| Код ТН ВЭД | 567866 |
Как аккредитованный EMS-Grivory Grilamid L 20H FWA черный 9225 нейлон 12, модифицированный ударом, кондиционированный завод, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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In underhood validation programmes where vehicle-level thermal cycling follows OEM schedules derived from ISO 16750-4 climatic loads and SAE J2044 governs quick-connector interface compatibility, substitution of low-carbon steel spring clips with EMS-Grivory Grilamid L 20 H FWA black 9225 transfers the failure mode from corrosion fatigue and hydrogen embrittlement to creep stress relaxation at the barb interface. The conditioned nylon 12 grade is processed with melt temperature from 230 °C to 260 °C and mould temperature from 40 °C to 60 °C; the lower melt boundary is selected for wall sections below 1.2 mm to prevent flash under fast injection, while the upper boundary is limited by yellowing and impact loss when cumulative residence time exceeds 8 min at 260 °C. The material is specified at 100 wt% virgin for safety-critical retainers, and clean PA12-only regrind from identical production lots is limited to 15 wt% after drying to 0.10% moisture or below. Multi-cavity tools with valve-gated hot runners are used, with screw L/D between 20:1 and 24:1, compression ratio around 2.5:1 and hold pressure between 60% and 80% of peak injection pressure; actual injection pressure varies with runner balance and part thickness. Tensile and impact verification follows ISO 527-2 and ISO 179/1eA, while article-level salt spray, fuel immersion and vibrational endurance are OEM-specific and are not supplied by resin datasheet values. Final article types include quick-connector housings, fuel line clips, brake line retainers and service-port covers.
The limiting process parameter in pawl-type cable ties is not melt temperature but core deflection and hold-pressure decay across the pawl geometry, where the flexural hinge has wall sections below 0.8 mm and the ratchet shut-off creates local shear heating. EMS-Grivory Grilamid L 20 H FWA black 9225 is injected at melt temperatures from 220 °C to 250 °C into moulds held at 40 °C to 80 °C; at 250 °C melt residence time should not exceed 8 min, and screw rotation is adjusted so that frictional overshoot in the cushion does not exceed 260 °C. The ready-to-mould compound is dry-blended with clean cold-runner regrind up to 25 wt% when the regrind has been dried at 80 °C for 4–6 h to 0.10% moisture; above this regrind fraction, pawl flexibility decreases because of cumulative thermal history and the ductile-to-brittle transition shifts upward. Mechanical and flammability compliance for cable management articles is evaluated under UL 62275 and IEC 62275; flame classification is typically HB under UL 94 at the designated wall thickness, and any V classification requires separate article validation. Production-scale high-cavitation tools with 32 to 64 cavities operate on 800–2,500 kN clamp force, with cycle times from 6 s to 10 s depending on wall thickness and gate freeze. The observed production failure mode is inconsistent pawl release when mould temperature falls below 40 °C, because the hinge freezes before full crystallinity develops; this appears as cracked teeth and reduced loop tensile strength under UL 62275 testing. Terminal article types include indoor and outdoor cable ties, wire harness clips, security seals and identification marker tags.
Thread-bearing pneumatic connection bodies moulded from impact-modified PA12 require unscrewing or collapsing cores; demoulding torque rises sharply when mould temperature drops below 50 °C, and premature core rotation tears thread flanks because the material is still above its glass transition and the thread root is in a low-crystallinity state. Processing uses melt temperature from 230 °C to 260 °C and mould temperature from 50 °C to 70 °C; hold pressure is maintained until the sealing face is fully packed, and the screw L/D is kept at 20:1 to 24:1 to limit residence-time variation. The formulation is set at 100 wt% virgin for pressure-bearing bodies, while clean regrind up to 20 wt% is restricted to non-wetted external knobs and collars; no external impact modifier or colour masterbatch is added, because impact modification is part of the compound and black 9225 is self-coloured. Drying is mandatory at 80 °C if bags have been open above 60% relative humidity for more than 4 h, with residual moisture reduced to 0.10% maximum before moulding. Article-level validation is performed under ISO 14743 and system-level requirements under ISO 4414; material characterization follows ISO 527-2 and ISO 179/1eA. The main operational boundary is pressure-cycle fatigue in thread roots: aromatic-hydrocarbon thread sealants and aggressive cleaners can initiate stress cracking, so only PA12-compatible sealants and assembly fluids are acceptable. Terminal products include push-in fittings, flow-control regulator bodies, silencer housings and manifold connectors.
| Application field | Virgin/regrind ratio | Melt temperature | Mould temperature | Residual moisture limit |
|---|---|---|---|---|
| Automotive quick connectors and clips | 100 wt% virgin; regrind ≤ 15 wt% | 230–260 °C | 40–60 °C | 0.10% |
| Cable ties and harness management | 100 wt% virgin; regrind ≤ 25 wt% | 220–250 °C | 40–80 °C | 0.10% |
| Pneumatic push-in fittings | 100 wt% virgin for pressure bodies; regrind ≤ 20 wt% | 230–260 °C | 50–70 °C | 0.10% |
In low-mineral or demineralised water circuits, brass components show metallic migration and PA6 exhibits dimensional growth from water uptake that can exceed 2.5% by mass under long immersion, creating thread bind and hoop stress in inserted seals. EMS-Grivory Grilamid L 20 H FWA black 9225 is used where lower water uptake reduces swelling-induced cracking in threaded inserts; the FWA designation indicates that the grade is intended for food and water contact applications, but final compliance must be established on the finished article under EU 10/2011, FDA 21 CFR 177.1500 and NSF/ANSI 61 or NSF/ANSI 51 as applicable. Migration limits are article-specific and process-history dependent, so published data for this specific configuration are limited and extraction testing is part of mould qualification. The production process uses dedicated hoppers and dryers to prevent cross-contamination from non-compliant grades; external processing aids, mould-release sprays or lubricants are excluded unless explicitly listed for direct contact. The compound is run at 100 wt% virgin material; reuse of in-house scrap is limited to the same compliant grade, dried to 0.08% moisture or below, and scrap reuse must be covered by the migration testing plan. Melt temperature is set from 230 °C to 250 °C and mould temperature from 50 °C to 70 °C to maximize crystallinity and reduce post-mould migration of low-molecular fractions. Continuous exposure above 60 °C in pressurised water requires article-specific testing because hydrolytic ageing shifts impact resistance and dimensional stability. Terminal article types include beverage dispensing valve bodies, filter housings, quick-disconnect water couplings and equipment bushings.
Office seating and appliance lid snap joints that undergo more than 50,000 actuation cycles compare conditioned impact-modified PA12 with acetal and PA66 on actuation noise, creep recovery and low-temperature impact after moisture conditioning. EMS-Grivory Grilamid L 20 H FWA black 9225 is processed at melt temperature from 230 °C to 250 °C and mould temperature from 50 °C to 80 °C; the higher mould temperature is selected for parts with thick bosses to reduce void formation and improve dimensional stability under ISO 291 standard atmosphere. The formulation is used as a self-coloured compound, eliminating dry masterbatch addition at the press; reclaimed sprues and runners from identical material may be dry-blended up to 30 wt% for non-safety aesthetic covers, while functional snap arms are run at 100 wt% virgin because contamination with a single PA66 pellet or an incompatible regrind source shifts the ductile-to-brittle transition above −10 °C in unnotched impact tests. Structural validation uses ISO 527-2 tensile, ISO 179/1eU unnotched Charpy and DIN EN 12520 furniture load-cycle testing; appliance parts are assessed under IEC 60335-1 abnormal-heat and mechanical strength clauses. The production bottleneck occurs at thick-to-thin transitions: the relatively high melt viscosity of impact-modified PA12 leads to underfilled flexural hinges if the thin section is below 0.6 mm, so sequential valve gating or gas-counterpressure is used for full packing. Terminal products include chair armrest brackets, height-adjustment levers, appliance door hinges and ergonomic handles.
Cable glands moulded from impact-modified PA12 are specified when installation temperatures reach −40 °C and the sealing-ring groove must retain roundness after moisture equilibration. EMS-Grivory Grilamid L 20 H FWA black 9225 is injection moulded at melt temperature from 230 °C to 250 °C and mould temperature from 50 °C to 70 °C; because the grade is precolored black 9225, no carbon black masterbatch is added at the press, avoiding screw slip, agglomerate formation and lot-to-lot colour shift. The compound is used at 100 wt% virgin for the threaded body, while clean regrind up to 20 wt% may be used in locknuts that are not part of the flame path; all regrind is dried at 80 °C to 0.10% moisture before use. Compliance for cable glands references IEC 62444, EN 50262, RoHS 2011/65/EU and REACH 1907/2006; where explosion-protection equipment is involved, the final enclosure certification governs polymer acceptance, not the raw-material datasheet. The main process conflict is sealing-ring groove geometry: at mould temperatures below 50 °C, the groove surface freezes before full packing, causing out-of-roundness that increases in service after moisture uptake. Terminal products include polyamide cable glands, thread adapters, locknuts and strain-relief components.
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EMS-Grivory Grilamid L 20 H FWA black 9225 is a black-pigmented impact-modified polyamide 12 injection-moulding compound supplied with conditioned-state mechanical data. The full product code serves as the model identifier: the L family denotes the PA12 base produced from laurolactam, the numeric position and H suffix identify the viscosity and stabilisation modification, the FWA suffix positions the product in the food-contact and potable-water approval portfolio, and 9225 identifies the black colour batch. The term “conditioned” does not imply a plasticiser or surface treatment; it refers to moisture uptake to equilibrium at 23 °C/50 % RH under ISO 291 or accelerated conditioning under ISO 1110. Absorbed water lowers tensile modulus and yield stress while increasing notched impact energy because it disrupts intermolecular hydrogen bonding in the amorphous phase without removing the primary crystalline melting endotherm.
At equilibrium in 23 °C/50 % RH, PA12 absorbs approximately 0.7 % moisture by weight when determined to ISO 62. This uptake is roughly one-quarter of the value for PA6 under the same exposure, which is commonly reported at 2.8 %; the difference is a core reason the material is selected where humid dimensional stability and electrical consistency are required. For design purposes, dry-as-moulded data should not be used interchangeably with conditioned data because the mechanical response changes measurably after moisture equilibration.
Mechanical data for this grade are published in both dry-as-moulded and conditioned states. The conditioned values are determined after moisture uptake to equilibrium at 23 °C/50 % RH, or after accelerated conditioning under ISO 1110. The practical consequence is that a part tested immediately after moulding may exhibit higher stiffness and lower ductility than the same part tested after several weeks in humid air. The following typical values are drawn from supplier technical literature for injection-moulded specimens; they are not release limits and should be verified against the producer’s certificate of analysis for the specific production lot and colour batch. In the conditioned state, tensile modulus measured to ISO 527-1/-2 is typically 1300 MPa, yield stress is 35 MPa, and nominal strain at break remains above 50 %. Dry-as-moulded tensile modulus is typically 1500 MPa, yield stress is 40 MPa, and Charpy notched impact strength at 23 °C to ISO 179-1/1eA is typically 18 kJ/m², rising to 25 kJ/m² after conditioning. The influence of conditioning on the ductile–brittle transition is therefore a measured shift in the material’s energy-absorption capacity, not an artefact of surface moisture.
Table 1 summarises typical physical, thermal and mechanical values. Values are not specification minima and require confirmation on the production lot certificate.
| Property | Standard | Dry-as-moulded | Conditioned |
|---|---|---|---|
| Density | ISO 1183-1 | 1.02 g/cm³ | — |
| Water absorption, equilibrium | ISO 62 | — | 0.70 % |
| Water absorption, saturation | ISO 62 | — | 1.4 % |
| Tensile modulus | ISO 527-1/-2 | 1500 MPa | 1300 MPa |
| Yield stress | ISO 527-1/-2 | 40 MPa | 35 MPa |
| Nominal strain at break | ISO 527-1/-2 | >50 % | >50 % |
| Charpy notched impact strength, 23 °C | ISO 179-1/1eA | 18 kJ/m² | 25 kJ/m² |
| Charpy unnotched impact strength, 23 °C | ISO 179-1/1eU | no break | no break |
| Melting temperature | ISO 11357-1/-3 | 176 °C | — |
| Heat deflection temperature B, 0.45 MPa | ISO 75-1/-2 | 120 °C | — |
| Vicat softening temperature B50 | ISO 306 | 165 °C | — |
Compared with unmodified PA12, the impact-modified system lowers tensile modulus by approximately 200–300 MPa and elevates notched Charpy values. The modulus reduction is acceptable in applications where snap-fits, clips, or water-hammer resistant housings require higher energy absorption. Compared with a 30 wt% glass-reinforced PA12, the unreinforced grade sacrifices stiffness: short-glass PA12 grades typically exhibit tensile modulus values of 4000–6000 MPa, whereas this conditioned grade is in the 1300–1500 MPa range. The unreinforced impact-modified material is therefore selected where lower moisture uptake, better weld-line strength, and lower abrasive wear on mating parts are more important than maximum flexural rigidity. Against PA6 and PA66, the PA12 base provides lower equilibrium moisture absorption under ISO 62—about 0.7 % versus 2.5–2.8 %—and a lower density of 1.02 g/cm³ versus 1.13–1.14 g/cm³; however, PA6 and PA66 are often selected for short-term heat resistance because their melting temperatures are 220–260 °C, whereas this PA12 melts at 176 °C.
Production-scale processing of this compound requires desiccant drying at 80 °C for 4–8 h to a residual moisture below 0.10 % by weight; the dryer dew point should be −30 °C or lower. If the material has been exposed to ambient relative humidity above 60 % for more than a few hours, drying is mandatory to prevent hydrolytic degradation during plastication and surface splay at the gate. On a standard three-zone screw with L/D 20–22, a rising barrel profile from 210–230 °C in the feed zone to 235–260 °C at the nozzle maintains a melt temperature suitable for thin-wall flow without exceeding the upper processing limit. Mould wall temperatures of 40–80 °C are recommended; the upper range is used for flow paths above 150 mm or wall sections below 1 mm. Holding pressure on hydraulic machines is typically set at 40–70 MPa, with screw back pressure of 0.5–1.5 MPa and circumferential screw speed 0.15–0.25 m/s for a 25 mm screw. These setpoints are scalable by shot volume and screw geometry, and should be verified by short-shot and gate-seal studies on the actual mould.
Weld-line strength in impact-modified PA12 is significantly higher than in glass-filled grades, but it remains a function of melt-front angle and mould temperature. For multi-gated housings, weld lines should be moved away from pressure boundaries and tested to ISO 527-1/-2 or ASTM D638 on production-representative specimens. Higher mould temperatures of 70–80 °C promote polymer diffusion across the weld line; lower temperatures may produce a notch-like region that reduces burst pressure in water-carrying parts. Gate geometry should provide a shear rate below approximately 50 000 s⁻¹; higher shear rates may degrade the impact modifier and reduce Charpy notched impact energy.
On production lines, moisture content and mould temperature are the dominant variables affecting impact response; incoming-lot control should include a moisture analysis by ISO 15512 or an equivalent Karl Fischer method, not only a visual inspection of granule flow. Use of regrind for approved potable-water or food-contact components is governed by the application certification and should not exceed the percentage stated in the producer’s compliance letter. Long residence time at melt temperatures above 260 °C should be limited to 10 minutes; black pigmentation can mask early thermal discoloration, so purge intervals should be based on time and temperature rather than visual colour alone. In hot-runner systems, balanced thermal control across the manifold is required to prevent local overheating in low-shear zones, because impact-modified PA12 can lose toughness through cross-linking or chain scission in stagnant melt regions. For mould release, a non-amine, non-aromatic release spray is preferred; amine-based additives should be avoided because they can accelerate surface oxidation in the melt film.
The FWA suffix positions this grade for drinking water and food-contact uses, but compliance is an application-level property that depends on part geometry, surface-to-volume ratio, extraction temperature, and regrind content. Typical designations referenced for this product type are shown in Table 2. Certification status for the black 9225 colour batch under the latest revision of each standard must be confirmed with the producer’s compliance overview because regulatory status changes by country and by end-use. Under EU Regulation (EU) No 10/2011, overall migration is assessed in food simulants; the commonly applied limit is 10 mg/dm². Under FDA 21 CFR 177.1500, the resin must meet extractives and end-use limitations for the intended food type and temperature.
| Region/application | Standard or designation | Relevant condition |
|---|---|---|
| United States food contact | FDA 21 CFR 177.1500 | Extractives and end-use limitations |
| European food contact | EU Regulation (EU) No 10/2011 | Overall migration limit 10 mg/dm² |
| Potable water systems | NSF/ANSI/CAN 61 | Product-specific listing and maximum surface-area or volume ratio |
| German drinking water | DVGW W270 | Microbial growth resistance at 23 °C |
| United Kingdom water contact | BS 6920-1 | Odour, taste and water quality evaluation |
Typical applications for this conditioned impact-modified PA12 include cold-water meter housings, quick-connect fittings, shower and tap components, compressed-air line connectors, cable protection conduits, and snap-fit brackets for fluid systems. In water-bearing parts, the combination of 0.7 % equilibrium moisture absorption to ISO 62 and notched impact above 20 kJ/m² after conditioning supports dimensional stability and resistance to occasional water-hammer shock. However, long-term pressure-bearing service under hot water should be evaluated according to ISO 9080 because creep rupture behaviour cannot be inferred from short-term tensile data. Published data for this specific configuration in high-temperature chlorinated water service is limited; for such conditions, a mineral-reinforced PA12 or a semiaromatic polyamide may be required. Moulded parts should be allowed to condition in service for several weeks before final mechanical verification if the design data assume conditioned properties; otherwise snap-fit insertion force and clip deflection may shift as absorbed moisture increases from the dry-as-moulded state toward 0.7 %.