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Ecoblend HCL7110NH Halogen-Free Flame Retardant Polylactic Acid/PMMA Blend

    • Название продукта: Ecoblend HCL7110NH Halogen-Free Flame Retardant Polylactic Acid/PMMA Blend
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
    • Запрос цены: admin@ascent-chem.com
    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Спецификации
    Код ТН ВЭД 227051

    Как аккредитованная фабрика смеси Ecoblend HCL7110NH без галогенового огнезамедлительного полимолачной кислоты /PMMA, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение смеси Ecoblend HCL7110NH без галогена полимелочной кислоты/PMMA

    Ecoblend HCL7110NH is routed as a halogen-free flame-retardant PLA/PMMA blend into AC adapter shells and power-supply enclosures where UL 94 V-0 performance and IEC 62368-1 end-product criteria control the material selection. The pellets are dried in a closed-loop desiccant dryer at 80 °C for 4 h to a residual moisture target below 250 ppm. Drying is not optional at ambient relative humidity above 60 % because the PLA fraction hydrolyzes during plastication and generates acid intermediates that shift the thermal degradation onset lower. On an all-electric injection molding machine with 1200 kN to 1500 kN clamp force and a 20:1 to 24:1 L/D general-purpose screw, the barrel profile from rear to front is maintained at 175/190/200/205/210 °C. Melt temperature measured at the nozzle is confined to 190 °C to 210 °C. Residence time above 210 °C is limited to 5 min. The formulation is processed with 85 wt% virgin pellets and 15 wt% sprue/runner regrind. The regrind fraction is capped at 15 wt% because repeated extrusion causes PLA random chain scission, lowers melt-flow stability, and increases notch sensitivity in conditioned specimens. Injection speed is set between 30 mm/s and 60 mm/s, holding pressure between 60 MPa and 80 MPa, and back pressure between 0.5 MPa and 1.0 MPa. Mold temperature is held at 35 °C to 45 °C to preserve surface gloss while controlling post-mold shrinkage. Enclosure flammability is assessed according to UL 94 using 125 mm × 13 mm × 1.5 mm bars conditioned at 23 ± 2 °C and 50 ± 5 % RH for 48 h. End-product glow-wire testing follows IEC 60695-2-11 at 750 °C, with IEC 62368-1 clause 6.4.8 applied to connection-compartment enclosures. Comparative tracking index is screened under IEC 60112. Halogen content is determined by oxygen combustion followed by ion chromatography per EN 14582. The terminal part is a 1.5 mm charger shell or power-adapter housing with molded strain-relief bosses and snap fits.

    Why High-Gloss Keyboard Bezels Demand Sub-250-ppm Moisture Control

    High-gloss keyboard top cases impose an additional surface-quality boundary that separates this application from ordinary matte enclosures. The PMMA component in HCL7110NH increases surface hardness and gloss retention after repeated contact, but it also raises viscosity and amplifies moisture-induced splay. The raw pellets are dried at 80 °C for 4 h in a desiccant dryer with a dew point not exceeding -40 °C. A hot-air hopper dryer is insufficient because residual humidity above 250 ppm produces silver streaks on the visible surface at gate velocities above 40 mm/s. The molding setup uses S136 ESR tool steel with an SPI/SPE A2 diamond polish. The melt temperature is held at 195 °C to 205 °C at the nozzle. Mold temperature is elevated to 50 °C to 60 °C for gloss replication, though the higher mold temperature narrows the ejection window for tall keycap-opening blades. The injection profile uses a two-stage velocity ramp: 25 mm/s for the first 60 % of fill and 45 mm/s for the remaining pack phase. Holding pressure is set at 70 MPa with a holding-time decay of 0.3 s per step. Regrind is excluded from Class A keyboard bezels to prevent darkened flow lines and irregular gloss. The formulation ratio is 97 wt% virgin HCL7110NH and 3 wt% color masterbatch. Scratch resistance is characterized under ASTM D3363 pencil hardness, while specular gloss is measured at 60° according to ASTM D523. The compound is evaluated for UL 94 V-0 at 1.0 mm after 48 h conditioning to address thin-walled key openings. Regulatory screening includes RoHS Directive (EU) 2015/863, REACH SVHC obligations, and halogen-free verification by EN 14582. The terminal articles are keyboard top cases, mouse top shells, and numeric keypad bezels with UV-cured or laser-etched legends.

    Vehicle Interior Trim, Fogging, and FMVSS 302 Validation

    Automotive interior trim shifts the qualification emphasis to flame spread, fogging, and long-term low-gloss retention. The material is molded into door scuff plates, lower center-console side covers, and seat-belt escutcheon trims where surface temperature remains below 70 °C in service. This temperature boundary is derived from the PLA matrix; continuous exposure above 70 °C softens the part and reduces dimensional stability under clip load. Horizontal burn rate is tested per FMVSS 302 and ISO 3795 on specimens 100 mm × 356 mm × 2.0 mm conditioned at 23 ± 2 °C and 50 ± 5 % RH for 24 h. Fogging is assessed according to ISO 6452 gravimetric method at 100 °C for 16 h. The formulation used for interior trim contains 90 wt% virgin HCL7110NH, 7 wt% low-gloss masterbatch, and 3 wt% pigment concentrate. Regrind is limited to 10 wt% because recycled PLA/PMMA surfaces can carry low-molecular-weight fragments that elevate gravimetric fogging results. The part is textured with a VDI 3400 grain of 27 to 33 on the cavity surface. Melt temperature is 195 °C to 205 °C, mold temperature is 30 °C to 40 °C, and injection speed is increased to 50 mm/s to 100 mm/s for grain replication. The venting depth is limited to 0.015 mm to avoid flash at grain boundaries. The finished components are non-structural and must not be placed in airbag deployment zones due to brittle fracture risk. Published long-term UV data for this specific HCL7110NH configuration under SAE J2412 exterior exposure is limited; interior low-UV locations are preferred.

    For LED flat-panel diffusers and troffer lenses, the optical path length and flame-retardant loading create a narrow processing corridor that cannot be transferred directly from opaque enclosure molding. The part thickness is held at 2.0 mm to 2.5 mm to balance light transmission, mechanical stiffness, and UL 94 V-0 performance. The tool is designed for injection-compression molding with a compression gap of 0.5 mm to 1.0 mm and a polished lens-grade cavity. Melt temperature is 195 °C to 210 °C at the nozzle. Mold temperature is controlled at 50 °C to 65 °C using circulating water or oil to reduce shear-induced birefringence and improve optical uniformity. The screw recovery speed is reduced to 0.15 m/s to 0.25 m/s to avoid overheating the FR package. The injection speed is set at 20 mm/s to 35 mm/s for the first 70 % of fill. The regrind fraction must not exceed 10 wt% for diffuser applications because higher regrind levels reduce total luminous transmittance and increase visible haze. A color-neutral diffusing masterbatch is dosed at 2 wt% to 4 wt%. Optical properties are measured by ASTM D1003 total luminous transmittance and haze, specular gloss by ASTM D523, and refractive index by ASTM D542. Flammability evaluation follows UL 94 at 2.0 mm; long-term wet and UV exposure suitability is screened through UL 746C f1 outdoor conditions where applicable. The terminal articles are LED panel diffuser sheets, troffer lenses, and edge-lit sign cover lenses. A critical operational boundary is UV yellowing; if the diffuser is placed near high-UV LED arrays, an additional UV stabilizer masterbatch is required, and published data for this specific HCL7110NH formulation under UL 746C f1 conditions is limited.

    When a Washing Machine Fascia Must Meet IEC 60335-1 Glow-Wire Conditions

    The integration of a transparent PMMA-rich display window into a pigmented PLA/PMMA frame is used for washing-machine control fascias and dryer front panels. The part is produced by two-shot injection molding. The first shot is a pigmented HCL7110NH frame with a wall thickness of 2.5 mm. The second shot is a transparent or translucent PMMA-rich cover molded over the display area at 1.5 mm thickness. The first-shot melt temperature is 200 °C to 210 °C; the second-shot melt temperature is held at 195 °C to 205 °C to reduce visible knit lines over the display window. The mold rotation station uses a core temperature of 40 °C to 45 °C. The transparent subcomponent excludes regrind. The pigmented frame may use 12 wt% regrind if the regrind is dried to the same 250 ppm moisture limit as virgin material. Compliance is evaluated against IEC 60335-1 clause 30.2 for resistance to heat and fire. Unattended appliance parts with connections carrying current above 0.2 A are tested by glow wire according to IEC 60695-2-11 at 750 °C; parts in built-in appliances or parts accessible during servicing may be evaluated at 850 °C depending on product category and creepage distance. The material is also screened by UL 94 V-0 at 1.5 mm. Chemical resistance of the transparent window is checked against alkaline detergent formulations; PMMA-rich surfaces are vulnerable to stress crazing when exposed to concentrated amine-based cleaning agents. The terminal articles are washing-machine control fascias, dryer display housings, and freestanding appliance control knobs. In this application the PLA fraction is not exposed to steam lines or heating elements because saturated steam above 60 °C accelerates hydrolytic degradation of the matrix.

    Evaluate RAL-UZ 205 Low-Emission Criteria Before Specifying Photocopier Cladding

    Photocopier side panels and paper-tray covers require large thin-wall flow lengths, low indoor emission, and consistent flame-retardant dispersion across 250 mm to 400 mm flow paths. The parts are molded on a 8000 kN to 12000 kN hydraulic or hybrid injection machine with a 22:1 L/D general-purpose screw and a vented barrel. Melt temperature is maintained at 195 °C to 210 °C. Mold temperature is 30 °C to 40 °C. Injection speed is set at 70 mm/s to 120 mm/s to fill thin ribs and fixing bosses without short shots. The formulation ratio is 80 wt% virgin HCL7110NH, 15 wt% closed-loop regrind, and 5 wt% color/processing aid masterbatch. Higher regrind fractions are avoided because PLA-rich recycled fluff varies in bulk density and can cause screw feeding instability. The melt is purged with high-viscosity HDPE after production runs to remove FR deposits from the screw, barrel, and non-return valve. Indoor air emission is evaluated under RAL-UZ 205 Blue Angel criteria for office equipment with chamber testing by ISO 16000-3 for volatile organic compound identification and ISO 16000-6 for total volatile organic compound quantification. Flame retardancy is measured by UL 94 V-0 at 1.5 mm. The material is screened for halogen content by EN 14582. Because the PLA/PMMA matrix is not a high-temperature engineering resin, the parts are not specified for fuser-section covers or other areas where surface temperatures exceed 70 °C. The terminal articles are photocopier side cladding, document scanner lids, and paper-tray front covers. Published chamber-emission data specifically for HCL7110NH under RAL-UZ 205 is limited; each production lot must be validated independently.

    Application segmentPrimary test standardMeasured conditionOperational boundary
    AC adapter shellUL 94, IEC 62368-1 clause 6.4.81.5 mm bars, 750 °C glow wireResidence above 210 °C max 5 min
    Keyboard top caseUL 94, ASTM D3363, ASTM D5231.0 mm, pencil hardness, 60° glossMoisture above 250 ppm causes splay
    Automotive interior trimFMVSS 302, ISO 3795, ISO 64522.0 mm, 100 °C foggingService temperature below 70 °C
    LED diffuserUL 94, ASTM D1003, UL 746C2.0 mm, luminous transmittance/hazeUV yellowing risk; f1 data limited
    Washing machine fasciaIEC 60335-1 clause 30.2, IEC 60695-2-11750 °C glow wire, 1.5 mm ULAvoid saturated steam above 60 °C
    Photocopier claddingRAL-UZ 205, ISO 16000-3, UL 941.5 mm, chamber emission testingFuser-section contact excluded
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    Конкурентоспособные цены на смесь Ecoblend HCL7110NH без галогена с опожарением полимелочной кислоты /PMMA, которые соответствуют вашему бюджету - гибкие условия и индивидуальные котировки для каждого заказа.

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    Более подробное введение

    Ecoblend HCL7110NH is a halogen-free flame retardant thermoplastic compound based on a polylactic acid and poly(methyl methacrylate) alloy, supplied as pellets in 25 kg moisture-barrier bags. The compound is intended for injection molding and extrusion operations in which self-extinguishing classification must be achieved without brominated or chlorinated flame retardants. Typical density measured according to ISO 1183-1:2019 is 1.27 g/cm³, and melt volume-flow rate measured at 210 °C under 2.16 kg load by ISO 1133-1:2022 is 18 cm³/10 min. These flow characteristics place the grade between high-flow flame-retardant ABS and unmodified PLA, allowing thin-wall fill without the high injection speeds that commonly introduce shear heating and gate blush. The PMMA fraction contributes higher heat deflection temperature and surface hardness than neat PLA, while the PLA fraction provides partially bio-based carbon content. The material is not a simple PLA/PMMA mixture; the halogen-free flame retardant package is melt-compounded to form a char-forming system that affects both rheology and weld-line strength.

    What Processing Constraints Apply to the HCL7110NH Melt?

    Pre-drying is mandatory before molding. A desiccant-wheel dryer with a dew point no higher than -40 °C should be used, with hopper temperature set to 80 °C for 4 h. The target residual moisture is below 0.025 %; moisture levels above 0.05 % are sufficient to produce visible silver streaks and reduce molecular weight during plastication. Hot-air hopper dryers alone are not recommended, particularly when ambient relative humidity exceeds 60 %, because PLA-phase hydrolysis begins before visible surface defects appear. Dried pellets should be conveyed to the feed throat with dry air and held in the hopper for no more than 1 h at 80 °C to avoid moisture regain.

    Processing on reciprocating-screw injection molding machines with general-purpose screws of 20:1 to 24:1 L/D and compression ratio 2.2:1 to 2.8:1 has been reported. Barrel set points from feed to nozzle are typically 175 °C, 185 °C, 195 °C, 200 °C, and 205 °C. Melt temperature measured at the nozzle should not exceed 215 °C. The processing window is narrow, approximately ±5 °C around the recommended melt temperature, because both the PLA phase and the halogen-free flame retardant system are thermally sensitive. Sustained residence time above 8 min at melt temperatures above 210 °C induces viscosity drift, yellowing in natural grades, and plate-out on mold vents. Mold temperature is maintained between 25 °C and 60 °C; higher mold temperature improves knit-line strength but extends cycle time.

    Screw recovery speed should be set to limit shear heating. Capillary rheometry on the compounded grade at 210 °C shows reported viscosity of approximately 420 Pa·s at 1 000 s⁻¹ and 95 Pa·s at 10 000 s⁻¹. Backpressure in the range of 3–8 bar is used to maintain shot consistency without excessively increasing melt residence time. Thin-wall electronic enclosures typically require 80–120 MPa packing pressure, depending on flow length and gate geometry. Regrind usage is limited to 20 % by weight because repeated heat history accelerates poly(lactic acid) chain scission and can shift the vertical burn rating from V-0 to V-1 at 1.5 mm.

    On production-scale twin-screw compounding lines using 40:1 L/D co-rotating extruders, the reported bottleneck is not dispersive mixing but thermal management. Barrel zones above 220 °C generate low-molecular-weight species that deposit on the die plate and raise die-head pressure. Vacuum venting at -0.08 MPa or lower is used to remove moisture and residual monomer. A screen changer with 100 µm or 150 µm mesh is recommended for injection molding feedstock; finer filtration increases backpressure and can reduce throughput without improving mechanical properties.

    Tensile properties determined on injection-molded ISO 527-2:2012 type 1A specimens show a yield stress of 48 MPa and elongation at break of 6 %. Flexural modulus by ISO 178:2019 is 3.1 GPa. Notched Charpy impact at 23 °C under ISO 179-1:2023 is 2.4 kJ/m². Heat deflection temperature under 1.8 MPa load by ISO 75-2:2013 is 78 °C. These values are typical for a PLA/PMMA alloy containing a phosphorus-based flame retardant, but they are not design minima. Because the PLA phase exhibits moisture-dependent mechanical property drift, parts conditioned at 50 % relative humidity and 23 °C may show lower stiffness than dry-as-molded specimens within the first 100 h of exposure. Published data for this specific configuration under long-term heat and humidity aging is limited, so accelerated testing according to IEC 60068-2-78 is required for outdoor electrical enclosures.

    Flame Retardant Mechanism and Smoke Behavior in Enclosure Thicknesses

    The compound achieves UL 94 V-0 at 1.5 mm and 3.0 mm when tested under IEC 60695-11-10. Glow-wire flammability index is reported at 960 °C for 1.5 mm specimens under IEC 60695-2-12:2021, and glow-wire ignition temperature is 775 °C under IEC 60695-2-13:2021. Compared with brominated ABS/polycarbonate blends meeting V-0, the HCL7110NH grade produces lower visible smoke density in cone calorimeter screening at 35 kW/m²; peak heat release rate and total smoke release data remain application-specific and require documentation of specimen thickness and conditioning. The flame retardant mechanism is dominated by char formation and intumescent action rather than gas-phase halogen radical scavenging. Consequently, the material should not be blended with halogenated regrind, because even small amounts of brominated polymer can alter char morphology and reduce vertical burn performance.

    The following representative property set is taken from supplier-controlled laboratory measurements on dry-as-molded specimens. It should not be interpreted as a guaranteed specification for every batch or color.

    Property Test standard Typical value Unit
    Density ISO 1183-1:2019 1.27 g/cm³
    Melt volume-flow rate ISO 1133-1:2022 18 cm³/10 min
    Tensile yield stress ISO 527-2:2012 48 MPa
    Elongation at break ISO 527-2:2012 6 %
    Flexural modulus ISO 178:2019 3.1 GPa
    Notched Charpy impact at 23 °C ISO 179-1:2023 2.4 kJ/m²
    Heat deflection temperature at 1.8 MPa ISO 75-2:2013 78 °C
    Bio-based carbon content ASTM D6866-22 42 %

    Relative to unfilled PLA, the PMMA component raises heat deflection temperature and surface pencil hardness, and reduces visible whitening at knit lines in dark colors. Relative to unfilled PMMA, the PLA component reduces melt processing temperature and improves renewable carbon content, but lowers service temperature and chemical resistance to alcohols. Relative to halogen-free flame-retardant ABS or PC/ABS, Ecoblend HCL7110NH offers lower smoke opacity and requires no antimony trioxide synergist, but exhibits a narrower processing window and lower notched impact strength. These differences make the grade suitable for enclosures and structural carriers where a partially bio-based material with V-0 performance is required, but not for high-impact clips or snap-fit arms subject to repeated bending.

    When Halogen-Free Classification Must Be Documented for Regulated Markets

    Compliance documentation for this grade should include raw-material declarations and batch-level analytical data because the final article classification depends on the finished part, not only on the thermoplastic compound. The halogen-free status is supported by limits under IEC 61249-2-21, with bromine below 900 ppm, chlorine below 900 ppm, and total bromine plus chlorine below 1500 ppm. The compound is designed to meet the substance restrictions of RoHS 2, Directive 2011/65/EU as amended by (EU) 2015/863. Each homogeneous material in the final component must still be verified because downstream printing, adhesive bonding, or metalizing can introduce regulated substances not present in the supplied pellets.

    Directive or standard Scope Reported threshold or status
    RoHS 2 2011/65/EU including (EU) 2015/863 Lead, mercury, cadmium, hexavalent chromium, PBB, PBDE, DEHP, BBP, DBP, DIBP 0.1 % per homogeneous material, cadmium 0.01 %
    IEC 61249-2-21 Halogen-free electronic materials Bromine 900 ppm, chlorine 900 ppm, total 1500 ppm
    REACH 1907/2006/EC Substances of very high concern 0.1 % per article
    UL 94 Flammability classification V-0 at 1.5 mm and 3.0 mm

    Injection molding trials on a 120-ton hydraulic machine with a 32 mm screw produced housing components with wall thickness 1.5 mm and flow length 160 mm using a single edge gate. Fill time was 1.4–1.8 s, with holding pressure 70 MPa and cooling time 18 s. Weld-line strength in a double-gated cover remained acceptable for non-structural snap-fit bosses; however, gate blush increased when injection velocity exceeded 120 mm/s. High-speed filling can generate localized overheating at gates and produce surface defects in natural colors. The same trial showed that mold temperatures above 50 °C improved knit-line appearance but increased ejection sticking. A mold release agent was not required, and release difficulty was controlled by increasing draft angle or reducing packing pressure rather than adding external lubricants.

    The compound should not be compounded with amine-based light stabilizers or halogenated flame retardants. Amine additives can interfere with the phosphorus-based intumescent system and reduce char integrity. PVC purges and halogenated processing aids must be avoided because acid evolution can degrade the PLA phase and contaminate the melt stream. Continuous service temperature under mechanical load is near 60 °C; parts exposed to 85 °C and 85 % relative humidity require validation because PLA hydrolysis can reduce tensile strength by more than 10 % after 1 000 h. The compound is not formulated for outdoor UV service without stabilization or opaque pigmentation. Direct contact with strong alkaline cleaning solutions, esters, or ketones is not recommended. Processors should perform weld-line and chemical compatibility trials on production tooling before release, because UL 94 V-0 results are thickness-dependent and cannot be extrapolated from a 1.5 mm plaque to a 0.75 mm thin-wall part.

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