor after 30–50 cycles. Published data for this specific Clariant ABS black filament under cyclic vacuum-forming loads is limited; commissioning is restricted to 10–20 trial pulls with inspection of cavity width against a CMM reference. Final outputs are cavity plugs used to produce low-volume PETG trays for electronics packaging development, not production thermoforming.
For benchtop analytical instruments, the filament is printed at 0.12 mm layer height with 3 perimeters and 30% gyroid infill to produce light-tight enclosure shells with minimal mass. The chamber is maintained at 55 °C and the bed at 100 °C; after deposition, the outer surface is dry-sanded and acetone vapour polished at 40 °C for 2 min to reduce stray-light scattering from interlayer ridges. Optical sealing is evaluated with a white LED source inside the shell and a photodiode outside; the black ABS material is opaque at wall thicknesses above 1.2 mm. Compliance for laboratory use is confined to RoHS 2011/65/EU and general flammability screening under UL 94 HB; no claim of IEC 61010-1 electrical enclosure compliance is made unless the printed shell is mounted around an existing metal chassis. Final parts include lamp-housing covers, detector shields, and cable-management shrouds for fluorescence and absorbance readers. The main processing boundary is residual acetone uptake after vapour smoothing: assemblies are forced-air conditioned at 50 °C for 6 h to reduce retained solvent before optical components are installed.
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Clariant Acrylonitrile Butadiene Styrene Black 3D Printer Filament is supplied as a rigid, carbon black-pigmented terpolymer monofilament for fused filament fabrication. Nominal spool formats include 1.75 mm and 2.85 mm diameters, with roundness and ovality tolerances controlled within ±0.05 mm by laser micrometry during winding. The feedstock is moisture-sensitive because the acrylonitrile phase absorbs atmospheric water; storage at 20 °C and 40 % RH limits equilibrium moisture to below 0.1 wt%. The black pigmentation is produced by dispersing a carbon black masterbatch into the ABS melt during compounding, which modifies surface resistivity and opacity without forming a separate coating layer.
Extrusion temperatures from 230 °C to 250 °C are used for 0.4 mm brass or hardened steel nozzles, with bed temperatures from 90 °C to 110 °C on PEI or ABS-polycarbonate hybrid build surfaces. Melt viscosity under shear rates of 10²–10³ s⁻¹ permits linear print speeds between 30 mm/s and 60 mm/s. Exceeding 60 mm/s without raising nozzle temperature above 250 °C can produce under-extrusion in direct-drive systems with 0.4 mm orifices. A heated enclosure held at 60–70 °C reduces delamination in tall geometries by lowering the cooling rate below the glass transition temperature of approximately 105 °C.
Carbon black influences thermal and electrical behavior. At loadings below 2 wt%, the pigment raises ultraviolet resistance by absorbing incident radiation but can lower volume resistivity relative to natural ABS, which is relevant for electrostatic dissipative applications. The exact resistivity depends on dispersion quality and carbon black grade; published data for this specific Clariant configuration is limited. Carbon black does not form a semicrystalline phase, so the amorphous character of ABS is retained. The glass transition temperature remains near 100–110 °C, but the black surface can read differently on infrared pyrometers because of emissivity changes, so contact thermocouples provide more reliable bed-temperature verification.
Corner lifting in amorphous ABS parts is governed by differential thermal contraction between the extruded road and the build surface. Unfilled ABS exhibits linear mold shrinkage of 0.4 % to 0.7 % per ISO 294-4:2018, and FFF parts can display in-plane shrinkage from 0.3 % to 0.8 % depending on raster angle. Enclosure temperatures below 70 °C create a thermal gradient across the z-axis; once a part exceeds 15 mm in z-height, accumulated stress at the interface may exceed adhesion of untreated glass or bare aluminum. Use of PEI film, polycarbonate sheet, or ABS slurry on borosilicate glass raises practical adhesion. For full-bed parts with an aspect ratio above 4:1, reducing first-layer speed to 15 mm/s and increasing first-layer width to 150 % of nozzle diameter reduce edge peel without introducing elephant-foot artifacts.
Comparative distinction of Clariant ABS black filament from PLA, PETG, and compounded ABS grades appears in solvent resistance, thermal softening, and failure mode. PLA exhibits lower thermal resistance and brittleness after moisture exposure, while PETG shows higher elongation but lower modulus and greater stringing tendency. The styrene-acrylonitrile matrix in ABS gives resistance to dilute aqueous acids and bases and to nonpolar hydrocarbons, but stress cracking occurs in ketones, esters, and aromatic solvents. Within ABS grades, the black variant differs from natural ABS primarily in colorant loading and ultraviolet screening; mechanical properties may remain within the standard deviation of unfilled ABS when the carbon black masterbatch is well dispersed below 2 wt%.
Moisture in ABS feedstock volatilizes at extrusion temperatures, producing steam splay, reduced interlayer fusion, and diameter swell at the nozzle. Drying at 80 °C for 4–6 h in a desiccant dryer with a dew point below −20 °C lowers moisture to below 0.1 wt%; spools left at 60 % RH recover moisture within 24–48 h. On multi-head production systems with Bowden tubes longer than 500 mm, moisture uptake after drying can be detected as first-layer width variation exceeding 0.05 mm when measured by optical comparators. Vacuum drying at 70 °C for 6 h is an alternative where desiccant beds are unavailable. Avoid drying above 90 °C for extended periods because the butadiene phase is susceptible to thermo-oxidative yellowing and surface degradation.
Applications in functional prototyping, jigs, fixtures, and low-volume manufacturing are constrained by the amorphous thermal response. Parts loaded continuously above 80 °C can creep; polycarbonate or polyamide may be required above that threshold. For dimensional verification, compensation factors can be derived from first-article measurements on a coordinate measuring machine and then applied to the CAD model. The black surface provides contrast for optical scanning, but carbon black pigmentation can interfere with capacitive touch sensing where surface resistivity falls below 10¹¹ Ω/sq.
| Property | Test method | Representative range |
|---|---|---|
| Density | ISO 1183-1:2019 | 1.03–1.07 g/cm³ |
| Melt flow rate | ISO 1133-1:2022 at 220 °C/10 kg | 5–20 g/10 min |
| Tensile yield stress | ISO 527-2:2012 | 35–50 MPa |
| Tensile modulus | ISO 527-2:2012 | 1.8–2.5 GPa |
| Notched Izod impact at 23 °C | ISO 180/A:2019 | 15–35 kJ/m² |
| Flexural modulus | ISO 178:2019 | 1.6–2.4 GPa |
| Heat deflection temperature at 1.82 MPa | ISO 75-2:2013 | 85–105 °C |
| Vicat softening temperature B50 | ISO 306:2013 | 95–110 °C |
| Mold shrinkage parallel | ISO 294-4:2018 | 0.4–0.7 % |
| Moisture absorption 24 h | ISO 62:2008 | 0.3–0.8 % |
First-article dimensional compensation is performed by measuring a hollow calibration cube with a coordinate measuring machine and comparing X-Y side-wall positions to the CAD model. For a 25 mm cube printed at 0.2 mm layer height, in-plane deviation from CAD often remains within ±0.15 mm when shrinkage is compensated, while z-axis deviation is governed by first-layer compression and can be corrected by adjusting the initial layer offset. Batch-to-batch variation in black ABS lots can shift this offset by 0.03–0.06 mm if the pigment masterbatch changes melt viscosity; therefore, revalidation on each new spool lot is required for gauge fixtures.
Regulatory position for Clariant ABS black filament should be confirmed from the supplier’s safety data sheet and REACH SVHC declaration. RoHS 2011/65/EU compliance applies only to electrical and electronic equipment and does not automatically follow from the base polymer; antimony-free or halogen-free additives may be required where fire ratings are specified. The product is not supplied as a food-contact material unless an FDA 21 CFR Part 177.1020 letter is explicitly issued for the specific grade. Storage under ultraviolet radiation is acceptable due to carbon black, but prolonged contact with aqueous sodium hypochlorite above 0.5 % concentration can cause surface etching.
FFF parts from black ABS are orthotropic rather than isotropic. Tensile specimens printed with 0° raster orientation show higher longitudinal tensile strength than those printed at 90°; the difference commonly reaches 15–30 % in unfilled ABS. Layer-to-layer fusion strength depends on contact temperature and wetting time. Slow print speeds below 30 mm/s allow the incoming road to reheat the previous layer above the glass transition, but excessive dwell can introduce surface texture artifacts. The carbon black grade may lower surface gloss but does not change the fundamental layer-boundary weakness. Notched Izod specimens tested per ISO 180/A:2019 can produce misleadingly high values for FFF parts with crack propagation along layer interfaces; fracture toughness measured across z-layers is commonly lower than in-plane values by a factor of 2–3.
Compatibility with process auxiliaries is limited. Cleaning agents containing acetone, methyl ethyl ketone, toluene, or chlorinated hydrocarbons attack the styrene-acrylonitrile phase and cause microcracking at layer interfaces. Use isopropyl alcohol with wipe drying for build-surface degreasing; isopropyl alcohol does not dissolve ABS but may leave a monolayer that reduces bed adhesion on PEI if not evaporated. For support removal, petroleum-based lubricants that contain esters are not recommended. These restrictions are particularly important for black parts used in optical inspection, where surface microcracking from solvent exposure may be mistaken for material contamination.
Ventilation during printing is required because ABS emits styrene, acrylonitrile, and butadiene-related volatile organic compounds at processing temperatures. Local exhaust ventilation with a capture velocity of 0.5 m/s at the nozzle is recommended, or an enclosure with activated carbon filtration. Operators should monitor airborne styrene against occupational exposure limits; typical process emissions remain below the short-term exposure limit only when continuous ventilation is maintained. The black filament should be stored sealed with desiccant after opening to prevent spool-to-spool moisture variation. Purge blocks and rejected parts should be disposed of according to local styrene emission regulations.