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Mitsubishi FGF Recycled ASA-X 20% Glassfibe ASA, 30% Glass Fiber Filled 3D Printing Polymer

    • Название продукта: Mitsubishi FGF Recycled ASA-X 20% Glassfibe ASA, 30% Glass Fiber Filled 3D Printing Polymer
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    Код ТН ВЭД 601903

    Как аккредитованный завод Mitsubishi FGF Recycled ASA-X 20% Glassfiber ASA, 30% Glassfiber Filled 3D Printing Polymer, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение Mitsubishi FGF переработанного ASA-X 20% стекловолокна ASA, 30% стекловолокна наполненного 3D-печати полимера

    In exterior automotive trim, the 20 wt% glass-fiber-reinforced recycled ASA-X compound is introduced as a direct injection-molding feed for unpainted black and dark-gray components whose long-term weather resistance is specified against SAE J2527:2017 xenon exposure cycles rather than short-term color checks. The addition ratio at the press is 100 wt% direct compound for tight-tolerance Class A textured surfaces; the only permitted secondary additions are 2–4 wt% of an ASA-carrier color masterbatch for dark-gray trim and up to 20 wt% of clean gate and runner regrind in outer belt and lower cladding parts. Higher regrind levels are avoided because glass-fiber length attrition in recompounding lowers notched Charpy impact below 8 kJ/m² when tested under ISO 179-1:2010. Production processing requires pre-drying at 80 °C until residual moisture falls below 0.02 wt%, typically 4 h, followed by screw plastication in a 25:1 L/D single-screw injection unit with bimetallic barrel and hardened flights. Melt temperature is maintained between 240 °C and 260 °C, mold surface at 60–80 °C, and valve-gate hot-runner temperature at 245 °C; profiled holding pressure and medium-to-high injection velocity are required to avoid knit-line brightness around mirror pivot pins and grill mounting bosses. Terminal product types include mirror shell covers, cowl vent grilles, wiper arm caps, D-pillar covers, and antenna bezels. The compliance path references EU ELV 2000/53/EC, EU RoHS 2011/65/EU Annex II, REACH 1907/2006, ISO 11469:2016, ISO 1043-1, ISO 527-2:2012, ISO 178:2019, ISO 75-2:2013 method B, and ISO 1133-1:2022. When warehouse relative humidity exceeds 60%, pre-drying is mandatory before any molding campaign to prevent surface splay and viscosity swings caused by moisture hydrolysis of the ASA matrix.

    What Process Window Sustains a 30 wt% Glass-Fiber Filled ASA in Pellet-Fed Large-Format Fabrication?

    The 30 wt% glass-fiber-filled ASA-X polymer is supplied as pellet feed for open-chamber fused granulate fabrication and is not a dry blend for screw-compounded virgin material. Its formulation addition ratio is fixed at 30 wt% glass-fiber content in the pellet; further chopped-glass addition at the machine hopper is not recommended because uncontrolled fiber overload on a grooved feed section can produce melt-pressure instability of more than ±2 MPa at constant screw speed. In one production-scale FGF cell with a 15 kW melt pump, 4 mm nozzle, and 20:1–30:1 L/D three-zone extruder, acceptable interlayer fusion was obtained only after pellet drying at 80 °C for 4 h to below 0.03 wt% moisture; melt temperature was held between 240 °C and 265 °C, bed or chamber temperature between 90 °C and 110 °C for parts exceeding 600 mm, layer height 1.5–2.0 mm, and extrusion width 8 mm. Compliance for tooling applications is documented under ISO/ASTM 52900:2021 for additive manufacturing terminology, ASTM D638-14 for tensile, ISO 178:2019 for flexural, ISO 75-2:2013 method B at 1.8 MPa, ISO 4892-2:2013 method A for UV, REACH 1907/2006, and RoHS 2011/65/EU. Terminal products are thermoforming plug assists, vacuum form trays, assembly nests, composite layup molds, and robotic end-of-arm gripper frames. A continuous tool-surface temperature of 105 °C is the observed threshold before creep distortion exceeds 0.2 mm over 300 mm under 0.5 MPa bearing pressure; published data for this specific recycled grade under cyclic mechanical load is limited, so mold thermal mapping is required before tooling release.

    Process boundary20 wt% GF ASA injection30 wt% GF ASA FGF
    Pre-drying target80 °C for 4 h to <0.02 wt%80 °C for 4 h to <0.03 wt%
    Melt / barrel temperature240–260 °C240–270 °C
    Mold / bed / chamber60–80 °C90–110 °C
    Screw L/D20:1–25:120:1–30:1
    Regrind limit20–25 wt% depending on impact retention30 wt% only after shredding and sieving

    Because ultraviolet radiation, rain ingress, and thermal cycling govern replacement cycles in outdoor electrical enclosures, the 20 wt% glass-fiber-reinforced recycled ASA-X grade is used as a full mass-flow polymer for opaque equipment shells, connection boxes, and solar inverter shrouds instead of painted steel or standard ABS. The addition ratio for UL-recognized enclosures is 100 wt% compound; post-industrial regrind is capped at 20 wt% to maintain the UL 94 HB flame class and to retain notched impact above 8 kJ/m² under ISO 179-1:2010. The production process uses 200–500 t injection clamp systems with screw L/D between 20:1 and 25:1, feed-throat cooling at 40–60 °C, melt temperature 245–260 °C, and cavity steel at 70–90 °C to control post-mold warpage in wall sections above 3.5 mm. Conformance is evaluated under IEC 62208:2011 for empty low-voltage enclosures, EN 60529:1991+A1:2000 for IP65 gasketed designs, NEMA 250 Type 4 only where gasket and sealing geometry are machined to print, UL 94 HB for flame class, ISO 4892-2:2013 method A for UV stability, and RoHS 2011/65/EU. Terminal product types include pole-mounted telecom splice boxes, EV charging station side panels, outdoor camera housings, ventilation louver frames, and solar combiner-box covers. Chemical resistance should be confirmed under ISO 175:2010; continuous immersion in strong ketones or aromatic hydrocarbons is an operational boundary and not recommended for unstabilized ASA formulations.

    Agricultural and construction vehicle trim where 20% GF ASA survives UV, fuel splash and stone impact

    A 20 wt% short-glass-reinforced recycled ASA-X compound enters agricultural and construction vehicle applications through high-pressure injection molding with an addition ratio of 100 wt% for structural exterior trim; in non-safety-critical brackets, up to 25 wt% in-house regrind is accepted if impact retention after 5 regrind cycles remains above 7 kJ/m² in ISO 179-1/1eA at −20 °C. Melt temperature is held between 250 °C and 265 °C, mold surface at 80–95 °C, and rib-root radii between 1.0 mm and 2.0 mm to reduce notch stresses behind visible surfaces. The screw and barrel must be wear-protected and the check ring hardened because 20 wt% glass fiber accelerates clearance growth by approximately 0.03–0.08 mm per 1,000 t of processed compound on a 40:1 L/D twin-screw compounding line; regular plastication recovery time checks are used as an indirect wear indicator. Compliance standards include SAE J2527:2017 for automotive exterior xenon weathering equivalence, ISO 4892-2:2013 method B for wet/dry cycles, ISO 175:2010 for fuel and hydraulic fluid resistance, ISO 527-2:2012, ISO 178:2019, and ISO 899-2 for creep behavior at under-hood ambient temperatures. Finished product types include tractor hood side shields, combine cab defroster vent grilles, sprayer fender extensions, construction equipment light-bar mounts, and telematics antenna covers. The grade is not a structural substitute for long-glass polyamide in engine-compartment brackets; sustained oil-sump temperatures above 110 °C are a design boundary and should trigger creep verification rather than short-term tensile acceptance. Uncompatibilized blends with polyamide are to be avoided because differential shrinkage and fiber-size migration can produce interlayer delamination and cracking at bayonet-mount bosses.

    For short-run structural building components, the 30 wt% glass-fiber-filled FGF ASA-X grade is deposited directly from pellets in robotic large-format cells without tooling; the fixed fiber content is 30 wt% and dilution with unfilled ASA is not recommended when printed wall thickness is below 8 mm, because reducing glass content lowers flexural modulus below the 5,000 MPa threshold needed for bracketry under wind load. If reclaimed printed scrap is shredded and sieved to 2–4 mm, a blend of 70 wt% virgin pellet and 30 wt% regrind may be used only when the melt flow rate under ISO 1133-1:2022 at 260 °C/5 kg remains within ±15% of the virgin lot value. The extrusion process uses a three-zone heated screw at 240–260 °C, a heated bed or enclosure at 90–110 °C for parts over 600 mm, deposition speed 50–120 mm/s, layer height 1.2–2.0 mm, and perimeter count not less than 3. For comparable short-glass ASA, a six-axis robot deposition cell operating at 10 kg/h has demonstrated corner warpage below 0.4 mm/m after annealing; this acceptance limit is practical for first-article verification but is not a guaranteed property without lot-specific data. Compliance for building-integrated components references ISO 527-2:2012, ASTM D638-14, ISO 178:2019, ISO 75-2:2013 method B, ISO 4892-2:2013 method A, and local building-code smoke/toxicity verification because this grade is not inherently flame-retardant. Terminal product types include façade louver brackets, rail-mounted sensor supports, air-handling louver frames, transit station sign frames, and custom HVAC diffuser housings.

    When paint-shop fixtures require 30% glass fiber ASA instead of machined billet at 110°C bake cycles

    When a production cell replaces machined aluminum fixtures in pre-production paint-shop validation, the 30 wt% glass-filled FGF ASA-X compound is used as a full pellet feed for printed carriers, masking jigs, and oven-safe dunnage. The formulation addition ratio is 100 wt% pellet; published data for blending this specific recycled grade with virgin unfilled ASA at high temperature is limited, so diluent addition is not advised before a two-level thermomechanical validation is performed at the target paint-bake cycle. Process requirements include pre-drying at 80 °C for 4 h to below 0.03 wt% moisture, extrusion melt temperature 250–270 °C, and a heated chamber at 95–110 °C; printed wall thickness above 6 mm should use 35–50% infill density and 3 consecutive perimeter contours to avoid buckling during forced-convection oven cycles at 110 °C. Dimensional stability is checked with ISO 75-2:2013 method B at 1.8 MPa, ASTM D648-18, and flatness measurements on a calibrated granite plate before and after 20 h soak at 110 °C. Compliance standards are ISO 527-2:2012, ISO 178:2019, REACH 1907/2006, and RoHS 2011/65/EU. Finished product types include paint-shop carriers, powder-coat hook racks, fixture baseplates, robotic end-of-arm frames, and engine-bay masking jigs. The material boundary under solvent exposure should be verified by ISO 175:2010; solvent-borne paint detackifiers with high aromatic content may cause surface micro-cracking and are incompatible with unstabilized ASA over repeated cycles.

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    The material designated Mitsubishi FGF Recycled ASA-X 20% Glassfibe ASA, 30% Glass Fiber Filled 3D Printing Polymer is a granulate-format, glass fiber-reinforced acrylonitrile-styrene-acrylate compound intended for fused granulate fabrication. The designation contains two fiber-loading descriptors: 20% Glassfibe ASA and 30% Glass Fiber Filled. Because “Glassfibe” is treated as a surface-level transcription variant for glass fiber, the controlling lot-specific value must be confirmed against the manufacturer’s technical data sheet and batch certificate before processing parameters are locked. The product is not filament; it is a pelletized extrusion-grade feedstock requiring a screw-driven FGF system rather than a filament-fed fused filament fabrication toolhead. Material identification under ISO 1043-1 and ISO 11469 should reflect the confirmed glass fiber loading, for example ASA-GF20 or ASA-GF30, but the exact grade marking depends on the lot.

    Moisture control is a primary processing boundary for recycled ASA-X glass fiber granulate. Pre-drying in a desiccant-air dryer at 80 °C for 4 h to a moisture target below 0.02% by weight is recommended, with verification by ISO 15512:2019. Wet granulate produces surface splay, irregular melt pressure, and localized viscosity shifts in the metering zone. A hopper dryer with insulated conveying hoses and a dew point of -40 °C or lower is preferable for continuous large-format runs. The feed zone should remain closed during humid plant conditions above 60% relative humidity, and granulate exposed for more than 8 h should be re-dried before reintroduction.

    What Distinguishes Recycled ASA-X Glass Fiber Granulate from Standard ABS or Unfilled ASA?

    ASA differs from ABS in that the polybutadiene impact modifier is replaced with an acrylic ester elastomer. This substitution contributes to improved outdoor color retention and surface chalking resistance when assessed under ISO 4892-2 weathering protocols, although lot-specific recycled feedstocks may exhibit wider variation than virgin ASA. The presence of 20–30% glass fiber raises tensile modulus, flexural modulus, and heat deflection temperature while reducing elongation at break and notched impact strength. Compared with unfilled ASA, the fiber-reinforced compound also produces higher melt viscosity and greater abrasive wear on extruder screws, barrels, and nozzles. Compared with a filament-grade ABS or ASA, this FGF product supports higher deposition rates because pellet-fed screw extrusion does not require intermediate filament winding and diameter roundness control. The recycled ASA-X base can shift melt flow rate, color, and thermal stability between lots; therefore ISO 1133-1:2022 melt flow testing and a thermal stability check should be performed for each incoming lot.

    Mechanical Property Benchmarks and Batch-Specific Verification

    The following values are representative ranges for glass fiber-reinforced ASA polymer families and are not lot-specific guarantees for this recycled FGF designation. Published lot-independent data for this specific recycled ASA-X configuration is limited; the manufacturer’s batch certificate remains the controlling source for mechanical property acceptance.

    Property Test standard Unreinforced ASA ASA-GF20 ASA-GF30
    Density ISO 1183-1:2019 1.06–1.08 g/cm³ 1.20–1.24 g/cm³ 1.27–1.31 g/cm³
    Tensile stress at break ISO 527-2:2012 40–50 MPa 70–90 MPa 95–115 MPa
    Tensile modulus ISO 527-2:2012 2.2–2.5 GPa 5.5–6.5 GPa 7.5–9.0 GPa
    Flexural modulus ISO 178:2019 2.0–2.4 GPa 5.0–6.0 GPa 6.8–8.0 GPa
    Heat deflection temperature at 1.82 MPa ISO 75-2:2013 88–98 °C 105–115 °C 115–125 °C
    Notched Izod impact at 23 °C ISO 180/A 10–20 kJ/m² 6–10 kJ/m² 5–8 kJ/m²

    Anisotropic shrinkage is the dominant dimensional challenge in FGF processing of glass fiber-reinforced ASA. The fiber orientation induced by the print path reduces in-plane shrinkage but creates differing longitudinal and transverse contraction behavior. Operators should calibrate CAD scaling using a printed metrology gauge block and coordinate measuring machine verification in accordance with ISO 10360-2. Large unsupported surfaces should be sectioned into shorter deposition lengths to reduce warpage at free edges.

    When Large-Format FGF Requires Controlled Chamber Temperature and Hardened Nozzle Hardware

    Processing a 20–30% glass fiber reinforced recycled ASA-X compound through a pellet extruder imposes hardware constraints not present with unfilled filament. The screw should have a compression ratio of 2.5:1–3.0:1 and an L/D ratio between 24:1 and 30:1. Barrel and screw surfaces should be nitride-treated or bimetallic to resist glass fiber abrasion. The nozzle orifice should be 0.8 mm or larger to reduce clogging, and the nozzle should be hardened tool steel or tungsten carbide rather than brass or unhardened stainless steel. Barrel temperature zones may be set from 230–240 °C in the feed section, 240–260 °C in compression, and 250–270 °C in metering, with melt temperature kept below 280 °C to limit acrylic ester degradation. The bed or fixture temperature for reinforced ASA should be held at 90–110 °C, and a chamber temperature of 60–80 °C is advisable for parts exceeding 500 mm in the longest axis to reduce quench-induced delamination. Melt residence time should remain below 15 min at maximum barrel temperature to avoid brown streaking and odor generation.

    The intended application space for this FGF material includes outdoor tooling, inspection fixtures, robotic end-of-arm tooling, jigs, and low-run thermoforming molds exposed to ultraviolet light and moderate heat. The acrylic ester component of the ASA matrix provides better UV resistance than ABS tooling materials under the same outdoor exposure after ISO 4892-2 evaluation, but unpainted surfaces may still exhibit gloss loss over extended service. Because the compound is fiber-reinforced, applications requiring high elongation, high-speed impact, or thin living hinges should be excluded unless prototype testing demonstrates adequate ductility. Wall sections below 1.5 mm are difficult to fill consistently at 30% glass fiber loading.

    Compliance Is Not Assumed Without Lot-Level Certification

    Recycled feedstock complicates regulatory documentation because batch composition can vary across incoming post-industrial and post-consumer streams. A supplier lot-specific compliance file should be requested before using this material in regulated applications. The following matrix summarizes the documentation normally required from the compounder or distributor.

    Document or standard Scope Required verification
    REACH SVHC candidate list Substances above 0.1 wt% Lot-specific supplier declaration
    RoHS Directive 2011/65/EU Annex II Pb, Hg, Cd, Cr(VI), PBB, PBDE RoHS compliance certificate
    ISO 1043-1 / ISO 11469 Material identity ASA-GF20 or ASA-GF30 marking code confirmation
    ISO 9001:2015 Quality management Batch certificate and change notification
    UL 94 Flame class Not assigned unless module test confirms a class

    Service incompatibilities include ketone, ester, and aromatic solvent exposure, which can attack the ASA matrix and promote environmental stress cracking. Mixing with ABS regrind is not recommended because it may reduce outdoor color retention and produce irregular rheology. For large outdoor tools subjected to repeated thermal cycles, dimensional inspection should be performed after a 24 h soak at the maximum expected service temperature to establish a stable metrology baseline.

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