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Envalior Novamid AM1030 FR (F) 3D Printing Grade, Flame Retardant (halogen free)

    • Название продукта: Envalior Novamid AM1030 FR (F) 3D Printing Grade, Flame Retardant (halogen free)
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
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    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Спецификации
    Код ТН ВЭД 390871

    Как аккредитованный завод Envalior Novamid AM1030 FR (F) 3D Printing Grade, FlameRetardant (без галогена), мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение Envalior Novamid AM1030 FR (F) 3D-печати класса, retardant огня (без галогена)

    In low-volume industrial automation enclosures, fused filament fabrication of Envalior Novamid AM1030 FR (F) is specified where machined glass-filled polyamide plate stock carries excessive material waste and where flame-retardant enclosure data must be available for the as-built polymer wall. The material is a polyamide 6/66 copolymer, halogen-free flame-retarded, supplied in filament form. In this segment, the terminal product is a control-panel cable entry plate and DIN-rail mounting adapter. The dimensional envelope is typically 180 mm × 120 mm × 28 mm. The print setpoint is 270 °C ±5 °C with a 0.4 mm hardened steel nozzle. A heated glass bed at 110 °C ±5 °C and a chamber temperature of 50–60 °C are maintained. Moisture is the primary process conflict. Polyamide 6/66 hydrolyzes above 0.15 wt% residual moisture. Filament spools are dried at 80 °C for 6 h using a forced-air desiccant dryer with a dew point of -40 °C. The drying hopper outlet RH is held below 2%. After drying, spools are stored in sealed containers with silica gel. The layer height-to-nozzle diameter ratio is 0.3 with a 0.12 mm layer height. Four perimeter walls and five solid top and bottom layers are used. Infill is 35% gyroid pattern. The extrusion multiplier is 0.98 to reduce inter-bead void formation. Hollows between laid-down rasters act as flame paths in vertical burn tests. Interlayer void density above 0.8% by micrograph analysis can shift a UL 94 V-0 plaque to V-2 because molten drip or wicking occurs along raster boundaries. Continuous machine-mounted filament diameter logging is used; diameter variation exceeding ±0.05 mm changes volumetric flow by approximately 2% and produces inconsistent bead width. Under IEC 61010-1, the fire enclosure must be evaluated in the end product; UL 94 V-0 at 1.6 mm wall thickness is the acceptance data point. The material’s published UL 94 V-0 rating at 1.6 mm is based on injection-molded plaques; as-built FFF coupons require verification because lamination planes are anisotropic. Sectioning at the narrowest wall before full-scale burn is standard incoming inspection.

    Process constraints are defined by the viscosity of halogen-free flame-retarded PA6/66. Below 260 °C, the melt is insufficiently fused between layers. Above 285 °C, residual moisture off-gassing produces pinholing. Therefore setpoint is locked at 270 °C ±5 °C. Dimensional tolerance after conditioning at 23 °C and 50% RH per ISO 291 is affected by moisture uptake, which expands unreinforced PA6/66 by up to 0.3% in service. For terminal product design, hole-to-edge distances are set at 2.0 mm, not less than 2× wall thickness, to avoid crack initiation at fasteners. The terminal product is installed with brass heat-set inserts at 220 °C, not above 230 °C, to avoid local flame-retardant package degradation.

    Where Do Halogen-Free Requirements Intersect With Automotive Battery Enclosure Prototypes?

    During early-stage battery management system prototyping, AM1030 FR (F) is used for carrier frames that position slave modules inside a traction battery enclosure. The terminal product is a 0.8 kg BMS slave board carrier with integrated snap-fits. The part is printed with a 0.6 mm hardened steel nozzle at a layer height of 0.20 mm, giving a layer height-to-nozzle diameter ratio of 0.33. Wall count is 4 perimeters, top and bottom solid layers are 6, and infill is 60% triangular. Extrusion multiplier is 1.0. Bed temperature is 110 °C ±5 °C. Chamber temperature is 60 °C. The material is dried to <0.15 wt% moisture before printing. In this application, the halogen-free composition is not a certification shortcut; it reduces acid gas accumulation during thermal propagation testing. Halogenated additives generate hydrogen chloride and hydrogen bromide at elevated temperature, which corrode cell tab connections and copper bus bars. The absence of halogenated flame retardants supports assembly-level corrosion control but does not eliminate ventilation requirements. Published data for the electrochemical corrosion rate of printed AM1030 FR (F) on copper at 85 °C and 85% RH is limited. The primary fire acceptance criterion is UL 94 V-0 at 1.6 mm, verified on a printed coupon section. For battery pack enclosures outside the passenger compartment, FMVSS 302 does not apply; UL 94 V-0 at 1.6 mm is typically invoked in OEM prototype specifications. The bracket must not be used as a structural load path because the unreinforced PA6/66 grade has a lower modulus than glass-filled alternatives. Snap-fit deflection is verified with ISO 527-2:2012 tensile specimens machined from a printed plaque. Z-direction tensile strength is evaluated with ISO 527-2:2012 1BA specimens milled from an as-built plaque; because FFF laminations are anisotropic, values are compared to XY specimens from the same print batch rather than to injection-molded datasheet values. If visual interlayer delamination appears after tensile loading, print chamber temperature is raised to 60 °C and printing speed is reduced to 40 mm/s.

    On rolling stock interior cable management systems, AM1030 FR (F) is printed as cantilever clips that retain low-voltage harnesses in ceiling voids. The terminal product is a cable cleat backing block with a 12 mm offset and a 6.2 mm clearance hole. The printed part may be required to demonstrate EN 45545-2:2020 R22/R23 compliance depending on hazard level and location. Halogen-free flame-retardant polyamide is specified because halogenated PA6/66 emits dense acid gas under EN 45545-2 test conditions. The typical print configuration is 0.15 mm layer height with a 0.4 mm hardened steel nozzle, giving a layer height-to-nozzle diameter ratio of 0.375. Four walls and 100% solid infill are used under the screw bosses. The remaining volume uses 50% rectangular infill to reduce mass. Extrusion multiplier is 0.97. The bed is set to 110 °C ±5 °C and the chamber is heated to 60 °C. Moisture control before printing is identical to industrial enclosure processing. Dimensional stability must account for moisture uptake. Under ISO 291 standard atmosphere 23 °C and 50% RH, unreinforced PA6/66 can expand by up to 0.3%; the clip slot is designed with 0.5 mm clearance to avoid binding. The fire test data for printed coupons is generated by ISO 5660-1 cone calorimetry and ISO 5659-2 smoke density testing. Published data for this specific printed grade under EN 45545-2:2020 R22/R23 is limited; end-product testing on the as-printed component is mandatory before installation. Batch-to-batch filament diameter variation is logged and spools outside ±0.05 mm are rejected because the rail clip wall thickness tolerance is ±0.15 mm. The clip is annealed at 110 °C for 1 h after printing to reduce internal stress before drilling. No amine-based mold release or epoxy adhesive is used in fixture assembly because solvent migration into the PA6/66 matrix alters UL 94 classification.

    Application segmentStandard or test methodVerification parameterCondition measured on
    Industrial control enclosureUL 94 Section 8 vertical burnV-0 at 1.6 mm wall; afterflame + afterglow ≤ 30 s per specimen after second flameAs-built FFF plaque
    Rail interior clipEN 45545-2:2020 R22/R23; ISO 5659-2, ISO 5660-1Ds max, VOF4, CIT per hazard levelPrinted component or representative coupon
    LED ballast housingIEC 60695-2-11:2014 glow wire flammability index750 °C tip; flames extinguish within 30 s; no tissue ignitionAs-built top face 2.0 mm wall
    UAV avionics coverUL 94 Section 8 vertical burnV-0 at 1.6 mm wallAs-built FFF plaque with 0.12 mm layers

    Glow Wire Ignition Resistance in Industrial Lighting Ballast Housings

    LED driver and electronic ballast housings for unattended installations are printed with AM1030 FR (F) when the enclosure must pass a 750 °C glow wire ignition test per IEC 60695-2-11:2014. The terminal product is an IP20 driver housing with internal dimensions 110 mm × 75 mm × 42 mm. Wall thickness at the top surface is set at 2.0 mm, not at the minimum 1.6 mm, because glow wire contact on FFF surfaces produces localized melt flow along raster lines. The housing is printed with 0.16 mm layers, a 0.4 mm hardened steel nozzle, 3 perimeter walls, 5 solid top and bottom layers, and 55% triangular infill. The layer height-to-nozzle diameter ratio is 0.4. Print temperature is 270 °C ±5 °C; bed temperature is 110 °C ±5 °C. The spool is dried to <0.15 wt% moisture. Printing speed is kept below 50 mm/s because higher speeds reduce interlayer fusion in thin wall sections and increase the number of open voids. After printing, the housing is annealed at 100 °C for 2 h in dry air to relieve lamination stress and reduce gross dimensional movement. The end-product standard IEC 61347-1:2015 requires that lamp controlgear enclosures withstand abnormal thermal conditions. Polymeric enclosures that are not verified to the end-product standard are tested to IEC 60695-2-11:2014. A 750 °C glow wire tip is applied for 30 s; the printed housing must not support burning longer than 30 s after tip removal, and the underlying tissue paper must not ignite. The test is performed on the as-built top face, not on an injection-molded plaque. Halogen-free composition is relevant because glow wire ignition of halogenated materials produces acidic smoke that corrodes driver terminals and wire bonds. Interlaminar voids at the glow wire contact point are controlled by setting infill overlap to 30% and perimeter overlap to 30%; void area is checked by optical microscopy at 25×. If the void area fraction exceeds 0.8% in a polished section, the part is scrapped.

    When UAV Avionics Enclosures Require UL 94 V-0 Without Halogenated Retardants

    For small unmanned aerial vehicle avionics enclosures adjacent to lithium polymer packs, AM1030 FR (F) is applied as a fire barrier lid and electronic speed controller cover. The terminal product is an ESC cover with nominal wall thickness 1.6 mm and mass 42 g. The printed part maintains a UL 94 V-0 rating at 1.6 mm; wall sections below 1.6 mm are not used because the rating is thickness-dependent and FFF laminations reduce consistency at depressions. The process uses a 0.4 mm hardened steel nozzle, 0.12 mm layer height, 2 walls in non-structural covers, 4 walls around the mating flange, 5 solid top and bottom layers, and 30% gyroid infill. Layer height-to-nozzle diameter ratio is 0.3. Extrusion multiplier is 0.96 to reduce oversize at thin walls. Print temperature is 268 °C ±5 °C; bed temperature is 105 °C ±5 °C. Chamber temperature is 50 °C. Drying to <0.15 wt% moisture is mandatory. Forced air flow and convective heat transfer during flight are not covered by UL 94; published data for this specific printed grade under forced-air flame spread per RTCA DO-160 Section 26 is limited. The enclosure must therefore be evaluated inside the full UAV fire propagation test if the air vehicle type certification requires it. The halogen-free formulation is selected to avoid acid gas deposition on adjacent avionics boards after pack venting. The printed cover is not a structural load path; load-bearing standoffs are metallic. Fasteners are stainless steel M2.5 hardware threaded into brass heat-set inserts set at 220 °C. The cover is annealed at 100 °C for 1 h in dry air to reduce stress cracking at insert bosses.

    When short-run consumer electronics battery housings must carry a UL 94 V-0 fire enclosure rating without halogenated flame retardants, AM1030 FR (F) replaces injection-molded polycarbonate/ABS in pilot runs. The terminal product is a battery compartment cover and frame for a handheld industrial measuring instrument. The housing is printed with a 0.4 mm hardened steel nozzle, 0.10 mm layer height, layer height-to-nozzle diameter ratio of 0.25, 3 perimeters, 6 solid top and bottom layers, and 45% honeycomb infill. The extrusion multiplier is 0.97. Print temperature is 265 °C ±5 °C, bed temperature is 105 °C ±5 °C, chamber temperature is 50 °C. Filament drying at 80 °C for 6 h to <0.15 wt% moisture is required; high ambient RH above 60% shortens shelf life in open-frame printers. The part is printed in the orientation that places the largest face on the build plate to minimize Z-height. Fire enclosure performance under IEC 62368-1:2018 is not certified by the material alone; the printed assembly is subjected to the end-product fire enclosure test or evaluated with UL 94 V-0 at 1.6 mm wall thickness. The snap-fit geometry is designed with deflection below the yield strain of the material; ISO 527-2:2012 1B specimens are milled from a printed plaque and tested after conditioning to ISO 291 at 23 °C and 50% RH. Halogen-free composition prevents corrosive smoke damage to battery terminals and PCB connectivity. The part is limited to internal or short-run validation quantities because FFF production speed and layer-to-layer mechanical anisotropy are not equivalent to injection molding. Moisture uptake above 0.15 wt% during printing produces bubbling and loss of interlayer adhesion; nylon filament is stored with desiccant and printed from a sealed dry box.

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    Envalior Novamid AM1030 FR (F) is an unfilled polyamide 6/66 filament grade formulated for fused filament fabrication. The grade carries a halogen-free flame-retardant package and is classified UL 94 V-0 at 1.5 mm and 3.0 mm thickness under the vertical burn method. The parenthesized F designation corresponds to the filament extrusion stream of the Novamid family and distinguishes the material from pellet-based injection-molding grades. Manufacturer-published typical data place melt temperature near 198 °C by ISO 11357-3 at 10 °C/min, density near 1140 kg/m³ by ISO 1183-1, and Vicat softening temperature near 196 °C by ISO 306 under 50 N and 50 °C/h. The mechanical property envelope quoted for dry specimens includes tensile modulus near 3100 MPa, yield stress near 66 MPa, and notched Charpy impact strength near 7.5 kJ/m² at 23 °C when tested according to ISO 527-1/-2 and ISO 179-1/1eA.

    The choice of a PA6/66 copolymer rather than a PA66 homopolymer lowers the peak crystallization exotherm and reduces in-plane shrinkage that can produce lifting and Z-axis delamination in open-chamber machines. The same copolymer structure reduces heat deflection temperature compared with glass-filled PA66 fire-retardant compounds. The grade is therefore used in printed parts where fire performance is required but sustained structural load at elevated temperature is not the primary service condition. The base formulation contains no glass fiber, mineral filler, or carbon fiber; the unfilled nature preserves filament flexibility and reduces nozzle wear compared with reinforced flame-retardant materials. Printed tensile data are not equivalent to injection-molded data because raster anisotropy, void fraction, and interlayer contact are process variables.

    How Does the Halogen-Free Phosphorus–Nitrogen System Attain UL 94 V-0 in a PA6/66 Matrix?

    The flame-retardant chemistry operates through phosphorus-driven char formation in the condensed phase and nitrogen gas-phase dilution. During vertical burn testing, a coherent intumescent char layer forms at 1.5 mm and 3.0 mm thickness, preventing dripping and ignition of the cotton indicator. UL 94 V-0 requires total afterflame time no greater than 50 s across five specimens, no single afterflame time greater than 10 s, and no flaming drips. The limiting oxygen index of the dry compound is commonly reported near 32 % under ISO 4589-2. The char layer is thin and coherent; it does not show the glass-fiber wicking effect observed in reinforced systems in which reinforcement can transport fuel to the surface and disrupt intumescence. The product meets the halogen-free limits of IEC 61249-2-21, which sets bromine and chlorine thresholds at 900 ppm each and total halogen at 1500 ppm. Because the flame-retardant package is not brominated, combustion by-products are not dominated by the same brominated dioxin or furan profile; however, all engineering thermoplastics release toxic gases under fire, and fume extraction during processing and burning remains mandatory.

    Before Printing, Condition the Filament as a Hydrolysis-Sensitive Melt

    Conditioning of the filament follows a hydrolysis-controlled protocol. At 23 °C and 50 % RH, equilibrium moisture uptake is approximately 2.4 % according to ISO 62; saturation moisture content for the polyamide can exceed 9 %. Open spools are dried at 80 °C for 4 h to 12 h in a dry-air oven with dew point no higher than -30 °C. On production floors, filament is kept in a heated dry-box with dew point below -40 °C during long prints. Ambient relative humidity above 60 % can raise spool moisture above 0.15 % within 8 h. Wet filament produces visible surface foaming, poor layer fusion, and hydrolysis-induced molecular weight loss; these defects cannot be recovered by raising nozzle temperature. Dried spools should remain sealed until installed, and feed paths should minimize open-air residence time.

    Melt Rheology and Extrusion Hardware Boundaries

    The melt volume-flow rate of the grade is nominally 10 cm³/10 min at 260 °C and 2.16 kg per ISO 1133-1. This places the material in a viscosity range requiring a direct-drive or high-torque Bowden extruder with a hardened-steel or ruby orifice. Brass orifices can be used at the lower temperature boundary, but phosphorus-containing decomposition products accelerate surface oxidation of copper alloys at sustained 260 °C exposure. The standard extrusion range for 1.75 mm filament is 250 °C to 270 °C; 2.85 mm filament is processed near the upper end of the range when nozzle diameter exceeds 0.6 mm. Bed temperature is held at 100 °C to 110 °C for first-layer adhesion on PEI or PVA-coated glass, with chamber heating to 60 °C where available. All-metal hot ends are required because PTFE-lined hot ends degrade above 250 °C and cause unstable melt temperature. The practical nozzle-temperature window extends from approximately 245 °C to 280 °C. At temperatures above 280 °C, phosphorus-flame-retardant volatilization can create nozzle deposits; below 245 °C, insufficient melt thermal energy reduces interlayer diffusion. Long melt residence times above 30 min in a hot nozzle or heat break are avoided because phosphorus-based flame-retardant packages undergo thermal discoloration and may lose vertical burn performance.

    Nominal Published Property Set for AM1030 FR (F)

    Values are manufacturer-published typical data for the filament grade. They are not lot-release specification limits and do not represent printed-part properties at all orientations.

    PropertyTest MethodTypical ValueCondition
    DensityISO 1183-11140 kg/m³23 °C
    Melt temperatureISO 11357-3198 °C10 °C/min
    Vicat softening temperatureISO 306196 °C50 N, 50 °C/h
    Heat deflection temperatureISO 75-272 °C1.8 MPa
    Tensile modulusISO 527-1/-23100 MPadry as molded
    Tensile stress at yieldISO 527-1/-266 MPadry as molded
    Nominal strain at breakISO 527-1/-222 %dry as molded
    Charpy notched impact strengthISO 179-1/1eA7.5 kJ/m²23 °C
    Charpy notched impact strengthISO 179-1/1eA3.2 kJ/m²-30 °C
    Melt volume-flow rateISO 1133-110 cm³/10 min260 °C, 2.16 kg
    Limiting oxygen indexISO 4589-232 %dry
    FlammabilityUL 94V-01.5 mm, 3.0 mm
    Moisture absorptionISO 622.4 %23 °C, 50 % RH

    In printed-specimen testing under ISO/ASTM 52921, measured tensile modulus and strength vary with raster angle, extrusion multiplier, layer height, and layer time. XY-oriented specimens may diverge from the injection-molded values listed above by 15 % to 35 %. Z-oriented specimens generally exhibit lower tensile strength because interlayer diffusion is the controlling failure mechanism. Published data for Z-strength specific to this configuration are limited; process qualification therefore requires a build-orientation matrix on the same machine, nozzle size, and chamber temperature used for production.

    When the Grade Replaces Unfilled PA6 or PA12 in Open-Chamber FFF Lines

    Unfilled PA6 filament in the same application class commonly carries no V-0 rating and can drip under vertical burn, while AM1030 FR (F) forms a stable char at 1.5 mm and 3.0 mm. Compared with unfilled PA6, the flame-retardant package increases melt viscosity and reduces elongation at break. The tensile modulus remains similar to a typical PA6/66 base. In a direct comparison on the same open-platform FFF system, replacing PA6 filament with AM1030 FR (F) typically requires raising the extruder setpoint by 10 °C to 20 °C and increasing the first-layer bed temperature by 10 °C. The extrusion multiplier may require adjustment because melt density and die swell differ from unfilled PA6. Field data from open-platform systems indicate increased nozzle pressure with 0.4 mm nozzles; a 0.5 mm or 0.6 mm orifice reduces backpressure for long deposition runs without shifting XY tensile properties outside the same order as baseline PA6.

    Compared with unfilled PA12, AM1030 FR (F) requires a higher bed temperature and more aggressive drying but provides a halogen-free V-0 option that unfilled PA12 without flame retardant cannot. The moisture regain is higher than PA12, and continuous immersion in hot water above 80 °C should be avoided because hydrolysis degrades the amide backbone. Relative to brominated flame-retardant PA66 compounds, the halogen-free chemistry avoids antimony trioxide and brominated flame-retardant listing concerns under IEC 61249-2-21. Halogen-free systems typically produce denser char and lower visible smoke density in standard laboratory observations, but published comparative smoke-density data for this specific compound are limited. Against carbon-fiber-filled print grades, the unfilled flame-retardant system is not electrically conductive and has lower stiffness; short carbon fiber increases tensile modulus but creates nozzle wear and can reduce surface resistance to flame spread by splitting the char layer.

    The compliance matrix below summarizes resin-level declarations. These declarations do not cover pigments or additives introduced by masterbatch at the converter, and they do not replace certification of the printed article.

    RequirementStandard or RegulationLimit or Status
    Halogen-free classificationIEC 61249-2-21Br 900 ppm, Cl 900 ppm, total halogen 1500 ppm
    Vertical burn classificationUL 94V-0 at 1.5 mm and 3.0 mm
    RoHS flame-retardant restrictionsDirective 2011/65/EU, Annex IINo declared PBB or PBDE above 0.1 % w/w
    REACH SVHC declarationEC No 1907/2006No SVHC above 0.1 % w/w as declared on safety data sheet

    What Operational Boundaries Limit Long-Term Part Service?

    The heat deflection temperature under 1.8 MPa is near 72 °C by ISO 75-2. Load-bearing printed parts should not operate above this value without creep testing, because the HDT method does not represent continuous stress at elevated temperature. Hydrolysis is the major chemical boundary: exposure to hot water, acids, or glycol-water mixtures above 60 °C reduces molecular weight and causes surface cracking. The grade is not recommended for continuous contact with strong acids or polyol-based brake fluids. Stress concentrations from holes, sharp radii, and support scars initiate interlayer cracks before bulk material yield; design radii should be maximized and supports removed before annealing. Annealing at 90 °C to 100 °C for 2 h can reduce residual stress but may alter flame-retardant exudation and dimensions; any annealed part must be re-evaluated for UL 94 classification at the final wall thickness.

    Raw material UL 94 V-0 classification does not automatically transfer to end-product flammability certification. Final printed parts can differ by wall thickness, infill density, surface roughness, and flame exposure orientation. End-use certification requires testing the printed configuration in the final thickness and orientation. Combustion gases remain hazardous; thermal decomposition releases carbon monoxide, nitrogen oxides, and phosphorus-containing species, so fume extraction is required.

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