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Henkel Loctite 3D IND402™ A70 High Rebound Black Elastomeric UV Photocurable Resin

    • Название продукта: Henkel Loctite 3D IND402™ A70 High Rebound Black Elastomeric UV Photocurable Resin
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
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    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Код ТН ВЭД 872769

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    Применение Henkel Loctite 3D IND402™ A70 High Rebound Black Elastomeric UV Photocureable Resin

    In footwear midsole and removable insole production, Henkel Loctite 3D IND402™ A70 High Rebound Black Elastomeric UV Photocurable Resin is processed as a ready-to-photopolymerize elastomer for vat photopolymerization lines operating in the 385–405 nm band. The formulation addition ratio in the digital light processing vat is 100 wt% as-supplied solids, with 0 wt% external solvent, thermal initiator, or reactive diluent, because even small reactive-diluent additions shift the Shore A 70 hardness plateau and reduce rebound consistency across batch builds. Production-scale workflow requires pre-conditioning the resin in a cabinet at 25–30°C before vat loading; field batch logs indicate that vat temperatures below 22°C produce slow recoat, meniscus tearing, and layer delamination on bottom-up DLP systems. Lattice midsoles are generated from gyroid, Schwarz-P, or body-centered cubic cell architectures, with printed density controlled by strut wall thickness and cell size rather than by chemical foaming agents. Critical processing parameters include layer heights of 50–100 μm, black-grade exposure calibration to compensate for higher UV absorption than clear resins, and reduced lift speeds to avoid viscous re-coating failures. After printing, parts are washed in a two-stage isopropyl alcohol or propylene glycol ether bath, force-air dried, and UV post-cured in a 405 nm LED chamber; under-curing is a known failure mode because residual uncured monomer plasticizes the lattice and raises compression set. Post-cure cycles observed in production environments commonly run 30–60 min at mild chamber temperatures, but thick lattice sections can generate exothermic crosslinking heat and must be profiled by measured Shore A rather than fixed time alone. Industry compliance anchors include REACH Regulation (EC) No 1907/2006, RoHS Directive 2011/65/EU amended by (EU) 2015/863, ASTM D2240-15e1 for durometer, ISO 815-1:2019 for compression set, ASTM F1614-99(2018) for athletic footwear force attenuation, and ASTM D2632-15 for rebound resilience where dynamic energy return is specified. Terminal product types in this sector are recovery sandals, performance running shoe midsoles, removable insoles, and clog footbeds that use the high-rebound character for cyclic loading. Published data for long-term dynamic fatigue of this exact resin in athletic footwear is limited; original equipment manufacturers should commission in-house cyclic testing under ISO 23529:2021 specimen preparation.

    What Must Be Validated Before Replacing Compression-Molded EPDM Gaskets with UV Elastomer Prints?

    In low-pressure pneumatic and hydraulic access cover applications, the resin is printed directly as a gasket profile with a conformal sealing bead and, where flexure is required, a thin wall or hollow core to manage bolt compression. The formulation addition ratio in the vat is 100 wt% resin, with 0 wt% external curative, silicone oil, or plasticizer; the black pigment is already dispersed in the photopolymer, and containers must not be topped up with reactive diluent because altered crosslink density changes the Shore A 70 sealing behavior and recoating response. Downstream production includes DLP/LCD printing at 50–100 μm Z resolution, two-stage solvent washing in high-purity isopropyl alcohol, forced-air drying, and 405 nm LED post-cure. For flange installation, the printed seal is typically compressed 20–30% in the groove; field experience shows that compression set after thermal soak, not initial durometer reading, determines whether the gasket maintains contact force after assembly. Industry compliance standards include ASTM D2000-18 for rubber materials classification, ASTM D412-16 for tensile stress-strain, ISO 815-1:2019 for compression set, and ISO 3601-1:2012 for O-ring housing geometry when the part is installed in a standardized gland. A critical boundary is that this black elastomeric photopolymer is not automatically a substitute for EPDM or FKM in continuous high-temperature service; published data for long-term thermal aging of this exact resin in hot air above 80°C is limited, and compatibility with mineral oil, glycol-water, or ester-based fluids must be verified against the intended sealing media. Terminal product types are pneumatic cylinder access gaskets, battery enclosure face seals, cable entry gaskets, and inspection cover seals for low-temperature industrial enclosures.

    Wearable electronic device housings present a manufacturing environment where a Shore A 70 black elastomer is used for wristband links, strap loops, button covers, and gasket lips that require compliance, repeated flexural recovery, and resistance to skin oils and cosmetic lotions. The resin is processed at 100 wt% in bottom-up DLP printers equipped with 385–405 nm LED arrays; no secondary photoinitiator or thermoplastic toughener is added, and external colorants are not recommended because the black formulation is already compounded and adding even 0.1–0.5 wt% liquid pigment dispersion can alter cure depth and layer adhesion. Downstream manufacturing for wearable parts includes high-resolution printing at 50 μm layer thickness, two-stage solvent washing to remove uncured resin from micro-fine strap perforations, and UV post-cure in a vented or inert chamber to stabilize surface tack. Thin-wall sections are more exposed to oxygen inhibition during printing, so the green-state surface can remain tacky until sufficient post-cure conversion is achieved; this is a production bottleneck when wash racks are loaded too densely. Industry compliance for wearable electronic accessories is anchored to RoHS Directive 2011/65/EU amended by (EU) 2015/863, REACH Regulation (EC) No 1907/2006, and IEC 62368-1:2018 for information technology and audiovisual equipment safety. Skin-contact parts are market-ready only after the responsible organization commissions ISO 10993-5:2009 cytotoxicity and ISO 10993-10:2021 skin irritation testing, because published skin-sensitization data for this specific black photopolymer grade is limited. Terminal product types are smartwatch strap segments, AR/VR headset gasket interfaces, earbud housing seals, and wrist-worn sensor covers.

    When Impact Liners Move from Foam Pads to High-Rebound Photopolymer Lattices

    In sports protective equipment, the transition from crosslinked polyurethane foam or ethylene-vinyl acetate foam to high-rebound photopolymer lattice liners is viable only where the printed component is designed as an energy-returning protective layer inside a fully assembled protector, not as a standalone impact-certified barrier. The resin is consumed at 100 wt% neat; the functional compression response is set by lattice volume fraction, cell size, and wall thickness through CAM slicing parameters, not by formulation additions. No blowing agent, chemical foaming agent, or air-loaded filler is introduced, and any external plasticizer addition above 0 wt% is treated as an unvalidated formulation change. In downstream production, the liner is printed with a black-resin exposure profile on a vat photopolymerization system, washed in two-stage solvent baths, dried until mass stabilizes, and post-cured under 405 nm LED irradiation. Because black elastomer lattices with thin nodes can retain cleaning solvent after washing, premature packaging causes long-term softening and dimensional drift; forced-air drying until no mass loss is measurable is required. Compliance for impact-protective wearables includes EN 1621-1:2012 for limb joint impact protectors, relevant sport-specific assembled-protection certification such as ASTM F2439-17 where headgear attenuation is evaluated, and chemical restrictions under REACH and CPSIA for consumer gear. Terminal products are shin guard impact backings, goalkeeper padding inserts, helmet comfort liners, and chest protector energy-returning layers. Published data for pass/fail performance of this exact Henkel resin in a finished protective garment is limited; each integrator must test the assembled protector as sold rather than relying on material-level rebound data alone.

    Shore A 70 Photopolymer Liners in Orthotic Interface Fabrication

    Orthotic and prosthetic interface products require thin elastomer layers that diffuse shear and reduce peak pressure on residual limbs or plantar surfaces. In this sector, the resin is loaded into vat photopolymerization equipment at 100 wt% as-supplied, with 0 wt% additive ratio; because the material is not automatically certified as a skin-contacting medical device polymer simply by being printed, manufacturing quality systems must conform to ISO 13485:2016, and biological evaluation must be planned under ISO 10993-1:2018 with at least ISO 10993-5:2009 and ISO 10993-10:2021 alongside leachable screening where applicable. The downstream production sequence is digital scan or cast capture, CAD offset and lattice generation, printing at 50–100 μm layer height, solvent washing, and 405 nm post-cure. For socket liners and orthotic top covers, printed surfaces may require a non-photopolymer skin-contact coating to manage moisture absorption and residual tack; compatibility of any coating with the photocured network must be tested, and amine-heavy primers should be avoided because amine functional groups can cause surface degradation and discoloration in acrylate elastomers. If ambient relative humidity exceeds 60%, printed elastomer surfaces should be dried before coating or bonding to prevent interfacial adhesion loss. Terminal products include prosthetic socket interface pads, metatarsal pads, toe crest inserts, heel shear-reducing inserts, and custom foot orthosis top layers. Published data for this exact black elastomer in extended domiciliary orthotic use is limited.

    Converting Low-Volume Interior Damping Components to Vat-Polymerized Elastomers

    Automotive interior and adjacent low-volume production lines use the resin for soft damping collars, grommets, snap-fit isolators, and noise-vibration-harshness tuned inserts where compression-molded elastomer tooling would be uneconomical for batch sizes below a few thousand units. The formulation addition ratio remains 100 wt% resin, with no secondary plasticizer; when overmolding or bonding to a rigid polycarbonate or nylon substrate is required, the bond surface must be primed or mechanically textured because the photopolymer surface alone shows limited adhesion to non-porous thermoplastics. In downstream processing, DLP/LCD machines print at 50–100 μm layers, followed by two-stage solvent rinsing, forced-air drying, and 405 nm LED post-cure; for automotive interior parts, a further thermal soaking step is sometimes used to reduce residual odor and monomer migration, but no universal cycle can be specified because cavity size and wall thickness control solvent and monomer retention. Compliance anchors include ISO 3795:1989 or an OEM-specific flammability test, VDA 278:2011 for volatile organic compound and fogging emissions, the EU End-of-Life Vehicles Directive 2000/53/EC, and IATF 16949 process control within the supply chain. Terminal product types are HVAC blend door dampers, wire harness grommets, sensor isolator mounts, and low-run interior trim isolators. A strict boundary is that this elastomeric photopolymer is not a drop-in replacement for silicones in engine-bay or continuous high-temperature 85°C-plus locations; validated behavior for specific automotive fluids and thermal cycling must be generated by the tier supplier.

    Compliance test matrix for downstream application sectors
    SectorPrimary standards and directivesTest objective
    Footwear midsoles and insolesASTM D2240-15e1, ISO 815-1:2019, ASTM F1614-99(2018), REACH, RoHSDurometer, compression set, force attenuation
    Industrial seals and gasketsASTM D2000-18, ASTM D412-16, ISO 3601-1:2012, ISO 815-1:2019Classification, tensile, gland fit, sealability
    Wearable electronicsIEC 62368-1:2018, ISO 10993-5:2009, ISO 10993-10:2021, RoHS, REACHProduct safety, cytotoxicity, skin irritation
    Sports impact protectionEN 1621-1:2012, ASTM F2439-17, REACH, CPSIAImpact attenuation, assembled-protection testing
    Orthotic and prosthetic interfacesISO 13485:2016, ISO 10993-1:2018, ISO 10993-5:2009, ISO 10993-10:2021Quality management, biological evaluation
    Automotive interior dampingISO 3795:1989, VDA 278:2011, ELV 2000/53/EC, IATF 16949Flammability, emissions, recycling, process control
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    Henkel Loctite 3D IND402™ A70 High Rebound Black Elastomeric UV Photocurable Resin is a single-component, acrylate-based photopolymer formulated for vat photopolymerization systems operating at UV wavelengths of 385–405 nm. The material cures by radical polymerization under digital light processing, liquid crystal display masked exposure, or laser scanning. The cured network is specified at 70 Shore A hardness and is engineered for elastic recovery under cyclic loading. The black pigmentation strongly attenuates actinic light, which increases the curing exposure required relative to clear resins and limits through-depth cure in thick sections. The material is used for components that must bend, compress, or absorb impact while returning to shape, including seals, gaskets, cushioning pads, protective boots, and midsole-like structures. Handling follows liquid acrylate protocols; uncured resin is a skin and eye irritant and requires nitrile gloves, ventilation, and sealed storage.

    What Are the Principal Mechanical Specifications for the Cured Elastomer?

    Post-cured tensile and hardness data for IND402™ A70 are generated from printed coupons that have been cleaned, dried, and post-cured with a 405 nm flood source. Values should be treated as representative of the manufacturer’s published technical data, not as lot-specific guarantees. The table below consolidates typical ranges reported for mechanically relevant properties.

    PropertyTypical rangeTest designation
    Cured hardness70 Shore AASTM D2240-15
    Tensile strength at break7–9 MPaASTM D638-14
    Elongation at break150–220 %ASTM D638-14
    Tear strength25–35 kN/mASTM D624-00(2020)
    Rebound resilience35–45 %ASTM D2632-15 / ISO 4662:2017
    Uncured viscosity at 25 °C15,000–25,000 mPa·sASTM D2196-20
    Density1.05–1.10 g/cm³ISO 1183-1:2019

    The tensile and tear specimens are highly sensitive to printing orientation, layer thickness, support removal damage, and post-cure dose. At 50–100 µm layer thicknesses, interlayer conversion gradients can reduce elongation and tear strength if the post-cure energy is insufficient. Industrial qualification should therefore include a design-of-experiments matrix across build orientation and post-cure irradiance rather than relying solely on datasheet values.

    Exposure Parameters, Working Curves, and Pigment-Limited Cure Depth

    In vat photopolymerization, the cure depth follows the Jacobs working curve relation; cured depth is proportional to the natural logarithm of the applied energy dose. For black resins, the penetration depth is lower than for transparent resins because carbon black or dark pigments absorb actinic radiation within the first few microns. The result is a higher critical energy dose and a thinner strongly polymerized layer for a given exposure. Production lines therefore measure resin bath irradiance with a calibrated radiometer at the build plane and adjust exposure per layer to remain above the gelation threshold while avoiding overcure that expands part features. For 50 µm layer thickness, cure-through adhesion requires enough energy to polymerize beyond the layer boundary, but excessive energy in black resin is absorbed in the upper surface and can create overcure artifacts rather than deeper cure. Equipment suppliers often use grey-level masks or anti-aliasing to manage edge accuracy. The black color makes through-cure measurement difficult by visual inspection; green-state mechanical integrity should be verified by bending or indentation coupons after a partial build. Published working-curve constants for this product are not always included in public summaries; lab-scale working curve generation on the specific light engine is recommended before scaling to production.

    Processing in vat photopolymerization equipment requires a preheated resin bath or build chamber at 25–30 °C because viscosity increases significantly at lower temperatures and recoating uniformity suffers, especially in continuous bottom-up systems with silicone or fluoropolymer release films. The product is compatible with 385 nm and 405 nm LED, DLP, and galvo-scanning laser sources; light engine power density should be measured at the vat surface. In bottom-up systems, large flat cross-sections generate higher separation forces than small sparse geometries. Production lines commonly orient large elastomeric parts at 20–40° from the build platform, add drainage holes in enclosed sections, and reduce layer thickness for curved sidewalls to limit film sticking and release failures. After printing, parts are removed from the platform, washed in isopropanol or supplier-approved solvent to remove uncured resin, blown dry, and post-cured in a 405 nm flood chamber. Residual surface tack from oxygen inhibition should be eliminated during post-cure; incomplete post-cure leaves a soft, sticky, low-tear surface that fails application testing. Black resin also shortens the depth of cure relative to clear materials because the pigment absorbs UV energy, so large solid cross-sections must be printed with longer exposures or lower layer thicknesses than clear analogs.

    Dimensional stability after post-cure must be characterized on production geometry because volumetric shrinkage during residual conversion can alter thin-walled sections and flatness. Constrained post-cure fixtures are commonly used to hold critical sealing surfaces flat while the 405 nm flood source completes polymerization. Production-level failure modes observed with black elastomeric resins include under-cured internal sections that exude liquid from cut surfaces, surface tack after solvent washing, support tear-out at thin bonding interfaces, and layer delamination if the exposure window is too narrow. These failure modes are reduced by controlling bath temperature, post-cure dose, and orientation rather than by modifying the resin formulation on the line.

    When Dynamic Compression and Repeated Flexure Define the Part Function

    Designs that undergo repeated compression, twisting, or bending benefit from the combination of 70 Shore A hardness and rebound recovery. Compression set and fatigue life should be evaluated on printed production specimens because datasheet rebound values alone do not predict long-term performance in cushioning applications. Test protocols such as ASTM D395-18 for compression set, ASTM D2632-15 for rebound resilience, and dynamic mechanical analysis per ISO 6721-1:2019 provide more useful data when the part is subject to impact or cyclic strain. The material is specified for applications where repeated elastic deformation is required: protective case liners, gaskets with irregular mating surfaces, vibration isolators, flexible hinges, sports protection, and footwear cushioning components. Because the thermoset network does not melt-flow, printed parts retain geometry during compression but are not reworkable by thermal forming. For high-cycle sine or random vibration, S-N behavior must be characterized on production-equivalent parts; published data for this specific product under fully reversed fatigue loading is limited. Users should generate application-specific data rather than extrapolating from tensile elongation alone.

    Limitations Arise from Solvent Sorption and Thermal Aging

    The cured acrylate network is resistant to short-term water contact and many nonpolar greases, but prolonged immersion in aggressive solvents can soften the polymer and induce swelling. Chemical compatibility should be tested according to ISO 175:2010 or ASTM D543-21 with the actual process fluids. Continuous-use temperature limits are not defined by a single datasheet value; the glass transition and storage modulus should be mapped by dynamic mechanical analysis before specifying the material in hot environments. UV exposure can continue to advance crosslinking or cause surface oxidation over time; black pigmentation reduces through-thickness UV penetration, which helps preserve internal elastomeric properties but does not eliminate surface embrittlement. The uncured resin is moisture-sensitive and should be stored in sealed opaque containers at 15–30 °C. Material transferred from vats should not be returned to virgin containers without filtration because partially cured gel particles and debris cause print defects. Uncured resin is classified as a skin and eye irritant and may be toxic to aquatic organisms; ventilation and nitrile gloves are mandatory on the production floor. Cured parts are not approved for food-contact or implantable medical use unless separately validated under the relevant regulatory pathway. Waste streams containing uncured resin must be handled as hazardous liquid waste; cured waste can often be disposed as industrial solid waste, subject to local regulations. Regulatory declarations, including REACH candidate-list status and RoHS compliance, are lot- and jurisdiction-dependent and should be confirmed through the manufacturer’s safety data sheet and compliance certificate.

    How Does IND402™ A70 Differ from Rigid and Low-Resilience Flexible Photopolymers?

    Relative to rigid high-toughness photopolymers such as Loctite 3D 3843 or impact-resistant structural resins, IND402™ A70 is selected for elastic strain capacity and Shore A hardness rather than flexural modulus or heat deflection temperature. Commodity flexible photopolymers in the 50–60 Shore A range may provide lower hardness and high elongation but often exhibit lower resilience and lower tear resistance under sharp edge loading. The present product is formulated to balance softness with recovery; the black pigmentation also differentiates it from translucent flexible resins in applications requiring light blocking or aesthetic consistency. Compared with thermoplastic polyurethane processed by fused filament fabrication, this UV-curable thermoset can produce fine details and smooth surfaces without tooling, but it cannot be melt-welded or recycled into filament. It also requires washing and post-curing before service, and part stiffness is set by the crosslink density rather than by hard-segment crystallization. Direct numerical comparison with other elastomeric resins requires identical print orientation, layer thickness, post-cure dose, and test coupon geometry; published data for this specific configuration is limited for some materials. Selection should therefore be made on application-specific mechanical testing, not on single-point datasheet comparisons.

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