| Код ТН ВЭД | 373857 |
Как аккредитованный завод по производству полипропиленового кополимера Lehvoss LUVOCOM 3F PP CF 9928 BK для аддитивного производства, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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In automotive low-volume production cells where ethylene glycol/water coolants are handled at temperatures not exceeding 85 °C, the LUVOCOM 3F PP CF 9928 BK polypropylene copolymer is processed by pellet-fed fused granulate fabrication to replace machined acetal and glass-filled nylon fixtures. The compound is dried at 80 °C for 4 h in a desiccant wheel dryer to reach a residual moisture content below 0.02 wt%, then fed into a single-screw extruder with an L/D ratio of 30:1 and melt temperature controlled at 255 ± 5 °C. Deposition through a hardened tool-steel nozzle with a nominal bore of 0.8 mm and a compression zone ratio of 3:1 onto a polypropylene film-laminated bed held at 95 °C yields interlayer fusion strength values measured according to ISO 527-2 that fall within the expected range for carbon-fiber-reinforced polypropylene when the chamber temperature is maintained at 60 °C and the build volume is limited to 400 mm in the z-axis. Compliance in this application is governed by REACH Regulation (EC) No 1907/2006 Annex XVII for restricted substances, by EU Directive 2000/53/EC end-of-life vehicle requirements, and by RoHS 2 Directive 2011/65/EU Annex II; no substance of very high concern above declarable thresholds is introduced by the carbon-filled PP feedstock. The formulation addition ratio is normally 100 wt% as-supplied compound; regrind from failed builds is limited to 15 wt%, and every regrind fraction is sieved to 1.0–3.0 mm particle size and re-dried at 80 °C before extrusion. Downstream production consists of fused granulate fabrication at a layer height of 0.25 mm, extrusion width of 0.9 mm, and print speed of 50 mm/min, followed by a 2 h annealing stage at 100 °C in a recirculating air oven with ramp rate not exceeding 1 K/min. Terminal finished product types include low-volume battery pack coolant line brackets, ECU mounting plates, sensor retention clips, and inspection gauges used on the assembly line.
Tool-changing sequences in collaborative assembly cells impart bending moments that are absorbed largely by the grip interface, so the gate area and screw bosses in the printed end-effector must be packed sufficiently to avoid void coalescence at fiber ends. The LUVOCOM 3F PP CF 9928 BK compound is processed at 100 wt% as-supplied pellet feedstock in a pellet-fed machine or as precision filament with diameter tolerance below 0.05 mm; regrind is limited to 10 wt% because impact strength measured under ISO 179-1/1eA declines when recycled mass fraction exceeds that threshold. Deposition uses a hardened steel nozzle of 0.6 mm bore, melt zone temperature 260 ± 5 °C, bed temperature 90 °C, chamber temperature 55 °C, layer height 0.20 mm, extrusion width 0.65 mm, and print speed 45 mm/s. Cooling fan output is set to 25 % after the first 4 layers; higher airflow creates surface skin solidification that blocks weld-line diffusion at the interface between the infill and the perimeter. Threaded inserts for repeated M4 and M5 assembly are installed with a heat-staking tool set to 220 °C; the printed boss outer diameter must be at least 7.0 mm for M5 inserts to prevent radial cracking. Compliance is governed by ISO 10218-2:2025 for robot cell integration, ISO 9409-1:2004 for mechanical interface dimensions, and the environmental directives 2011/65/EU and 1907/2006. Terminal finished product types include gripper finger blanks, vacuum cup adapter plates, cable management arms, and quick-change tool housings for payloads not exceeding 5 kg.
| Standard | Designation | Scope |
|---|---|---|
| ISO | 10218-2:2025 | Collaborative robot cell integration |
| ISO | 9409-1:2004 | Mechanical interface dimensions |
| ISO | 527-2 | Tensile modulus and strength |
| ISO | 178 | Flexural properties |
| ISO | 179-1/1eA | Notched Charpy impact |
| ISO | 75-1/-2 | Heat deflection temperature |
| EU | 2011/65/EU | RoHS restricted substances |
| EU | 1907/2006 | REACH Annex XVII |
Chemical compatibility data for carbon-filled PP copolymer at ambient temperature support the use of LUVOCOM 3F PP CF 9928 BK in pH-neutral chemical dosing skids where aluminum and acetal fail through crevice corrosion or through surface whitening after repeated hypochlorite contact. The compound is printed as instrument enclosure panels and bracket bodies only after confirming that the service fluid contains no aromatic hydrocarbons, strong oxidizing acids, or chlorine above 2 ppm; published data for this specific configuration is limited for continuous exposure to sodium hypochlorite above that threshold. Compliance statements reference ISO 527-2 for tensile properties, ISO 178 for flexural modulus, ISO 62 for water absorption, and IEC 61010-1 for enclosures that carry low-voltage instrumentation; the material itself is not a UL-listed fire-rated resin, so any enclosure requiring UL 94 V-0 must be evaluated with an additional flame-retardant strategy. The formulation addition ratio in this application is 100 wt% compound; no dilution with unfilled PP is performed because wall sections as thin as 2.0 mm would lose the carbon-fiber load-bearing network and develop sink marks. Downstream production uses a filament-fed FFF machine with a hardened steel nozzle of 0.4 mm bore, melt temperature 265 ± 5 °C, bed temperature 100 °C, chamber temperature 50 °C, layer height 0.15 mm, and print speed 40 mm/s. Post-print edge sealing with a hot-air welding nozzle at 230 °C is applied to close surface porosity before electrical panel assembly. Terminal finished product types include pH meter panel bezels, level sensor brackets, chemical feed line clips, and flow indicator housing covers for non-cleanroom industrial equipment.
Moisture absorbed by the PP copolymer matrix before printing reduces molecular weight at melt temperature and produces steam-driven microvoids that lower short-beam strength as measured under ASTM D2344; this effect is amplified when carbon fiber loading increases viscosity and reduces outgassing pathways. In small UAS component fabrication, the compound is therefore dried to residual moisture below 0.02 wt% using a desiccant dryer at 80 °C for 4 h, and the print chamber dew point is maintained below -20 °C during builds that exceed 6 h. The processing window for melt temperature is narrow: at 260 °C the carbon-filled melt still exhibits measurable yield stress at low shear, while at 270 °C the matrix begins chain scission if residence time in the hotend exceeds 15 min; barrel residence time is therefore limited by reducing barrel volume and using a 0.4 mm hardened steel nozzle with an internal flow path under 16 mm. Build parameters are set at a layer height of 0.20 mm, extrusion width of 0.50 mm, print speed of 35 mm/s, bed temperature of 80 °C, and chamber temperature of 70 °C; cooling fan output is held at 0 % for the first 3 layers and then stepped to 20 %. These settings produce raster-aligned carbon fiber orientation that raises tensile modulus along the print direction but creates anisotropy in the transverse direction; published data for this specific configuration is limited for full fatigue spectra, so only non-primary airframe parts are released. Compliance for non-critical small UAS components follows ISO/ASTM 52900:2021 for process definition and ISO/ASTM 52921 for coordinate and part orientation terminology; no harmonized airworthiness standard applies to these non-primary parts, so material certification relies on ISO 527-2, ISO 178, and ASTM D790 data from the build campaign. The formulation addition ratio remains 100 wt% compound; thin-walled sections use a solid-shell infill of 60 % and internal triangular ribbing rather than dilution with unfilled resin. Terminal finished product types include camera isolation plates, motor mount spacers, antenna brackets, and non-structural access covers for small fixed-wing and multirotor platforms.
Pneumatic ejector bodies machined from PEEK or acetal are replaced by carbon-filled PP copolymer when the pressure boundary is limited to 0.35 MPa or below and the working fluid is clean, dry compressed air filtered to 5 μm particulate size. Compliance with pneumatic system design uses ISO 4414:2010 for system layout and ISO 8573-1:2010 for compressed air quality classes; material-level certification includes ISO 527-2, ISO 178, and REACH Annex XVII restrictions for customer contact. The formulation addition ratio in venturi blocks is 100 wt% compound with 100 % infill and extra perimeters to reduce porosity; no regrind is used for parts hydrostatically tested at 0.4 MPa. Downstream production proceeds via FFF with a 0.6 mm hardened steel nozzle, melt temperature 255 ± 5 °C, bed temperature 85 °C, chamber temperature 55 °C, layer height 0.25 mm, and print speed 45 mm/s. After printing, each block is annealed at 80 °C for 2 h and then face-machined only on sealing surfaces; threads are tapped with a forming tap rather than a cutting tap to preserve fiber continuity at the thread root. The compound is not evaluated for continuous exposure to strong oxidizing agents, aromatic hydrocarbons, or synthetic ester compressor oil carryover because environmental stress cracking may occur at stressed thread roots. Terminal finished product types include venturi ejector bodies, vacuum generator manifolds, air-jet nozzle holders, and sensor mounting blocks used on slitter-rewinder, pouch-forming, and carton-erecting machines.
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In extrusion-based additive manufacturing, Lehvoss LUVOCOM 3F PP CF 9928 BK Polypropylene copolymer for Additive Manufacturing occupies a narrow position between unfilled polyolefin filaments and carbon-fibre-filled engineering thermoplastics such as PA6 and PC. The product model identifies LUVOCOM 3F as the fused-filament fabrication grade family, PP copolymer as the matrix, CF as short carbon fibre reinforcement, 9928 as the product code, and BK as black. In comparison with unfilled PP, the fibre reduces warpage, increases tensile and flexural modulus, and lowers elongation at break. In comparison with PA6/CF, the material offers lower moisture uptake and better dilute-acid and alkali resistance, but lower heat-deflection temperature and lower transverse impact toughness. This grade is selected for jigs, fixtures, lightweight robotic end-effectors, battery-handling guides, and small chemical-service parts where dimensional stability, low density, and olefin chemical resistance are controlling.
Polypropylene copolymer undergoes crystallisation-driven shrinkage during cooling. The carbon-fibre interphase constrains some of the volumetric change, but the effect is not isotropic: shrinkage along the raster is lower than shrinkage across raster lines. In open-frame machines, the material is therefore handled with a bed temperature of 80–100 °C and, for part footprints above approximately 120 mm, a peripheral brim or polyolefin adhesive build surface. The filament is brittle compared with neat PP filament. Sharp bending radii below 50 mm, especially at low ambient humidity after spool drying, can cause filament fracture between the spool and extruder. A direct-drive extruder with a PTFE throat of 2.0–2.2 mm inner diameter reduces feed-path friction for 1.75 mm filament.
Mechanical values for carbon-fibre-filled FFF specimens are orientation-dependent. The ranges below are representative for flat-printed coupons with 100 % infill and alternating 0°/90° raster, conditioned at 23 °C and 50 % RH. Properties in the Z direction are lower; tensile strength perpendicular to layers commonly falls to 40–60 % of in-plane values. These data are selection values, not design allowables. Published data for this specific configuration at high strain rate, fatigue, and long-term creep above 80 °C is limited.
| Property | Method | Representative range |
|---|---|---|
| Density | ISO 1183-1 | 1.00–1.04 g/cm³ |
| Tensile strength | ISO 527-2/1A, 23 °C | 25–35 MPa |
| Tensile modulus | ISO 527-2/1A, 23 °C | 2.2–2.8 GPa |
| Elongation at break | ISO 527-2/1A | 2–5 % |
| Flexural strength | ISO 178 | 40–55 MPa |
| Flexural modulus | ISO 178 | 2.8–3.6 GPa |
| Notched Charpy impact, 23 °C | ISO 179-1/1eA | 4–8 kJ/m² |
| Heat deflection temperature, 1.80 MPa | ISO 75-2/A | 95–120 °C |
| Vicat softening temperature, A/50 | ISO 306/A50 | 125–140 °C |
| Melt volume-flow rate, 230 °C/2.16 kg | ISO 1133-1 | 8–20 cm³/10 min |
Differences between X and Y raster directions typically remain below 20 % when a 0°/90° alternating infill is used. If a single 0° raster is used, the transverse modulus can be lower by 30–50 % and notched Charpy values become invalid because delamination precedes crack propagation. Regulatory status is lot-dependent. During supplier qualification, the certificate of conformance should be checked against RoHS Directive 2011/65/EU and REACH Regulation EC 1907/2006. These are product-class requirements; they do not replace part-specific food-contact or medical approvals, which are not implied for this grade.
Pre-extrusion drying is specified at 80 °C for 4–6 h in a desiccant dryer with dew point below -30 °C. Moisture uptake in the PP matrix is low, but the carbon-fibre sizing can retain adsorbed water that disrupts strand surface quality and creates microvoids at raster intersections. The extrusion temperature is set between 230 °C and 250 °C at the nozzle. Below 230 °C, interlayer diffusion is incomplete and tensile delamination at raster boundaries occurs at stresses 15–30 % below the in-plane value. Above 250 °C, oxidative chain scission is accelerated by shear heating in the fibre-filled melt; the result is surface hazing, a burnt odour, and reduced molecular weight as measured by a fall in melt viscosity.
The nozzle bore is 0.40–0.60 mm. Brass is unsuitable; carbon fibre abrades the bore, and a diameter increase of 0.05 mm can occur within a few hundred grams of throughput on open-frame production machines, shifting line width and causing stringing. Hardened steel, tungsten carbide, or ruby-orifice nozzles are required. Because pressure drop in a cylindrical nozzle scales with the fourth power of the radius, replacing a 0.40 mm nozzle with a 0.60 mm nozzle at constant flow reduces the required extrusion pressure by approximately 80 %. The lower shear rate also reduces melt-temperature rise, which is beneficial when the barrel is already near the upper limit of the processing window. The melt exhibits pseudoplastic behaviour; apparent shear rate at 30–60 mm/s through a 0.40 mm nozzle is in the range 100–300 s-1, where viscosity decreases with increasing shear.
Build surface preparation is the main bottleneck. Polypropylene does not wet glass, PEI, or bare steel. Production lines use PP tape, solvent-welded PP sheet, or a polyolefin adhesive applied at 20–40 µm wet thickness. For parts longer than 120 mm on a 350 × 350 mm bed, a brim of 10–15 mm is applied; otherwise corner lift can exceed 0.5 mm. Cooling fans are set to 0–30 % after the first six layers. An active enclosure at 45 °C reduces warpage but extends the time spent in the crystallisation temperature range; parts thicker than 6 mm can retain heat and show differential shrinkage between the shell and core.
Layer height is maintained between 0.15 mm and 0.25 mm. At 0.30 mm, the lower contact pressure across the raster width decreases transverse tensile strength by 15–25 %. Print speed is restricted to 30–60 mm/s; above 60 mm/s, incomplete melting at the nozzle wall creates fibre-rich domains and local die swell. Fibre orientation follows the raster direction; a ±45° alternating infill improves in-plane pseudo-isotropy but reduces on-axis tensile modulus. Infill below 35 % produces a sharp decline in flexural stiffness and increases buckling in unsupported walls.
Compounding of this product class is performed on a co-rotating twin-screw extruder with length-to-diameter ratio of 40:1 or higher. Fibre breakage depends on screw speed and backpressure. If fibre length shifts toward the subcritical length, tensile modulus can fall toward the lower end of the published range even when ash content remains constant. Melt flow rate should be tracked per ISO 1133-1 at 230 °C/2.16 kg; a variation of more than 15 % from the certificate of analysis warrants adjustment of the extrusion multiplier before production.
Compared with PA6/CF, PP CF 9928 BK absorbs less water. PA6/CF can reach 2.0–3.0 % moisture at 23 °C and 50 % RH, while PP CF remains below 0.1 %. The practical consequence is lower dimensional change in humid assembly areas and no requirement for the prolonged drying needed by PA6/CF. The penalty is heat resistance: PA6/CF commonly exceeds 180 °C in HDT/A at 1.80 MPa, whereas PP CF remains below 120 °C. PP CF is therefore not used for autoclave tooling or engine-adjacent components.
Against ABS/CF, PP CF has better resistance to dilute acids, alkalis, and many non-polar hydrocarbon fluids, but lower stiffness and lower dimensional stability at warm temperatures. ABS/CF bonds more easily to standard styrene-based build surfaces, while PP CF requires a dedicated polyolefin build surface. Against unfilled PP, the carbon-fibre grade reduces in-plane shrinkage from approximately 1.2–2.0 % to below 0.8 % and increases tensile modulus by 1.5–2.5 ×. Elongation at break drops from 20–60 % in unfilled PP to 2–5 % in the reinforced grade. Notched Charpy impact is lower, so the material is not suitable for snap-fits or components subjected to high-strain impact.
| Criterion | PP CF 9928 BK | PA6/CF | ABS/CF | Unfilled PP |
|---|---|---|---|---|
| Moisture uptake at 23 °C, 50 % RH | below 0.1 % | 2.0–3.0 % | 0.3–0.5 % | below 0.1 % |
| HDT/A at 1.80 MPa | 95–120 °C | >180 °C | 95–110 °C | 50–60 °C |
| Dimensional stability on open-frame FFF | moderate high | moderate | high | low-to-moderate |
| Build surface requirement | PP tape or PP sheet | PA-targeted adhesive or PA film | styrene-based surface | PP tape or PP sheet |
| Chemical exposure profile | dilute acids, alkalis, non-polar hydrocarbons | oils and fuels; susceptible to strong acids | susceptible to ketones, esters, some hydrocarbons | similar olefin resistance, lower stiffness |
| Failure mode | brittle delamination and fibre pull-out | tougher with moisture, but hydrolytic aging | crazing and solvent stress cracking | ductile yielding, high warpage |
Chemical immersion tests should follow ISO 175, and environmental stress-cracking evaluation should follow ISO 22088-2 where the service fluid is known. Strong oxidising acids, aromatic solvents, and chlorinated hydrocarbons are outside the recommended service envelope for the PP matrix. At 80 °C and above in hydrocarbon contact, mechanical properties decline because the amorphous phase is plasticized. Published data for this specific formulation under combined mechanical load and aggressive chemical exposure is limited.
Machining of printed parts is carried out with carbide end mills at spindle speeds below 8,000 rpm. High-speed steel tooling wears rapidly and produces fibre pull-out. Drilling of walls thinner than 3 mm requires a 2-flute carbide drill and a sacrificial backing plate to prevent exit-side delamination. If tapping is required, a coarse-thread profile with 60 % thread engagement reduces notch stress in the carbon-fibre-filled matrix.