| Код ТН ВЭД | 206834 |
Как аккредитованный завод Clariant Polyethylene Terephthalate Glycol Black 3D Printer Filament, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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Clariant Polyethylene Terephthalate Glycol Black 3D Printer Filament is processed as a 100% virgin thermoplastic polyester feedstock with a nominal diameter of 1.75 mm or 2.85 mm. The filament is not diluted with regrind at the print head; post-industrial returns from failed builds must not be re-extruded in-house unless the resulting filament diameter tolerance can be held to ±0.03 mm. The common processing window is 230–260 °C nozzle temperature, 70–85 °C build plate temperature, 0.10–0.28 mm layer height, and 30–60 mm/s print speed. Pre-drying at 65–70 °C for 4–6 h is required when ambient RH exceeds 60%; hydrolytic chain scission can reduce tensile strength by more than 12% after 72 h of uncontrolled moisture exposure. The following scenarios apply the material only where continuous service temperature does not exceed 50–60 °C under load; published data for this specific black formulation is limited for long-term UV ageing and repeated sterilisation.
In automotive interior clip and sensor bracket replacement programmes, the material is used as a 100% feedstock addition ratio: no regrind, no glass fibre, no colour masterbatch is introduced at the FDM/FFF print head. If a second interface material is used for soluble supports, that material is excluded from the part body and remains below 5% of total build volume. Cabin clips are printed on a direct-drive Cartesian platform with a 0.4 mm hardened steel nozzle, 0.15 mm layer height, 250–260 °C nozzle temperature, 75 °C PEI build plate, and 45% cooling fan to balance interlayer fusion against stringing. Printed specimens typically fall within 47–53 MPa tensile yield and 15–25% elongation at break under ISO 527-2:2012, and 65–72 MPa flexural strength under ISO 178:2019. Compliance for interior occupant compartments is evaluated by FMVSS 302 and ISO 3795 horizontal burning rate methods on printed plaques; flammability results are geometry-dependent and must not be transferred from injection-moulded datasheets. The operational boundary is a continuous air temperature below 60 °C; unfilled PETG heat deflection temperature under 0.45 MPa is typically 68–75 °C per ISO 75-2:2013 method B, but clip retention beams lose spring force above 50 °C. Batch-to-batch ovality above ±0.03 mm on Bowden feed systems alters effective volumetric flow by approximately 3–5%, requiring feed multiplier correction per spool. Terminal products include HVAC duct clips, sensor bracket clips, trim alignment dowels, and cable retainers for low-volume interior applications.
The limiting factors in cleanroom structural brackets are non-volatile residue, particle shedding from interlayer grooves, and electrostatic charge. The feedstock addition ratio is 100% black PETG filament; no release agent, assembly adhesive, or polish is permitted on the part because these additives become contamination sources. Production on a cleanroom-compatible FDM cell uses a 0.4 mm abrasion-resistant nozzle, 0.20 mm layer height, 245–255 °C nozzle temperature, 70–80 °C build plate, and 40–60% cooling fan. After printing, parts are washed in 70% isopropanol/DI water and dried with filtered air. The printed article is evaluated under ISO 14644-1:2015 for particulate release in the target cleanroom class, and for static behaviour under IEC 61340-5-1:2016. Surface resistivity of standard black PETG remains above 1012 Ω/sq; therefore the part is insulative, not static-dissipative, and must not be specified for ESD-sensitive product contact unless the grade is specifically compounded with conductive carbon. For outgassing-sensitive zones, ASTM E595-15 total mass loss and collected volatile condensable material should be requested because printed void surfaces can retain low molecular weight oligomers. Terminal products include equipment covers, pass-through frames, non-wafer-contact guide rails, and cable management brackets for Class 7 and Class 8 areas. Published data for this specific black formulation under cleanroom cleaning cycles is limited; replacement intervals should be based on particle count trending.
If ethylene oxide sterilisation is mandated for diagnostic device housings or laboratory instrument enclosures, black PETG can be used only after a material-addition control plan that excludes regrind and release agents: the feedstock addition ratio is 100% spooled filament, with no post-print solvent polishing unless residual solvent testing according to ISO 10993-12:2021 is completed. The production process uses a 0.4 mm nozzle, 0.16 mm layer height, 255 °C nozzle temperature, 80 °C build plate, and a passively controlled chamber near 35 °C; the filament spool is maintained in a dry box with a dew point below −10 °C to prevent moisture-related blistering. Biocompatibility is not an inherent property of the printed part; the finished housing must be tested under ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2010 for skin sensitisation, with the manufacturing process validated under ISO 13485:2016. A standard EtO cycle at 55 °C and 45–60% RH, followed by 7-day aeration at 40–50 °C, is within the short-term thermal tolerance of unfilled PETG; steam autoclave is outside the operating boundary because ISO 75-2:2013 method B heat deflection temperature is typically 68–75 °C at 0.45 MPa and saturated steam at 121 °C will induce gross dimensional change. Terminal products include benchtop analyser enclosures, diagnostic housing shells, and non-implant device enclosures. Gamma irradiation may reduce molecular weight and shift mechanical properties; published data for this specific black formulation is limited for radiation dose mapping.
For assembly fixtures, CMM holding fixtures, and robotic end-of-arm gripper bodies, short-term tensile yield is not the controlling design criterion; creep under sustained clamp load is. The feedstock addition ratio is 100% filament, with no glass fibre reinforcement added at the printer. The fixture body is printed at 240 °C nozzle temperature, 70 °C build plate, 0.20 mm layer height, 30 mm/s print speed, with 4 perimeter walls, 5 top and bottom layers, and 100% infill. Under ISO 527-2:2012, short-term tensile modulus is typically 1900–2200 MPa; under ISO 178:2019, flexural modulus is typically 1900–2100 MPa. Dimensional verification follows ISO 2768-1 and form/position tolerancing follows ISO 1101:2017. Long-term fixture deformation is evaluated under ASTM D2990-17; at ambient temperature above 45 °C, the allowable clamp stress is reduced by 30–40% to keep creep within fixture repeatability limits. In production cells, the common failure mode is not part fracture but loss of clamping force after several hundred hours of continuous use when the fixture is stored above 40 °C; anti-creep steel bushings are recommended at clamp contact points. Terminal products include assembly fixture bases, toggle clamp mounts, CMM holding fixtures, and robot gripper jaws. Published data for this specific black formulation is limited for creep at 60 °C and must be validated on target equipment.
Cosmetic jar, cap, and oral solid dose dispenser prototype builds use black PETG as a 100% filament feedstock with no regrind or colour masterbatch; the addition ratio is unchanged from the supplied spool because process returns would alter the 1.75 mm diameter tolerance. Primary packaging prototypes printed from this material are not automatically compliant with food-contact or pharmaceutical-contact regulations merely because the base glycol-modified PET resin may be referenced by FDA 21 CFR 177.1315 or EU 10/2011; the black colour system and filament processing aids require overall migration and specific migration testing on the printed article. If the tablet dispenser ramp is used for pharmaceutical contact, the sealed article may require USP <661.1> plastic packaging testing. For non-contact prototype enclosures and caps, process conditions include 0.20 mm layer height, 250 °C nozzle, 75 °C build plate, 50% cooling fan, and 6 perimeter walls to reduce through-wall porosity. Post-processing for jars and tablet contact chutes is limited to mechanical buffing or a solvent-free clear seal coat; amine-based epoxy coatings should be avoided where the seal coat must flex because interfacial adhesion to the black PETG surface without flame or plasma treatment is generally weak. Terminal products include cosmetic bottle prototypes, closure retention test parts, tablet dispenser ramps, and filling line guide rails. The downstream process remains FDM/FFF; injection moulding transfer data from FDM prototypes should not be used for product qualification without correction for anisotropic shrinkage. Published data for this specific black formulation under commercial dishwashing or autoclave cleaning is limited.
Low-voltage electronics enclosures, front panels, cable guides, and connector brackets are printed from black PETG only when the application does not require a V-class flame rating. The material is used as a 100% filament addition ratio, with no FR masterbatch and no conductive carbon addition; therefore the printed wall remains electrically insulating with a surface resistivity typically above 1012 Ω/sq, and cannot be claimed as ESD-safe under IEC 61340-5-1:2016 unless a separately validated conductive grade is used. Flame testing must be conducted on printed plaques according to UL 94 HB or IEC 60695-11-10; applications near uninsulated line voltage or arcing components are outside the stated boundary. The enclosure is printed at 245–250 °C, 70–75 °C build plate, 0.16 mm layer height, 60 mm/s perimeter speed, 6 perimeter walls, and 100% infill in screw boss bearing zones. Threaded brass inserts are installed with heat-stake tooling at 185–195 °C; insertion below 185 °C produces excessive hoop stress in PETG walls, while insertion above 195 °C risks local thermal degradation and insert pull-out. Cooling-fan settings above 60% on unheated-chamber machines can reduce interlayer tensile strength by more than 15%; fan maps should be fixed per geometry and validated by ISO 527-2:2012 z-axis specimens. Terminal products include control enclosures, front panels, cable routing clips, and DIN rail adapters. Published data for this specific black formulation under electromagnetic compatibility screening is limited; conductive coatings are necessary if shielding is required.
| Application boundary | Compliance references | Feedstock addition ratio | Terminal product types |
|---|---|---|---|
| Automotive interior clips and sensor brackets | FMVSS 302; ISO 3795; ISO 527-2:2012; ISO 178:2019; ISO 75-2:2013 | 100% black PETG; no regrind, no fibre | HVAC duct clips, sensor bracket clips, trim alignment dowels, cable retainers |
| Cleanroom structural brackets and guides | ISO 14644-1:2015; IEC 61340-5-1:2016; ASTM E595-15 | 100% black PETG; no release agent, no adhesive | Equipment covers, pass-through frames, non-wafer-contact guide rails, cable brackets |
| EtO-sterilised medical device housings | ISO 10993-5:2009; ISO 10993-10:2010; ISO 10993-12:2021; ISO 13485:2016 | 100% spooled black PETG; no regrind, no solvent polish | Benchtop analyser enclosures, diagnostic housing shells, non-implant device enclosures |
| Assembly fixtures and CMM holding fixtures | ISO 527-2:2012; ISO 178:2019; ISO 2768-1; ISO 1101:2017; ASTM D2990-17 | 100% filament; no glass fibre reinforcement | Assembly fixture bases, toggle clamp mounts, CMM holding fixtures, robot gripper jaws |
| Cosmetic and pharmaceutical packaging prototypes | FDA 21 CFR 177.1315; EU 10/2011; USP <661.1> | 100% black PETG; no regrind, no masterbatch | Cosmetic bottle prototypes, closure retention test parts, tablet dispenser ramps, filling line guide rails |
| Low-voltage electronics enclosures | UL 94 HB; IEC 60695-11-10; IEC 61340-5-1:2016 | 100% black PETG; no FR masterbatch, no conductive carbon | Control enclosures, front panels, cable routing clips, DIN rail adapters |
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The Clariant Polyethylene Terephthalate Glycol Black 3D Printer Filament is a pigmented glycol-modified copolyester feedstock for fused filament fabrication. The base resin is a copolyester in which a portion of the ethylene glycol repeat unit is replaced by cyclohexanedimethanol, producing a polymer with suppressed crystallization and an amorphous or weakly semicrystalline morphology after cooling from the melt. The black configuration is compounded with a carbon black dispersion, and procurement records generally identify the material by polymer family, colorant package, melt flow class, and wire diameter rather than by a single alphanumeric grade code uniformly reproduced in all regional documentation. Because published data for this specific Clariant black polyethylene terephthalate glycol configuration is limited, downstream qualification should rely on lot-specific certificates of analysis and printed-coupon testing rather than on generic PETG datasheets. Nominal supply forms include filament diameters of 1.75 mm and 2.85 mm; typical diameter tolerance is ±0.05 mm with an ovality limit of ≤0.03 mm. The material is amorphous enough to provide a glass transition temperature near 78 °C and a heat deflection temperature under 0.45 MPa generally in the range of 65 °C to 70 °C.
In boundary terms, the black pigment is not a passive optical additive. Carbon black increases opacity, modifies low-shear viscosity, and can act as a mild abrasive against brass extrusion nozzles. In fused filament fabrication, direct-drive extruders with hardened steel or ruby nozzle orifices are used to limit wear. Typical deposition parameters for a 0.4 mm nozzle are nozzle setpoints from 235 °C to 255 °C, heated bed setpoints from 70 °C to 85 °C, and part cooling fan speeds restricted to 20 % to 50 % of maximum flow for overhang and small feature stability. Chamber temperatures above 45 °C may soften thin overhangs and degrade dimensional stability. Actual setpoints should be confirmed by printing a temperature tower and a Z-direction tensile bar because the carbon black masterbatch can shift the melt viscosity relative to natural polyethylene terephthalate glycol.
Applications for the black product include functional prototyping, positioning fixtures, low-volume assembly tooling, cable routing hardware, and light-shielding enclosures where ductility and resistance to warp are required. The material is not a direct substitute for polycarbonate in continuous service above 70 °C, nor for nylon in snap-fit designs requiring sustained high-cycle fatigue. It is more ductile than many black pigmented PLA compounds, emits less styrene during open-frame printing than ABS, and has lower wet-state dimensional change than unfilled nylon. Chemical exposure to ketones, chlorinated solvents, esters, and some aqueous alkaline cleaning baths can produce stress crazing; suitability must be confirmed by immersion testing under load according to the relevant ASTM or ISO chemical resistance protocol. Food-contact use is constrained by pigments and printed surface texture, not automatically granted by the base resin status.
The cyclohexanedimethanol units in polyethylene terephthalate glycol reduce the chain regularity that drives primary crystallization in PET. During cooling from the nozzle, the black filament therefore solidifies without the sharp crystallization exotherm that creates high shrinkage in semicrystalline PET. Shrinkage is lower than in semicrystalline PET, and warp is generally lower than in ABS under the same bed conditions. However, interlayer fusion is controlled by molecular diffusion across the weld line at temperatures above the glass transition. A slow-crystallizing amorphous melt can retain sufficient open time for chain interdiffusion at the interface, but this advantage is reduced if the black pigment raises local viscosity and restricts wetting. Printed specimens must be tested in the Z direction according to ISO 527-2 or ASTM D638-14, because XY-direction tensile data do not capture the limiting interlayer strength. The anisotropic behavior is a product of the FFF process path and is not eliminated by the copolyester chemistry alone.
The reduction in warp relative to ABS is operationally relevant: ABS can require heated chamber temperatures of 70 °C to 80 °C and controlled cooling to prevent corner lifting, whereas black PETG can often be printed on a 70 °C to 85 °C heated bed with chamber temperatures below 45 °C. The trade-off is a lower heat deflection temperature. Where the part sees continuous heat soak above 70 °C, the load-bearing capability of black PETG can fall more rapidly than that of polycarbonate or polysulfone, so design verification should include short-term creep at the maximum service temperature.
Moisture control is among the strongest determinants of black PETG melt quality. At 50 % relative humidity, polyethylene terephthalate glycol filaments can pick up surface and absorbed moisture within hours. Printing wet material hydrolyzes ester linkages at melt temperature, lowers molecular weight, creates gas splay, and reduces interlayer strength. Pre-drying in a desiccant dryer at 65 °C for 4 h to 6 h with a dew point of −40 °C or better is the standard boundary. Drying above 65 °C risks deformation of spooled filament under winding stress. A moisture target below 200 ppm is commonly applied to PETG extrusion and FFF feedstocks; lot-specific certificate of analysis should confirm the actual value. Unopened spools should be stored at 20 °C to 25 °C and 30 % to 50 % relative humidity in sealed barrier bags with desiccant; once opened, hot-air drying should be used before printing if exposure exceeds 8 h.
Filament production benefits from vented twin-screw compounding with L/D ratios of 36:1 to 52:1 and a vacuum vent to pull residual moisture from the melt. Melt filtration after compounding is typically set at 20 μm or finer to remove carbon black agglomerates. Agglomerates above 20 μm can create diameter spikes, nozzle clogging, and poor surface finish in a 0.4 mm nozzle. Carbon black masterbatch dispersion should be verified by pressure rise across a screen pack or by microscopic film analysis; batch-to-batch variation in pigment dispersion can shift melt viscosity even if the resin lot remains unchanged.
Increasing carbon black concentration to improve opacity changes the rheological and mechanical response of polyethylene terephthalate glycol. At low shear rates, carbon black agglomerates can form a network that raises viscosity. In filament extrusion, this can lower melt pump stability and produce higher head pressure. In FFF, highly loaded black PETG may require nozzle temperatures near the upper end of the 235 °C to 255 °C window and may still exhibit reduced weld ductility if the pigment restricts interlayer diffusion. For practical black filament production, carbon black content is generally held below 2.0 % by weight to balance opacity, melt processability, and mechanical toughness. Published data for the exact Clariant black loading is limited; the masterbatch formulation may vary by region and should be confirmed with the supplier.
The carbon black surface absorbs ultraviolet radiation and can slow surface embrittlement during intermittent outdoor exposure, but black PETG is not automatically a UV-stabilized grade for long-term outdoor service. Tensile impact retention after accelerated weathering should be tested under ISO 4892-2 or ASTM G154. The black product should also not be confused with impact-modified or glass-fiber-filled PETG compounds unless the certificate of analysis explicitly lists an impact modifier or filler package.
A systematic comparison against adjacent polymer classes clarifies the positioning. The table below uses representative property envelopes for black PETG filament, amorphous PET, and ABS. The values are class-level ranges and may not represent the exact Clariant certificate of analysis; they should be used only for preliminary material screening.
| Property | Black PETG filament representative class | Amorphous PET | ABS | Test method |
|---|---|---|---|---|
| Density | 1.26–1.29 g/cm³ | 1.33–1.35 g/cm³ | 1.03–1.07 g/cm³ | ISO 1183-1 / ASTM D792 |
| Tensile strength at yield | 45–55 MPa | 50–60 MPa | 35–45 MPa | ISO 527-2 / ASTM D638-14 |
| Tensile modulus | 1900–2200 MPa | 2000–2400 MPa | 1800–2500 MPa | ISO 527-2 / ASTM D638-14 |
| Elongation at break | 15–30 % | 3–5 % | 5–15 % | ISO 527-2 / ASTM D638-14 |
| Heat deflection temperature at 0.45 MPa | 65–70 °C | 70–75 °C | 88–100 °C | ISO 75-2 / ASTM D648 |
| Notched Izod impact at 23 °C | 7–10 kJ/m² | 3–5 kJ/m² | 10–20 kJ/m² | ISO 180/A |
| Moisture target before printing | <200 ppm | <100 ppm | <300 ppm | Internal drying specification |
The comparison demonstrates that black PETG occupies a lower-temperature ductile envelope: it exceeds ABS in elongation under tensile loading but does not match ABS in heat deflection temperature. Against amorphous PET, black PETG offers much higher elongation and lower tendency to catastrophic brittle failure, but amorphous PET may display higher tensile modulus. Those trade-offs matter when selecting the product for non-load-bearing housings versus load-bearing fixtures in warm environments.
Regulatory compliance cannot be assumed from the base polymer class alone because the black masterbatch and any processing additives are separate components. The matrix below summarizes the verification boundaries that should be checked against the Clariant lot-specific documentation.
| Standard or regulation | Scope | Verification boundary |
|---|---|---|
| REACH 1907/2006 | Registration and SVHC declaration | Supplier SDS and article-level declaration required for the formulated black filament; raw resin compliance is not sufficient |
| RoHS 2011/65/EU | Restricted substances: Pb, Cd, Hg, Cr(VI), PBB, PBDE | XRF screening or supplier certificate for the black masterbatch and final filament lot |
| FDA 21 CFR 177.1630 | PETG base resin for food contact | Does not automatically cover black pigment; migration testing under intended use is required |
| EU Regulation 10/2011 | Plastic food-contact materials | Overall migration and specific migration for pigment package required |
| ISO 527-2 / ASTM D638-14 | Tensile properties of printed coupons | Anisotropy and Z-direction interlayer strength must be included |
| ISO 1183-1 / ASTM D792 | Density | Incoming material control and lot-to-lot consistency |
| ISO 1133-1 / ASTM D1238 | Melt volume or mass flow rate | Verify rheological shift caused by carbon black masterbatch |
The most common processing failure with black PETG is feeding inconsistency caused by spool winding tension or by diameter variation beyond ±0.05 mm. Excessive tension can ovalize the filament at the feed drive; under-driven or over-driven tension in direct-drive extruders produces under-extrusion or filament stripping. The second most common issue is nozzle buildup from carbon black and partially degraded polymer when the nozzle sits idle above 250 °C for extended periods. Purge with a low-temperature purge compound or natural PETG between production runs. Continuous printing of black PETG at the upper nozzle temperature for more than 8 h may progressively darken or degrade the melt if the hot-end residence time is prolonged and the filament is not adequately dried; periodic cold pulls and nozzle cleaning are required.