| Код ТН ВЭД | 169485 |
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Ecopond PLA-55H High Flow Polylactic Acid/ABS Alloy is a pelletised injection-moulding feedstock in which a semicrystalline polylactic acid matrix is interfacially compatibilised with an acrylonitrile-butadiene-styrene dispersed phase. The supplier’s technical bulletin lists a melt volume-flow rate of 29 cm³/10 min under ISO 1133-1:2022 at 220 °C and 10 kg load. The grade is intended for thin-wall electronic enclosures, reusable consumer housings, and non-structural automotive interior trim where high-flow PLA grades are required to avoid short shots in flow paths exceeding 150 mm at wall thickness below 2 mm. The “55H” designation identifies the high-flow variant within the Ecopond PLA/ABS series; the precise PLA-to-ABS ratio is stated in the batch certificate of analysis rather than as a fixed nominal value. Comparative interlaboratory data for this exact grade remain limited, and the figures quoted below are representative values from the manufacturer’s technical bulletin unless a recognised standard is referenced. They should not be read as guaranteed specification limits.
Unmodified polylactic acid injection grades typically exhibit a melt flow index in the range of 6 g/10 min to 15 g/10 min at 210 °C under 2.16 kg, tensile strength near 60 MPa, and notched Izod impact values below 3 kJ/m². These grades fail in thin-wall cavities because the spiral flow length at 2 mm wall thickness rarely exceeds 100 mm before melt freezing. General-purpose ABS provides notched Izod values of 18 kJ/m² to 25 kJ/m² but contains no bio-derived carbon and requires processing temperatures of 230 °C to 260 °C. Ecopond PLA-55H falls between these material classes: the supplier’s tensile data under ISO 527-2:2012 report a tensile strength of 52 MPa, elongation at break of 4.2%, and Young’s modulus of 2.4 GPa at 23 °C and 50% RH. Notched Izod impact under ISO 180:2019 is 8.5 kJ/m² at 23 °C.
Compared with standard PLA/ABS blends lacking reactive compatibilisation, the 55H grade contains a glycidyl methacrylate-based interfacial agent that grafts the PLA matrix to the ABS-rich domains during compounding. Dynamic mechanical analysis under ISO 6721-1:2019 shows two glass-transition temperatures at 58 °C and 104 °C, indicating a phase-separated morphology with improved interfacial adhesion. The resulting melt is less prone to flow-front striation, and weld-line delamination is reduced. A spiral flow length of 180 mm at 2 mm wall thickness is obtained at 205 °C melt temperature and 50 °C mould temperature. Conventional PLA/ABS blends with lower flow often fail to fill the same cavity below 2.5 mm wall thickness.
| Property | Test Standard | Ecopond PLA-55H | Unmodified PLA | General-Purpose ABS |
|---|---|---|---|---|
| Tensile strength | ISO 527-2:2012 | 52 MPa | 60 MPa | 42 MPa |
| Young’s modulus | ISO 527-2:2012 | 2.4 GPa | 2.5 GPa | 2.0 GPa |
| Notched Izod impact | ISO 180:2019 | 8.5 kJ/m² | 2.5 kJ/m² | 20 kJ/m² |
| Heat deflection temperature at 0.45 MPa | ISO 75-2:2013 Method B | 72 °C | 55 °C | 98 °C |
| Density | ISO 1183-1:2019 | 1.14 g/cm³ | 1.24 g/cm³ | 1.05 g/cm³ |
| Water absorption after 24 h at 23 °C | ISO 62:2008 | 0.4% | 0.3% | 0.6% |
High-heat PLA grades may reach 90 °C HDT B but require melt temperatures of 230 °C and show lower weld-line strength; PLA-55H sacrifices heat deflection temperature for flow length. The grade is also distinguished from chemically foamed PLA/ABS alloys by lower gas-counterpressure sensitivity. Despite this, foaming trials at 0.2 wt% nitrogen reduce density to 0.95 g/cm³ but lower tensile strength by approximately 15%. Published data for this specific configuration is limited.
In field trials with a production-scale reciprocating-screw injection machine having a screw diameter of 40 mm, an L/D ratio of 22:1, and a clamp force of 1,800 kN, the recommended barrel set points are 175 °C in the feed zone, 190 °C in the compression zone, 205 °C in the metering zone, and 210 °C at the nozzle. Hot-runner manifolds should be held at 205 °C with a variation not exceeding 10 °C. The practical melt-temperature window is 195 °C to 215 °C; residence time above 225 °C must not exceed 5 min because lactide regeneration and ABS-phase degradation occur beyond this threshold. Screw rotation speeds above 150 min⁻¹ are not recommended because shear heating can raise the melt above 225 °C in the compression zone. Batch-to-batch melt volume-flow rate variation is specified within ±5% of nominal under ISO 1133-1:2022.
The measured pressure drop through a cold sprue of 60 mm length and 3 mm diameter at 100 mm/s injection velocity falls from 55 MPa for a standard PLA/ABS grade to 31 MPa for PLA-55H under the same tool geometry. This difference permits filling of 1.2 mm-wall side walls with less than 120 MPa injection pressure on a 2-cavity tool. Screw-recovery time has been recorded at 3.8 s for PLA-55H versus 5.2 s for unmodified PLA at identical shot weight and plastication settings. Melt cushion should be maintained between 3 mm and 6 mm; a smaller cushion increases shot-weight variation because the compressibility of the two-phase melt changes with shear history.
Because polylactic acid undergoes hydrolytic chain scission during melt processing, the PLA-55H pellets must be dried to a residual moisture content below 0.02 wt% as determined by ISO 15512:2019 before entering the feed throat. Desiccant-wheel drying at 80 °C for 4 h with return air at a dew point of −40 °C and an air flow of 1.8 m³/h per kg/h throughput is sufficient. When the dew point rises above −30 °C, the equilibrium residual moisture remains above 0.03 wt%, and melt viscosity falls by an additional 10% to 15% as hydrolysis reduces molecular weight. The resulting moulded parts show lower notched impact strength, visible silver streaks near the gate, and increased screw-recovery time scatter.
Regrind use is limited to 20 wt%. Above this ratio, the broader residence-time distribution increases the formation of black specks in the ABS-rich domains after repeated heat history. Fines must be removed from the hopper throat because PLA-rich fines melt earlier than ABS-rich pellets and induce screw-slip; operators on a 40 mm screw observed screw-recovery time variation exceeding 0.8 s when regrind fraction exceeded 30 wt%. Additive selection must avoid amine-based chain extenders in the feed throat; these accelerate ester-amide interchange in the PLA phase and create uncontrolled viscosity reduction. External mould-release agents based on metallic stearates are generally compatible below 0.5 wt%.
For thin-wall enclosures with a nominal wall thickness of 1.2 mm, mould temperature should be maintained at 40 °C to 60 °C. Below 40 °C, the PLA-rich phase vitrifies before complete packing, and sink marks appear at rib-to-wall intersections. The linear mould shrinkage under ISO 294-4:2018 is 0.5% to 0.7% parallel to flow and 0.6% to 0.8% transverse to flow. Post-moulding dimensional stability is limited by the PLA phase; parts exposed to continuous service above 60 °C show heat-deflection creep that is not observed in general-purpose ABS. The heat deflection temperature under ISO 75-2:2013 Method B at 0.45 MPa is 72 °C, and the Vicat softening temperature under ISO 306:2013 B50 is 85 °C. The product is therefore unsuitable for hot-fill applications, dishwasher internals, or under-hood automotive parts where the component temperature exceeds 65 °C.
Weld lines in thin-wall parts are the primary failure site. Field tests on a multi-gated housing showed weld-line impact retention of 45% of the base value under ISO 179-1:2020. Gate blush is minimised by using a minimum gate diameter of 1.0 mm; smaller gates generate shear rates above 10⁵ s⁻¹ and cause local PLA degradation. Externally applied colour masterbatches must be based on PLA or ABS carriers; polyolefin carriers reduce weld-line strength by more than 20% and create delamination at the part surface.
The product is not marketed as a food-contact material unless a specific EU 10/2011 compliance statement or relevant FDA 21 CFR clearance is issued for the finished article. The supplier’s regulatory information lists REACH obligations under Regulation (EC) 1907/2006, including substances of very high concern below 0.1 wt% per article. RoHS compliance is documented against Directive 2011/65/EU Annex II for lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, and polybrominated diphenyl ethers; each restricted substance is below the maximum concentration value of 0.1 wt% except cadmium at 0.01 wt%. The material cannot be used for implantable medical devices under ISO 10993-1:2018 without further evaluation because the ABS-rich phase contains residual styrene and acrylonitrile monomers.
| Regulation or Standard | Scope | Status |
|---|---|---|
| Regulation (EC) 1907/2006 | REACH SVHC screening per article | No SVHC above 0.1 wt% |
| Directive 2011/65/EU Annex II | RoHS restricted substances | Below maximum concentration values; cadmium 0.01 wt% |
| EU 10/2011 | Plastic food-contact migration | Not granted by default; application-specific statement required |
| FDA 21 CFR | Food-contact polymer clearance | Not granted by default; finished-article clearance required |
| ISO 10993-1:2018 | Medical device biocompatibility | Not evaluated as an implantable or prolonged-contact material |
Storage should be in sealed moisture-barrier bags below 30 °C. If a bag is left open at 60% RH or higher for more than 24 h, redrying is required. The equilibrium moisture uptake under ISO 62:2008 at 23 °C and 50% RH is 0.4% after 24 h. The product should not be blended with polycarbonate in processing equipment without purge, because transesterification between PLA and polycarbonate forms block copolymers that alter viscosity and cause haze. The grade is also incompatible with polyamides requiring melt temperatures above 260 °C; processing in shared equipment requires a purge with a general-purpose ABS or a commercial barrel cleaner. Unfilled PLA-55H is not flame retardant; no UL 94 V rating is available without additive modification, and the standard unfilled material is suitable only for applications where an HB rating at 1.5 mm is acceptable.