| Код ТН ВЭД | 191670 |
Как аккредитованный завод Envalior Arnitel ID 2060-HT Copolyester, 3D-печати, 100% перерабатываемого, для высокотемпературных приложений, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
| Упаковка | Envalior Arnitel ID 2060-HT Copolyester supplied in 25 kg moisture-barrier foil bags, palletized, labeled 100% recyclable for high-temperature 3D printing. |
| Погрузка контейнера (20-футовый контейнер) | Container Loading (20′ FCL): Palletized 25 kg bags of Envalior Arnitel ID 2060-HT copolyester pellets, wrapped and strapped. |
| Доставка | Envalior Arnitel ID 2060-HT Copolyester ships as a non-hazardous, 100% recyclable thermoplastic resin in sealed moisture-barrier bags, drums, or octabins. Palletized and protected from moisture, heat, and contamination. Store dry at ambient temperature. Standard transport regulations apply; no special hazard classification typically required. |
| Хранение | Store in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and ignition. Keep containers tightly sealed in original packaging to prevent moisture absorption. Use desiccant if needed. Avoid contact with strong oxidizers. Recommended storage temperature 15–30°C. Maintain clean, dry conditions; protect from physical damage. Shelf life may be reduced by moisture or excessive heat. |
| Срок годности | Shelf life is typically 24 months when stored unopened in original packaging, dry, cool, and away from moisture and UV. |
Short-series turbocharger inlet elbows on Stage III off-road diesel engines operate with wall temperatures between 130 °C and 150 °C, cyclic boost pressure from 1.8 bar to 2.4 bar absolute, and partial oil mist contact. Arnitel ID 2060-HT is processed as a 100 % thermoplastic copolyester elastomer filament with a melting region sufficiently above steady under-hood temperatures. The printed part is not a drop-in equivalent to injection-moulded Arnitel grades until interlayer fusion is normalised through orientation-specific tensile testing. The filament is dried in a desiccant wheel dryer at 100 °C for 4 h to a residual moisture content below 0.02 % by ISO 15512:2016. A hardened steel 0.4 mm nozzle is run at 245 °C, with first layer 250 °C and bed 100 °C. The heated build chamber is held at 70 °C for the full build to suppress warping. Layer height is fixed at 0.15 mm, with extrusion width 0.45 mm, three perimeters, and 100 % infill using a 0° cross-hatch raster. Cooling fan speed is disabled after the first three layers to prevent skin freezing ahead of the weld zone.
For under-hood service parts, automotive screening is performed to ISO 188:2019 hot-air ageing at 140 °C for 1,000 h, with tensile retention measured on ISO 527-2/1B specimens cut in both XY and XZ orientations. Oil resistance is screened using ASTM D471-16a in IRM 903 at 100 °C for 168 h. Volume swell above 20 % is the boundary condition for removing the part from further durability testing. REACH EC 1907/2006 Article 33 SVHC disclosure and RoHS 2011/65/EU Annex II apply to the final replacing part. Annealing at 120 °C for 2 h with 10 °C/h ramp rates removes residual stress. Un-annealed parts crack at the layer interface when clamped over a 4 mm retaining bead. The end product is a 55 mm internal diameter induction-side elbow with three integrated bellows convolutions and a spring-band groove. Batch-to-batch variance on a 600 mm/s open-frame fused filament fabrication machine remains within ±0.3 mm on the outer diameter when the spool is kept in a dry box at <10 % RH. Rejected prints and purge coils are re-ground, dried, and re-extruded into filament on a single-screw line with L/D 30 at 230 °C. Carboxyl end-group content rises after each thermal cycle, so reclaimed material is limited to non-pressure service brackets.
In chlorine-free high-purity water skids, flexible diaphragm seats are printed directly from Arnitel ID 2060-HT when the metal-bodied valve requires a snap-in dovetail seal with compression set below 25 % after 24 h at 100 °C under ISO 815-1:2019. The printed seat is not sold as a wetted pharmaceutical component until the moulder performs extractables screening under USP <665> and cytotoxicity per USP <87>. The base polymer also falls within REACH EC 1907/2006 and RoHS 2011/65/EU. The extrusion profile uses a 0.4 mm nozzle at 238 °C, bed 95 °C, chamber 65 °C, and a 0.10 mm layer height to reduce the staircase effect on the sealing land. Two outer perimeters surround 100 % infill. Flow rate is reduced to 0.95 to avoid overpacking at sharp dovetail roots. After printing, the seats are annealed at 110 °C for 4 h in forced air to close microvoids and relieve stress.
The application boundary is hydrolysis resistance in low-pressure steam cycles. TPC ester bonds degrade in wet heat. The user limits continuous exposure to 90 °C demineralised water and validates intermittent 121 °C sanitisation for 30 min cycles with hardness retention measured by ISO 868. When the part is installed in a stainless steel diaphragm head, compression set is evaluated on 25 × 25 × 6.3 mm printed plaques. On a pilot line using a 350 mm × 350 mm open-frame fused filament fabrication machine with a 65 °C chamber, outer diameter repeatability of ±0.2 mm was maintained only when spool residence time outside the dry box was below 20 min. The resulting part is a low-volume replacement diaphragm seat for a positive-displacement metering pump with 3 mm axial sealing beads. It is not a static O-ring substitute because the TPC sets under continuous compressive strain at the upper temperature limit.
Printed housings for handheld diagnostic readers must withstand pre-vacuum steam sterilisation at 134 °C for 3 min according to ISO 17665-1:2006 when terminal sterilisation is required between patient contacts. The base Arnitel ID 2060-HT grade is not automatically certified to USP Class VI. Each production lot is screened for cytotoxicity according to ISO 10993-5:2009 and for sensitisation or irritation according to ISO 10993-10:2010. The housing is printed on a fused filament fabrication machine with a 0.25 mm hardened nozzle at 250 °C, bed 100 °C, chamber 70 °C. Layer height is 0.08 mm to reduce surface porosity. Infill is 100 % with conical heat-break fan speed below 20 %. Parts are annealed at 100 °C for 8 h under nitrogen to limit thermal oxidation. Dimensional change after annealing is recorded across the 180 mm length. Shrinkage of 0.3 % to 0.5 % is typically compensated by scaling the STL file in the machine slice programme.
| Validation parameter | Standard | Condition | Acceptance criterion |
|---|---|---|---|
| Dimensional stability after terminal sterilisation | ISO 17665-1:2006 | 134 °C, 3 min pre-vacuum, 250 cycles | Linear change ≤ 1.0 % |
| Non-cytotoxicity | ISO 10993-5:2009 | Extraction in MEM, 37 °C, 24 h | Cell viability ≥ 70 % |
| Irritation sensitivity | ISO 10993-10:2010 | Occluded patch, 48 h | No erythema or oedema > 1.0 |
Warpage is the primary process conflict. With a chamber temperature of 70 °C, a 180 mm long housing footprint remains flat to within 0.4 mm after 72 h at 50 °C storage. If the chamber is below 55 °C, layer splitting occurs at the corners. The end product is a sealed front cover and rear shell pair with snap-fit latches, not a fluid-contact component. Battery pack removal requires crosshead screws with brass heat-stake inserts. Hole diameters are undersized at 3.8 mm and reamed to 4.0 mm after annealing. The printed housing is therefore a dimensional-prototype and short-run service part, not a substitute for a fully validated injection-moulded medical enclosure.
In electric vehicle charge inlet assembly, prototype insulating spacers and cable strain-relief clamps are printed from Arnitel ID 2060-HT because continuous conductor temperature during 350 kW fast charge can reach 105 °C next to terminal blocks. The grade is processed at 248 °C nozzle temperature, 105 °C bed, 75 °C chamber, and 0.12 mm layer height with 100 % infill. Electrical characterisation is performed according to IEC 60112:2020 for comparative tracking index. The printed substrate must survive 50 drops of 0.1 % ammonium chloride without forming a conductive path at 600 V. Dielectric strength is measured on 2 mm plaques per IEC 60243-1:2013 with 25 mm cylindrical electrodes in air. Volume resistivity is tested by IEC 62631-3-1:2016 at 500 V for 60 s. RoHS 2011/65/EU Annex II and REACH EC 1907/2006 SVHC disclosure are required for EV charging station components.
The printed insulator replaces a machined PEEK spacer where a snap-fit detail cannot be milled. The final part is installed in a 1,000 V HVDC busbar prototype. The main limitation is that this TPC is not inherently flame-retardant and cannot be used adjacent to unprotected busbars unless the system enclosure meets IEC 60695-11-10 at the final housing level. Failed prints are re-compounded with virgin pellets at a maximum 20 wt% regrind on a twin-screw extruder with L/D 40. Carboxyl end-group content is monitored by titration and must remain below 30 meq/kg for electrical retention after re-extrusion. The end product is a low-volume insulating retainer for a prototype fast-charge inlet, produced in batches of six on a 300 mm × 300 mm high-temperature build plate.
Robotic end effector soft jaws used on a paint line carry thermoplastic wheel centre caps through a 140 °C convection bake for 35 min. Arnitel ID 2060-HT is selected over thermoplastic polyurethane because TPU softens below 130 °C and nylon jaws mar the painted surface. The TPC jaw is printed with a 3-perimeter skin and 30 % gyroid infill to allow controlled compliance during a 90 N clamp force. Nozzle temperature is 243 °C, bed 100 °C, chamber 60 °C, layer height 0.20 mm, line width 0.50 mm, and cooling fan speed is limited to 30 % after layer four. After printing, jaws are annealed at 130 °C for 4 h and then machined on the gripping face with a 6 mm ball end mill to remove top-layer roughness. Solvent resistance is screened by 24 h immersion at 23 °C in a 50:50 by volume mixture of aromatic solvent and 2-butoxyethanol. Volume change is measured to ISO 1817:2015. The boundary condition is less than 5 % volume change and no visible edge cracking. This grade is not suitable for continuous immersion in methyl ethyl ketone or concentrated chlorinated solvents.
The production scenario is low-volume, typically 8 to 12 jaw inserts per paint line cell. Batch-to-batch variability in Shore hardness after annealing is controlled by checking ISO 868 with a Type D durometer on a 6 mm plaque. Readings between 55 D and 60 D are accepted. The end product is a form-locked jaw insert mounted to a Schunk PGN-plus gripper with two M6 bolts. Printed inserts survive approximately 3,000 cycles before the snap-fit ridge shows permanent deformation of 0.5 mm. Hard anodised aluminium inserts are used where cycle count exceeds 10,000. The TPC jaw therefore occupies a narrow operating band between painted-surface protection and long-term dimensional recovery.
Low-head hot water circulation pump thrust washers are printed from Arnitel ID 2060-HT where a conventional bronze washer causes corrosion currents in mixed-metal loops. The washer is produced with a 0.10 mm layer height to control radial leakage across the wear face. Nozzle temperature is 242 °C, bed 98 °C, chamber 65 °C, and infill is 100 % with a concentric raster pattern. The top and bottom wear faces are annealed at 120 °C for 6 h and then fly-cut with a single-point diamond tool to remove 0.05 mm from each face. If the part is intended for potable water contact, NSF/ANSI/CAN 61 screening is mandatory. This grade has no automatic certification. Extraction is evaluated at 85 °C for 168 h with pH 5 and pH 10 water. For industrial closed-loop water, chemical compatibility is screened by ISO 1817:2015 immersion in a 30 % ethylene glycol-water mixture at 100 °C for 72 h.
The operating boundary is defined by continuous flow temperature. At 120 °C continuous flow, the washer retains dimensional thickness within ±0.08 mm after 500 h. Above 135 °C, local creep at the shaft land exceeds 0.2 mm and the washer is rejected. End use is confined to circulator pumps with low specific load, typically below 0.3 MPa projected bearing pressure. The printed thrust washer is not a substitute for PEEK or ceramic wear rings in high-load, continuous slip service. The part is installed as a service replacement in a 25 mm shaft diameter pump with a three-lobe anti-rotation geometry. Printed lot acceptance checks include ISO 1183-1:2019 density and ISO 527-2/1B tensile yield on XY plaques. Density variation above ±0.02 g/cm³ indicates void formation and triggers immediate drying verification.
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Envalior Arnitel ID 2060-HT is a thermoplastic copolyester elastomer grade formulated for fused filament fabrication of parts that must retain elastomeric recovery after exposure to elevated air temperatures. The material is supplied as 3D printing filament in nominal diameters of 1.75 mm and 2.85 mm, with a stated diameter tolerance of ±0.05 mm, and the producer classifies the grade as 100% recyclable through mechanical regrind and re-extrusion. The designation ID identifies the industrial 3D printing range, 2060 denotes a Shore D hardness in the 60 range, and HT indicates high-temperature stabilization relative to standard thermoplastic copolyester filament grades.
Unlike rigid high-temperature thermoplastics such as polyetherimide or polyether ether ketone, the product is not intended for hard-shell structural components. It is used where flexural fatigue resistance, low-temperature impact, hot-air dimensional stability, and solvent tolerance are required simultaneously. Candidate parts include convoluted cable sheaths, underhood bellows, hot-air duct couplings, release-finger fixtures, vibration isolators, and industrial seals exposed to short-term surface temperatures up to 150°C.
The polymer matrix is a block copolyester composed of alternating hard crystalline domains based on poly(butylene terephthalate) and soft amorphous polyether segments. Differential scanning calorimetry according to ISO 11357-3 typically shows a hard-segment melting endotherm between 200°C and 220°C and a soft-segment glass transition below −40°C. This morphology allows the printed part to maintain flexibility below 0°C while retaining dimensional stability under hot-end service loads better than standard thermoplastic polyurethane.
The following values are summarized from Envalior technical datasheet data for dry-as-molded specimens and are not design allowables. Application-specific validation should include orientation-dependent testing of fused filament fabrication specimens.
| Property | Test method | Typical value |
|---|---|---|
| Density | ISO 1183-1 | 1.20 g/cm³ |
| Shore D hardness, 3 s | ISO 868 | 60 |
| Tensile stress at break, 50 mm/min | ISO 527-1/-2 | 40 MPa |
| Elongation at break, 50 mm/min | ISO 527-1/-2 | 350% |
| Flexural modulus | ISO 178 | 120 MPa |
| Charpy notched impact strength, 23°C | ISO 179-1/1eA | no break |
| Vicat softening temperature, A50 | ISO 306/A50 | 200°C |
| Heat deflection temperature, B 0.45 MPa | ISO 75-2/B | 120°C |
| Melt volume-flow rate, 260°C/2.16 kg | ISO 1133-1:2022 | 8 cm³/10 min |
The 120°C heat deflection temperature at 0.45 MPa is not a continuous-use ceiling for unstressed exposure. Hard-segment melting begins above 200°C, but viscoelastic softening reduces load-bearing capability below the melt point. For statically loaded parts, creep modulus measured according to ISO 899-2 at 100°C is the appropriate design basis rather than single-point HDT.
Moisture sensitivity is moderate compared with polyamide. Ester linkages hydrolyze when residual moisture enters the melt above 240°C, producing surface roughness and reduced interlayer adhesion. Production-scale processing therefore requires drying to a residual moisture content below 0.02 wt% before extrusion. Storage at relative humidity above 60% can return sufficient surface moisture to cause visible steam porosity within 24 h if the material is not protected.
Prior to hot-end extrusion, the filament is conditioned for 4–6 h at 100–110°C in a desiccant dryer with a dew point of −40°C or lower. A direct-drive extruder is recommended; the Shore D 60 filament is sufficiently stiff to avoid buckling in constrained filament paths but can deform in long Bowden tubes when retraction settings exceed 4 mm. Starting process parameters in a convection-heated chamber are a nozzle temperature of 250–270°C, a build plate temperature of 80–100°C, and a chamber temperature of 40–60°C. Layer heights of 0.10–0.20 mm and print speeds from 30 mm/s to 60 mm/s are reported to improve layer fusion; part cooling fans should be throttled to 20–40% to avoid warping and delamination. On a 0.4 mm brass nozzle, first-layer calibration at 0.15 mm thickness with 110% extrusion width is a common setup.
Rheological data from capillary rheometry according to ISO 11443 show that apparent melt viscosity at 250°C and 100 s⁻¹ is in the range of 300–800 Pa·s. This moderate viscosity permits flow through a 0.4 mm nozzle without excessive back pressure but can produce oozing during idle travel. Retraction settings therefore require a travel speed of at least 60 mm/s and a retraction distance of 1–3 mm on direct-drive systems. If melt residence time exceeds 10 min above 280°C, yellowing and loss of elongation occur due to thermal oxidation of the soft-segment ether groups.
Compounding and filament re-extrusion on a twin-screw extruder with L/D 32:1 typically uses a barrel profile of 230/245/255/260/260/255°C, a die temperature of 250°C, and a screw speed of 120 min⁻¹. Specific mechanical energy in the range of 0.18–0.24 kWh/kg is reported in production trials. Process conflicts occur when regrind content exceeds 30 wt%: the melt viscosity shifts, and a 5–10°C reduction in the feed zone is required to prevent over-plasticization and die swell. Vacuum venting at −0.08 MPa or lower is necessary to remove residual volatiles from recycled material.
Thermoplastic polyurethane with Shore A 95 softens rapidly above 90°C and loses clamp retention in hot fixtures. Nylon 11 has high impact and chemical resistance but is stiffer, moisture-sensitive, and typically not supplied as a flexible 100% recyclable filament. Arnitel ID 2060-HT combines a Shore D hardness of 60 with elongation at break above 300% and a Vicat softening temperature near 200°C. In comparative flexural fatigue testing at 80°C, the TPC grade retains a larger fraction of its room-temperature secant modulus than TPU 95A, while printed layer adhesion is less notch-sensitive than rigid PEEK blends. Unlike thermoset silicone or cast polyurethane, the material can be re-extruded without losing the continuous hard-segment network, which supports the 100% recyclable designation.
The difference is evident in heat aging. TPU 95A typically loses more than 30% of its tensile stress at break after 168 h at 120°C in unstrained specimens, while this TPC grade retains a higher proportion of original strength because the aromatic polyester hard segments are more resistant to oxidative embrittlement than polyether soft segments. Against PA11, the copolyester exhibits lower moisture uptake and less change in glass transition after conditioning at 50% relative humidity. However, PA11 has better resistance to high-pressure hot water and certain solvents, so material selection should include chemical compatibility testing rather than thermal ranking alone.
Validation protocols for automotive underhood bellows often use ISO 188:2023 hot-air aging at 150°C for 500 h followed by ISO 527-1/-2 tensile pull. Published data for this specific printed configuration is limited; producers report that unstrained specimens retain more than 80% of initial tensile strength, with modulus increase caused by secondary crystallization. For compression seals, ISO 815-1:2019 compression set at 100°C for 24 h is used as a screening method, with typical values below 60% depending on infill density and print orientation. Pneumatic duct couplings are tested with cyclic internal pressure at 80°C to confirm that Z-axis interlayer adhesion does not predominate in hoop stress fracture. The material is also used for paint-bake fixtures where short excursions to 180°C occur, although part geometry must avoid static load at the peak temperature.
For chemical-contact applications, ISO 175:2010 immersion testing is recommended before production release. At 85°C in ASTM reference fuel C for 168 h, the TPC grade can show moderate mass uptake; published data for the specific printed grade is limited, and universal fluid compatibility should not be assumed from molded TPC values. Compatibility with greases, transmission fluids, and dilute acids is generally favorable, but strong oxidizing acids, hot alkalis, and certain glycol ethers are outside the recommended service envelope.
Continuous immersion in hot water above 85°C or exposure to alkaline media above pH 9 accelerates hydrolysis of the ester hard segments. The resulting failure mode is a loss of elongation, surface whitening, and brittle fracture at layer lines rather than catastrophic softening. The grade should not be specified for steam-sterilized medical components requiring repeated autoclave exposure above 121°C unless the part is unloaded and the cycle count is limited. Contact with amine-based additives, certain glycol ethers, and strong oxidizing acids can degrade molecular weight faster than thermal aging alone. For chemical-contact applications, a 7-day immersion test in the service fluid at 85°C followed by ISO 527-1/-2 tensile testing is recommended before production release.
Mechanical recycling of spool waste, purge, and printed scrap is performed by size reduction to particles below 3 mm, drying to below 0.02 wt% moisture, and re-extrusion on a single-screw extruder with an L/D 25:1 and a 200 µm screen pack. Barrel temperatures in the 240–280°C range and a melt temperature limit of 280°C prevent thermal degradation. Regrind fractions above 30 wt% in virgin filament can reduce melt-flow stability; a 5–10°C reduction in the feed zone and a 10% reduction in screw speed are common compensations on production lines. Published data for repeated closed-loop recycling beyond five cycles is limited, so recyclate intended for load-bearing parts should be qualified with at least ISO 527-1/-2 tensile and ISO 179-1/1eA impact testing after each cycle.