| Код ТН ВЭД | 434194 |
Как аккредитованная фабрика смеси полимолочной кислоты FC 45270 /PBAT /крахмала, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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For blown-film converters running EN 13432-certified shopping bag lines, FC 45270 is supplied as a pre-compounded base resin, not as a masterbatch. All additive loadings are calculated on total resin mass. The processing window is narrow because the starch fraction begins to caramelize above 165 °C while the PLA phase requires at least 150 °C for complete melting. Single-screw extruders with L/D ratio 25:1 to 30:1 are typical. Feed-throat temperature is maintained at 20–30 °C to prevent pellet bridging. Pre-drying at 70 °C for 4 h to residual moisture below 250 ppm is mandatory when ambient relative humidity exceeds 60%. A desiccant dryer with a dew point of −40 °C is preferred. The barrel profile is set to 130–140 °C in the feed zone, 145–155 °C in the compression zone, and 150–160 °C in the metering zone. The die temperature is held at 155–165 °C. Extended residence time above 170 °C generates free lactic acid, lower melt viscosity, and gas bubbles in the web. A barrier screw with Maddock mixing section improves dispersion of the starch domains. Blow-up ratios between 2.5:1 and 3.2:1 are run on dies with 1.5–2.0 mm gap. Film thickness for checkout bags is 15–25 µm. The output per revolution is lower than for LDPE because the melt strength of the PBAT phase drops sharply above 160 °C. At frost-line height, the bubble is quenched with air at 10–20 °C. Film properties are tested according to EN ISO 527-3 for tensile, ISO 6383-2 for tear resistance, and ISO 7765-1 for puncture. Certification requires ≥90% ultimate biodegradation within 180 days under ISO 14855-1 or ASTM D5338 conditions and ≥90% disintegration after 12 weeks under EN 13432 pilot composting. Heavy metal limits follow EN 13432 Annex E. Printing on the web uses water-based or solventless inks with polyurethane binders that do not survive industrial composting if application exceeds 5 wt%. This limitation is often ignored at commercial scale and causes certification batch failure. Edge trim and start-up scrap may be re-ground up to 10 wt% without post-consumer contamination, but the regrind must be dried identically.
Agricultural mulch film produced from FC 45270 falls under EN 17033:2018 when marketed in the European Union. The standard requires ≥90% ultimate biodegradation in soil within 24 months at 20–25 °C, measured by ISO 17556 or ASTM D5988. It also requires ecotoxicity testing by OECD 208 and EN 13432 Annex E heavy metal limits. Film thickness in tomato, cotton, and maize mulch applications is 10–20 µm. A black masterbatch with carbon black at 2–4 wt% is used to suppress weed germination. This loading retards UV penetration and extends service life. Uncoloured film begins to lose mechanical integrity earlier because PBAT and PLA undergo photolytic chain scission. Processors tune the stabilizer package with hindered amine light stabilizers at 0.2–0.5 phr and UV absorbers at 0.1–0.3 phr. There is a direct conflict between field residence time and soil biodegradation rate. Excessive stabilizer loading slows microbial assimilation after soil incorporation. Accelerated weathering per ISO 4892-2 is used as a screening tool, but correlation to field residence time is limited. Quantitative correlation between laboratory UV ageing and field removal date is limited. Published data for this specific compound is not available. The film must remain intact for 8–12 weeks after laying, then disintegrate before the next planting cycle. Mulch film is converted on blown film lines with internal bubble cooling. Die gap is 1.8–2.2 mm. Blow-up ratio is 2.2:1–2.8:1. Melt temperature does not exceed 160 °C. Output is typically limited by screw torque rather than by downstream pulling capacity because the starch phase increases melt viscosity at low shear. The terminal products are soil-biodegradable mulch films for tomato, cotton, maize, and strawberry producers. These films control weeds and manage soil temperature without requiring removal after harvest.
At 12–15 µm thickness, fresh produce overwrap made from FC 45270 is used for vegetable bags, fruit bags, and bakery window bags. EU food contact compliance falls under Commission Regulation (EU) No 10/2011. Overall migration must not exceed 10 mg/dm² under the assigned food simulant. Specific migration limits are assessed for low molecular mass degradation products from PBAT and PLA. US FDA status depends on the specific additives and must be supported by the supplier’s food contact notification. Commercial anti-fog masterbatches based on glycerol esters are used at 0.3–1.0 phr. The additive migrates to the surface and lowers surface tension. This reduces droplet condensation on packaged leafy greens. It also increases surface tack. The seal initiation temperature for FC 45270 is 20–30 °C lower than for neat PLA. Heat sealing is performed at 100–120 °C with a dwell time of 0.5–1.0 s. The hot-tack is lower than LDPE and drops sharply above 130 °C. Oxygen transmission is measured by ASTM F1927 or ISO 15105-2. Water vapour transmission is measured by ASTM F1249 or ISO 15106-2. The starch domains increase WVTR relative to neat PLA. This is functional for fresh-cut produce. It is a limitation for bakery products requiring moisture retention below 5% weight loss over 14 days. Corona treatment at 38–42 mN/m is required before printing. Water-based CI flexo inks are used for the outer surface. This segment is relatively shallow because barrier requirements are managed by the customer and no single processing threshold dominates.
The organic waste caddy liner segment is not a simple downgauging of the shopping bag. Because caddy liners must survive wet household organic waste for 7 days without pinholing, the conversion line is configured differently. Film thickness is 10–12 µm. The blend is run on 55–65 mm extruders with L/D 28:1 to 30:1. The screw is configured with two mixing zones rather than one. A third mixing zone overheats the starch and causes gel formation. The die gap is set to 1.2–1.6 mm to achieve thin gauge. Blow-up ratio is 2.8:1 to 3.4:1. The bubble is stabilised with pneumatic guiding. Secondary rollers are operated at a lower tension than LDPE to avoid stretching. Quench air temperature is 8–15 °C. Film properties are checked by ASTM D1709-22 Method A for dart impact, ASTM D1922 for Elmendorf tear, and ISO 7765-1 for puncture. Brand-specific wet-contact pinhole acceptance is not covered by a single ISO method. Test frequency is higher after each screw purge because starch residues cause random weak spots. Home compost certification is not automatically transferred from industrial compost certification. If the finished bag is stamped with a home compost conformity mark, it must pass the corresponding certification scheme at ambient temperature. Data for FC 45270 in home compost is limited unless a specific validation certificate is available. The terminal products are 10–30 L organic waste bin liners and municipal food waste collection bags.
| Application context | Primary standard | Critical test method | Limiting parameter |
|---|---|---|---|
| Compostable shopping bag | EN 13432 | ISO 14855-1 | ≥90% biodegradation in 180 days |
| Soil-contact mulch film | EN 17033:2018 | ISO 17556 | ≥90% biodegradation in 24 months at 20–25 °C |
| Fresh produce overwrap | Commission Regulation (EU) No 10/2011 | EN 1186-1 | ≤10 mg/dm² overall migration |
| Organic waste caddy liner | EN 13432 | ISO 7765-1 | No pinhole formation after 7 days wet contact |
| E-commerce mailer | EN 13432 | ASTM D1709-22 Method A | No tear propagation under sortation |
| Garment bag | EN 13432 | ISO 527-3 | Weld integrity at 130–150 °C |
E-commerce mailer construction starts with blown film in the 40–70 µm range. The higher gauge is required because the film must maintain a tear path that does not propagate under sortation. For FC 45270, the extrusion line is configured with a larger die gap of 2.0–2.4 mm. The cooling air temperature is 12–18 °C. A lower blow-up ratio of 1.8:1 to 2.2:1 is used to reduce orientation. The film is subsequently printed, coated, and sealed. The adhesive flap uses a compostable pressure-sensitive adhesive. The adhesive is applied at 10–20 g/m² dry coat weight. The adhesive must not interfere with disintegration. The terminal product is a compostable mailer bag for clothing, footwear, and consumer electronics accessories. Compliance is normally against EN 13432 and applicable REACH substance restrictions. The main processing conflict is heat sealing of thick film. Seal bars must maintain 110–130 °C for 1.0–2.0 s. A dwell time below 0.8 s produces weak seals. A dwell time above 3 s deforms the starch phase and creates shrink marks. The finished bag is not suitable for high-humidity shipment or liquid-containing goods because the starch phase absorbs moisture and swells. This is an operational boundary. The segment is less demanding than thin-gauge caddy liner because thickness masks some starch dispersion defects.
For transparent garment packaging, the film is run at 25–35 µm. The film is used as a single-web sleeve without lamination. It is folded and sealed on side-weld bag machines. The difference from food overwrap is the absence of anti-fog additive and the reduced focus on migration. The conversion line uses a blade or rotary sealing system. Seal temperature is 130–150 °C because the thicker web needs more heat to reach the seal interface. The film is dust-sensitive. Static charge accumulates rapidly. Anti-static additives are not always compatible with EN 13432 disintegration. Processors use ionising bars instead of additives. The terminal product is a compostable garment bag with a perforation for air evacuation. This is a shallow application because the functional requirements are less severe than food contact or soil contact.
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FC 45270 is a flexible film extrusion grade based on polylactic acid (PLA), poly(butylene adipate-co-terephthalate) (PBAT), and thermoplastic starch (TPS). The designation identifies a ternary compound in which PBAT supplies low-temperature flexibility and tear resistance, PLA contributes stiffness and renewable carbon, and starch functions as a plasticized particulate filler that lowers compound cost and accelerates disintegration in industrial composting. Published data for this specific commercial formulation are limited. The property values that follow are therefore representative ranges for PLA/PBAT/TPS flexible film blends of comparable composition, not batch certificates for FC 45270.
Incoming inspection for this product class typically records density between 1.20 g/cm³ and 1.30 g/cm³ according to ISO 1183-1:2019, melt flow rate between 2.0 g/10 min and 6.0 g/10 min at 190 °C under 2.16 kg load according to ISO 1133-1:2022, and residual moisture below 0.05 wt% after drying. Bio-based carbon content measured by ASTM D6866-22 typically falls between 40% and 60%, depending on PLA and starch ratio.
Film mechanical response measured according to ISO 527-3:2018 on 25 to 50 µm specimens commonly shows machine-direction elongation at break from 150% to 400%, transverse-direction elongation from 100% to 300%, tensile strength from 15 MPa to 30 MPa, and secant modulus from 150 MPa to 450 MPa. Tear resistance according to ISO 6383-2:1983 is typically between 20 N/mm and 60 N/mm, and dart drop impact according to ISO 7765-1:1988 may range from 100 g to 300 g for 25 µm film. Oxygen transmission rate through 25 µm film measured according to ASTM D3985-17 is typically higher than LDPE and may range from 500 to 1500 cm³/(m²·day·atm) at 23 °C and 0% relative humidity. Water vapour transmission rate according to ISO 15106-1:2013 at 38 °C and 90% relative humidity generally exceeds 100 g/(m²·day) because of the hydrophilic starch fraction.
Conversion on conventional polyethylene blown film equipment is feasible only after removal of hygroscopic starch-bound moisture. A desiccant dryer with air dew point below -40 °C, inlet temperature between 60 °C and 70 °C, and residence time of 4 to 6 h is the minimum starting condition. Target residual moisture is below 250 ppm; above this level, hydrolytic degradation of PLA reduces melt viscosity and produces gel particles and unstable bubble geometry.
Barrel profiles are typically set from 145 °C in the feed zone to 165 °C at the die, with a melt temperature ceiling of 175 °C to limit thermal degradation of starch and PLA. Screws with L/D ratios of 30:1 to 36:1 and low-shear mixing sections are preferred; compression ratios above 3.5:1 generate excessive viscous dissipation and torque instability. Blow-up ratio is usually maintained between 2.0:1 and 3.0:1. Lower ratios improve bubble stability but reduce transverse tensile properties; higher ratios increase frost line height and may initiate melt resonance. Frost line position is typically held at 2 to 4 die diameters. Die tip gaps below 1.0 mm create high die pressure and melt fracture, while gaps above 2.5 mm reduce drawdown and increase thickness variation.
On chill-roll cast film lines, melt temperature of 150 °C to 170 °C and chill-roll temperature of 15 °C to 30 °C are typical. Lower melt strength relative to LDPE limits line speed and requires a short air gap to prevent neck-in and draw resonance. Dynamic shear rheology at 170 °C shows shear-thinning behaviour. In small-amplitude oscillatory tests the complex viscosity at 1 rad/s typically lies between 500 Pa·s and 2000 Pa·s, and at 100 rad/s between 50 Pa·s and 200 Pa·s. Melt strength measured on a Rheotens strand is commonly 5 to 15 cN, compared with 15 to 30 cN for LDPE under similar throughput. The reduced strain hardening limits maximum blow-up ratio and film width, especially on wide-bubble lines.
Differential scanning calorimetry according to ISO 11357-2:2020 shows a glass transition associated with PLA near 55 °C to 62 °C and a melting endotherm between 150 °C and 170 °C. PBAT contributes a broad melting region between 110 °C and 130 °C depending on its comonomer ratio. The starch phase does not show a sharp melting transition; its gelatinisation during compounding is controlled by plasticizer and water content.
Heat-sealing response differs from LDPE. Seal initiation is commonly observed between 100 °C and 120 °C on laboratory heat seal testers. Peel strength according to ASTM F88/F88M-21 is typically 5 to 15 N per 25.4 mm for 25 µm film, below that of LDPE. Seal bar temperatures above 135 °C can generate interfacial bubbles and inconsistent seal transfer because starch particles create weak boundary layers.
The comparative values below are representative envelopes from public literature and standard test methods. Actual FC 45270 performance must be confirmed with a certificate of analysis because starch type, plasticizer chemistry, and PBAT molecular weight can shift individual values beyond the listed range.
| Attribute | PLA/PBAT/starch class | PLA/PBAT binary | Neat PLA | LDPE |
|---|---|---|---|---|
| Tensile secant modulus, ISO 527-3:2018 | 150–450 MPa | 120–400 MPa | 2000–3500 MPa | 150–350 MPa |
| Elongation at break, machine direction | 150%–400% | 300%–700% | 2%–10% | 300%–600% |
| Tear resistance, ISO 6383-2:1983 | 20–60 N/mm | 40–100 N/mm | 5–15 N/mm | 50–120 N/mm |
| Bio-based carbon, ASTM D6866-22 | 40%–60% | 30%–70% | 100% | 0% |
| Disintegration response under ISO 20200:2023 | Rapid, starch accelerates fragmentation | Moderate | Slow, thickness-dependent | No compost disintegration |
| Moisture sensitivity at 50% RH | High | Moderate | Low | Very low |
| Typical processing window | 150–175 °C | 160–190 °C | 170–210 °C | 180–240 °C |
Primary application areas include short-service flexible packaging, compostable shopping bags, agricultural mulch films, and waste-collection sacks where industrial composting is specified. Food-contact status must be evaluated under the relevant national regulation. A compostability claim under EN 13432:2000 or ASTM D6400-23 does not automatically include food-contact approval.
For compliance under EN 13432:2000, the compound must meet characterisation limits for volatile solids and heavy metals, achieve at least 90% ultimate biodegradation relative to a positive reference within 180 days per ISO 14855-2:2018 or equivalent, disintegrate to less than 10% of the original dry mass retained on a 2.0 mm sieve after 12 weeks, and pass ecotoxicity tests. Under ASTM D6400-23, the corresponding threshold is at least 90% conversion to carbon dioxide within 180 days, with disintegration and ecotoxicity criteria similar in structure but not identical in detail. A valid third-party certificate is required for labelling.
At starch loadings above approximately 30 wt% with insufficient plasticizer, the film exhibits surface roughness, micro-voids, and reduced transverse-direction tear resistance. Processing trials on 25 mm twin-screw compounding equipment show torque fluctuations and vent clogging when starch is not fully gelatinised. The critical limit is not a fixed compositional boundary because gelatinisation efficiency, PBAT molecular weight, and plasticizer selection shift the phase inversion point. Published data for this specific configuration is limited; pilot-scale verification on the intended blown film line is required before commercial run-off.
Unprocessed starch particles also increase moisture regain. Films stored at 23 °C and 50% relative humidity can reach equilibrium moisture content of 2.0 to 4.0 wt% and lose stiffness. When relative humidity exceeds 60%, edge blocking and pouch curl are reported on high-speed converting lines. Pre-conditioning of the film before printing and sealing is therefore required. Unopened bags should be stored at 15 °C to 30 °C and below 50% relative humidity. Opened silos or hoppers exposed to ambient moisture for more than 30 min require re-drying before extrusion.
Compatibility with additives is narrower than polyolefins. Acidic melt pH depressants accelerate chain scission of PLA and hydrolytic degradation of starch. Epoxy-functional chain extenders, high-molecular-weight plasticizers, and mineral nucleants are used in small quantities to modify melt strength and crystallization kinetics, but their addition must be validated by melt flow and film tear testing because interactions with the starch phase are not linear. Colour masterbatch carriers should be PLA or PBAT based; polyethylene or polypropylene carriers are not compatible and can appear as gels at the film surface.
This material is incompatible with polyolefin recycling streams. Co-mingling with polyethylene or polypropylene at concentrations above 2 wt% can generate layered delamination and reduced weld strength in recycled polyolefin articles. It should not be processed on equipment previously used for polyvinyl chloride without a thorough purging protocol because residual acidic chlorine species can accelerate polyester hydrolysis.
For blown film conversion, continuous gravimetric dosing is preferred over volumetric premix. When virgin pellets and regrind are combined, regrind content should not exceed 20 wt% unless the film is post-annealed, because reprocessing reduces molecular weight and increases gel defect density. Edge trim from cast film can be reintroduced at similar ratios if dust and moisture are controlled below 0.05 wt%.
Surface energy of PLA/PBAT/starch films after corona treatment commonly measures 38 to 46 mN/m according to ISO 8296:2003; without treatment, values around 32 to 36 mN/m reduce ink adhesion. Print trials should verify ink anchorage and blocking behaviour at 40 °C because the starch-rich surface can soften under roll pressure and elevated storage temperatures.