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Как аккредитованная EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry фабрика, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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Specifications governing fuel-vapor quick connectors on low-permeation fuel systems have increased scrutiny on weld-line integrity at the connector locking legs after exposure to methanol-blended gasoline and calcium chloride road brines. Components moulded from EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry replace unfilled PA12 in these geometries because the 20 wt% glass-fibre reinforcement raises hoop stress retention but also concentrates fibre orientation at the barb root, which is the dominant failure location when connector retention force is tested after thermal shock. Production requirements for this downstream segment fall under SAE J2044 for fuel and vapour quick-connect couplings, ISO 16750-4:2023 environmental load testing, REACH Regulation (EC) No 1907/2006, and RoHS Directive 2011/65/EU Annex II substance restrictions. The recommended feedstock proportion is 100 wt% virgin dry pellets for first-shot connector bodies, with regrind from sprues and full hot-runner drools limited to 20 wt% and only after re-drying at 80°C to a final moisture content below 0.10 wt%; adding more regrind shifts the loss-on-ignition glass content outside the 20 wt% ± 2 wt% control band and reduces weld factor at the retention barb below the connector pull-off requirement. Injection moulding equipment for these parts typically uses a wear-resistant bimetallic screw with L/D 20:1 to 25:1 and a compression ratio of 2.0:1 to 2.5:1, with barrel temperature zones from 230°C in the feed zone to 255°C at the nozzle, mould temperature 60–80°C, injection velocity 80–150 mm/s, hold pressure 60–80 MPa, and total cooling time 15–25 s depending on wall thickness at the latch. The unlabelled application boundary is that continuous exposure to >50% sulphuric acid, phenolic brake fluids, or molten alkali falls outside the validated resistance envelope for this grade. Terminal components include fuel-line quick connectors conforming to SAE J2044 classes, evaporative emission vapour return couplings, and SCR diesel exhaust fluid line connectors where calcium chloride spray resistance is required.
Control of outer diameter ovality in thermoplastic air brake tubing becomes the primary extrusion conflict when glass-fibre-reinforced PA12 is run at line speeds above 40 m/min. In this downstream application, EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry is processed on a single-screw extruder with L/D 24:1 to 30:1, a three-zone screw with mixing pins, and a static mixer between screw tip and die to homogenize fibre distribution before the die land. The material is dried at 80°C for 4–6 h in a desiccant dryer to a dew point below -30°C, because residual moisture above 0.10 wt% creates internal microvoids that lower burst strength by more than 10% in spiral-burst testing according to ISO 1402-type procedures. Formulation proportion for the extrusion run is 100 wt% virgin dry pellets, with start-up purge regrind held at 5–10 wt% and no additional chain extender or impact modifier; raising regrind above 10 wt% widens the molecular weight distribution sufficiently to cause outer diameter ovality drift beyond 0.15 mm at the calibration sleeve. Die design uses a land length-to-gap ratio of 10:1 to 15:1, die temperature 245–250°C, barrel profile 230/235/240/245°C from feed to metering, and a gear pump to reduce pressure pulsation below 0.5 bar. Vacuum calibration at 0.5–0.8 bar with a water temperature of 20–40°C sets the final outside diameter before haul-off and inkjet marking. If the line speed exceeds 40 m/min without closed-loop diameter control, post-die swell variation can exceed 0.3 mm and compromise fitting retention. Terminal finished products are 12 mm, 14 mm, and 16 mm compressed-air brake tubing for commercial vehicles, trailer air suspension lines, and pneumatic control lines in rail rolling stock where dimensional stability after thermal cycling is verified under SAE J844, ISO 7628-1, and DIN 74324-1.
| Standard | Designation | Relevant requirement |
|---|---|---|
| SAE J844 | Thermoplastic air brake tubing | Burst strength retention after thermal conditioning |
| ISO 7628-1 | Road vehicles — thermoplastic tubing for air braking systems | Dimensional tolerance and marking criteria |
| DIN 74324-1 | Thermoplastic tubing for air braking systems | Diameter, wall thickness, and material requirements |
| ISO 1402 | Rubber and plastics hoses — hydrostatic testing | Burst pressure verification of extruded tube |
When high-voltage harness routing moves into splash zones under battery packs, the conduit clips previously moulded in PA66 exhibit brittle failure at -25°C, leading to a shift toward 20 wt% glass-fibre-reinforced PA12 for low-temperature impact retention. EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry is processed as 100 wt% dry pellets in thin-wall clip moulds, with 2–4 wt% carbon black masterbatch added only where UV exposure is specified; no additional nucleating agent is used because the glass fibre already accelerates crystallization. The downstream production process is injection moulding with fast fill speeds of 150–250 mm/s, mould temperature 50–80°C, hot-runner valve gates to avoid glass-fibre breakage at the gate, and asymmetric cooling circuits to counter the differential shrinkage induced by fibre orientation along the clip length. The relevant compliance framework includes IEC 61386-1 for conduit system mechanical integrity, UL 94 HB for flame propagation, ISO 4892-2 Method A for UV weathering, and RoHS Directive 2011/65/EU Annex II. The operational boundary is that direct contact with concentrated hydrochloric acid or strong polar solvents can induce environmental stress cracking and is outside the validated service envelope. Terminal components are corrugated conduit connectors for electric vehicle battery trays, high-voltage cable harness clips, cable gland locknuts for charging infrastructure, and strain-relief fittings in industrial robotics.
Chemical dosing pump housings and filter bowls demand post-mould dimensional stability after short-term immersion in dilute process acids and alkaline cleaning solutions at operating temperatures up to 60°C. The use of EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry in this segment requires a formulation proportion of 100 wt% virgin dry pellets, with colour masterbatch limited to 3 wt% because common pigment carrier resins can lower chemical resistance at the weld line and are a known source of premature stress cracking. The production route is injection moulding in two-cavity or four-cavity tools with rectangular edge gates or fan gates; melt temperature is held at 235–250°C, mould temperature at 40–60°C, and total melt residence time is capped below 10 min to avoid thermo-oxidative degradation at the screw tip. Packing pressure is set at 50–70 MPa for 8–12 s, followed by annealing at 90–100°C for 2 h to relieve internal stresses and reduce post-mould dimensional change after water absorption. The applicable compliance standards for industrial fluid handling are ISO 175:2010 for chemical resistance by immersion, REACH Regulation (EC) No 1907/2006, and RoHS Directive 2011/65/EU; drinking-water contact applications require separate formulation-specific testing to NSF/ANSI 61 or WRAS, and published data for this specific glass-filled configuration is limited. The incompatibility boundary is that amine-based process additives and fluids above 80°C can accelerate polyamide hydrolysis and must be excluded from the chemical resistance qualification. Terminal products include dosing pump heads, filter bowl support rings, chemical injection manifold blocks, and dilute sodium hypochlorite metering housings.
When irrigation rotor bodies shift from acetal to 20 wt% glass-fibre-reinforced polyamide 12, the main processing variable is not hydrolysis but slow crystallinity development in thick sections that delays ejection without dimensional stabilisation. EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry is used at 100 wt% dry pellets; where grey or black bodies are required, 2–3 wt% masterbatch is acceptable, but mixed-metal oxide pigments should be avoided because they can accelerate chain scission during plastication at 250°C. Injection moulding of valve bodies and rotor housings uses melt temperatures of 240–270°C, mould temperatures of 60–80°C, pack-and-hold pressures of 50–70 MPa, and cycle times up to 45 s for wall sections between 6 mm and 10 mm. Post-mould annealing at 100°C for 2 h is recommended before machining of threaded bosses to prevent subsequent stress relaxation. Compliance for residential and commercial water components is evaluated under ISO 175:2010 for water and antifreeze exposure, NSF/ANSI 61 and WRAS where potable water contact is claimed, and REACH Regulation (EC) No 1907/2006; potable water certification is formulation-specific and cannot be assumed solely from the base polymer designation. The material should not be blended with recycled PA6/66 because phase separation at the weld line reduces pressure retention in threaded valve bodies. Terminal products include irrigation rotor bodies, water softener valve bodies, flow meter housings, and pump venturi inserts.
Industrial push-to-connect fittings are produced in high-cavitation tools where cavity-to-cavity fill imbalance above 2.5% generates wall thickness variation that directly affects the interference fit of the collet and the O-ring retention groove. EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry is run at 100 wt% virgin dry pellets; regrind from rejected fittings is capped at 10 wt% because higher regrind levels widen the melt viscosity distribution and increase cavity-to-cavity fill fluctuation in 64-cavity hot-runner systems. The production process uses a L/D 20:1 screw with a shut-off nozzle, melt temperature 235–255°C, mould temperature 40–60°C, injection pressure 100–140 MPa hydraulic, and sequential valve gating for balance; after ejection, the fittings are conditioned at 80°C for 4 h in a dry environment to stabilise moisture content before leak testing. Industry compliance for pneumatic fittings includes ISO 14743 for push-in connectors, ISO 4414 for pneumatic fluid power system safety, REACH Regulation (EC) No 1907/2006, and RoHS Directive 2011/65/EU Annex II. The operational boundary is that methanol-containing compressed air at concentrations above 20% may induce environmental stress cracking; published data for this specific configuration is limited, so pre-validation is required. Terminal components are push-to-connect fittings for compressed air lines, vacuum tube connectors, pneumatic manifold blocks, and speed control fittings used in factory automation.
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EMS-Grivory Grilamid L 20 W 20 Nylon 12, Dry is a plasticizer-modified semi-crystalline polyamide 12 compound supplied as pre-dried granulate. According to ISO 1043-1:2011, the base polymer is designated PA12; the L 20 W 20 suffix is EMS-Grivory product nomenclature and is not part of ISO designatory data. The PA12 backbone, polymerised from laurolactam, contains an amide group separated by an eleven-methylene sequence, giving lower amide density than PA6 or PA66 and yielding intrinsically low saturated water absorption, low density, and resistance to non-polar fuels, oils, and greases. Within the Grilamid L portfolio, the L 20 W 20 designation identifies a flexible extrusion and injection-moulding grade with Shore D hardness and tensile modulus below unmodified PA12 while retaining the chemical resistance of the PA12 backbone. The dry designation indicates sealed low-moisture packaging; residual moisture in the granulate is controlled below the supplier processing threshold, and Karl Fischer titration or ISO 15512:2019 should confirm moisture after storage or package damage. In the dry state, density determined according to ISO 1183-1:2019 is typically 1.01 to 1.03 g/cm³, and melting temperature determined by differential scanning calorimetry according to ISO 11357-3:2018 falls between 170 and 180 °C. Primary application areas include flexible automotive tubing, air brake tubing, cable sheathing, and moulded clips where cold-impact ductility and resistance to operational fluids control material selection.
Plasticizer modification produces shear-thinning melt behaviour and lower melt strength than unmodified PA12. On single-screw extrusion lines, stable output is obtained with 24:1 to 30:1 L/D barrier screws, compression ratios of 2.5:1 to 3.0:1, and screen packs of 60/80/100 mesh where filtration is required. Barrel temperatures are set from 200 to 230 °C, and melt temperature measured by an immersion probe at the die adapter is held at 210 to 240 °C. Melt temperatures above 250 °C cause plasticizer volatilisation, die drool, surface splay, and molecular weight degradation; residence time at melt temperature is therefore limited to less than 10 minutes. Screw back pressure of 10 to 30 bar at the die reduces output fluctuation. The grade is hygroscopic; granulate exposed to plant air at 60% relative humidity or higher should be re-dried at 80 °C for 4 to 8 hours in a desiccant dryer with dew point at or below -30 °C. Residual moisture is maintained below 0.10 wt%; hopper-inlet verification by ISO 15512:2019 or Karl Fischer titration detects lot-to-lot variation. On co-rotating twin-screw compounding or degassing extrusion lines, vacuum venting at 20 to 70 mbar absolute removes low-molecular-weight volatiles without excessive plasticizer stripping.
For injection moulding with 60 to 100 t clamp force, barrel temperatures follow the same upper limit, and mould temperature is held from 20 to 60 °C. Hold pressure of 400 to 800 bar and fill time of 0.5 to 1.5 seconds for 2 mm wall sections reduce sink marks and internal voids. The melt volume-flow rate should be read from the lot certificate; ISO 1133-1:2022 is the reference method. Processors should not infer lot viscosity from spiral flow alone because the plasticizer content shifts flow length independently of molecular weight.
For small-diameter flexible tubing manufactured on 19 to 45 mm grooved-feed single-screw extruders, the reduced melt strength of plasticized PA12 requires die gaps set 10% to 20% below the target wall thickness, followed by controlled draw-down into a water-filled vacuum calibrator. Quench water is held at 15 to 40 °C; lower temperatures increase line speed but may introduce stress whitening at the tube inner wall. Vacuum sizing pressure of 0.2 to 0.5 bar differential is used for outer diameters up to 12 mm, and closed-loop laser micrometer gauges controlling haul-off speed maintain diameter tolerances within ±0.05 mm. Because plasticizer modification lowers the crystallisation rate, post-extrusion shrinkage continues for up to 48 hours; dimensional audits should be repeated after 24 hours and compared with internal lot control limits. Air brake tubing produced from this grade must meet end-user specifications such as SAE J844 and DIN 73378; material approval alone does not override the requirement for full assembly validation.
Cable jacket lines running 2.5 to 8.0 mm outer diameter on 30 to 60 mm single-screw extruders use pressure dies with a draw ratio between 1.1:1 and 1.5:1. Melt temperature is kept near 225 °C to avoid plasticizer decomposition; conductor preheating to 60 to 80 °C improves adhesion and prevents jacket shrinkage. Payoff and take-up tension is set below 5 N for stranded conductors to prevent insulation neck-down. The stripped jacket is checked for elongation at break at 50 mm/min according to ISO 527-1:2021 and ISO 527-2:2021 to confirm that plasticizer distribution remains uniform after high-speed extrusion.
Mechanical values are generated on ISO 527-2 multipurpose specimens after conditioning to ISO 291:2008 at 23 °C and 50% relative humidity; dry-as-moulded values are measured immediately after specimen preparation for comparison with the dry state. Because PA12 absorbs atmospheric moisture, moisture acts as a secondary plasticizer and reduces tensile modulus. The following table lists representative ranges for plasticized PA12 compounds of this nominal flexibility; lot-specific values must be read from the certificate of analysis and are not superseded by generic portfolio ranges.
| Property | Test method | Typical range |
|---|---|---|
| Density at 23 °C | ISO 1183-1:2019 | 1.01–1.03 g/cm³ |
| Tensile modulus, 1 mm/min | ISO 527-1:2021, ISO 527-2:2021 | 250–350 MPa |
| Tensile stress at yield, 50 mm/min | ISO 527-1:2021, ISO 527-2:2021 | 8–12 MPa |
| Nominal strain at break, 50 mm/min | ISO 527-1:2021, ISO 527-2:2021 | >200 % |
| Charpy notched impact strength at 23 °C | ISO 179-1:2023 | no break or >60 kJ/m² |
| Charpy notched impact strength at -30 °C | ISO 179-1:2023 | 15–40 kJ/m² |
| Melting temperature, DSC | ISO 11357-3:2018 | 170–180 °C |
| Water absorption, saturation at 23 °C | ISO 62:2008 | 1.0–1.6 wt% |
| Shore D hardness, 15 s | ISO 868:2003 | 50–60 |
PA12 is used in selective catalytic reduction fluid lines carrying 32.5 wt% aqueous urea solution at operating temperatures up to 80 °C. The PA12 backbone provides better resistance to neutral-pH aqueous urea than PA6 or PA66; however the plasticizer package is the limiting factor under hot-water ageing. Chemical resistance is evaluated by immersion testing according to ISO 175:2010; changes in tensile elongation after 1000 hours at 80 °C in 32.5 wt% urea solution are typically set by the end-user specification rather than by a single generic supplier value. Low-temperature flexibility of this product class is assessed by brittleness temperature according to ISO 974:2000; plasticized PA12 grades of this nominal flexibility show ductile failure below -30 °C, whereas unmodified dry PA12 may show brittle failure at or above -20 °C depending on moisture condition. The presence of plasticizer increases total extractables relative to unmodified PA12; therefore applications requiring minimal extractable organic carbon require a grade-specific extraction study under the intended fluid and temperature.
Conversely, unmodified PA12 extrusion grades exhibit tensile modulus in the range of 1200 to 1600 MPa, Shore D hardness near 70, and lower elongation; they are used for rigid tube, connectors, and clips requiring higher dimensional stiffness. PA6 and PA66 absorb 8 to 10 wt% water at saturation under ISO 62:2008, causing marked modulus reduction and dimensional instability in humid or immersed conditions. Glass-fibre-reinforced PA6/66 grades reach tensile modulus above 9000 MPa but show reduced ductility and higher notch sensitivity at low temperature. The plasticized L 20 W 20 grade is therefore selected where bend radius, repeated flexing, cold impact, and fuel or urea compatibility dominate; it is not selected for high-pressure fittings, structural brackets, or wear components. Its plasticizer content also places it below PA12 elastomer block copolymers in cost and above them in modulus and creep resistance; the exact balance must be confirmed by creep testing to ISO 899-1:2017.
Table 2 compares the plasticized grade against unmodified PA12 and unreinforced PA6/66 using standardised test methods.
| Property | Plasticized PA12 L 20 W 20 | Unmodified PA12 | PA6/66 unreinforced |
|---|---|---|---|
| Density, ISO 1183-1:2019 | 1.01–1.03 g/cm³ | 1.01–1.02 g/cm³ | 1.13–1.14 g/cm³ |
| Tensile modulus, dry, ISO 527-1:2021, ISO 527-2:2021 | 250–350 MPa | 1200–1600 MPa | 1500–3200 MPa |
| Water absorption saturation at 23 °C, ISO 62:2008 | 1.0–1.6 wt% | 1.0–1.2 wt% | 8–10 wt% |
| Shore D hardness, ISO 868:2003 | 50–60 | 70–75 | 75–80 |
| Low-temperature ductility, notched Charpy, ISO 179-1:2023 | ductile below -30 °C | ductile at -20 °C when conditioned | brittle below 0 °C when dry |
After saturation in water at 23 °C according to ISO 62:2008, plasticized PA12 typically takes up 1.0 to 1.6 wt% water; at 50% relative humidity equilibrium uptake is below 0.5 wt%. Dimensional expansion after moisture uptake is anisotropic, with wall-thickness growth in extruded tube exceeding axial growth by approximately a factor of 2. The dry designation applies only to the sealed supplied state; once a bag is opened, the granulate must be protected by a dry-air hopper purge or re-dried. At relative humidity at or above 60%, exposure longer than 30 minutes triggers re-drying at 80 °C for 4 to 8 hours. Drying air dew point must be -30 °C or lower, and hopper inlet moisture should be verified at below 0.10 wt% by ISO 15512:2019. Drying above 100 °C is not recommended because plasticizer migration to the granule surface can cause hopper bridging, feed instability, and non-uniform plasticizer distribution in the final extrudate.
For regulatory submissions, the supplier should provide raw material composition statements and absence declarations against Regulation (EC) No 1907/2006 REACH, Directive 2011/65/EU RoHS Annex II, and FDA 21 CFR 177.1500 where food-contact use is intended. Specific medical-device or drinking-water clearances are grade- and lot-dependent and require written confirmation; the plasticizer system must be evaluated for migration under the intended temperature and contact medium. Personnel handling regrind must control the ratio of dry regrind to virgin material below 20% for critical tubing applications, because repeated extrusion increases plasticizer loss and lowers cold-impact resistance. The material must not be combined with amine-based additives or strong oxidising agents; strong polar solvents, concentrated acids, and high-alcohol fuel blends above the grade-specific compatibility limit can extract the plasticizer and reduce service life.