| Код ТН ВЭД | 287737 |
Как аккредитованный завод DSM Somos ProtoGen™ 18920 для жидких фотополимеров, ультрафиолетового и термического посткурения, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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For direct-shelling investment casting patterns in gas turbine repair cell operations, the build configuration is defined by ceramic shell expansion stresses rather than photochemical conversion alone. DSM Somos ProtoGen™ 18920 liquid photopolymer is built on a 355 nm vat photopolymerization system with a 0.10 mm layer thickness, a 0.15 mm laser spot diameter, and a hatch spacing of 0.08 mm to 0.12 mm. The pattern is generated as a hollow shell with an internal hexagonal lattice, a wall thickness of 2.5 mm to 3.5 mm, and drain holes of 3 mm to 5 mm diameter. After solvent rinse in tripropylene glycol monomethyl ether and UV postcure at 1.5 J/cm² UVA, the pattern receives a thermal postcure at 70°C for 2 h in forced air. The thermal step raises surface conversion above 92% before ceramic investing. Insufficient postcure leaves residual acrylate unsaturation that softens during autoclave exposure at 150°C and causes shell distortion. Foundry protocols require linear shrinkage measurement per ASTM D2566-86 on a 100 mm bar before primary slurry application. Shell cracking during pattern burnout is managed by targeting ash residue below 0.05% and ramping from 200°C to 900°C at 2°C/min under an oxidizing atmosphere. Published data specific to ProtoGen 18920 in industrial turbine blade shelling is limited; production foundries validate each batch by casting a 15 mm wedge section and sectioning it for porosity.
For small rotating parts, the pattern is oriented 20° to 40° from the vertical so that recoat blade pressure does not induce layer delamination on unsupported leading edges. Support contact marks are removed by wet sanding with 600-grit silicon carbide paper before applying a 0.5 mm primary slurry coat of fused silica and colloidal silicate. The primary coat pH is held between 9.5 and 10.5 to avoid acid hydrolysis of residual photopolymer at the pattern surface. Secondary slurry viscosity is 8 s to 10 s on a Zahn #4 cup. Terminal cast parts include turbine blade replacement components and pump impellers in 17-4PH stainless steel and Inconel 625. The pattern is not suitable for direct resin-burnout in microwave dewax systems where local temperatures exceed 1,200°C before oxygen can penetrate the thick shell.
Master patterns for room-temperature vulcanization silicone tools are prepared from ProtoGen 18920 at a layer thickness of 0.05 mm when the average surface roughness of the tool must be below 0.8 µm Ra per ISO 4287. Platform parameters shift to a 250 mW laser power at 355 nm, and a 0.05 mm hatch spacing. Published data for this exact photopolymer in platinum-cured RTV applications is limited. However, residual amine or sulfide species in photopolymers are known to poison platinum-catalyzed hydrosilylation at the master interface. To reduce inhibition risk, the master pattern undergoes UV postcure at 1.8 J/cm² in a 360 nm to 420 nm broadband chamber, followed by thermal postcure at 75°C for 4 h and an additional 30 min at 90°C under vacuum. Outgassing of residual low-molecular-weight acrylate species is monitored with a vacuum pressure rise test; a master is not released to tooling until chamber pressure remains below 1.0 kPa after 10 min isolation. If tin-condensation-cure RTV is substituted, inhibition is avoided but tool shrinkage increases to 0.6% to 1.2% compared with 0.1% to 0.3% for platinum cure. Terminal outputs are polyurethane cast parts in 45 Shore A to 65 Shore A elastomer. The pattern is frequently molded with a 10 mm to 15 mm silicone wall over a rigid epoxy backup shell. No silane-coupling release agent is used because it alters interfacial wetting of platinum RTV.
Dimensional control for the silicone mold is referenced to ISO 16916:2016 for tool-in-use shrinkage. The master is kept in a desiccated cabinet at 23°C and 35% RH for 48 h before molding to stabilize moisture expansion. Build orientation for flat master plates is 15° from horizontal to reduce cupping. After thermal postcure, the surface is lightly polished with 3 µm aluminum oxide slurry; deep polishing cuts through the highly crosslinked surface skin and can expose less-cured core material, which increases silicone inhibition.
Design verification groups producing portable diagnostic instrument housings with ProtoGen 18920 operate under ISO 13485:2016 document control, but the photopolymer is not designated as a body-contact material. The housing prototypes are used for benchtop usability testing, board fitment checks, and drop-tower evaluation. Mechanical property acceptance is anchored to ASTM D638-14 tensile values obtained on solid specimens built in the same build orientation as the housing walls. The material is postcured with UV at 1.2 J/cm² followed by thermal cure at 65°C for 2 h. Surface cleanability is tested by wiping with a 70% isopropyl alcohol / 30% deionized water solution for 60 cycles; unpigmented photopolymer surfaces may exhibit slight tack after repeated exposure to strong solvents. The manufacturer has not published a full ISO 10993-5:2009 cytotoxicity dataset for this product, so biocompatibility screening is outsourced only when the prototype contacts intact skin for more than 24 h in a formative study. The housing prototypes are assembled with brass heat-stake inserts. Insert retention strength is measured at 23°C using a screw pull-out speed of 5 mm/min. The material is not recommended for steam autoclave sterilization at 121°C because the heat deflection temperature under 0.46 MPa falls below this temperature for most unfilled stereolithography resins.
| Evaluation | Test method | Acceptance criterion |
|---|---|---|
| Tensile modulus | ISO 527-2:2012 | Report value at 23°C, 50% RH |
| Notched Izod impact | ASTM D256-10(2018) | Report value at 23°C |
| Heat deflection temperature | ISO 75-2:2013 | Report value at 0.46 MPa |
| Surface wipe resistance | ASTM D543-21 | No visible tack after 60 cycles with 70% IPA |
| Drop resistance | IEC 60068-2-31:2008 | No fracture at 1 m onto plywood |
In subsonic wind tunnel development for underbody aero components, ProtoGen 18920 models are built as scale 1:4 and 1:5 shells with a 0.10 mm layer thickness. The surface must be sealed because the as-built stereolithography stair-step roughness, typically Ra 2.0 µm to 3.0 µm at 0.10 mm layer thickness, exceeds the Ra 1.0 µm requirement for attached flow visualization. Post-processing includes solvent rinse in 2-propanol, UV postcure at 1.5 J/cm², thermal cure at 60°C for 1.5 h, then hand sanding with 320-grit abrasive and a polyester spray filler. The filler is wet-sanded to 600-grit. The wind tunnel model is tested at airspeeds up to 40 m/s because the heat deflection temperature of this unfilled photopolymer limits use at higher stagnation temperatures. The part is mounted on a six-axis force balance through a 10 mm aluminum backbone cast into the model. Pressure taps of 0.8 mm inner diameter are produced as sacrificial holes and cleared with a 0.8 mm reamer. The terminal output is an aero load map for front splitter and rear diffuser development. The photopolymer shell is not used for transonic or hot-cycle testing where surface temperatures exceed 50°C. Build orientation is set at 5° to 15° from the airflow direction to minimize separated flow from layer steps. Published data for this exact use is limited; teams typically run a baseline test with an aluminum reference plate to correct for model flexure.
Because the model is a hollow shell, internal ribs are spaced at 25 mm to 30 mm and wall thickness is 2.0 mm to 2.5 mm. Drain holes are placed in low-pressure regions. The resin is not loaded with abrasive fillers, so machining of pressure tappings must use new high-speed steel drills at 4,000 rpm with soluble coolant to prevent heat buildup. Model weight is kept below 3.5 kg for the balance load cell. The postcure is necessary to reduce creep under aerodynamic loads; uncured or UV-only postcured models show time-dependent deflection of 0.2 mm over a 60 s load period at 30°C.
Assembly lines that depanel thin FR-4 boards use router fixtures with vacuum channels and clamp nests produced from ProtoGen 18920. The fixtures are designed with a 0.10 mm or 0.15 mm layer thickness, depending on whether locating features are smaller than 2 mm. Thermal postcure is set to 80°C for 2 h in a recirculating oven to maximize the glass transition onset and reduce creep at room temperature. The material is an electrical insulator with surface resistivity typically above 10¹³ Ω when dry, so it is not inherently static-dissipative. An engineered conductive carbon-loaded acrylic coating is applied to the upper surface to achieve a surface resistivity between 10⁶ Ω and 10⁹ Ω per IEC 61340-5-1. The control plan requires the fixture to be marked with a lot number and the coating thickness to be verified at 25 µm to 40 µm by an eddy-current probe. Terminal use is a router fixture for depaneling 150 mm by 220 mm boards with 1.6 mm thickness.
Board locators are built to +0.05 mm / -0.00 mm over a 165 mm span. Because unfilled stereolithography resins absorb moisture from air, fixture dimensions shift by 0.1% to 0.2% when stored at 80% RH for 48 h; a conditioning protocol of 23°C and 50% RH for 24 h before coordinate measuring machine verification is mandatory. The router spindle creates a lateral cutting force of 25 N to 40 N at 40,000 rpm; the fixture walls are stiffened with 8 mm ribs on a 25 mm grid.
Prototype thermoforming tools for PETG blister packaging are occasionally produced from ProtoGen 18920 for short runs. PETG is processed at sheet surface temperatures of 110°C to 130°C. The unfilled photopolymer has a heat deflection temperature that is field measured according to ISO 75-2:2013 at 0.46 MPa. In most unfilled epoxy/acrylate stereolithography resins, the HDT at 0.46 MPa ranges from 50°C to 70°C. A tool made from ProtoGen 18920 therefore operates in a transient heat transfer mode; the aluminium tool base acts as a heat sink, and the photopolymer face must not remain in continuous contact with the heated sheet for more than 15 s per cycle. Vacuum holes of 0.6 mm to 0.8 mm are drilled through the face after thermal postcure at 70°C for 3 h. The tool face is coated with a PTFE dry-film lubricant to reduce PETG sticking. The mould is used for 20 to 50 cycles, not for production volumes exceeding 1,000 parts. Published data for this specific configuration is limited; a trial tool is validated with a thermocouple embedded 1.0 mm below the face, and face surface temperature is kept below 55°C with forced-air cooling between cycles.
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DSM Somos ProtoGen™ 18920 Liquid Photopolymer, UV & Thermal Postcure is an opaque stereolithography feedstock formulated for 355 nm vat photopolymerization platforms. The material is supplied as a liquid photopolymer that requires sequential ultraviolet and thermal postcure after the laser build to reach full mechanical conversion. Manufacturer technical data place the liquid density in the 1.13 g/cm³ range at 25 °C when tested per ASTM D4052. Fully postcured specimens exhibit tensile modulus in the 2000–2500 MPa range, notched Izod impact in the 20–30 J/m range, and heat deflection temperature in the 55–65 °C range at 0.46 MPa when evaluated per ASTM D638, ASTM D256, and ASTM D648, respectively. Green-state mechanical response is substantially lower; datasheet values apply only after complete UV and thermal aging. The product differs from clear SLA grades by the presence of an opaque pigment system and by a two-stage postcure requirement that modifies final crosslink density, moisture uptake, and dimensional stability.
| Property | Test method | Typical range |
|---|---|---|
| Tensile strength | ASTM D638 | 42–48 MPa |
| Tensile modulus | ASTM D638 | 2000–2500 MPa |
| Elongation at break | ASTM D638 | 15–25% |
| Flexural strength | ASTM D790 | 60–70 MPa |
| Flexural modulus | ASTM D790 | 1800–2300 MPa |
| Notched Izod impact | ASTM D256 | 20–30 J/m |
| Heat deflection temperature at 0.46 MPa | ASTM D648 | 55–65 °C |
| Hardness | ASTM D2240 | 83–86 Shore D |
Typical uses include rigid housing prototypes, jigs, fixtures, and short-run tooling masters. Functional snap-fit features should be evaluated using notched Izod impact per ASTM D256; load-bearing structural behaviors should be validated under ASTM D638 and ASTM D790 rather than inferred from single-point hardness or Shore D readings. For components exposed to wet or humid environments, dimensional changes should be benchmarked using conditioned specimens per ASTM D618 and water-absorption testing per ASTM D570. Published data for this specific resin configuration is limited for long-term hydrolysis and creep; users should generate service-life data when the part operates above 50 °C or in continuous contact with water.
Free-radical photopolymerization at the part surface is partially quenched by ambient oxygen because molecular O₂ acts as a radical scavenger. In interior lamellae the laser irradiance exceeds the scavenging capacity, but the outermost 5–20 µm can remain tacky after the build. If the part is moved directly to thermal postcure without UV flood exposure, the tacky surface can exude unreacted acrylate and generate contact marks or layer-face transfer. Production-scale stereolithography lines therefore specify an initial UV flood exposure in a reflection chamber or rotary UV station. The exact UV dose is system-dependent; published data for this specific configuration is limited, but process controls typically monitor intensity with a UV-A radiometer and maintain part surface temperature below the green-state distortion point. Nitrogen-blanketed UV chambers reduce oxygen inhibition but introduce ventilation requirements for solvent vapour and residual monomer off-gassing. Surface tack after UV exposure is an indicator of incomplete conversion and should not be corrected by extending thermal soak alone.
In humid environments, moisture uptake occurs preferentially in the green state because the partially cured oligomer network contains polar urethane and ester groups. Green parts should be stored in sealed containers with desiccant when relative humidity exceeds 60%; conditioning for mechanical testing at 23±2 °C and 50±5% RH follows ASTM D618. Build trays left in open air for more than 12 h may exhibit dimensional creep and surface blush. Pre-drying of sealed green parts at 40 °C for 2–4 h can reduce moisture-induced defects, but the drying schedule must remain below the temperature at which green-state thermal expansion causes warpage.
Liquid viscosity near 30 °C is typically reported in the 200–300 cP range. Viscosity below 150 cP at elevated vat temperature is not recommended for extended intervals because pigment and stabilizer settling can create non-uniform optical density. Above 400 cP, recoater blade travel pulls a thicker meniscus, increasing layer thickness variation and resin carry-out on part edges. On production platforms with gravity-fed recoater blades, an increase in resin temperature to 35 °C can reduce blade shear force but may also accelerate dark polymerization in heated zones; the vat should be maintained at constant temperature. A vat temperature drift greater than ±5 °C from the setpoint changes both viscosity and reaction rate. The recorded impact is not linear: a 5 °C increase lowers resin viscosity and reduces recoater drag but also decreases gel threshold fidelity. Failure modes observed on manufacturing lines include edge curl on large flat parts when the vat center becomes warmer than the corners. Operators measuring viscosity beyond the specified range should recalibrate laser exposure and recoat delay before adjusting blade gap.
Layer thickness is usually maintained between 50 µm and 100 µm. At 100 µm layers, the recoater must level a larger liquid volume, and trapped gas bubbles can persist near vertical sidewalls. At 50 µm layers, blade-induced shear elongates the liquid meniscus and can disturb fine features if the blade speed is too high. Published data for the optimum recoat speed for this specific resin is limited; users should derive a working curve using cure depth tests on the target machine. Dimensional compensation in the Z-axis must account for overcure into previous layers and for shrinkage during thermal postcure. Calibration blocks with known step heights are measured after full postcure and compared with the design file using coordinate measurement equipment calibrated to ISO 10360.
Thermal postcure drives latent free-radical propagation and permits stress relaxation in the network. If the oven setpoint approaches or exceeds the heat deflection temperature of the green or partially cured part, warpage occurs before conversion reaches full density. The recommended thermal aging cycle for this resin is a forced-air oven operation below the published HDT band of 55–65 °C; published data for this specific configuration is limited, and the manufacturer’s current technical data sheet should be used for exact settings. Process engineering practice is to ramp the part from ambient to the postcure temperature at 1–2 °C/min and to support unsupported overhangs with fine glass bead beds. Thick sections above 6 mm can exhibit exothermic cure acceleration; thermocouple probes inserted into sacrificial blocks of similar cross-section provide a more reliable control signal than oven air temperature. Thermal postcure in the absence of prior UV exposure does not compensate for surface inhibition and may create a hard shell over a partially cured core.
The thermal cycle also affects the final degree of conversion and residual stress state. Underheated parts may retain residual unreacted monomer and show lower modulus and lower HDT than datasheet values. Overheated parts may become brittle through thermal oxidation or additional crosslinking. Dimensional inspection after thermal postcure should be conducted after the part returns to 23±2 °C because the coefficient of linear thermal expansion distorts measurements taken above ambient. For parts with large flat sections, warpage can be reduced by postcuring in a constrained fixture, but the fixture mass adds thermal lag and requires longer soak times.
Dense packing of parts in a UV chamber or forced-air oven changes local irradiance and airflow. In rotary UV chambers, shadowed surfaces can receive less than half the dose of directly exposed surfaces. In forced-air ovens, closely spaced parts create stagnant zones where the part temperature lags the air temperature by 10–15 °C. Production-scale stereolithography operations counter this by limiting tray loading to a single layer and maintaining air exchange rates above 10 volume changes per hour. Temperature mapping of the oven under full load should be performed with thermocouples placed at the geometric center and corners of the load. Load-dependent cure variation is a documented failure mode on manufacturing lines: parts from the center of a dense batch exhibit lower hardness and lower HDT than parts from the exposed edges because the local thermal history differs. If loading density cannot be reduced, the thermal soak must be extended based on measured part temperature rather than nominal air temperature.
Relative to Somos WaterShed XC 11122, this product is opaque and therefore not specified for transmissive optical evaluation under ASTM D1003; its moisture uptake after 24 h immersion is higher than low-hygroscopic clear grades. Compared with high-modulus composite grades such as Somos PerFORM, ProtoGen 18920 has a lower flexural modulus and lower heat deflection temperature, but its reduced filler content allows thinner wall sections to be machined without chipping. Unlike UV-only postcure resins, this product requires a thermal aging step before final mechanical testing. If thermal postcure is omitted, tensile elongation may remain elevated, but tensile modulus and HDT may not reach the datasheet envelope. Users selecting between this resin and a clear grade should allocate the clear material only when light transmittance or visual clarity is a functional requirement; for opaque structural prototypes, the opaque product is processed without the additional filtration needed for optical clarity.
Sanding, drilling, and tapping are performed on fully postcured parts with coolant to avoid localized heating above the glass transition. The opaque surface accepts urethane and epoxy primers, but adhesion should be validated per ASTM D3359. High-pH alkaline cleaners above pH 10 can hydrolyze ester linkages after prolonged contact, and ketone-based wipe solvents can soften the surface before full postcure. Users requiring REACH, RoHS, or medical-grade documentation must request current regulatory data from the resin manufacturer; no ISO 10993 certification should be assumed absent specific grade documentation.