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Covestro Addigy FPU 77D X1010 3D Printing Polyurethane Filament

    • Название продукта: Covestro Addigy FPU 77D X1010 3D Printing Polyurethane Filament
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
    • Запрос цены: admin@ascent-chem.com
    • Производитель: Ascent Petrochem Holdings Co., Limited
    • Свяжитесь сейчас
    Спецификации
    Код ТН ВЭД 535216

    Как аккредитованный завод Covestro Addigy FPU 77D X1010 для 3D-печати полиуретановых нитей, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

    Упаковка и хранение
    Упаковка Covestro Addigy FPU 77D X1010 comes as a 1 kg spool, vacuum-sealed in a moisture-barrier bag inside a cardboard box.
    Погрузка контейнера (20-футовый контейнер) 20′ FCL: palletized, shrink-wrapped filament spools in cartons, loaded and secured in dry container; protect from moisture, heat, direct sunlight.
    Доставка Covestro Addigy FPU 77D X1010 is shipped as solid, non-hazardous polyurethane filament in sealed moisture-barrier bags with desiccant, packed in cartons or on pallets. Store dry at moderate temperatures, away from heat, sunlight, and moisture. No special DOT/IMDG transport classification is typically required. Follow supplier SDS and local regulations.
    Хранение Store Covestro Addigy FPU 77D X1010 filament sealed in its original moisture-barrier bag with desiccant. Keep in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, and incompatible chemicals. Maintain 15–25°C and below 50% relative humidity. For opened spools, use airtight dry boxes or filament dryers. Avoid prolonged exposure to humid air and UV light.
    Срок годности Shelf life is typically 12 months when stored unopened in original packaging, cool, dry, and protected from moisture.
    Применение Covestro Addigy FPU 77D X1010 3D печати полиуретановой нити

    Footwear Soleing Components Where Shore 77D Replaces Injection Molding for Short-Run Athlete-Specific Tooling

    In athletic footwear development, short-run athlete-specific sole components require a material that maintains 77D Shore hardness, high tear initiation resistance per ASTM D624, and interlayer adhesion sufficient to survive elliptical shear at the outsole-to-midsole bond. Addigy FPU 77D X1010 is selected for direct extrusion of cleat plates, semi-rigid heel counters, and load-bearing outsole zones where injection-molded TPU would impose tooling lead time and minimum order quantities that athlete-specific programs cannot absorb. Compliance for this class of footwear component falls under EU REACH 1907/2006 Annex XVII restrictions for residual monomers and plasticizers, EU Directive 94/11/EC material labelling, and, for bonded sole constructions, ISO 22649:2019 water absorption and desorption testing when full sole unit validation is required. The formulation addition level in the printed component is 100 wt% Addigy FPU 77D X1010; the grade is fully compounded and no plasticizer, chain extender, or filler is added at the dryer or hot end. When the printed TPU is integrated as an outsole over an EVA midsole, the TPU fraction may be 50–90 wt% of the final sole assembly depending on wall thickness and infill. Terminal finished product types include replacement outsoles, perforated footbed supports, soccer cleat plates, and semi-rigid heel counters.

    Downstream manufacturing uses fused filament fabrication with a direct-drive extruder; bowden tubes are not recommended because the 77D grade retains enough elastic recovery to buckle in long filament paths during rapid retraction. Spools are dried at 80 °C for 4 h to residual moisture below 0.02 wt%, and production cells above 60% relative humidity require closed-loop dry feed or point-of-use desiccant. The hot end is set to 240–250 °C, the heated bed to 60–70 °C, layer height between 0.12 mm and 0.20 mm, and linear print speed between 25 mm/s and 40 mm/s. Toolpath for heel counters uses 3–4 perimeter walls and 60–80% triangular infill; ground-contact outsole plates use 85–100% rectilinear infill. Post-processing is typically limited to support removal and edge deburring; forced-air annealing at 100 °C for 2 h may increase interlayer bond strength but produces 0.4–0.8% anisotropic dimensional shift that must be compensated in scan algorithms.

    Processing Window for Shore 77D Polyurethane Filament in Footwear Soleing Fused Filament Fabrication
    Process variableTarget rangeObserved failure outside range
    Spool moisture after dryingbelow 0.02 wt%Hydrolysis porosity at interlayer boundaries and foamed extrusion lines
    Hot end zone240–250 °Cbelow 230 °C poor interlayer peel; above 260 °C yellowing and viscosity instability
    Heated bed60–70 °Cbelow 50 °C curl at thin heel counter flanges; above 85 °C edge slump
    Linear print speed25–40 mm/sabove 45 mm/s feed skipping at the drive gear; below 15 mm/s stringing and local overheat

    Robotic end-of-arm tooling inserts printed from Addigy FPU 77D X1010 occupy the gap between hard polyamide-CF structural jaws and soft silicone vacuum pads, providing a 77D Shore polyurethane contact face that resists abrasive wear and does not mar plastic or painted workpieces. Safety compliance for gripper cells follows ISO 10218-1:2011 clause 5.4 for hazards, ISO 10218-2:2011 for robot systems, and ISO/TS 15066:2016 for human-robot contact force and speed limits when cobots are used. The material addition configuration in multi-material EOAT is 80–90 wt% Addigy FPU 77D X1010 for the contact face, co-printed or mechanically keyed to a 10–20 wt% rigid polyamide or metal jaw backing; for monolithic soft jaws the polyurethane is 100 wt% and the backing is machined aluminium.

    Manufacturing process uses fused filament fabrication with direct-drive hardware and a 0.6–0.8 mm hardened steel nozzle to reduce backpressure at 30–40 mm/s linear travel. Drying at 80 °C for 4–6 h is mandatory because robotic cell downtime magnifies moisture-related defects such as hydrolysis bubbles at the interface with rigid backing. Interlayer adhesion is maintained by disabling the part cooling fan for the first 4 layers and limiting fan speed to 20–30% thereafter. Terminal finished product types include workpiece-specific gripper fingers, part locators, feed fingers, and palletizing guide rails. This grade is not validated for direct food contact under FDA 21 CFR 177.2600 or for sustained washdown with amine-based detergents, which can swell the surface and reduce tear resistance.

    What Happens When Shore 77D Urethane Filament Replaces Nylon 12 in Engine-Bay Harness Clips?

    Within engine compartments, harness routing clips and connector covers are subjected to continuous vibration, thermal cycling from -40 °C to 105 °C, and intermittent exposure to fuels, oils, and coolant mists. Addigy FPU 77D X1010 is processed into low-volume clip bodies, locking collars, and dust covers where its flexural recovery prevents snap tab stress whitening and its abrasion resistance reduces harness sleeve fretting. Industry compliance anchorages include EC 2000/53/EC ELV Annex II for lead, cadmium, mercury, and hexavalent chromium; REACH 1907/2006 Annex XVII; environmental endurance validation per ISO 16750-3:2012 mechanical vibration and shock and ISO 16750-4:2010 temperature and humidity cycling. The printed clip body is 100 wt% Addigy FPU 77D X1010; for dual-material clips, the TPU snap feature is 25–40 wt% of assembled part, with a PA12 base retained only where heat-set metal inserts or bolt bosses are required.

    Processing uses a 0.4 mm nozzle, layer height between 0.10 mm and 0.15 mm, print speed 30–35 mm/s, nozzle temperature 240–255 °C, and bed temperature 60–70 °C. For thin snap tabs, 3–4 perimeter walls and 35–50% triangular infill are used to preserve flexural modulus while reducing part mass. Failure modes observed on vehicle trial builds include interlayer delamination at abrupt neck areas when layer cooling exceeds 50% fan duty, and dimensional drift when spool moisture is not held below 0.02 wt%. Terminal finished products are engine harness routing clips, cold-side connector dust covers, sensor bracket isolators, and grommet locking rings. The material is not suitable for direct exhaust or turbocharger attachment points where continuous temperature exceeds 120 °C, and it should not be exposed to hot engine oil above 80 °C for extended cycles without end-use validation.

    Semirigid orthotic shells carrying 77D Shore hardness are produced from Addigy FPU 77D X1010 for custom ankle-foot orthosis prototypes, prosthetic check sockets, and dynamic hinge trials. Compliance for these devices is controlled by the device manufacturer: ISO 10993-1:2018 biological evaluation planning, ISO 10993-5 cytotoxicity testing for skin-contacting devices, ISO 22523:2006 for orthoses, and EU MDR 2017/745 custom-made device procedures. Raw resin compliance alone does not confer medical device approval; the filament supplier does not provide a drug master file or implantable-grade certification. The printed shell is 100 wt% Addigy FPU 77D X1010 with no additives; load-bearing struts are generated with 3.0–4.0 mm wall thickness and 80–100% infill, while flexible hinge zones are locally reduced to 1.2–1.8 mm by perimeter-only toolpaths.

    Fabrication requires a 0.4 mm nozzle, layer height 0.12–0.15 mm, nozzle temperature 235–250 °C, bed temperature 60–70 °C, and print speed 20–30 mm/s; the part cooling fan remains off for the initial 3 layers and is capped at 20% above that point to maintain interlayer peel resistance. After build, contour adjustment is performed with circulating hot air at 110–130 °C; locally exceeding 150 °C produces surface discoloration and oxidation that can reduce tear resistance. Published data for this specific configuration is limited, so device-specific mechanical and skin-contact validation remains the responsibility of the orthotic or prosthetic production unit. Terminal finished product types include custom AFO shells, diagnostic check sockets, prosthetic interface prototypes, and dynamic orthotic hinge components. The material is not validated for permanent soft tissue contact or for insertion into mucosal tissue.

    Industrial Gasket and Sealing Elements for Low-Pressure Hydrocarbon and Aqueous Service

    Where bolted flanges on inspection ports require compressed sealing elements outside the manufacturer’s molded inventory, Addigy FPU 77D X1010 is printed as short-run flange gaskets, wiper rings, and scraper edges. Compliance for industrial sealing service is anchored to ASTM D412-16 tensile property measurement, ASTM D2240-15 durometer verification, ISO 815-1:2019 compression set, ASTM F36-15 gasket compressibility and recovery, and ISO 3601-1:2012 for O-ring dimensional acceptance where applicable. The printed gasket body is 100 wt% Addigy FPU 77D X1010; sealing faces are generated with 98–100% infill at 0.08–0.12 mm layer height to minimize leakage paths along extrusion lines. In twin-material sealing assemblies, the TPU sealing lip represents 60–75 wt% of the component mass, with the metallic or rigid thermoplastic retainer accounting for 25–40 wt%.

    Processing conditions: 0.4 mm nozzle, nozzle temperature 235–250 °C, bed temperature 65–75 °C, print speed 20–30 mm/s, and cooling fan limited to 5–15% to permit interlayer chain diffusion. After build, compression set conditioning at 70 °C for 22 h per ISO 815-1:2019 can be used to stabilize the sealing response before installation. Terminal finished products include low-pressure flange gaskets, inspection port seals, hydraulic wiper rings, and pump service scraper edges. Service boundaries should be observed: continuous exposure above 80 °C in hot hydrocarbon or aggressive amine-containing process fluids increases compression set, and gas sealing above 5 bar requires end-use validation because printed sealing surfaces may exhibit void-assisted permeation.

    When Electronic Enclosure Hinges Require Repeated Flexure Without Polyamide Brittle Fracture

    Hinges and snap-fit covers in field instruments and battery-operated diagnostic tools demand repeated flexure resistance without the brittle fracture of glass-filled polyamide. Addigy FPU 77D X1010 is used for hinge strips, battery cover tethers, and snap-fit enclosure gaskets where 77D Shore hardness provides enough stiffness to hold position but sufficient yield to survive installation cycles. Enclosure compliance requires IEC 60529:2013 dust and water protection testing for final assembly, UL 94 HB flammability classification of the printed polymer, EU RoHS Directive 2011/65/EU for restricted substances, and REACH 1907/2006 Annex XVII. The hinge component is printed at 100 wt% Addigy FPU 77D X1010 with hinge thickness 1.5–2.0 mm, 40–60% infill, and 3 perimeter walls; in dual-material enclosures the TPU hinge strip is 30–50 wt% of the cover assembly, with the rigid shell made from polycarbonate or ABS.

    Fused filament fabrication uses a 0.4 mm nozzle, layer height 0.08–0.12 mm for hinge line resolution, nozzle temperature 235–255 °C, bed temperature 60–70 °C, and print speed 25–35 mm/s. The fan is switched off along the hinge path for the first 3 layers and limited to 30% afterward to prevent embrittled transverse welds. Terminal finished products include hinged inspection flaps, battery door tethers, snap-fit enclosure gaskets, and reinforced wearable diagnostic housing components. Long-term UV exposure without a stabilizing coating can reduce tensile strength and should be validated per ASTM G154 fluorescent UV exposure testing before deployment in outdoor field instruments.

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    Более подробное введение

    Covestro Addigy FPU 77D X1010 is a thermoplastic polyurethane filament engineered for material extrusion processes classified under ISO/ASTM 52900 as MEX-FRF feedstock. The grade suffix 77D corresponds to a nominal indentation hardness of 77 on the Shore D scale determined by ISO 7619-1 or ASTM D2240, placing the material close to the rigid boundary of elastomeric polyurethane. Unlike filament grades sold as flexible TPU with Shore A values of 85A to 95A, the 77D chemistry contains a higher weight fraction of hard segments, generating elevated melt viscosity and improved creep resistance at ambient temperature. The product is supplied in 1.75 mm and 2.85 mm nominal diameters with laser-verified roundness; current lot certificates should be consulted for exact tolerance and spool dimensions. The X1010 suffix denotes a particular rheological and additive package within the Addigy FPU family and should not be assumed to be interchangeable with other 77D TPU filaments unless the melt-flow index measured under ISO 1133-1:2022 and mechanical lot data are matched. Public multi-laboratory datasets for this specific configuration remain limited; most published values originate from the manufacturer’s technical data sheet and lot-specific certificates.

    What Distinguishes a 77D Polyurethane Filament from Flexible TPU and Engineering Thermoplastics?

    The primary distinction is mechanical modulus. Flexible TPU products in the 85A to 95A range typically show flexural modulus below 200 MPa under ISO 178, while Shore D grades above 70D commonly exceed 1,000 MPa. This shifts part behavior from rubber-like bending to snap-fit or fixture-like rigidity while retaining higher notched impact resistance than unmodified PLA or PMMA when tested under ISO 179-1/1eA. In comparison with polycarbonate or ABS, the polyurethane soft segment contributes lower sliding friction against metal counterfaces and better recovery after localized deformation. Abrasion resistance in this class is assessed according to ISO 4649-A or DIN 53516; the manufacturer’s specification sheet for FPU 77D X1010 should be reviewed for the specific mass-loss value because generic Shore D TPU formulations fall within a broad range of 20 mm³ to 50 mm³ depending on soft-segment chemistry. The material also differs from unfilled nylon in lower moisture absorption and from POM or PA-GF in lower sliding noise, but these properties are application-specific and must be verified on printed specimens rather than transferred from injection-molding datasheets.

    Pre-drying is not optional. At melt temperatures required for layer fusion—typically 240 °C to 260 °C on all-metal hot ends—residual moisture above approximately 0.02% by mass hydrolyzes urethane linkages, producing splay, microvoids, and reduced Z-axis tear strength. A desiccant dryer set to 80 °C for 4 h to 6 h with an outlet dew point below -40 °C is the standard conditioning method for rigid TPU resins, and the spool should be processed from a sealed container or maintained at relative humidity below 35% during builds longer than 12 h. Moisture regain can be monitored by weight loss after drying; a weight gain of 0.1% to 0.2% after 24 h at 50% relative humidity is a typical uptake range for rigid TPU and is sufficient to degrade layer adhesion. The narrow processing window relative to PETG results from the same hard-segment concentration that provides the 77D hardness; insufficient nozzle temperature produces interlayer delamination, while excessive temperature causes polymer degradation and viscosity drift within 8 h of heated residence time.

    When Oil-Exposed Fixtures and End-of-Arm Tooling Require a Semi-Rigid Abrasion-Resistant Material

    In manufacturing cells where printed tooling is exposed to cutting oils, greases, and coolant emulsions, FPU 77D X1010 offers an operational advantage over ABS and PLA in solvent stress-cracking resistance. The relevant evaluation is ISO 175 immersion testing followed by residual tensile strength measurement according to ISO 527-2, not visual inspection alone. On production floors, jigs printed from similar 77D TPU have been run in machining environments where ABS fixtures show stress whitening around clamped inserts and PC/ABS blends fail by environmental stress cracking at sharp fillet radii. The polyurethane grade retains strain tolerance at notches but has a creep limit; continuous static loads above 50 °C may exceed the usable service envelope unless loads are derated. Published data for the long-term creep of this specific grade under ISO 899-2 are limited, so a practical alternative is to measure part deflection under the actual service load for 72 h before relying on additively manufactured tooling.

    The selection of extruder hardware changes markedly when moving from 95A TPU to a 77D polyurethane filament. Direct-drive extruders with dual-drive hardened steel gears are preferred because the high filament stiffness resists buckling under feed pressure, but gear tooth pressure above the slip threshold creates filament shaving that migrates into the hot end and increases clogging frequency. Bowden systems with tube lengths greater than 500 mm may require reduced retraction distances below 1.5 mm and print speeds not exceeding 30 mm/s with a 0.4 mm nozzle to maintain consistent melt pressure. On direct-drive tools, starting parameters of 0.5 mm to 1.0 mm retraction at 15 mm/s to 25 mm/s reduce stringing without inducing air ingestion. Nozzle temperatures between 240 °C and 260 °C are typical; temperatures above 270 °C are not recommended on open-air printers because of the onset of urethane depolymerization and volatile decomposition products. A heated bed at 60 °C to 80 °C with a polyetherimide or glass build surface and a release layer improves first-layer adhesion, but the bed temperature should be reduced after the first 5 layers to avoid edge softening on high-infill parts.

    Chemical Compatibility Boundaries in Solvent- and Steam-Exposed Applications

    FPU 77D X1010 resists aliphatic hydrocarbons, mineral oils, and many dilute inorganic acids, but it is not a universal solvent-resistant substitute for semicrystalline fluoropolymers. Ketones, esters, chlorinated solvents, and aromatic hydrocarbons can swell the soft-segment phase and produce a drop in Shore D hardness of more than 5 points after 24 h immersion at 23 °C under ISO 175. Steam above 100 °C and hot aqueous alkali are aggressive because of hydrolysis; polyester-based soft segments undergo ester cleavage, while polyether-based soft segments may degrade oxidatively. The supplier’s safety data sheet and REACH documentation should be consulted before using the material in medical, food-contact, or potable water environments. RoHS compliance is not automatic for pigmented or flame-retardant variants; unmodified natural grades should be verified against EU 2011/65/EU lot declarations. For load-bearing chemical exposure, stress-cracking tests under ISO 22088-2 are recommended over simple immersion because residual stresses from fused filament fabrication lower the critical strain for craze initiation.

    Interlayer bonding is the controlling variable in mechanical performance and cannot be inferred from injection-molded TPU datasheets. In FFF, the Z-direction tensile strength of a stiff TPU often falls to 40% to 70% of the XY value when measured according to ISO 527-2 and depends on chamber temperature, raster width, and cooling fan use. Addigy FPU 77D X1010 is no exception. Reducing cooling fan speed to 20% to 50% and printing parts in a warm chamber at 40 °C to 60 °C extends interlayer diffusion time, but may reduce overhang accuracy. For parts loaded in Z, design stress should be derived from printed specimens in the same orientation, not from supplier tensile data. Fracture surfaces from insufficient interlayer fusion show smooth raster boundaries with limited deformation, distinct from the ductile rupture observed in fully fused specimens. This failure signature is a useful diagnostic on production lines when settings drift after nozzle changes or firmware retraction updates.

    Why Does the 77D Grade Need Different Slicer Settings Than Glass-Filled Nylon or PETG?

    The answer is dominated by the temperature-viscosity curve and shrinkage behavior. Glass-filled nylon and PETG crystallize during cooling, but a high hard-segment thermoplastic polyurethane develops a phase-separated morphology in which the hard domains act as physical crosslinks; this reduces warping but increases melt elasticity. The slicer should use lower acceleration and jerk values than PETG to avoid extruder pressure oscillations, typically below 1,000 mm/s² acceleration for a 0.4 mm nozzle. Volumetric flow rate should be limited to 5 mm³/s to 8 mm³/s in unheated enclosures to prevent under-extrusion. Unlike nylon, no high-temperature chamber above 80 °C is required, but a stable ambient temperature is beneficial. The filament also does not require the filament-drying temperatures used for PA6/PA66; 80 °C is sufficient, and higher temperatures can distort the spool. These slice-level boundaries are directly observable as under-extrusion artifacts at high speed and as seam splitting when pressure advance is set too aggressively.

    In comparison with glass-filled or carbon-fiber-reinforced filament brackets, FPU 77D X1010 is not designed to meet stiffness targets above 10 GPa. The grade is unfilled, so nozzle wear is comparable to standard unfilled thermoplastics; a hardened steel nozzle is not mandatory unless abrasive fillers are introduced by the user. This is a practical difference when maintaining a large print farm: the same hardened nozzles required for PA-CF or GF-PETG are not necessary, but the polyurethane’s high melt viscosity still increases nozzle backpressure compared with PLA. Feed-path maintenance focuses on preventing filament shaving at the extruder gear and avoiding moisture accumulation at the spool surface, not on abrasion-related nozzle replacement. Layer height above 0.2 mm with a 0.4 mm nozzle improves interlayer strength in rigid TPU because the larger melt bead holds heat longer; layer heights below 0.1 mm can produce sharp details but reduce interdiffusion time and may require a chamber temperature at the upper end of the range.

    When specifying this material for an engineering print, the procurement document should require certificates referencing ISO 527-2 tensile properties, ISO 178 flexural modulus, ISO 179-1/1eA notched Charpy impact, ISO 4649-A abrasion loss, and ISO 306/A50 Vicat softening temperature. The lot certificate should state specimen printing orientation, raster geometry, and any annealing applied. Without these metadata, comparisons between suppliers are not valid. If annealing is used, dimensional change must be evaluated on a constrained fixture before production release, because rigid TPU parts can relieve frozen-in orientation stresses and shift critical dimensions during post-print heating.

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