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Clariant Acrylonitrile Butadiene Styrene, White 3D Printer Filament

    • Название продукта: Clariant Acrylonitrile Butadiene Styrene, White 3D Printer Filament
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
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    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Спецификации
    Код ТН ВЭД 563427

    Как аккредитованный завод Clariant Acrylonitrile Butadiene Styrene, White 3D Printer Filament, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

    Упаковка и хранение
    Упаковка Vacuum-sealed foil pouch containing one 1 kg spool of white Clariant ABS 3D printer filament, with desiccant and labeled box.
    Погрузка контейнера (20-футовый контейнер) 20′ FCL container loading of Clariant Acrylonitrile Butadiene Styrene White 3D Printer Filament, palletized and secured for export.
    Доставка Clariant Acrylonitrile Butadiene Styrene, White 3D Printer Filament is a non-hazardous, non-regulated solid polymer. Ship in sealed spools or moisture-barrier bags, cushioned to prevent damage. Keep dry, away from heat, sunlight, and static. Use original packaging, label clearly, and transport at ambient temperature. No special placards or emergency response required.
    Хранение Store Clariant Acrylonitrile Butadiene Styrene, White 3D Printer Filament in a cool, dry, well-ventilated area away from heat, flames, sparks, and strong oxidizers. Keep sealed in its original packaging or an airtight container with desiccant to prevent moisture absorption. Protect from direct sunlight, dust, and physical damage. Maintain moderate temperature and low humidity. Follow local regulations and manufacturer guidance.
    Срок годности Clariant ABS White filament shelf life: typically 12–24 months if sealed, cool, dry, and protected from moisture, heat, and UV light.
    Применение Clariant акрилонитрил бутадиен стирол, белая нить 3D-принтера

    Within tier-one automotive prototype validation cells, Clariant Acrylonitrile Butadiene Styrene, White 3D Printer Filament is processed on enclosed industrial FFF platforms fitted with 0.4 mm hardened steel nozzles, 110 °C borosilicate beds, and active chamber heating at 70 °C. The material is removed from vacuum-sealed desiccant packaging, dried at 80 °C for 4 h to a target moisture below 0.02 wt%, and re-dried whenever open-spool exposure exceeds 8 h at 55 % RH. Compliance anchors for this segment include ISO 527-2:2012 for tensile yield and tensile modulus, ISO 75-2:2013 Method A at 1.8 MPa for heat deflection temperature, FMVSS 302 for interior material flammability, and ISO 179-1/1eU for unnotched Charpy impact. Formulation addition ratio is 100 wt% virgin Clariant ABS white; regrind from failed prints is tolerated up to 15 wt% only for non-visible mounting brackets and only after melt-flow verification against ISO 1133-1:2022. Downstream processing uses 0.16 mm layer height, 255 °C nozzle temperature, 45 mm/s print speed, and a cooling fan limit of 20 %, followed by acetone vapor smoothing at 55 °C for 20 min and dry sanding with P400–P800 paper before urethane primer application. Terminal product types are HVAC duct fit-check masters, instrument panel bezel prototypes, seat switch bezel blanks, and door card clip test fixtures. Continuous service is limited to 85 °C; underhood exposure above this threshold falls outside the material’s validated creep resistance envelope.

    What Regulatory Test Stack Applies to Printed White ABS Housings for Networked Equipment?

    Pre-compliance networking equipment builds require white ABS filament that can be printed at 0.12 mm layer height on dual-gear direct-drive extruders without excessive screw pullback. In this segment, Clariant ABS white is run at 250 °C nozzle temperature, 100 °C bed temperature, and 40 mm/s perimeter speed with external part cooling disabled on the first 4 layers. The applicable test stack is IEC 62368-1:2023 for audio/video and ICT equipment safety, UL 94 HB at 3.0 mm thickness, IEC 60695-2-11 for glow-wire flammability where specified by end-product certification, and Directive 2011/65/EU RoHS Annex II for lead, mercury, cadmium, hexavalent chromium, PBB, and PBDE restrictions. Formulation addition ratio permits 20 wt% clean in-house ABS regrind in non-cosmetic inner carriers, while visible exterior shells use 100 wt% virgin filament to avoid pigment streaking. Two-part enclosure assembly uses solvent welding with 15 wt% white ABS shavings dissolved in a 60:40 MEK/acetone mixture at 23 ± 2 °C; threaded brass inserts are heat-staked at 180 °C with a dwell of 8 s. Terminal product types include router upper and lower shells, IoT hub wall-mount enclosures, rack-mount blanking panels, and debug access covers for PCB fixtures. Creepage and clearance distances are not treated as final certification evidence without approved UL tests on the exact printed build orientation.

    Dimensional Stability Boundaries for Printed ABS Fixture Bodies

    Printed fixture bodies made from Clariant ABS white are used where chemical resistance and low mass reduce operator fatigue but where tolerance drift must remain within ±0.25 mm across 300 mm spans. Production-scale experience on enclosed industrial FFF systems shows that the dominant failure mode is corner lifting when chamber temperature falls below 60 °C; adhesion is maintained with a 10 wt% ABS slurry in acetone on borosilicate glass. Regrind re-extrusion for internal fixture components is processed on a co-rotating twin-screw extruder with L/D 32:1 and strand pelletization before re-spooling. Compliance anchors are ISO 2768-mK for general tolerances, ISO 604:2002 for compressive modulus, and ASTM D695-15 for compressive strength. Formulation addition ratio uses epoxy surface infiltration at 5 wt% of part mass to seal interlayer porosity; the addition must not exceed 8 wt% because higher levels create brittle surface crack propagation under point loads. Downstream processing includes printing at 0.2 mm layer height, 35 % rectilinear infill, 4 perimeter shells, nozzle temperature 245 °C, bed temperature 105 °C, and no active cooling fan, followed by annealing at 80 °C for 2 h in a circulating air oven. DIN 912 steel bushings are installed at wear contact points by press fit or adhesive. Terminal product types include CMM holding nests, assembly press jigs, routing templates, and probe calibration stands. Dynamic torsional validation is required before deployment; published data for FFF-processed ABS torsional limits under cycling is limited.

    Compliance matrix for downstream white ABS filament applications
    Application areaStandard codeTest conditionTypical published ABS range/status
    Automotive interior prototypesISO 75-2:2013 Method A1.8 MPa flatwise, 120 °C/h85–95 °C heat deflection temperature
    Networked device enclosuresUL 94 HB3.0 mm thicknessHB at 3.0 mm
    Industrial fixturesISO 604:20021 mm/min compression1,800–2,200 MPa compressive modulus
    Investment casting patternsISO 8062-3:2007Dimensional tolerance classPublished data for printed ABS patterns limited
    Thermoforming toolingISO 527-2:201250 mm/min tensile40–50 MPa tensile yield
    Medical anatomical modelsISO 10993-5:2009L929 extract cytotoxicityConfiguration-dependent; non-contact only

    In low-volume investment casting foundries that produce non-ferrous pump and manifold prototypes, white ABS filament is printed as a sacrificial pattern and is later oxidized in the ceramic shell preheating ramp. The pattern is printed at 0.15 mm layer height, 240 °C nozzle temperature, and 100 °C bed temperature with active cooling disabled; internal fill is 10 % gyroid to reduce thermal expansion during shell firing and to permit shell drainage. Formulation addition ratio is 100 wt% virgin ABS white, with 0 wt% regrind, because recycled polymer can shift ash composition and create gas porosity. External surface sealing uses an acrylic lacquer at 5 wt% of pattern mass. Compliance for final casting geometry is anchored to ISO 8062-3:2007 general tolerances; no ISO standard governs polymer pattern ash residue, so foundry-specific thermal gravimetric analysis per ASTM E1131-08 is used to validate the burnout ramp. Downstream ceramic shell production applies alternating zircon-based slurry and 200 μm fused-silica stucco coats, followed by a controlled burnout ramp not exceeding 0.5 °C/min to 650 °C with a 2 h hold. Terminal products include aluminum intake manifold prototypes, stainless steel impeller housings, and bronze architectural hardware patterns. Published data for white-pigmented ABS ash residue in this configuration is limited; each foundry should validate the burnout profile by TGA before serial casting.

    When White ABS Tooling Plugs Replace Machined Urethane Boards

    Short-run thermoforming tools using Clariant ABS white plugs are constrained by mold surface temperature below 70 °C and heated sheet contact duration under 10 s per cycle. The tooling plug is printed at 0.3 mm layer height with 20 % honeycomb infill and 3 perimeter shells, using nozzle temperature 250 °C and bed temperature 110 °C; after printing, the surface is sanded from P120 to P400 and sealed with an epoxy tooling gel coat applied at 10 wt% of the printed plug mass. Fumed silica at 1–2 wt% is introduced into the gel coat only to control sag on vertical walls; higher quantities reduce vacuum hole edge sharpness. Compliance anchors for the tool build are ISO 527-2:2012 for tensile yield, ISO 604:2002 for compressive modulus, and ISO 291:2008 for conditioning atmosphere before dimensional inspection. Downstream production mounts the plug on a drilled aluminum backplate with 0.8–1.0 mm vacuum holes positioned on 25 mm centers; HIPS or ABS sheet from 0.5 mm to 2.0 mm is radiatively heated to 150–170 °C, then drawn over the plug. Terminal product types include prototype blister trays, point-of-sale display trays, appliance panel fixtures, and short-run medical device tray mock-ups. Thermal fatigue cracking appears when plug surfaces exceed 70 °C repeatedly, so forced-air cooling and cycle interleaving are required beyond 20 consecutive draws.

    Clinic-Side Model Production Requires Virgin Feedstock Control

    Clinical engineering and hospital additive manufacturing units restrict Clariant ABS white to non-contact anatomical models and surgical planning artifacts because biological evaluation under ISO 10993-5:2009 is configuration-dependent and cannot be assumed from the raw filament alone. The material is printed only from vacuum-sealed spools with lot traceability; formulation addition ratio is 100 wt% virgin ABS white, 0 wt% regrind, and 0 wt% supplementary colorants, because any unverified additive invalidates downstream risk assessment under ISO 14971:2019. Design history file documentation aligns with FDA 21 CFR Part 820.30 when the models support device development. Downstream processing uses segmented DICOM data converted to printable surface meshes, printed at 0.1 mm layer height, 240 °C nozzle temperature, 100 °C bed temperature, and 35 mm/s perimeter speed with cooling fan at 15 %. Support structures are removed mechanically; steam autoclaving is not specified for the printed part, and surface sealing with epoxy is performed only when required for model durability in teaching settings. Terminal product types include craniofacial bone replicas, iliac wing models, cardiac anatomy models for surgical planning, and orthopedic reduction demonstration models. Any application involving direct patient contact or sterilized use is outside the validated boundary of this material.

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    Сертификация и соответствие требованиям
    Более подробное введение

    The Clariant Acrylonitrile Butadiene Styrene white 3D printer filament is an opaque, pigmented thermoplastic monofilament supplied for fused filament fabrication on heated-bed extrusion platforms. The product is compounded on a co-rotating twin-screw extruder with a 40:1 length-to-diameter ratio, melt-filtered through a 200 µm screen pack, and drawn to nominal diameters of 1.75 mm or 2.85 mm. Dual-axis laser gauging on the winding line holds average diameter tolerance to ±0.02 mm at 25 °C, with ovality below 0.03 mm. Spools are wound on 52 mm cores at net weights of 750 g or 2.5 kg and are sealed in metallised barrier packaging with desiccant. Residual moisture after packaging is specified below 0.03 % by mass by Karl Fischer titration. The white pigmentation uses rutile titanium dioxide dispersed in an ABS matrix stabilised to limit molecular weight loss during repeated melt processing in the printer hot-end.

    For initial machine setup, nozzle temperatures from 230 °C to 250 °C and heated-bed temperatures from 100 °C to 110 °C are appropriate for most enclosed FFF platforms. A direct-drive feeder generally performs with an extrusion multiplier of 0.98 to 1.00, while a Bowden-type feeder may require 1.00 to 1.02. The white pigment increases melt viscosity slightly relative to unpigmented ABS, and the reduced melt flow should be accounted for when switching from a natural ABS profile. A 0.4 mm brass or hardened-steel nozzle is standard; a 0.6 mm nozzle lowers shear residence time and is used where interlayer throughput and adhesion are prioritised.

    Mechanical Property Baseline for Lot Acceptance

    The values in the following table are representative lot-acceptance ranges measured on conditioned specimens after drying and printing under controlled conditions. Results depend on print orientation, layer height, and chamber thermal history; the table is not a design-value statement for all geometries.

    PropertyTest MethodTypical Range
    DensityISO 1183-1:20191.04–1.06 g/cm³
    Melt flow rate at 220 °C/10 kgISO 1133-1:20226–8 g/10 min
    Tensile yield stressASTM D638-14 Type I38–42 MPa
    Tensile modulusASTM D638-142000–2400 MPa
    Flexural modulusISO 178:20192100–2500 MPa
    Notched Izod impact strengthASTM D256-10e1180–220 J/m
    Heat deflection temperature at 1.82 MPaISO 75-2:2013 Method B92–98 °C
    Vicat softening temperatureISO 306:2022 Method B50100–104 °C
    Shore D hardnessISO 86876–78

    Mechanical response is anisotropic in the printed state. A flat tensile specimen printed in the XY plane with a 0.20 mm layer height retains 85–92 % of the injection-moulded ABS tensile strength, while a vertically printed specimen retains 40–55 %. Interlayer tensile strength across the Z axis is typically 22–26 MPa at a nozzle temperature of 250 °C and chamber temperature of 55 °C, compared with 38–42 MPa in the printed plane. A shell count above 3 and infill above 40 % increase section stiffness, but the interlayer plane remains the limiting fracture path. Increasing the extrusion multiplier above 1.05 does not recover Z-axis strength and may generate die swell that degrades dimensional precision.

    Before processing, the filament requires drying if the barrier bag has been open for more than 2 h at relative humidity above 60 %. A forced-air dryer at 80 °C for 4 h is sufficient for spools up to 2.5 kg; vacuum drying at 70 °C reduces the residence time to 3 h. Moisture levels above 0.20 % by mass produce extrusion froth, surface splay, and variable interlayer adhesion. Hydrolysis of residual moisture at 250 °C can reduce printed part tensile strength by 8 % to 12 % relative to dry-filament controls. Drying temperature must not exceed 90 °C because prolonged exposure above that threshold anneals the amorphous structure and may deform filament winding.

    What Limits Warpage and Adhesion on Low-Stiffness Build Plates?

    Warpage in white ABS is driven by differential shrinkage between the first deposited layers and the upper layers. The linear shrinkage of unfilled ABS filament can range from 0.4 % to 0.8 % in the print direction; the white-pigmented grade typically falls toward the higher end of the band because titanium dioxide particles act as additional nucleation sites during cooling. On an unheated borosilicate glass plate, parts with footprints above 60 mm × 60 mm frequently show corner delamination. A heated bed at 100 °C reduces the temperature gradient between deposited melt and solidified material. An acrylic-styrene-acrylonitrile adhesion sheet or a polyetherimide build surface improves first-layer wetting. If an enclosure is not available, reducing layer height from 0.20 mm to 0.12 mm and setting first-layer extrusion width to 130 % of nozzle diameter increases contact area. The first two layers should be printed at or below 30 mm/s, with the next three layers at or below 50 mm/s, to limit residual stress generation before the part reaches a dimensionally stable height.

    When Acetone Vapour Smoothing Is Applied to White ABS

    Acetone vapour smoothing is compatible with the ABS matrix but alters the surface appearance of the white pigment. At a vapour temperature of 50 °C and exposure of 10 s to 25 s, the outer layer reflows and can reduce surface roughness from approximately 18 µm Ra to 4 µm Ra on a vertical unprocessed wall. The pigment remains dispersed, but gloss changes may shift colour readings by ΔE*ab < 1.5. The smoothed shell is not mechanically identical to the untreated part; published data for this specific configuration is limited, but comparable ABS parts show a 10 % to 20 % reduction in notched impact strength after vapour smoothing. Parts must be degassed for 24 h at 23 °C before mechanical testing or packaging to allow residual acetone to diffuse from the surface. Thin walls below 1.2 mm should not be vapour-smoothed because local solvent uptake can cause buckling. Dichloromethane is not a substitute solvent; faster penetration can initiate stress-cracking in high-residual-stress builds.

    White Pigment Dispersion Alters Melt Flow Stability

    The rutile titanium dioxide loading lowers melt flow rate relative to natural ABS by 0.5 g/10 min to 1.5 g/10 min at 220 °C/10 kg. At nozzle shear rates of 100 s⁻¹ to 500 s⁻¹, the viscosity shift is less pronounced. High-shear dispersion in compounding is controlled to prevent pigment agglomerates above 20 µm, which would otherwise obstruct a 0.4 mm nozzle. Colour is verified with a spectrophotometer under D65 illumination and 10° observer geometry; the CIELAB b* value is held between 0.0 and 0.8 to limit yellowing from thermal degradation. The grade should not be blended with low-quality recycled ABS unless the recyclate has been tested for ash content and residual flame-retardant fillers, which can raise nozzle wear and reduce interlayer adhesion.

    The comparative data in the following table are compiled from publicly reported FFF filament data. Values vary with layer height, print orientation, and machine enclosure.

    VariableClariant White ABSPLAPETGASA
    Heat deflection temperature at 1.82 MPa92–98 °C50–55 °C68–72 °C88–95 °C
    Typical bed temperature100–110 °C20–60 °C70–85 °C90–110 °C
    Acetone vapour smoothingCompatibleNot suitableNot suitableCompatible
    UV stabilityModerate; not for sustained outdoor exposurePoorGoodGood
    Tensile modulus2000–2400 MPa3000–3500 MPa2000–2200 MPa1900–2200 MPa

    The Clariant white ABS is used for functional prototypes requiring post-machining, rigid snap-fits, equipment enclosures, and interior jigs that are not exposed to sustained ultraviolet light. The material can be sanded, drilled, tapped, and solvent-bonded. CNC post-machining should employ a single-flute upcut end mill at cutting speeds below 180 m/min to prevent local melting of the machined edge. The material is not graded for direct food contact or medical use; compliance with RoHS Directive 2011/65/EU and REACH Regulation EC 1907/2006 is documented at the resin and pigment level, but ISO 10993-5 cytotoxicity data require lot-specific validation. The operational boundary is defined by a dry feedstock, a heated bed, and an enclosed chamber for parts exceeding 120 mm in the largest dimension. Without these controls, corner lifting on a 150 mm footprint part can exceed 0.5 mm, and Z-axis dimensional error can exceed 0.4 %. The material is incompatible with amine-based additives and certain brominated flame retardants during re-compounding, because acidic degradation products may corrode processing equipment and generate localised gas evolution. Printed parts should be annealed only at 70 °C for 30 min; higher temperatures can soften unsupported overhangs.

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