| Код ТН ВЭД | 100304 |
Как аккредитованный завод Clariant Polylactic Acid Natural Color 3D Printer Filament, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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In short-run tooling for room-temperature-vulcanizing silicone components, Clariant Polylactic Acid Natural Color 3D Printer Filament is processed as a low-heat cavity material only where continuous cavity wall temperatures remain below the heat deflection threshold reported under ISO 75-2:2013 Method B. Spools are dried at 45 °C for 4 h to 6 h when ambient relative humidity exceeds 60%. Drying below this moisture boundary is initiated because absorbed water reduces extrusion viscosity stability and can produce interlayer voids. The cavity is printed with a nozzle temperature of 205 °C to 215 °C, a bed temperature of 55 °C to 60 °C, and a layer height of 0.10 mm to 0.12 mm. The tooling geometry uses 4 perimeter shells and 95% rectilinear infill to limit surface porosity under cast RTV-2 silicone. Following the build, the cavity is sealed with an acrylic barrier coat of 20 µm to 30 µm dry film thickness and cured at 20 °C for 24 h. A polyvinyl alcohol release film is applied before casting. The barrier layer reduces the risk of cure inhibition in platinum-catalyzed addition-cure silicone systems. Published data for this specific PLA grade are limited, but barrier application is standard risk mitigation for porous fused deposition modeling tooling. Tooling temperature limits are set at 50 °C to 55 °C continuous cavity wall temperature. Localized exotherm during silicone cure must remain below 60 °C. Higher temperatures produce creep and loss of mold registration. Mechanical properties of the printed tooling are verified according to ISO 527-2, and chemical handling follows REACH 1907/2006. Terminal products include RTV-2 silicone gaskets, soft-touch overmolds, pad-printing transfer pads, and soft robotics skins. This method is not suitable for high-consistency rubber or peroxide-cure elastomer tools where cure temperatures exceed 120 °C.
Investment casting operations use the unfilled PLA pattern as a sacrificial positive for short-run metal parts. The printed pattern is designed with wall thickness from 1.0 mm to 1.5 mm and internal gyroid infill of 15% to 20%. Solid cross-sections above 6 mm are avoided because thermal expansion of PLA before decomposition can pressurize the surrounding ceramic shell. Shell construction follows foundry practice with 8 to 10 ceramic slurry and stucco layers. Stucco grading is adjusted to pattern complexity. Burnout is the primary process conflict. PLA expands and softens between 60 °C and 100 °C. If the shell is heated too quickly through this window, the primary coat can crack and metal ingress can occur during later pouring. A conservative schedule starts at ambient and ramps at 0.5 °C/min to 1.0 °C/min to 300 °C, holds for 2 h, then ramps at 2.0 °C/min to 600 °C and holds for 1 h. Published data for this specific configuration are limited. Foundries should validate the cycle on shell permeability coupons and pattern geometry representatives. Residual ash is measured according to ASTM D5630-22. If ash residues remain above the foundry threshold, the burnout air supply is increased and the high-temperature hold is extended. Dimensional acceptance of cast features follows ISO 8062-1. Terminal products include A356 aluminum brackets, silicon bronze actuator housings, and stainless steel impeller prototypes. The ceramic shell, not the PLA, carries the metal pour. Patterns above 20 mm in cross-section require internal drain openings to prevent shell pressurization. The PLA pattern shall not remain in the shell after burnout.
Static positioning nests and press-fit guides for PCB assembly are printed with 0.20 mm layer height, 3 perimeter shells, and 50% hexagonal infill. The infill density balances stiffness against total build time and limits long-term compressive creep. Mating pockets for electronic components receive clearance allowances of 0.15 mm to 0.25 mm. Fixture features that locate on hardened steel dowels use a radial clearance of 0.05 mm to 0.10 mm. These allowances compensate for staircase surface texture and anisotropic shrinkage in fused deposition modeling. Heat-set threaded inserts are installed with a tip temperature of 180 °C to 190 °C and a dwell time below 5 s. Longer dwell or higher temperature produces boss collapse and local melt fracture. The fixture must not operate above 50 °C continuous service temperature. Soldering stations adjacent to the fixture require thermal isolation. Threaded joint torque for M3 brass inserts is limited to 0.8 N·m. Higher torque causes insert pull-out and layer delamination. PLA is an insulative material. Surface resistivity data for this specific grade are limited, but unprotected FDM fixtures are not suitable for ESD-protected assembly areas without ionizers or carbon-loaded coatings. Verification follows IEC 61340-5-1. Material declarations are checked under RoHS 2011/65/EU and REACH 1907/2006. Terminal products include solder stencil alignment frames, connector insertion nests, wire-routing fixtures, and automated optical inspection staging plates. The dimensional stability window is narrow by design. Thermal overload at one local contact point can permanently deform the fixture.
| Application zone | Nozzle temperature | Bed temperature | Layer height | Critical boundary |
|---|---|---|---|---|
| RTV-2 silicone tooling | 205 °C to 215 °C | 55 °C to 60 °C | 0.10 mm to 0.12 mm | Continuous cavity wall temperature below 50 °C |
| Lost-PLA investment casting | 205 °C to 215 °C | 50 °C to 60 °C | 0.15 mm to 0.20 mm | Burnout ramp not more than 1.0 °C/min through 60 °C to 100 °C |
| Electronics assembly jigs | 210 °C to 220 °C | 55 °C to 60 °C | 0.20 mm | Service temperature below 50 °C; insulative surface requires ESD control |
| Anatomic planning models | 205 °C to 215 °C | 50 °C to 55 °C | 0.15 mm | Non-sterile external use only |
| Packaging prototypes | 215 °C | 60 °C | 0.10 mm | Not food-contact valid; thread pitch offset +0.2 mm |
| Laboratory test coupons | 210 °C | 55 °C | 0.20 mm | Z-direction anisotropy; conditioning per ASTM D638-14 |
When DICOM imaging data are converted into a patient-specific surface mesh for craniofacial review, the natural-color PLA build is printed directly from segmented bone threshold data. Segmentation thresholds are selected per tissue window, and the mesh is trimmed to isolate the anatomical region of interest. The slicing workflow uses 0.15 mm layer height, 2 perimeter shells, and 20% cubic subdivision infill. The unpigmented surface accepts water-based acrylic dyes and cold-curing polyurethane coatings for region highlighting. No autoclave or steam sterilization is used. The model is intended as a non-sterile external reference. Dimensional verification is performed by point-cloud comparison between the CT-derived mesh and the printed model. Published data for this specific PLA grade are limited. The clinical workflow should document root-mean-square error and alignment thresholds before use. The model is operated under ISO 13485 quality controls in hospital additive manufacturing cells where applicable. It must not contact breached skin or mucosa and is not evaluated for long-term tissue contact or implantation. Terminal products include orbital floor defect reference models, craniosynostosis planning skulls, and maxillofacial osteotomy spacing blocks. The material is not a load-bearing surgical instrument and shall not be used as a cutting or drilling guide without additional validation.
Rigid packaging closures and container bodies are printed from natural-color PLA when the objective is thread geometry verification and assembly force mapping before injection mold production. The thread geometry is printed with 0.10 mm layer height, 3 perimeter shells, a nozzle temperature of 215 °C, and a bed temperature of 60 °C. Thread pitch diameter is offset by +0.2 mm to compensate for layer stair-stepping and shrinkage. Internal threads are chased with a tap or printed with a radial clearance of 0.25 mm. Terminal products include cosmetic jar closures, dispensing pump collars, beverage cap thread prototypes, and tablet vial child-resistant feature mock-ups. Functional child-resistant closure testing under ISO 8317 is not valid on FDM prototypes with anisotropic mechanical behavior. Final qualification must be repeated on injection-molded production samples. Food-contact status is not established by printing alone. Untreated FDM surfaces contain interlayer voids and surface roughness that are not considered acceptable under Regulation (EU) No 10/2011 without migration testing on the final injection-molded article made from the production-grade resin. Repeated flexural cycling of living hinges is not recommended because PLA exhibits low fatigue resistance and craze initiation at layer interfaces. The printed packaging prototype is therefore limited to form, fit, and short-duration assembly force evaluation.
In teaching laboratories, type IV tensile bars and rectangular flexural coupons are produced from the same natural-color filament to demonstrate process-property relationships and interlayer anisotropy. Specimens are printed with 100% rectilinear infill, 0.20 mm layer height, a nozzle temperature of 210 °C, and a bed temperature of 55 °C. The long axis is oriented in the X-Y build plane for baseline tensile data. Vertical coupons are printed in the Z orientation to measure interlayer tensile strength reduction. Specimens are conditioned at 23 °C and 50% relative humidity for 48 h before testing according to ASTM D638-14 and ISO 527-2. Flexural modulus comparisons follow ISO 178. Published data for this specific PLA grade are limited. Laboratory-reported values are required for each print orientation. The practical teaching objective is to quantify Z-orientation reduction, which typically falls below the X-Y baseline due to incomplete interlayer bonding. These printed coupons are used for method instruction and are not selected as production validation specimens without batch-specific data.
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The Clariant Polylactic Acid Natural Color 3D Printer Filament is an unfilled, uncolored polylactic acid monofilament intended for material extrusion additive manufacturing under ISO/ASTM 52900. The product is specified by diameter class—1.75 mm or 2.85 mm—and by spool mass, with 750 g and 2.3 kg pack formats commonly encountered in industrial distribution. The natural designation indicates the absence of added pigments, mineral fillers, and impact modifiers; it does not exclude low-level processing stabilizers or slip agents used in monofilament extrusion. No widely published numerical model suffix distinguishes the grade, so procurement should reference the Clariant natural-color PLA designation and the required diameter class. Published Clariant-specific datasheet values for this particular natural-color configuration are limited, and the specification should require a batch-level dimensional report rather than relying solely on nominal diameter. Comparable industrial PLA monofilaments are typically controlled to ±0.05 mm diameter tolerance for the 1.75 mm class and ±0.10 mm for the 2.85 mm class, measured with dual-axis laser micrometers at 0.5 m intervals along the spool.
Unfilled PLA lacks inorganic pigments, reducing residue after combustion. For unfilled PLA, residual ash measured by ASTM D5630 typically remains below 0.5 wt%, whereas pigmented or mineral-filled grades may exceed 1.0 wt% depending on colorant chemistry and loading. In nozzle orifices of 0.4 mm or smaller, pigment agglomerates and mineral particles can initiate partial clogging and produce intermittent under-extrusion; the natural grade avoids this colorant-related failure mode. The absence of pigment also removes colorant-specific effects on crystallization kinetics. Pigments can promote heterogeneous nucleation, shifting non-isothermal crystallization peaks by several kelvin and altering weld-line morphology. A natural grade therefore exhibits more predictable melt flow behavior across spool lots, with melt flow rate for unmodified PLA homopolymer usually specified in the range 6 g/10 min to 12 g/10 min at 210 °C/2.16 kg according to ISO 1133-1:2022. Product-specific MFR values for the Clariant natural grade should be confirmed from the certificate of analysis; published third-party data for this exact configuration are limited.
Before extrusion, moisture control directly affects weld-line quality. PLA hydrolyzes at processing temperatures when absorbed moisture exceeds approximately 0.25 wt% as measured by Karl Fischer titration per ISO 15512:2019. In an open production environment at 60% relative humidity or higher, spools should be dried in a vacuum oven at 40–50 °C for 4–6 h, or in a forced-air desiccant dryer with a dew point of −40 °C or lower. The heated bed should be set to 40–60 °C with a polyimide or glass bed surface; bed temperature above 65 °C can promote part softening and corner lift. Unopened spools should be stored at 15–25 °C and 30–50% relative humidity in sealed bags with desiccant. After opening, the material should be consumed or re-dried within 30 days if ambient humidity exceeds 50%.
Dimensional uniformity is a more important input than the nominal diameter itself. In a Bowden feed system, unsupported 1.75 mm filament traverses a low-friction tube between the extruder gear and the toolhead; when ovality exceeds 0.03 mm, the filament can buckle during retraction. Retraction should be constrained to ≤2.0 mm at 25 mm/s in Bowden configurations and 0.8–1.5 mm at 30 mm/s in direct-drive configurations. Feed-path drag should remain below 0.5 N measured at the extruder idler; higher drag produces skip marks on the filament and periodic under-extrusion. On production-scale FFF machines equipped with dual-drive extruder gears and 0.4 mm hardened nozzles, a diameter variation of ±0.02 mm is the threshold below which volumetric flow fluctuation is generally invisible in the printed part. The natural grade’s unpigmented surface tends to produce lower feed-path drag in polytetrafluoroethylene Bowden tubes than mineral-filled filaments, but this effect should not be used to compensate for poor spool winding or excessive entry angle from the spool holder.
Typical applications for the Clariant natural-color PLA filament are non-structural jigs, assembly fixtures, visual inspection aids, and sacrificial forming templates that remain below the heat deflection temperature of unmodified PLA. At 0.45 MPa loading, unfilled PLA exhibits HDT in the range 50–60 °C per ISO 75-2; therefore parts should not be specified for engine-compartment, hot-fluid, or continuous-load environments above 50 °C. The natural color permits post-print dyeing or solvent-free painting, but surface adhesion requires preliminary sanding at 600–1000 grit or plasma treatment; untreated PLA surfaces exhibit low surface energy and poor coating adhesion. Mechanical fastening of printed components should use threaded inserts installed with thermal insertion tools at 180–200 °C; self-tapping screws in as-printed PLA can split along layer lines unless pilot holes are oversized by 0.2–0.3 mm.
At a nozzle temperature of 200 °C, unmodified PLA exhibits melt viscosity suitable for layer bonding, but the processing window is bounded by two failure modes. At 170–180 °C, the melt phase remains stiff and the contact time between adjacent strands is insufficient for reptation-driven interdiffusion across the weld interface; tensile strength of printed test coupons measured per ASTM D638-14 can fall to 30% or less of the filament’s bulk yield strength. At 230 °C or above, thermal degradation produces a reduction in molecular weight, visible as a decrease in melt viscosity and the formation of acrid lactic acid decomposition products. Degradative chain scission shifts the melt flow rate upward, sometimes outside the 6–12 g/10 min range within 10 min of residence time in the hot end. The safe extrusion range for natural PLA is therefore typically 190–220 °C, with the nozzle temperature adjusted downward for high-flow toolheads with short melt zones and upward for hardened steel nozzles that conduct less heat than brass. Print cooling fans should be set to 20–50% speed for small layers and disabled for the first 2–3 layers to preserve bed adhesion on open-frame machines.
Product-specific mechanical data for the Clariant Polylactic Acid Natural Color filament are not fully disclosed in widely available public summaries; therefore the following table provides reference ranges for unfilled, natural-color PLA homopolymer from published polymer property compilations. These ranges identify what a buyer should expect if the Clariant lot conforms to the general class, but they do not replace a certificate of analysis for the actual spool batch.
| Property | Test method | Reference range for unmodified PLA |
|---|---|---|
| Melt flow rate at 210 °C/2.16 kg | ISO 1133-1:2022 | 6–12 g/10 min |
| Tensile strength at yield | ISO 527-2 | 50–70 MPa |
| Tensile modulus | ISO 527-2 | 3.0–3.8 GPa |
| Elongation at break | ISO 527-2 | 2–6% |
| Flexural modulus | ISO 178 | 2.5–3.5 GPa |
| Heat deflection temperature at 0.45 MPa | ISO 75-2 | 50–60 °C |
| Density | ISO 1183-1 | 1.24–1.26 g/cm³ |
| Glass transition temperature | ISO 11357-2 | 55–60 °C |
| Melting peak temperature | ISO 11357-3 | 165–180 °C |
Annealing of natural PLA at 65–80 °C for 30–60 min in a forced-air oven can increase crystallinity and raise heat deflection temperature, but linear shrinkage of 0.5–2.0% may occur, and thick sections are prone to distortion. The annealing cycle should be validated with a controlled fixture to prevent warpage. Published data for Clariant-specific annealing response are limited, so process qualification should be performed on printed specimens from the actual spool batch. Continuous contact with hot water above 60 °C, acetone, methylene chloride, or strong bases should be avoided because PLA undergoes hydrolytic and solvent-assisted degradation under these conditions.
Compared with pigmented PLA, the natural grade removes the influence of colorant nucleating agents on solidification and thereby reduces the probability of nozzle clogging in 0.25 mm and 0.4 mm orifices. Compared with ABS filaments, natural PLA has lower volatile organic emission during printing and lower bed temperature requirement, but it also exhibits lower heat deflection temperature and lower impact resistance. Compared with PETG, natural PLA has higher stiffness and lower elongation at break, typically 2–6% versus 15–25% for unfilled PETG, measured by ISO 527-2; this makes PLA less suitable for snap-fit closures that require large post-yield deformation. Compared with PLA blends containing polyhydroxyalkanoate or impact modifiers, the unmodified natural grade has a narrower processing window and lower toughness, but it provides more consistent melt flow and better dimensional reproducibility in low-cost open-frame equipment. Material substitution decisions should be validated using printed parts from the actual Clariant lot, the intended toolhead configuration, and the target build chamber environment.