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EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade

    • Название продукта: EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
    • Запрос цены: admin@ascent-chem.com
    • Производитель: Ascent Petrochem Holdings Co., Limited
    • Свяжитесь сейчас
    Спецификации
    Код ТН ВЭД 685354

    Как аккредитованная фабрика EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

    Упаковка и хранение
    Упаковка EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade is packed in sealed 20 kg foil-lined fiber drums with moisture barrier.
    Погрузка контейнера (20-футовый контейнер) EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade, 20′ FCL: palletized, securely stacked, moisture-protected, and sealed for safe ocean transport.
    Доставка Shipping description: EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade, non-hazardous solid, not regulated for transport. Packaged in sealed moisture-barrier bags with desiccant inside sturdy cartons. No UN number, hazard class, or labels required. Store cool, dry; avoid heat, moisture, and direct sunlight. Follow local and carrier rules.
    Хранение Store EcolGreen EGP-100 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers tightly sealed, preferably in original packaging with desiccant, to prevent moisture uptake. Maintain temperatures between 15–30°C and low humidity. Protect from physical damage. Avoid contact with strong oxidizers. Follow local regulations and the manufacturer’s SDS.
    Срок годности Store sealed in cool, dry, dark conditions; typical shelf life is 12 months from manufacture when unopened. Avoid heat, moisture.
    Применение EcolGreen EGP-100 нанокомпозитного биоразлагаемого ABS-подобного класса

    Consumer-interface electronic peripherals with non-accessible internal compartments are processed from EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade on 80–120 t hydraulic toggle injection machines fitted with 24:1–26:1 L/D general-purpose screws and smear-tip check rings. The formulation addition ratio is 100 parts by weight EGP-100, 0.2–0.5 wt% renewable polyester wax processing aid, and 0.4–0.8 wt% hydrolysis stabilizer masterbatch; no fossil-based virgin ABS is required for melt cohesion, but deep-tone laser-marking reproducibility may require 0.1–0.2 wt% mixed metal-oxide pigment masterbatch. The melt is conditioned in a closed desiccant dryer at 65 °C for 4 h to a target moisture content below 250 ppm; when ambient humidity exceeds 60 %RH, pre-drying is extended to 6 h and a dew-point sensor upstream of the feed throat is interlocked to screw rotation. The narrow processing window is defined by a melt-temperature upper limit of 210 °C, above which off-gassing from polycondensation produces surface splay, and a lower limit of 185 °C, below which nano-filler dispersion becomes visibly heterogeneous. On a 120 t electric-drive injection unit, the qualified barrel profile is 175/185/195/200/205 °C, nozzle 200 °C, mold surface 28–35 °C, injection velocity 35–55 mm/s, hold pressure 55–70 MPa, and back pressure 0.6–1.0 MPa for a 2.2 mm nominal wall. Compliance follows IEC 62321-2:2021 sample screening for restricted phthalates and brominated flame retardants, RoHS Directive 2011/65/EU Annex II substance limits, REACH SVHC candidate-list declaration, and IEC 62368-1:2018 fire-enclosure requirements for AV/ICT equipment. Terminal product types are restricted to enclosures not exceeding 65 °C continuous service: optical mouse shells, keyboard upper cases, webcam housings, USB hub covers, and snap-fit cable-management clamshells. Published data for thin-wall configurations below 1.2 mm in this grade remains limited; converter validation with a 0.9 mm side-wall insert is recommended before committing to production tooling.

    Does EGP-100 Provide the Gate-Free Surface Finish Required for Cosmetic Closures and Compact Cases?

    On multi-cavity cosmetic-packaging molds with polished A1 surfaces and sequential valve-gate control, the observable defect signature of EGP-100 is low-gloss blush at the gate if melt-front velocity falls below 45 mm/s; processing is therefore set with injection velocity of 50–75 mm/s, switch-over at 95–98 % of shot volume, and hold pressure at 45–60 MPa for 0.8 s/mm of nominal wall thickness. The formulation addition ratio is 100 parts by weight EGP-100, 0.3–0.6 wt% erucamide-free slip concentrate for demolding from textured side walls, 0.5–1.0 wt% mineral pearlescent masterbatch, and 2.0–4.0 wt% butylene adipate-co-terephthalate impact-modifier masterbatch only when hinge-turning closures are specified for more than 5,000 open-close cycles. Barrel profile on a 120 t electric injection machine with a 25 mm screw is 170/180/190/195/198 °C; the nozzle is maintained at 195 °C, and the cooled mold is held at 18–24 °C to reduce post-ejection crystallinity drift in deep-draw compacts. Industry compliance for this segment is anchored to EU Regulation EC 1223/2009 Article 17 for cosmetic-article safety, EU Directive 94/62/EC Annex II for aggregate heavy-metal limits in packaging, REACH Annex XVII entries 51 and 52 for phthalates in skin-contact articles, and EN 13432:2000 for organic recovery via industrial composting of finished parts routed to waste. Terminal product types include injection-molded lipstick tube bodies with internal snap ribs, compact mirror base plates, replaceable cream-jar shells with threaded closures, and airless-pump collars for hand-lotion dispensers. Direct contact with free-oil formulations above 30 % limonene or cream bulks above pH 9.5 is not recommended without a barrier liner, and amine-based antistatic additives are incompatible with this grade because they accelerate surface hydrolysis at residence times above 8 min.

    Low-Heat-Release Trim Components for Electric Passenger Vehicle Interiors

    Interior trim parts in electric passenger vehicles are qualified principally for low smoke density, controlled volatile emission, and horizontal flame propagation rather than high-temperature mechanical loading; EGP-100 is therefore confined to non-safety, non-structural surfaces where continuous service temperature remains below 60 °C and short-term exposure does not exceed 75 °C for 200 h. The addition ratio is 100 parts by weight EGP-100, 5.0–7.5 wt% halogen-free flame-retardant masterbatch composed of zinc borate and aluminum trihydrate at a 2:1 mass ratio, 0.2–0.4 wt% phenolic-phosphite antioxidant, and 0.3–0.6 wt% hindered amine light stabilizer. The compounding procedure for this flame-retardant package requires low-shear distributive mixing at screw speeds of 120–180 rpm on a 28:1 L/D twin-screw extruder; high-shear dispersion above 220 rpm reduces impact retention by more than 12 % when measured to ISO 180:2023 at 23 °C. Injection molding is performed on 180–250 t hydraulic presses with injection-compression capability, melt temperature 185–200 °C, mold surface 25–35 °C, hold pressure 50–65 MPa, and cooling time 18–25 s for a 2.5 mm wall. The compliance matrix is summarized below.

    EV interior trim compliance matrix for EGP-100 low-heat-release components
    StandardSpecimen configurationCondition / procedureAcceptance limit
    FMVSS 302 / ISO 3795:1989100 mm × 356 mm × part-thickness plaqueHorizontal flame application, 38 mm flame, 15 sBurn rate 100 mm/min or self-extinguishing before 102 mm mark
    ISO 12219-3:2012200 cm² exposed surface in 1 m³ chamber65 °C, 2 h, 5–10 L/min air exchangeTotal VOC 0.6 mg/m³; formaldehyde 0.08 mg/m³
    REACH Annex XVII entry 72Homogeneous polymer sampleGC-MS after solvent extractionSum of restricted phthalates ≤ 0.1 wt%

    Terminal products are low-load interior surfaces that do not form part of occupant restraint or impact-energy transfer paths: B-pillar lower scuff covers, seat side garnish panels, HVAC vent vanes, charge-port bezel frames, and floor-console side trim panels. Compatibility with alkaline leather-conditioning aerosols is limited; long-term contact with ethanol-based windshield washer fluid above 30 % ethanol should be avoided because stress-cracking initiates at injection-weld lines after 120 h exposure.

    Non-sterile diagnostic device housings fabricated from EGP-100 pass a skin-contact cytotoxicity screen after a 24 h extraction in Eagle’s minimum essential medium according to ISO 10993-5:2009, while injection-molded plaques are evaluated for irritation and dermal sensitization according to ISO 10993-10:2021 for materials that remain outside the body but contact intact skin during point-of-care use. The formulation is run at 100 parts by weight EGP-100, with 0.2–0.4 wt% hindered phenolic antioxidant, 0.5–1.0 wt% medical-grade titanium dioxide masterbatch for laser-marking contrast, and 0–15 wt% regrind generated only from the same production lot; the regrind fraction is limited to maintain notched Izod impact above 6.5 kJ/m² when tested to ISO 180:2023 at 23 °C. Processing on a 160 t all-electric injection machine with a 30 mm barrier screw and shut-off nozzle uses melt temperature 190–205 °C, coolant-fed mold channels held at 24–30 °C, and fill-to-pack transfer by screw position rather than time, with cushion held at 3–5 mm to avoid hold-pressure decay in multi-cavity tooling. Industry compliance includes ISO 13485:2016 control of injection-molding subcontractors, IEC 61010-1:2010 safety for electrical diagnostic equipment, and REACH Annex XVII restrictions on phthalates in articles intended for repeated skin contact. Terminal products are restricted to non-invasive, non-fluid-path components: point-of-care analyzer shells, glucose-meter outer cases, portable ultrasound console bezels, and specimen-transfer tray bases with snap closures for polymethylpentene lids. Ethylene oxide sterilization is not recommended because the grade absorbs 0.8–1.2 wt% moisture during conditioning at 55 %RH, and post-sterilization dimensional change exceeds 0.5 % in 2.0 mm walls; gamma sterilization above 25 kGy produces measurable yellowing without loss of impact resistance.

    When EGP-100 Replaces HIPS Sheet in Retail Display and Cosmetic Tray Fabrication

    When vacuum-formed point-of-sale trays in fossil HIPS are converted to EGP-100 sheet, the production line must compensate for lower hot-sag resistance by reducing the sheet temperature gradient and increasing mold vacuum draw speed. Sheet extrusion is performed on a co-rotating twin-screw extruder with 32:1 L/D, vent vacuum -0.08 MPa, die temperature 185 °C, and a polished three-roll stack held at 35–45 °C. The addition ratio for opaque retail trays is 100 parts by weight EGP-100, 1.0–1.5 wt% chain-extender masterbatch to maintain intrinsic viscosity above 0.82 dL/g, 0.2 wt% processing antioxidant, and 15–25 wt% calcium carbonate masterbatch for bending stiffness; transparent or translucent trays omit the calcium carbonate to preserve light transmission. Vacuum forming requires sheet surface temperature 105–120 °C, mold temperature 30–40 °C, and draw ratio below 2.5:1; higher draw ratios create localized thinning at corner radii below 0.5 mm that reduces drop resistance. Compliance for this segment is framed by EN 13432:2000 for organic recovery of packaging, ASTM D6400-19 for aerobic compostability testing, EU Directive 94/62/EC Annex II for packaging heavy metals, and EN 13501-1:2018 Class E for floor-adjacent retail display elements where local fire codes require a reaction-to-fire classification. Terminal products include shelf-edge display trays, cosmetic counter tester trays, product riser blocks, signage clip strips, and pop-up display panel clips. Repeated reassembly of snap-fit display modules is limited to 200 insertion cycles before retention force drops below 60 % of the initial value; metal-thread inserts are required when module mounting uses threaded fasteners.

    Footwear Counter and Shank Substitute Moldings with Biodegradable Nano-Composite ABS-Like Grade

    Molded footwear structural components made from EGP-100 are limited to low-stress heel counters and toe puffs where flexural fatigue after 150,000 cycles at 23 °C does not exceed 8 % loss in flexural modulus when tested to ISO 178:2019. The addition ratio is 100 parts by weight EGP-100, 4.0–6.0 wt% toughening masterbatch based on biodegradable copolyester, 0.3–0.5 wt% nucleating additive, and 0.2 wt% antioxidant; no external plasticizer is used because plasticizer migration into polyurethane and polychloroprene adhesives reduces bond peel strength below 3.0 N/mm. Injection molding is performed on 90–140 t hydraulic presses with barrel profile 170/180/190/195 °C, shutting nozzle at 195 °C, mold surface 15–25 °C, and cycle time 30–45 s for a 2.0–3.0 mm wall. Desiccant drying at 55 °C for 5 h is mandatory when feed moisture exceeds 300 ppm; failure to pre-dry at RH 60 % generates hydrolysis-induced splay on textured mold surfaces. Compliance for footwear components references REACH Annex XVII entry 52 for phthalates, California Proposition 65 for toluene and dimethylformamide, and ISO 16177:2012 for quantitative determination of dimethyl fumarate in footwear components. Terminal product types are heel counters in casual and light-hiking footwear, toe-puff inserts, eyelet reinforcement plates, and midfoot shank substitutes only in non-load-bearing lifestyle shoes where the shank flexes at less than 25 N midspan force. The grade is not suited to safety footwear toe caps or load-bearing shanks because notched Izod impact drops below 5.0 kJ/m² at -10 °C.

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    Сертификация и соответствие требованиям
    Более подробное введение

    EcolGreen EGP-100 Nano-Composite Biodegradable ABS-Like Grade is a pelletized thermoplastic compound based on an aromatic-aliphatic copolyester matrix with a dispersed organically modified nano-silicate phase. The model designation EGP-100 refers to the standard injection-molding and sheet-extrusion variant, not a flame-retarded or food-contact variant. The pellet geometry is cylindrical with nominal diameter 2.5–3.5 mm and length 3.0–4.0 mm; bulk density is specified at 0.70–0.80 g/cm³ according to supplier packaging data. The producer specifies pellet density at 1.22–1.28 g/cm³ under ISO 1183-1 and moisture content at <250 ppm for molding lots. The melt-temperature window is 180–210 °C, with a maximum of 220 °C and a cumulative residence-time limit of 6 min; these boundaries are narrower than those of general-purpose ABS. The material is not a direct drop-in replacement for petroleum-based high-impact ABS because it has higher moisture sensitivity, lower notched impact, and a lower continuous service-temperature ceiling. Published multi-lot mechanical data for this exact nano-composite configuration remain limited; values used for mold design should be confirmed on the intended production press.

    Relative to unfilled polylactic acid, EGP-100 shows lower tensile yield stress but higher notched impact stability after humid conditioning. The nano-composite phase shifts the failure from brittle fragmentation toward a lower-energy unstable crack mode, but it does not reproduce ABS rubber-phase cavitation. Relative to talc-filled polybutylene adipate terephthalate blends, the nano-silicate phase provides equivalent flexural modulus at lower filler loading because the high aspect ratio of the dispersed platelets contributes stiffness without the density penalty of mineral fillers. Relative to starch-based compounds, the aromatic-aliphatic copolyester matrix has lower water uptake at 50% RH and better melt stability on standard injection presses. Compared with general-purpose ABS, the compound overlaps the lower half of the ABS flexural-modulus range but falls below high-impact ABS in notched Izod impact. The surface gloss of EGP-100 molded parts is generally lower than that of ABS at equivalent mold polish, and weld lines are more visible because the copolyester phase does not produce the same styrenic melt-pool randomization.

    What Distinguishes the Rheological and Failure Signature of EGP-100 from High-Impact ABS?

    At equivalent melt-flow indices, the copolyester compound exhibits higher low-shear viscosity and more pronounced shear thinning than ABS, consistent with intercalated nano-silicate networks that break down under flow. The melt mass-flow rate specified under ISO 1133-1:2022 at 190 °C and 2.16 kg is 8–18 g/10 min, but the apparent viscosity at 20–50 s⁻¹ is not captured by the MFR test. Capillary rheometry on limited lab samples indicates a power-law index of approximately 0.35–0.45 over 10–1,000 s⁻¹. The failure signature under notched impact is brittle compared with high-impact ABS: EGP-100 typically shows unstable crack propagation at 23 °C, while high-impact ABS often displays ductile tearing, stress whitening, and crack arrest. Snap-fit design should not be copied from ABS guidelines. The producer recommends latch root radii of at least 0.8 mm and side-action draft of 1.0–1.5°. The coefficient of linear thermal expansion in limited thermomechanical analysis is 70×10⁻⁶ K⁻¹ to 90×10⁻⁶ K⁻¹ in the flow direction, higher than glass-filled ABS but lower than unfilled PBAT.

    Supplier-Defined Quality-Control Bands for EcolGreen EGP-100 Pellets
    Property Test Method Quality-Control Band
    Density ISO 1183-1 1.22–1.28 g/cm³
    Melt mass-flow rate ISO 1133-1:2022, 190 °C, 2.16 kg 8–18 g/10 min
    Tensile stress at yield ISO 527-2 38–52 MPa
    Tensile modulus ISO 527-2 2,100–2,800 MPa
    Flexural modulus ISO 178 1,900–2,600 MPa
    Notched Izod impact ISO 179-1/1eA, 23 °C 4.5–8.0 kJ/m²
    Heat deflection temperature ISO 75-2/B, 0.45 MPa 68–82 °C
    Residual moisture ISO 15512 <250 ppm

    Injection molding on a 90-tonne clamp-force press with a 28 mm diameter general-purpose screw indicates that switchover should occur 5–8% earlier than ABS of similar shot volume because melt compressibility is higher. Hold pressure is set 15–25% lower than typical ABS settings to avoid gate blush. Screw recovery time increases by 0.8–1.2 s on a 22:1 L/D screw at 180–200 °C barrel temperature. Mold temperature is specified at 20–45 °C; higher mold temperatures reduce molded-in stress but raise cycle time. Hot-runner use is possible only if the manifold temperature remains below 200 °C and residence time is below 5 min; otherwise oligomer deposits form at gate tips. Multi-cavity tools should use geometrically balanced runners because cavity-pressure decay after switchover is faster than ABS, and cavity filling imbalances become observable above four cavities.

    Compounding on a 40 mm co-rotating twin-screw extruder at 48:1 L/D uses a temperature profile of 150/165/175/180/180/175 °C from feed zone to die. Two kneading blocks before the first vacuum vent are necessary to achieve intercalation; a single mixing section leaves residual tactoids that reduce Charpy notched impact by 10–20%. The organoclay basal spacing increases from 1.8 nm to 3.2–3.8 nm under adequate shear, but complete exfoliation is not observed by wide-angle X-ray diffraction. Vacuum devolatilization at -0.08 MPa gauge reduces residual moisture to <250 ppm. Pelletizing is performed under water-ring cooling; process water temperature must remain below 30 °C to prevent pellet blocking. Production-scale experience indicates that the organic surface treatment of the nano-silicate begins to carbonize if the melt zone exceeds 200 °C for extended periods, producing a brown color shift. Screw design with aggressive reverse elements is not recommended because the copolyester matrix is shear-sensitive; a 48:1 L/D profile with moderate shear and two vent zones is preferred for stable melt pressure.

    If the Melt Temperature Remains Above 220 °C for More Than 6 Minutes, Thermal Degradation Accelerates

    Thermal decomposition of the copolyester phase is observed as a progressive reduction in melt viscosity and an increase in low-molecular-weight volatiles at the nozzle. The producer specifies a maximum melt temperature of 220 °C and a maximum cumulative melt residence time of 6 min. In a twin-screw compounding trial, a melt-temperature excursion to 235 °C during a material-transfer delay of 4 min reduced notched impact by 12–18% relative to lots processed at 205 °C. The degradation mechanism is predominantly esterolysis; the nano-silicate surface treatment does not fully arrest chain scission. For this reason, purging with low-melt-flow polyethylene after shutdown is specified, and any production interruption longer than 10 min requires barrel-temperature reduction to 150 °C. Regrind content should not exceed 20 wt% unless mechanical properties are re-qualified on the actual mold. The same limitation applies to off-spec parts that have been re-pelletized more than twice; additional heat history reduces intrinsic viscosity beyond the acceptable range for impact-sensitive applications.

    Pre-drying is mandatory when ambient relative humidity exceeds 60%. At 23 °C and 50% RH, pellets reach an equilibrium moisture of 0.3–0.5 wt%; at 60% RH, equilibrium exceeds 0.8 wt%. Desiccant drying at 60–70 °C for 4–6 h to a dew point of -30 °C or lower is specified. In an open hopper, moisture regains can occur within 15–20 min under 60% RH, producing gate-area splay, weld-line strength loss, and hydrolysis-induced viscosity drift. Closed conveying with dry-air purging is required in high-humidity plants. The appearance of splay should not be corrected by increasing barrel temperature; the appropriate corrective action is re-drying and reducing residence time. Moisture levels above 400 ppm in the feed throat are associated with a 25–35% reduction in weld-line tensile strength, based on limited production-run studies; published data for this specific configuration remains limited.

    Compliance Benchmarks and Biodegradation Testing Boundaries

    The supplier provides REACH and RoHS declarations for EGP-100. The biobased carbon fraction is measured under ASTM D6866 and reported in the range of 70–85%, reflecting the organic copolyester and reinforcement carbon. Industrial compostability data remain batch-dependent; mineralization under ISO 14855-1 reaches 60% within 180 days in some supplier reports, but the compound is not certified for home compostability and does not carry a marine-degradation claim. The material is not designed for food-contact use unless a specific migration evaluation under EU 10/2011 has been completed for the final part geometry. The nano-phase is organically modified quaternary ammonium montmorillonite; extracted organics should be characterized under ISO 10993-5 for any medical or skin-contact application. Avoid combination with amine-based additives; published data for this specific configuration is limited, but the available quality-control guidance indicates that such additives can accelerate transesterification and reduce melt stability. The grade does not require the use of styrene or acrylonitrile monomers, which distinguishes its residual monomer profile from conventional ABS.

    EcolGreen EGP-100 fits short-lifecycle rigid packaging, cosmetic closure components, and electronic accessory housings only when the continuous service temperature is below 65–75 °C. It is unsuitable for automotive underhood parts, hot-water plumbing fittings, or repeated autoclave sterilization because the heat deflection temperature under 0.45 MPa is 68–82 °C and hydrothermal aging reduces molecular weight faster than dry heat. The compound cannot be solvent-welded with MEK or acetone; cyclohexanone-based primers may provide temporary adhesion, but published data for this specific configuration is limited. Ultrasonic welding should be evaluated with horns operating at 20 kHz for less than 0.4 s, since longer cycles generate interfacial temperatures above 85 °C and produce surface hydrolysis marks. Hot-stamping and in-mold labeling are possible if tool residence time is kept below 3 s and the melt front temperature at the decorative layer does not exceed 200 °C. For chemical foaming, endothermic blowing agents are preferred over exothermic systems because the exotherm can push the local melt temperature above the degradation limit. The compound is also not recommended for parts with living hinges because repeated flexing at thicknesses below 0.3 mm produces rapid surface crazing in preliminary trials.

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