| Код ТН ВЭД | 950958 |
Как аккредитованный завод Clariant Black Polycarbonate 3D Printer Filament, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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Clariant black polycarbonate filament with a nominal diameter of 1.75 mm or 2.85 mm is processed in enclosed fused deposition modeling equipment where the build chamber is held at 70–85 °C, the polyetherimide build surface is maintained at 105–115 °C, and the all-metal hot end is controlled between 280 °C and 310 °C. Compliance for automotive assembly fixtures is governed by IATF 16949:2016 for supplier quality management, FMVSS 302 for any interior-adjacent polymer surface, and REACH Annex XVII for restricted substances. The material is fed at 100 wt% without point-of-use dilution; carbon black masterbatch is incorporated during filament compounding at 0.8–2.5 wt% to stabilize opacity and ultraviolet screening, while glass fiber reinforced variants at 10–20 wt% are used only when fixture deflection under clamp force exceeds the unfilled material’s flexural modulus. The downstream process begins with drying at 120 °C for 4 h in a desiccant dryer with a dew point ≤ −40 °C, followed by slicing at 0.15–0.20 mm layer height, deposition of 4–6 perimeter walls for load-bearing surfaces, and annealing at 120 °C for 2 h to reduce residual stress before installing threaded inserts by ultrasonic insertion. Terminal parts include robotic end-of-arm tooling plates, vacuum forming bucks, checking gauges, and assembly jigs intended for short-run production where solvent exposure is limited to alkyd-based mild cleaners; contact with methyl ethyl ketone or dichloromethane is avoided due to stress-crack propagation in polycarbonate.
On production lines using twin-screw extruders with L/D 40 for PC carbon black masterbatch dilution, batch-to-batch viscosity shifts of ±5% in melt flow rate measured under ISO 1133-1:2022 at 300 °C/1.2 kg have been correlated with screw speed deviations; printers with Bowden extruders exhibit feed inconsistency when the filament is stored at relative humidity above 60% for more than 24 h. Failure modes include corner delamination when the chamber temperature drops below 65 °C, and insert pull-out when the as-printed boss is not reinforced with 5–7 perimeters. Published data for Clariant’s proprietary carbon black loading and specific rheology is limited; the values above represent industrial PC filament processing ranges and should be confirmed against the supplier’s certificate of analysis.
Compliance for electrical control enclosures fabricated from black polycarbonate filament is assessed under UL 94; unfilled polycarbonate typically obtains V-2 at 3.0 mm, while phosphate-flame-retardant grades obtain V-0 at 3.0 mm. The base filament is fed at 100 wt% without point-of-use dilution; any phosphorous-based FR additive is compounded at 5–12 wt% before filament extrusion, and conductive carbon black masterbatch at 8–15 wt% is used only for static-dissipative variants. The relevant electrical standards are IEC 60243-1:2013 for dielectric strength and ASTM D257-14 for surface resistivity; unfilled polycarbonate typically exhibits surface resistivity above 1015 Ω, which excludes it from static-dissipative service unless the conductive filler is incorporated in the feedstock. The downstream manufacturing process uses a hardened steel nozzle at 260–290 °C, a bed temperature of 90–110 °C, and a chamber temperature of 60–80 °C; layer height is held at 0.10–0.20 mm, and the part is annealed at 100–120 °C for 1–2 h to stabilize creep resistance under terminal screw torque. Terminal products include DIN-rail enclosures, terminal block housings, control cabinet cable glands, sensor bodies, and low-voltage switch covers.
Measurement of dielectric strength on FDM polycarbonate housings is performed according to IEC 60243-1:2013 on 2.0 mm specimens; layer-boundary porosity reduces breakdown strength relative to injection-molded PC by as much as 10–20% when raster angle is parallel to the field. For static-dissipative control enclosures, compounders add conductive carbon black masterbatch at 8–15 wt% to achieve surface resistivity in the range 106–109 Ω per ASTM D257-14; this addition ratio must be selected before filament extrusion and is not possible at the printer. Process control requires a run-to-run bed flatness tolerance of ≤ 0.10 mm and layer time consistency to avoid side-wall curl at part heights above 80 mm. Terminal enclosure parts are inspected under IEC 60529:2013 for ingress protection only after surface sealing with a compatible acrylic conformal coating; unsealed FDM polycarbonate is not liquid-tight at IPX4.
Layer-bond-driven anisotropy in FDM polycarbonate is measured by ASTM D638-14 tensile specimens printed flat and upright; the upright orientation typically retains 60–80% of the Z-strength relative to the XY plane, which is a critical process conflict in enclosure designs with snap-fit lids. Control enclosures with wall thickness below 2.0 mm are susceptible to arc tracking at the layer boundary; a conformal acrylic coating applied at 25–50 µm dry film thickness is used to restore surface continuity. The process is operated with a bed flatness tolerance of ≤ 0.10 mm and ambient relative humidity below 40% to prevent moisture regain before printing.
Fabrication of aerospace cabin components from black PC filament is constrained by 14 CFR 25.853(a) vertical burn requirements and ASTM E595-15 outgassing limits of total mass loss ≤ 1.0% and collected volatile condensable material ≤ 0.10% when the part is intended for pressurized crew compartments. The formulation addition ratio at point of use is 100 wt% filament; no post-additive flame retardant can be introduced without invalidating the qualified material group, and any carbon fiber reinforced feedstocks are restricted to 10 wt% when electrostatic dissipative behavior is required for avionics tray covers. Downstream production uses a heated chamber at 80–90 °C, print speed 30–50 mm/s, layer height 0.12–0.18 mm, and a nozzle temperature 280–300 °C; post-print baking at 110 °C for 4 h reduces residual moisture before outgassing testing. Terminal finished parts include seat trim brackets, air vent grilles, electronic enclosure mounting brackets, and low-rate cabin service prototypes; structural or load-bearing airframe components are excluded because FDM PC does not meet qualified aerospace structural allowables without substantial process-specific statistical substantiation.
Outgassing screening for aerospace cabin parts uses ASTM E595-15 at 125 °C and 24 h; if the printed part has not been annealed, trapped moisture and low-molecular-weight oligomers at the layer surface can push collected volatile condensable material above the 0.10% threshold. Production experience indicates that chamber temperature fluctuation above ±5 °C during a build increases side-wall shrinkage at corners and yields dimensional deviation beyond ±0.25 mm on parts longer than 200 mm. The FDM process uses a 0.25 mm nozzle and 0.12 mm layer height for air vent grilles to limit visible layer lines; the same geometry printed at 0.20 mm may fail the aerodynamic fit check. Published data for Clariant-specific aerospace qualification is limited; qualification must be conducted on flight-ready parts by the integrator.
In medical device prototyping, the processing window narrows because the black polycarbonate filament must be dried to a moisture content below 0.02 wt% before extrusion; hydrolysis above this threshold produces splay, interlayer porosity, and reduced molecular weight at the layer boundary. The applicable compliance framework is ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2010 for skin irritation, but FDM-produced polycarbonate is not automatically certified to these standards; published data for this specific configuration is limited, and batch-level testing on finished devices is required before clinical use. The formulation addition ratio for the printed component is 100 wt% filament; if radiopacity is needed for imaging phantoms, barium sulfate masterbatch at 5–10 wt% must be compounded before filament extrusion rather than blended at the printer. Downstream production uses a nozzle temperature 270–300 °C, a bed temperature 100–115 °C, a chamber temperature 65–80 °C, and a print speed 20–40 mm/s; after printing, the part is annealed at 100 °C for 2 h and washed with 70% isopropanol to reduce surface bioburden. Terminal products are limited to non-implantable housings, surgical guide prototypes, anatomical models, and diagnostic console enclosures; steam sterilization at 134 °C is not recommended because FDM porosity and microcracks can harbor contamination and cause dimensional drift.
Post-print cleaning for medical housings follows ISO 15883-1:2006 washer-disinfector thermal cycling only when the part is placed in a non-implantable device with low bioburden classification; the use of enzymatic detergents above 60 °C can initiate stress-crack growth at internal radii below 1.0 mm. For anatomical models, the filament is printed at 100 wt% and post-processed by sanding and vapor polishing; published data on the cytotoxic potential of solvent-polished PC surfaces under ISO 10993-5:2009 is limited, so the polishing solvent must be fully evaporated and the part washed with 70% ethanol before use. The production process for diagnostic console enclosures includes raster orientation alignment at 0°/90°/−45°/+45° to reduce anisotropic shrinkage and a build plate temperature uniformity of ±3 °C across a 300 mm × 300 mm bed.
Rail interior bracket production from black PC filament must address EN 45545-2:2020 hazard level verification for rolling stock; unfilled polycarbonate does not inherently satisfy all R1 HL3 requirements without flame-retardant formulation, so any component-level certification must be conducted on the finished FDM part rather than inferred from the polymer datasheet. The formulation addition ratio is 100 wt% PC filament for the first-article shape; if a higher-toughness floor cover alignment fixture is required, a PC/ABS blend of 70/30 wt% is used in injection molding, not point-of-use modification of the filament. Downstream production for rail parts uses a bed temperature 100–120 °C, nozzle temperature 280–310 °C, chamber temperature 75–85 °C, and layer height 0.15–0.25 mm; after printing, the part is annealed at 120 °C for 3 h to reduce residual stress before dimensional inspection. Terminal finished products include seat tray table prototypes, armrest components, cable routing brackets, and vacuum forming tools for rail interior cladding; these parts are restricted to non-load-bearing and non-structural functions unless specifically validated under EN 12663-1:2010.
EN 45545-2:2020 compliance requires cone calorimeter and smoke density testing on the actual FDM part because the layered surface area and internal void volume differ from injection-molded plaques; published data for FDM black PC under R1 HL3 is limited, and unfilled PC typically fails smoke density limits without intumescent additives. For rail cable routing brackets, the part is printed at 0.20 mm layer height and annealed under fixture to prevent warpage; dimensional inspection after annealing is conducted under ISO 2768-1:1989 class m, with hole-to-hole tolerances held to ±0.15 mm. The formulation addition ratio remains 100 wt% for the PC filament; when the bracket requires soft snap features, a separate thermoplastic polyurethane inlay is used on a multi-material printer instead of blending the PC filament, because polycarbonate hard segments embrittle at the interface. Terminal parts include seat tray table prototypes, armrest components, cable routing brackets, and vacuum forming tools for rail interior cladding; these parts are restricted to non-load-bearing functions unless validated under EN 12663-1:2010.
Smoke density testing under EN 45545-2:2020 Ds max imposes a stricter constraint than tensile strength because polycarbonate’s aromatic carbonate structure releases high smoke under radiant panel exposure; published data for FDM black PC under R1 HL3 is limited. The bracket printing process therefore includes a closed-loop chamber heater with ±3 °C uniformity and an exhaust filter downstream of the print head to limit operator exposure to outgassing monomers. Fasteners installed in printed rail brackets are limited to threaded inserts compressed with 0.8–1.2 N·m torque; higher installation torque initiates radial cracks at the layer interfaces.
Thermoforming tool inserts produced from black polycarbonate filament are qualified by ISO 75-2:2013 method A heat deflection temperature of approximately 120–130 °C after annealing, and by ASTM D648-18 for comparative verification under 1.8 MPa. The formulation addition ratio is 100 wt% unfilled black PC; for tools subjected to sustained clamp pressure above 0.5 MPa at 120 °C, a glass-fiber reinforced PC grade at 10–20 wt% is substituted in the filament feedstock because the unfilled material exhibits creep at the upper service temperature. The downstream production route uses a 0.4–0.6 mm nozzle, 0.15–0.25 mm layer height, 280–310 °C nozzle temperature, and a build chamber held at 80–90 °C; the printed tool insert is machined with carbide tooling to ±0.10 mm on seal surfaces and then oven-annealed at 130 °C for 4 h to close microvoids at the tool surface. Terminal finished products include vacuum forming tool inserts for ABS and polystyrene sheets, low-pressure injection mold prototypes, and thermoforming fixtures for reusable packaging trays.
Vacuum forming tool inserts are exposed to repeated heating under quartz lamps and cooling cycles; the polycarbonate insert is rated for short-term surface temperature up to 130 °C but long-term exposure above 120 °C under load leads to creep. Process verification uses ISO 75-2:2013 method A with a heating rate 120 °C/h and flatwise specimen orientation. The tool surface is machined after printing to remove the layer-induced waviness of 0.02–0.05 mm; if the tool is used for transparent polystyrene, the surface is polished to Ra 0.4 µm with diamond paste. The formulation addition ratio in tooling service is 100 wt% unfilled PC, but tool sections around vacuum holes are reinforced with metal inserts because the PC matrix around holes with a diameter below 1.0 mm can crack at 120 °C after 50–100 forming cycles; published cycle-life data for this specific configuration is limited and should be established on a pilot line.
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At nominal diameter 1.75 mm or 2.85 mm, the Clariant Black Polycarbonate 3D Printer Filament is supplied as an unfilled, carbon black-pigmented polycarbonate monofilament intended for fused filament fabrication. A grade-specific model number is not consistently used across distribution channels; the incoming lot certificate therefore functions as the primary product identifier and should record polymer family, diameter, colorant class, melt volume-flow rate, residual moisture, and winding tractive force. Published test data for this specific Clariant product configuration are limited, so batch-specific verification against the certificate of analysis is required before production use. The nominal density falls between 1.19 g/cm³ and 1.21 g/cm³ when measured by ISO 1183-1:2019. Diameter tolerance is typically controlled within ±0.05 mm for the 1.75 mm offering and ±0.10 mm for the 2.85 mm offering when sampled with an optical micrometer at 20 °C to 23 °C.
Production-scale extrusion of pigmented polycarbonate on a twin-screw line with an L/D ratio near 40:1 uses vacuum venting at approximately -0.08 MPa to hold residual moisture below 0.02 % before pelletizing and filament winding. The black coloration is achieved with a carbon black masterbatch dispersed in bisphenol-A polycarbonate; the additive package does not convert the resin into a flame-retardant compound unless the lot certificate states a UL 94 classification. The product is not a low-temperature material. It is specified for builds where the part may see short-term thermal soak or where the design requires heat deflection temperature above that of ABS or PETG. The base resin and colorant are typically supplied with declarations referencing RoHS 2011/65/EU and the REACH candidate list in force at the time of supply, but the signed lot certificate must be requested for each batch.
Pre-drying is required. Residual moisture above 0.02 % by weight causes hydrolysis, splay, and molecular weight loss during extrusion. A forced-air desiccant dryer held at 80 °C for 4 h to 6 h is sufficient for filament stored below 35 % relative humidity. If the spool has been exposed at 60 % relative humidity or higher for more than 72 h, drying at 120 °C for 3 h to 4 h may be required, but the spool material and label must be removed or verified to withstand that temperature. Hot-air ovens without desiccant can retard moisture removal because the air dew point remains elevated; a desiccant bed with supply dew point below -20 °C is preferred.
The extrusion temperature window is bounded by melt viscosity on the cold side and chain scission on the hot side. Melt volume-flow rate for unfilled polycarbonate filament typically falls between 5 cm³/10 min and 10 cm³/10 min under 300 °C and 1.2 kg load according to ISO 1133-1:2022. The recommended nozzle set point is 270 °C to 310 °C, with direct-drive extruders usually run at the lower end. Below 260 °C, layer fusion declines and interlayer tensile strength is reduced. Above 320 °C, residence time must be limited to avoid thermal degradation and black speck formation. A heated bed at 100 °C to 120 °C, combined with an enclosed chamber stabilized at 55 °C to 80 °C, reduces asymmetric shrinkage. Open-frame printers can build small parts but may show corner lifting for flat dimensions greater than 80 mm unless raft, brim, or polyimide tape adhesion is used.
Layer deposition should use a hardened steel or stainless steel nozzle if carbon black pigmentation creates a mildly abrasive melt stream, although unfilled polycarbonate is less abrasive than carbon fiber-reinforced grades. A 0.4 mm brass nozzle is adequate for short production runs; a 0.6 mm nozzle lowers pressure drop in high-speed tool paths. Print speeds from 30 mm/s to 60 mm/s are typical. Retraction distance for direct-drive heads is 0.5 mm to 1.5 mm; Bowden systems may require 3 mm to 6 mm but introduce greater stringing risk. The part cooling fan should remain off for the first 10 to 20 layers; subsequent cooling is limited to 20 % to 40 % to prevent layer separation and edge curl.
When the filament is substituted for ABS or PETG in functional prototypes, the mechanical advantage is usually expressed through tensile yield stress, flexural modulus, and heat deflection temperature rather than ultimate elongation. Table 1 summarizes comparative property ranges from standardized test methods. The values are representative for unfilled black polycarbonate filament and for widely distributed unfilled ABS, PETG, and PC-ABS blend filaments; batch-specific values should be taken from the lot certificate. Unfilled polycarbonate exhibits a yield stress near 60 MPa to 70 MPa when tested at 50 mm/min according to ISO 527-2:2012. Flexural modulus is approximately 2,200 MPa to 2,400 MPa under ISO 178:2019. Heat deflection temperature typically ranges from 130 °C to 140 °C at 1.8 MPa using ISO 75-2/A. These characteristics make the material suitable for dimensionally stable jigs and fixtures that contact hot air or are located near heat sources, but published case data for this specific filament configuration is limited.
| Material type | Tensile yield stress (ISO 527-2:2012) | Flexural modulus (ISO 178:2019) | Heat deflection temperature at 1.8 MPa (ISO 75-2/A) |
|---|---|---|---|
| Unfilled polycarbonate | 60–70 MPa | 2,200–2,400 MPa | 130–140 °C |
| ABS | 35–45 MPa | 1,800–2,200 MPa | 90–100 °C |
| PETG | 45–55 MPa | 1,900–2,200 MPa | 70–80 °C |
| PC-ABS blend | 50–60 MPa | 2,000–2,300 MPa | 100–115 °C |
The high modulus carries a processing penalty. Unfilled polycarbonate exhibits higher volumetric shrinkage than PLA and requires a higher chamber temperature for flat parts. Mold shrinkage for unfilled polycarbonate is typically reported between 0.5 % and 0.7 %, but fused filament fabrication part shrinkage depends on build path, raster angle, and chamber temperature. Published data for this specific product configuration is limited. Interlayer tensile strength is not covered by a globally harmonized test method; internal qualification should use a Type V tensile specimen oriented in the z-axis and report the failure mode. Fracture at the layer interface, rather than through printed roads, indicates that extrusion temperature, chamber temperature, or layer time must be adjusted.
Polycarbonate is sensitive to environmental stress cracking in the presence of aromatic hydrocarbons, ketones, esters, and some amines. The black pigmentation does not alter the base chemical resistance, but stress concentrations from layer grooves and build orientation accelerate crack initiation. Acetone, methyl ethyl ketone, toluene, and xylene should be avoided for cleaning and for service contact because surface crazing can occur below the short-term yield stress when the part is under continuous load. Isopropanol and ethanol at room temperature are generally acceptable for wipe cleaning, provided the part is unstressed and the solvent is allowed to evaporate before mechanical loading. Alkaline solutions at pH 10 or higher can hydrolyze the polymer surface over repeated exposure. Sustained immersion in hot water above 60 °C reduces molecular weight by hydrolysis and should be qualified with a tensile test before production use.
Hydrocarbon-based lubricants and greases with high aromatic content can plasticize and reduce modulus. Silicone-based release agents are generally compatible but may interfere with painting or adhesive bonding. Flame-retardant additives are not claimed unless specifically stated in the lot certificate; therefore, the unfilled black grade should not be used as a substitute for UL-recognized flame-retardant polycarbonate compounds without independent testing. For electronic enclosures, the applicable standard is IEC 60695-11-10 or UL 94 at the final wall thickness. Unfilled polycarbonate often exhibits a V-2 rating at 1.5 mm, but performance depends on thickness and pigment loading. Published data for this specific black product is limited. Amine-based purge compounds and certain amine-containing flame retardant masterbatches should not be combined with polycarbonate because they can promote degradation and surface haze.
In contrast to carbon fiber-reinforced polycarbonate filament, the unfilled black grade has lower tensile modulus and lower brittleness, but it also avoids galvanic wear of brass nozzles and reduces the need for hardened tooling. Compared with PETG, the unfilled polycarbonate offers higher heat deflection temperature and higher tensile yield stress, but it requires a higher nozzle temperature and a closed chamber for flat parts. Compared with ABS, the polycarbonate filament does not evolve styrene monomer during printing, which reduces odor complaints in enclosed workspaces, but local exhaust ventilation is still required for any polymer melt processing. Compared with PC-ABS blends, the unfilled polycarbonate has higher heat deflection temperature but lower low-temperature impact toughness because no elastomeric phase is present. The operational boundary of the product is therefore defined by moisture control, chamber temperature, solvent exposure, and mechanical load. The material is used in fused filament fabrication for tooling and fixture components where dimensional stability under warm air or direct contact with heated surfaces is required. The product is not recommended for continuous immersion in water at temperatures above 60 °C unless hydrolysis is accounted for in the design safety factor.