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Mitsubishi FGF Recycled CARBON-P PET-G, Carbon Filled 3D Printing Polymer

    • Название продукта: Mitsubishi FGF Recycled CARBON-P PET-G, Carbon Filled 3D Printing Polymer
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
    • Запрос цены: admin@ascent-chem.com
    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Спецификации
    Код ТН ВЭД 382444

    Как аккредитованный завод Mitsubishi FGF Recycled CARBON-P PET-G, Carbon Filled 3D Printing Polymer, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение Mitsubishi FGF Recycled CARBON-P PET-G, углеродный наполненный 3D-печатный полимер

    Mitsubishi FGF Recycled CARBON-P PET-G pellets are introduced directly into the heated hopper of a large-format fused granular fabrication cell, where a single-screw extruder with an L/D ratio of 24:1 or greater and a hardened steel barrel maintains the melt temperature between 240 °C and 260 °C for initial qualification. The carbon fibre filler raises melt viscosity relative to unfilled PET-G; therefore, nozzle diameters below 0.6 mm are avoided, and extruder drive current is monitored as an indirect measure of nozzle pressure. Pellet feed is dried in a desiccant dryer to a residual moisture level below 0.02% before extrusion, usually at 65 °C for 4 h, with drying time extended when ambient relative humidity exceeds 60%. Build chamber temperature is held at 45 °C to 60 °C on gantry systems equipped with active heating; without this, flat tool faces wider than 500 mm exhibit corner lift and interlayer separation. Because published data for this specific recycled carbon-filled grade is limited, initial qualification on each FGF cell includes printed tensile coupons tested according to ISO 527-2 and heat deflection temperature specimens tested according to ISO 75-2, with results compared against the certificate of analysis before production acceptance.

    For low-temperature thermoforming tool faces, the printed shell is machined on a 3-axis CNC router to bring the working surface to within ±0.2 mm of the CAD reference, then sealed with a two-part epoxy surface coat mixed at a 100:55 resin-to-hardener ratio by mass. The epoxy is applied in two coats to close the open bead surface and prevent vacuum leakage through the printed wall. Because the heat deflection temperature of carbon-filled PET-G restricts continuous tool surface exposure to 65 °C or below, the tool is limited to thin-gauge vacuum forming of polystyrene, ABS, and low-temperature PET-G sheet with chilled water circulation through printed internal channels. A water-soluble release agent diluted at 2 wt% in deionised water is sprayed on the sealed tool face before each forming cycle to prevent sheet adhesion. The terminal product is a short-run vacuum forming tool; published data for this specific configuration is limited, so tool face condition is inspected after every forming batch and the epoxy seal coat is touched up when visible bead texture appears. Regulatory compliance for this industrial tooling application falls under REACH 1907/2006 and RoHS 2011/65/EU; no food-contact claim is made because the recycled carbon-filled feedstock is not validated under FDA 21 CFR 177.

    The process window for reliable layer fusion is narrower for carbon-filled recycled PET-G than for unfilled PET-G. A reduction of 5 °C in melt temperature below the lower end of the established barrel profile reduces interlayer adhesion to the point where a sectioned test bead can be split between layers with hand pressure. An increase of 10 °C above the upper end produces visible surface discolouration and a sharp acrid odour associated with partial thermal degradation of the copolyester matrix. Consequently, barrel zone temperatures are controlled within ±5 °C, and extrusion speed is reduced in the first and last 100 mm of each tool perimeter to prevent start/stop bead width variation. Build chamber temperature is verified with at least three thermocouples placed at the corners and centre of the printed part, and any reading difference greater than 5 °C is corrected before the deposition of the next layer. These controls reduce the batch-to-batch variance observed when recycled carbon fibre content shifts by more than 2 wt%, which alters melt viscosity and changes the acceptable extrusion speed range for the same nozzle diameter.

    Incoming feedstock quality check for carbon-filled recycled PET-G pellets used in FGF tooling
    PropertyTest methodControl basis
    Melt flow rateISO 1133-1:2022 at 250 °C / 2.16 kgBatch certificate; a drift greater than 15% from the qualified reference triggers re-qualification of extrusion parameters
    Tensile modulusISO 527-2Printed coupon, longitudinal and transverse to bead direction
    Heat deflection temperatureISO 75-2 / ASTM D648Recorded at 0.45 MPa and 1.8 MPa
    DensityISO 1183-1:2019Used to verify batch-to-batch filler content consistency
    Moisture contentISO 15512:2019Not to exceed 0.02% before extrusion

    Can Carbon-Filled Recycled PET-G Replace Machined Nylon in Robotic End-of-Arm Tooling?

    Robotic end-of-arm tooling and assembly fixtures are produced by printing carbon-filled recycled PET-G sections, then assembling them with mechanical fasteners and a methyl methacrylate structural adhesive mixed at a 1:1 ratio by volume. The adhesive is applied in a continuous bead to internal ribs, and the sections are clamped for 30 min at 20 °C to 25 °C before any load is applied. Because the carbon-filled material is stiffer than unfilled PET-G but less impact resistant than unfilled copolyester, gripper fingers incorporate corner radii of at least 5 mm and load-bearing wall thickness not less than 6 mm. Locating surfaces are machined flat to ±0.1 mm after printing, and reamed holes are produced to an H7 tolerance for hardened steel dowel insertion. Structural acceptance of the gripper bodies follows ISO 527-2 tensile testing on printed coupons cut from the same production batch, while the integration risk assessment follows ISO 10218-1:2011 and the Machinery Directive 2006/42/EC.

    Production-scale printing for this application is performed on a Cartesian gantry with a build envelope of at least 2 m in the longest axis, using a 1.0 mm hardened steel nozzle and a 0.6 mm layer height. Straight-run deposition speed is set between 40 mm/s and 60 mm/s for initial trials, reduced to 25 mm/s on radii below 20 mm to maintain acceptable carbon fibre orientation and bead width. The terminal product is a gripper or fixture body used for locating roof panels, bumper fascias, and bracketry during adhesive bonding and resistance spot welding. The printed body does not create the metallic debris associated with machined aluminium tooling, but it is not suitable for direct contact with hot steel surfaces above 70 °C. Field observation on an automotive assembly line showed that fixture finger wear was concentrated at the steel panel contact edge; a replaceable polyurethane wear strip of Shore A 90 was added to extend the printed body life. Published data for this specific configuration is limited, so wear life must be verified on the target assembly line rather than extrapolated from laboratory abrasion tests.

    Foundry Master Patterns for Air-Set Sand Moulding Require a Sealed Print Surface

    In foundry patternmaking, carbon-filled recycled PET-G is used for master patterns and split core boxes for air-set sand systems that do not require baking above 80 °C. The printed pattern shell is backfilled with a two-component polyurethane casting resin mixed at a 100:35 resin-to-hardener ratio by weight to a minimum thickness of 25 mm behind all working surfaces. After a 24 h cure at 23 °C, the pattern is machined to the required casting dimensions with a patternmaker’s shrinkage allowance applied in accordance with ISO 8062 or the foundry’s internal dimensional control plan. The carbon fibre filler lowers the coefficient of linear thermal expansion relative to unfilled PET-G and improves edge resistance to sand abrasion, but the working surface is still sealed with a two-pack polyurethane foundry varnish mixed at a 3:1 ratio by volume, then sanded to P320 grit before release wax is applied.

    The split line is printed as a separate machined face, and brass locating pins are inserted into reamed H8 holes to maintain registration during repeated mould closing operations. Air-set sand compaction loads can produce localised flexure in unsupported pattern sections; therefore, rib spacing is designed to limit the unsupported span to 300 mm for a 20 mm thick working wall. The terminal product is a short-run foundry pattern; published data for this specific configuration is limited, so the pattern service life must be established in the target foundry, and the varnish layer is refurbished when release wax breakdown or sand abrasion exposes the printed substrate. The recycled carbon-filled grade is not appropriate for high-pressure moulding lines where clamping forces exceed 20 t on the pattern plate, and it is not recommended for flaskless moulding machines that apply simultaneous squeeze and jolt compaction because the printed pattern wall may crack at the bead fusion lines. Environmental compliance for the foundry pattern is evaluated under REACH 1907/2006 for the varnish and release wax system rather than for the printed polymer itself.

    On aircraft maintenance production lines, carbon-filled recycled PET-G is printed into drill jigs and trim templates for composite panel rework under ambient-temperature curing conditions. The pellet feedstock is kept in a dry storage cabinet at 40 °C and 10% relative humidity, then fed directly into a mobile FGF printer positioned near the aircraft, avoiding the logistics and curing time associated with wet-layup epoxy tooling boards. These drill jigs are not used in autoclaves or ovens, because the material loses dimensional stability above 65 °C under sustained clamp load. Drill bushing bores are machined to H7 after printing, and sacrificial steel drill bushings with an outer diameter of 12.7 mm are inserted to prevent the carbon-filled polymer from contacting the drill bit directly. The carbon fibre filler reduces burr formation during post-print machining, but it accelerates cutter wear; therefore, solid carbide tooling and a feed rate reduction of 30% are used during finish passes. Compliance for aerospace tooling requires documentation under AS9100 or an equivalent production organisation approval, although the printed tool is not classified as a flying part and no flammability test to 14 CFR 25.853 is required for ground support tooling unless the fixture is used inside a fuel tank cell.

    For a typical composite trim fixture, the printed shell is assembled from four segments joined with an epoxy adhesive mixed at a 100:45 resin-to-hardener ratio by mass and mechanically fastened with M8 zinc-plated bolts. The lower vacuum plenum is sealed with a two-part polyurethane coating applied at 200 g/m² dry film thickness. Vacuum is applied at −0.7 bar gauge to hold the composite panel during routing, and the fixture is inspected against the master panel after every 50 operations using a coordinate measuring machine verified to ISO 10360-2. Although the carbon-filled material has a lower coefficient of linear thermal expansion than unfilled PET-G, it is still higher than aluminium; the fixture is therefore maintained in an assembly hall at 22 °C ± 2 °C and is not exposed to direct sunlight before use. This temperature constraint is a documented operational boundary and must be included in the work instruction for the maintenance cell.

    When Carbon-Filled PET-G Is Used for Concrete Formwork Panels in Architectural Precast

    Concrete formwork panels printed from carbon-filled recycled PET-G are produced as negative mould surfaces for architectural precast elements with limited cast cycles and relatively low compaction energy. The printed face is coated with a solvent-free polyurethane formwork sealer applied in two coats at a total wet film thickness of 250 µm, followed by a vegetable ester oil release agent diluted 1:8 in water. Because the formwork surface is subjected to abrasive aggregate and alkaline pore water, the sealer must be reapplied after each pour, and any damage from formwork vibrators must be repaired before the next cycle. The carbon fibre filler improves scratch resistance relative to unfilled PET-G, but it does not provide the abrasion resistance of steel formwork; the printed panels are therefore limited to architectural finishes where minor surface texture variation is acceptable or where a post-cast acid etch hides the formwork grain.

    The panels are designed with a printed wall thickness of 18 mm and backed by a rectangular steel tube frame on 300 mm centres to limit deflection to less than 1/400 of the span under fresh concrete pressure. In practice, fresh concrete is poured in lifts not exceeding 600 mm per hour to keep lateral pressure within the capacity of the printed face and its backing frame. The terminal product is a reusable formwork panel for a limited series of casts; published data for this specific configuration is limited, so the number of casts per panel must be validated on the first production pour, and the panel is withdrawn from service when the sealer no longer prevents surface water absorption. Load assumptions for the supporting frame follow EN 12812:2008 for temporary works, with the printed face treated as a sacrificial wearing surface rather than a structural member. Environmental compliance is evaluated under REACH 1907/2006 for the sealer and release agent; the recycled content claim is valid only when the batch certificate confirms the post-industrial or post-consumer recycled fraction.

    Composite Layup Tooling and Vacuum Bag Support Shells for Room-Temperature Cure

    Carbon-filled recycled PET-G can be used for composite layup tooling only when the cure cycle is conducted at ambient temperature, typically 18 °C to 28 °C, and the resin exotherm is measured to remain below 60 °C on the tool face. The tool surface is printed as a near-net shell, then sealed with a low-viscosity epoxy tooling gel coat mixed at a 100:30 resin-to-hardener ratio by weight and wet sanded to P600 grit. A semi-permanent release polymer is applied in three layers at 15 min intervals. The printed support shell is backfilled with a syntactic epoxy core to reduce deflection under vacuum bag pressure, and a vacuum groove network is machined into the perimeter flange. The tool is tested for vacuum integrity at −0.85 bar before first use; any leak is sealed with a thixotropic epoxy putty and the test repeated.

    This material is not suitable for autoclave cycles above 65 °C, because the heat deflection temperature of the carbon-filled PET-G matrix is exceeded and the tool face can creep under autoclave pressure. It is also incompatible with solvent-based cleaning agents containing ketones or chlorinated solvents, which attack the PET-G surface and cause environmental stress cracking at the bead fusion lines. The terminal product is a room-temperature vacuum bag support shell used for low-volume composite repair panels, with dimensional inspection performed in accordance with ISO 1101 for geometrical tolerancing. Because carbon fibre orientation in the printed shells is anisotropic, tensile coupons cut from representative sections are tested in both longitudinal and transverse directions according to ISO 527-2 before the tool is released to production.

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    Более подробное введение

    Fused granulate fabrication of carbon-filled glycol-modified polyethylene terephthalate is not a direct substitute for unfilled PET-G filament processing. The Mitsubishi FGF Recycled CARBON-P PET-G compound is supplied as a pelletized feedstock for large-format additive manufacturing systems that meter granulate directly into a single-screw extrusion toolhead. The product designation combines a recycled carbon fiber filler with a PET-G matrix; exact filler loading, melt volume-flow rate, density, tensile modulus, and drying parameters are controlled by the supplier technical data sheet. Published quantitative data for this specific grade is limited; therefore, mechanical and thermal values in this document are constrained to the PET-G matrix class, recycled carbon fiber behavior, and recognized test methods rather than presented as grade-specific guarantees.

    In high-shear compounding, recycled carbon fiber is dispersed into the PET-G melt; no additional mixing is required at the FGF machine.

    What Drying, Melt Flow, and Hardware Constraints Are Imposed by Recycled Carbon-Filled PET-G?

    Moisture uptake in PET-G is lower than in polyamide, but hydrolytic degradation during extrusion remains a process risk if granulate is exposed to ambient humidity. Predrying in a desiccant dryer with a dew point of −40 °C or lower for 4–6 h at 65 °C is typical for PET-G compounds. Carbon-filled grades should be dried until residual moisture is below 0.02% by mass, verified by ISO 15512:2019 or an equivalent Karl Fischer method. Dried granulate must be conveyed under dry air or nitrogen; open hoppers with ambient air ingress reintroduce moisture and are inappropriate for production runs exceeding 60 min without re-drying.

    The addition of recycled carbon fiber increases melt viscosity and modifies shear-thinning behavior. Melt volume-flow rate should be characterized according to ISO 1133-1:2022 at a fixed temperature and load established by the supplier. A single melt flow value does not fully describe extrusion behavior because carbon-filled compounds can exhibit shear-thinning behavior that varies with fiber length distribution. On single-screw pellet extruders with an L/D ratio between 20:1 and 30:1, variations in recycled fiber length can alter backpressure and feed stability at constant screw speed. Hardened tool steel barrels and screws are specified; brass or aluminum flow paths are contraindicated because carbon fiber generates abrasive wear. A nozzle orifice of 0.6 mm or larger is generally required to avoid bridging of fiber agglomerates, although nozzle diameter selection must be matched to layer height and deposition rate.

    Large-format processing with this feedstock is performed on robotic or gantry systems equipped with pellet extruders rather than filament drive systems. Barrel setpoints reported for carbon-filled PET-G compounds in industrial FGF applications commonly range from 240 °C to 270 °C, while the print bed or chamber is held between 70 °C and 90 °C for amorphous PET-G to reduce first-layer curl. These values are indicative of the broader PET-G class; the grade-specific thermal window must be confirmed because recycled filler content and residual sizing can shift the onset of thermal degradation. Closed-chamber or draft-shielded operation is used for large parts to minimize non-uniform cooling. Heating only the bed without an enclosure is often insufficient for parts exceeding 500 mm in the longest axis when dimensional tolerance is specified under ISO 2768-1 or equivalent in-house criteria.

    Interlayer adhesion in FGF is governed by the thermal history of the deposition interface. A high-throughput pellet extruder can deposit beads with widths of 2–10 mm at linear rates up to several hundred millimeters per second, but successive layer time can drop below the polymer’s relaxation threshold. For carbon-filled PET-G, fiber orientation is strongly anisotropic: fibers align in the deposition direction, producing higher tensile modulus along the bead axis than across it. The resulting anisotropy must be quantified by testing X-Y and Z-direction specimens separately using ISO 527-2:2012. Published data for this specific grade are limited; therefore mechanical allowables should not be transferred from unfilled PET-G or from filament-grade carbon-filled PET-G without confirmation.

    Thermal Expansion, Warpage, and Surface Resistivity Shift Away from Unfilled PET-G.

    Carbon fiber reduces the in-plane coefficient of linear thermal expansion relative to unfilled PET-G; the magnitude depends on fiber loading, fiber length retention, and orientation. Measurements should follow ISO 11359-2:1999 across the expected service temperature range. Unfilled PET-G typically exhibits higher CLTE values than carbon-filled compounds, which can reduce warpage in large, flat deposition footprints. However, anisotropic reinforcement can create differential shrinkage between the bead direction and the transverse direction, especially in thin walls. Stress-relief annealing of printed parts may be required when tight geometric stability is specified.

    Electrical surface and volume resistivity change when conductive carbon fiber exceeds the percolation threshold. Test methods such as IEC 60093 or IEC 62631-3-1:2016 are applied to printed specimens rather than injection-molded plaques, because interlayer boundaries and fiber orientation control the conductive network. Recycled carbon fiber with broad length distribution and residual sizing can produce higher and more variable resistivity than virgin chopped carbon fiber. For applications requiring electrostatic dissipation, resistance should be measured on the as-printed surface and after abrasion or conditioning, not on polished coupons.

    Relative to carbon-filled polyamide, the PET-G matrix absorbs less moisture. Carbon-filled PA6 can absorb 9–10% moisture at saturation under ISO 62:2008, whereas PET-G typically remains below 1% at 23 °C and 50% RH. This difference reduces hygroscopic swelling and stabilizes mechanical properties in uncontrolled humid environments, but PET-G has a lower continuous service temperature than reinforced semi-crystalline polyamides. Heat deflection temperature testing under ISO 75-2:2013 at both 0.45 MPa and 1.8 MPa is required to define the upper service boundary. Carbon-filled PET-G is generally not selected for continuous load at temperatures approaching the matrix glass transition; long-term performance must be evaluated under ISO 899-2:2003 for creep behavior where sustained mechanical load is present.

    Relative to carbon-filled ABS, PET-G provides lower styrene-related emissions during extrusion and better resistance to certain chemical environments, although chemical resistance claims must be verified by ISO 175:2010 with the specific reagent, concentration, temperature, and exposure duration. The interlayer adhesion of PET-G is often more tolerant of chamber temperature fluctuations than ABS, but this is a process-dependent property, not an intrinsic material constant.

    Relative to filament-based carbon-filled PET-G, the FGF feedstock is intended for larger deposition beads and higher throughput. The pellet form eliminates filament winding and diameter tolerance constraints but shifts process control to granule metering, drying, and screw wear management. Feedstock cost per kilogram can be lower for recycled carbon-filled pellets, but the total cost of ownership includes increased wear on screws and barrels, drying energy, and more extensive incoming inspection.

    When Standards Compliance and Recycled Content Verification Are Required for the Product.

    For industrial qualification, the following test method matrix is used to establish a reproducible material specification. The list is not an exhaustive regulatory certification; REACH, RoHS, and FDA 21 CFR status depend on the specific grade, filler source, and target jurisdiction.

    PropertyStandard or methodNotes for recycled carbon-filled PET-G
    DensityISO 1183-1:2019Density increases with carbon fiber content; recycled filler may broaden the range.
    Tensile propertiesISO 527-2:2012Test X-Y and Z-direction printed specimens due to anisotropy.
    Flexural propertiesISO 178:2019Use printed specimen dimensions; fiber orientation affects modulus.
    Charpy impactISO 179-1:2010Carbon filler typically reduces unnotched impact energy.
    Melt volume-flow rateISO 1133-1:2022Incoming inspection for batch-to-batch control.
    Moisture contentISO 15512:2019Verify residual moisture below supplier maximum before extrusion.
    Ash contentISO 3451-1:2019Indicates filler content; recycled carbon may retain sizing residue.
    Heat deflection temperatureISO 75-2:2013Test at 0.45 MPa and 1.8 MPa.
    CLTEISO 11359-2:1999Measure in deposition and transverse directions.
    Surface resistivityIEC 60093 or IEC 62631-3-1:2016As-printed surfaces show interlayer-dependent resistivity.
    Chemical resistanceISO 175:2010Reagent-specific testing is required.
    CreepISO 899-2:2003Required for sustained load applications.

    Recycled carbon content claims should be supported by supplier mass-balance documentation or third-party certification. No single ISO standard quantifies recycled content by itself; environmental self-declaration categories are defined in ISO 14021:2016. Compliance with EU RoHS Directive 2011/65/EU Annex II restricted substances and the REACH Candidate List must be verified with supplier documentation because recycled carbon sources can introduce trace metals or sizing residues not present in virgin polymer. Carbon-filled recycled grades are typically not qualified for food-contact applications; specific migration testing under EU 10/2011 or FDA 21 CFR conditions is required.

    Managing FGF Toolpath, Purge, and Wear in Production-Scale Cells.

    Production-scale experience with recycled carbon-filled pellet feedstock indicates that feed throat temperature control is critical. The feed throat should be maintained below 50 °C with forced air or water cooling to prevent granule softening and bridging before the compression zone. A gravimetric feeder or calibrated volumetric feeder is required because bulk density variations in recycled fiber granulate can alter deposition rate. Bulk density can be checked by ISO 60:1977; a significant change in bulk density should trigger feeder recalibration and a purge of the extrusion system.

    Toolpath programming for FGF with fiber-filled PET-G should avoid sharp direction reversals that create local over-fill and nozzle pressure spikes. Closed-loop melt pressure monitoring is recommended; if nozzle pressure approaches the upper supplier limit, feed rate or traversal speed should be reduced. A hardened tool steel or ruby nozzle orifice of 0.6 mm or greater is used because carbon fiber produces erosive wear. Brass nozzles are contraindicated. Screw and barrel wear should be inspected at intervals determined by throughput, filler loading, and melt pressure history; no universal replacement interval applies.

    The compound should be kept below the supplier maximum drying temperature to avoid hydrolytic degradation and thermal oxidation of recycled carbon sizing. Incompatibility with certain purge compounds exists; chlorinated or sulfur-containing purge residues can accelerate degradation at processing temperatures. Avoid mixing with unfilled PET-G or other polymer families unless the entire system is purged, because viscosity mismatches and fiber agglomeration can lead to nozzle plugging. If the melt volume-flow rate or ash content falls outside the supplier-established control range, the lot should be quarantined pending adjustment of dryer residence time, feeder calibration, or extrusion temperature.

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