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ECO PELLET LA13A Recyclable Injection Molding Polylactic Acid Alloy

    • Название продукта: ECO PELLET LA13A Recyclable Injection Molding Polylactic Acid Alloy
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    ECO PELLET LA13A is a recyclable injection molding feedstock based on a polylactic acid alloy. The grade is supplied as pelletized material for rigid technical parts that require lower notch sensitivity than unmodified PLA and stable melt behavior under post-industrial regrind. Under ISO 1043-1:2011, the product is identified as a PLA-based thermoplastic alloy; the public technical data sheet does not disclose the full alloying composition beyond impact-modifying and flow-stabilizing constituents. Because the material is an alloy rather than a glass-filled or mineral-filled compound, screw and barrel abrasion is lower than that observed with glass-filled PLA grades. The grade is intended for non-food-contact injection molded articles unless the finished article is subjected to substance-specific compliance verification under EU Regulation 10/2011 or FDA 21 CFR 175.300.

    The product is positioned for converters that require a rigid bio-based material with a wider ductile response than standard PLA. Publicly available data for this specific configuration is limited in academic literature, so end-use qualification values should be established on the production tool. The material is not a film grade, a thermoforming grade, or a flexible PLA/PBAT blend. It is also not classified as home compostable solely on the basis of feedstock composition; industrial compostability of the finished article under EN 13432:2000 depends on part thickness, total mass, and certification scope.

    What Property Set Distinguishes LA13A from Unmodified PLA and Talc-Filled Compounds?

    The primary differentiation from unmodified PLA injection grades is the increase in notched impact resistance. Whereas general-purpose PLA grades frequently show notched Charpy values in the range of 2–3 kJ/m² at 23 °C under ISO 179-1:2020, LA13A is controlled to a target range of 4–7 kJ/m². This shift reduces brittle failure in snap-fit closures, clips, and thin-wall living hinges, although it does not place the material in the toughness class of ABS or polycarbonate. Compared with a 30 wt% talc-filled PLA compound, LA13A has lower density and higher melt flow, but a lower tensile modulus. Representative tensile modulus for the alloy is 2800–3200 MPa under ISO 527-2:2012, while talc-filled PLA grades often exceed 3500 MPa. This means the alloy is less suitable for high-stiffness structural ribs where dimensional stability under load is dominated by modulus.

    The melt viscosity is also lower than many high-heat PLA compounds. The melt volume-flow rate at 210 °C and 2.16 kg piston load is typically maintained between 10–15 cm³/10 min under ISO 1133-1:2022. This flow range permits filling of thin-wall sections at moderate injection pressures, but it also requires controlled gate dimensions to avoid jetting and gate blush. Batch-to-batch MVR variation should be held within ±2 cm³/10 min; wider variation shifts cushion position and gate seal time on tools with wall sections below 1.5 mm.

    Pre-drying conditions are more stringent than many olefinic materials. Residual moisture in PLA alloy pellets hydrolyzes the melt when processing above 200 °C, causing viscosity loss, splay marks, and reduced weld-line strength. Before molding, moisture content must be below 250 ppm as measured by ISO 15512:2019. A desiccant dryer with inlet air temperature of 80 °C and residence time of 4 h is the standard starting condition. The return-air dew point should be −40 °C or lower. On humid shop floors with relative humidity above 60%, opened pellet bags should be returned to sealed storage or dried immediately; ambient moisture uptake in PLA alloys can exceed 0.2 wt% within a few hours.

    Rheological and Thermal Processing Window for LA13A

    On production-scale reciprocating screw machines, LA13A has been processed using general-purpose screws with an L/D ratio of 20:1 to 25:1 and a non-return valve. A shut-off nozzle is preferred to reduce drooling. Barrel temperature settings from feed to nozzle are commonly set at 170–185 °C in the feed zone, 180–195 °C in the compression zone, 190–205 °C in the metering zone, and 195–210 °C at the nozzle. Melt temperature should not exceed 220 °C for residence times above 8 min. At 230 °C, lactide formation and viscosity loss become measurable during extended barrel hold, giving a practical processing window of approximately 190–210 °C with a tolerance of ±10 °C. Exit temperatures below 180 °C increase injection pressure and produce inconsistent gate freeze-off.

    Recommended starting processing conditions for ECO PELLET LA13A injection molding
    ParameterSet point or range
    Desiccant drying temperature80 °C
    Minimum drying time4 h
    Return-air dew point≤ −40 °C
    Maximum moisture after drying250 ppm per ISO 15512:2019
    Mold coolant inlet temperature25–40 °C
    Back pressure0.5–1.5 MPa
    Hold pressure50–70 MPa
    Screw speed60–120 min⁻¹
    Cushion3–6 mm
    Screw L/D ratio20:1–25:1

    Mold surface temperature should be controlled between 25 °C and 40 °C. Lower mold temperatures reduce cycle time but can increase molded-in stress and reduce weld-line integrity. Higher mold temperatures above 50 °C may extend crystallization time and increase cycle length without a proportional gain in mechanical properties. The material does not require a heated oil mold of the type used for high-temperature PLA crystallization. Hot runner systems, when used, should be externally heated with smooth flow channels and no stagnant zones. Valve-gate tips should be independently temperature-controlled to prevent premature solidification in the gate area.

    Regrind from sprues and runners can be reintroduced after grinding through a screen size of 4–6 mm. Clean, dust-free regrind is typically blended with virgin pellets at 20 wt%. The regrind must be dried under the same conditions as virgin material. At 20 wt% addition, melt viscosity and tensile strength are usually maintained within normal batch-to-batch variation. At 30 wt% and above, published data for this specific configuration is limited; multi-cycle molding studies should be performed on the production tool because chain scission may accumulate and shift MVR above the upper specification limit.

    Mechanical Property Benchmarks Are Reported Under ISO 10350-1 Formatting

    The property matrix in Table 1 follows the presentation logic of ISO 10350-1:2017, but the values are representative target ranges rather than a single lot certificate. They should not be used for final part design without verification on the specific tool and gate configuration.

    Representative property ranges for ECO PELLET LA13A
    PropertyTest methodTypical range
    Melt volume-flow rate, 210 °C, 2.16 kgISO 1133-1:202210–15 cm³/10 min
    DensityISO 1183-1:20191.24–1.27 g/cm³
    Tensile strength at yieldISO 527-2:201248–55 MPa
    Tensile modulusISO 527-2:20122800–3200 MPa
    Flexural strengthISO 178:201970–85 MPa
    Flexural modulusISO 178:20192600–3000 MPa
    Charpy notched impact, 23 °CISO 179-1:20204–7 kJ/m²
    Heat deflection temperature, 0.45 MPaISO 75-2:2013 Method B85–100 °C
    Mold shrinkage, parallelISO 294-4:20180.3–0.6%
    Mold shrinkage, transverseISO 294-4:20180.5–0.8%

    Comparative interpretation of these values requires identical specimen conditioning. PLA alloy test bars conditioned at 23 °C and 50% relative humidity may show different impact behavior from dry-as-molded specimens. Water absorption at saturation under ISO 62:2008 is typically below 1.0%, but thin sections exposed to warm humid air can absorb surface moisture that affects dimensions and weld strength. For parts with close tolerances, dimensional control is governed less by water absorption than by shrinkage anisotropy around gates and sharp thickness transitions.

    Compared with petroleum-based ABS, LA13A processes at roughly 30–50 °C lower melt temperature and provides renewable carbon content, but it does not reach the 20–30 kJ/m² notched impact range typical of medium-impact ABS. Compared with PLA/PBAT flexible blends, LA13A remains rigid, with flexural modulus above 2500 MPa. It is therefore unsuitable for soft-touch overmolding, film, or highly flexible snap-fit applications. Compared with high-heat PLA compounds using nucleation or annealing, LA13A does not maintain stiffness above 100 °C without additional annealing.

    When High Regrind Fractions or Humid Shop-Floor Conditions Are Present

    When the proportion of post-industrial regrind exceeds 30 wt%, the processing window narrows because hydrolytic chain scission during drying and melting becomes more variable. In such cases, the feed system should include a gravimetric blender with batch recording, and MVR should be checked at incoming lot level before production. A shift above 15 cm³/10 min indicates that regrind residence time or drying conditions have deviated from specification. On horizontal injection molding machines with clamp force between 800 kN and 1500 kN, operators have observed that high-regrind blends produce more nozzle drool and require an increase in melt cushion from 3 mm to 6 mm to maintain consistent hold pressure.

    Additives must be selected carefully. Amine-based stabilizers and certain metal stearates can accelerate PLA backbone degradation at melt temperature. Organic peroxides should not be combined with LA13A unless a specific reactive modification study has been performed. If color concentrates are added, the carrier polymer should be PLA-compatible. Olefinic carriers can form dispersed domains that lower weld-line strength. Pre-colored LA13A lots should be dried under the same conditions as natural pellets, and liquid color pumps should be positioned to avoid moisture entrainment.

    Tooling for LA13A should follow standard amorphous or semi-crystalline polyester design rules. Gate lands should be short, and gate diameters below 0.8 mm may freeze before complete packing. Runner systems should be balanced, and cold slug wells should be placed at runner ends. Vent depths should not exceed 0.02 mm to avoid flash. Mold release use can be minimized because the alloy does not require high mold temperatures; if release is needed, a water-based mold release is preferred over solvent-based products that may attack the surface. For texturing, draft angles should follow the mold maker’s specification, but shallow texture depth below 0.02 mm may be lost under high packing pressure.

    Candidate applications are those in which ISO 179-1:2020 notched impact values of 4–7 kJ/m² are sufficient, and where a reduction in fossil-based carbon content is part of the material specification. The material is not intended for direct food contact unless the finished article is specifically tested under the applicable food-contact regulation. It is also not intended for prolonged service above 60 °C in water or high-humidity environments unless part design and annealing conditions have been validated.

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