| Код ТН ВЭД | 493845 |
Как аккредитованный завод Mitsubishi FGF Recycled PET-G 3D Printing Polymer, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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For large-format vacuum forming tooling, the Mitsubishi FGF recycled PET-G pellet feedstock is processed through a pellet-fed extrusion head with nozzle diameters from 2.0 mm to 4.0 mm and layer heights between 0.8 mm and 2.5 mm on a gantry platform with a heated bed held at 70°C to 80°C. Because reclaimed PET-G retains the glycol-modified backbone’s reduced crystallinity and low haze, the printed blank can be machined with woodworking routers and sealed with a two-component epoxy coating to maintain vacuum integrity under −0.8 bar forming pressure. The primary process conflict is not melt flow but residual stress accumulation: at a 4.0 mm bead width and 2.5 mm layer height, the center of a 900 mm × 600 mm × 300 mm tool can retain enough asymmetric cooling stress to lift edges from the build plate unless the bed temperature is maintained and the print is cooled under an insulated cover for 6 h to 8 h. Dimensional stability is checked after annealing at 65°C for 3 h; a deviation greater than 0.5 mm/m according to ISO 3127 or an internal coordinate measuring machine protocol indicates that the recycled lot requires pre-compounding or more aggressive drying. Published data for this specific recycled FGF configuration is limited; therefore tensile yield and elongation at break should be verified on the incoming lot using ASTM D638-14 and compared with the virgin PET-G baseline of approximately 50 MPa yield strength and 20% elongation at break. The operational boundary is thermal: the forming tool surface must remain below 60°C because the heat deflection temperature of unreinforced PET-G is approximately 70°C at 0.455 MPa per ASTM D648-18, and repeated contact with hot polycarbonate or ABS sheet at 140°C will cause localized plastic flow and loss of vacuum channel geometry.
Automotive interior trim prototypes and assembly jigs printed from this feedstock on a 1.2 m × 1.2 m × 1.0 m gantry machine expose the dependence of shrinkage on print geometry. The shrinkage factor of amorphous PET-G is typically between 0.3% and 0.7% measured parallel to the extrusion bead and 0.4% to 0.9% transverse to the bead, so a 1,000 mm long locating edge must be oversized by 4 mm to 9 mm before machining. A coordinate measuring machine set to a bilateral tolerance of ±0.25 mm per ISO 2768-1 class m is required to validate post-machining positions after 24 h of conditioning at 23°C ± 2°C and 50% ± 5% relative humidity. Use of a heated chamber above 45°C improves interlayer fusion but increases accumulated dimensional error in tall parts because the amorphous polymer cannot release heat quickly enough through the bead. On a high-flow pellet extruder with an L/D of 24:1, clogging has been observed when internally reground trim exceeded 15 wt% of the hopper blend and the fines passed 1.0% moisture by weight, producing acetaldehyde and acetic acid odor at the nozzle. This limits the direct reuse of internal scrap without desiccant drying at 65°C for 4 h to 6 h and melt filtration through a 200 µm screen pack. For trim fixtures, the printed PET-G surface can accept a two-part polyurethane primer, but the substrate must be abraded with 120-grit abrasive and flame-treated to 44 dyn/cm surface energy; otherwise adhesion falls below 3.0 MPa in pull-off tests per ISO 4624:2016. The upper service temperature of the jig must not exceed 55°C when under continuous clamping load because creep at 0.455 MPa becomes measurable after 12 h.
Retail point-of-purchase display structures are produced at lower resolution than tooling, commonly with 4.0 mm nozzles and 2.5 mm layer heights, because the economic case depends on deposition rate rather than surface finish. Cantilevered shelf loads above 12 kg require internal steel L-brackets, since the flexural modulus of unreinforced PET-G at approximately 2.0 GPa per ISO 178:2019 permits visible sag of more than 6 mm over a 600 mm span. Post-consumer recycled content batches vary in pigment dispersion; opaque black and white display panels should be inspected for melt fracture at screw speeds above 60 min⁻¹ on a 45 mm single-screw extruder. Edge lighting and backlit translucent panels are possible only when the recycled feedstock is lot-sorted, because mixed-color flakes reduce light transmission below 55% at 6 mm thickness, as measured by ASTM D1003-21. The only process-specific compliance requirement for a retail installation is the flammability classification of the final assembled fixture; bare PET-G is typically HB under UL 94, but the addition of paper, fabrics, or paints can change the final test result.
In container development, bottle and jar shape mockups are printed from this recycled PET-G only when the target article is made from a different polymer, because recycled FGF PET-G is not a direct predictor of bottle-grade PET blow-molding behavior due to different intrinsic viscosity and molecular weight distribution. The printed mockup is used as a visual and dimensional stand-in for shape approvals and for checking label panel geometry; no food-contact or pharmaceutical-contact claim is made because the recycled feedstock is not certified to FDA 21 CFR 177.1630 or EU Regulation No 10/2011 without a specific lot-specific migration study. The critical printing parameter is layer fusion at thin walls: a 3.0 mm nozzle with a 1.0 mm layer height can produce a 4.0 mm wall section that survives repeated handling at 23°C only if extrusion temperature is held between 235°C and 250°C; below 230°C, interlayer adhesion drops to less than 70% of the bulk tensile strength when tested by ASTM D638-14. Above 260°C, thermal degradation begins to generate acetaldehyde at levels detectable by smell at the nozzle, and the melt viscosity becomes unstable over a 10 min residence time. Drying is more aggressive for blow mold shape work than for display panels because small nozzle sizes and thinner layers amplify moisture splay; pellets are dried at 65°C for 5 h to a moisture content below 0.02% by weight using a desiccant dryer with a −40°C dew point. Shape mockups are then surfaced with a solvent-borne primer if dimensional inspection requires white-light scanning; unpainted PET-G can reflect enough light to confuse automated photogrammetry, so a very thin layer of titanium dioxide-filled primer with a dry film thickness below 10 µm is applied. The operational boundary is explicit: any attempt to use the printed shape directly as a blow mold insert or preform for actual parison molding is outside the material’s intended use, because the recycled FGF grade lacks the required crystallinity and thermal stability for repeated blow molding cycles at 95°C mold temperature.
| Verification point | Test method | Input condition | Useful acceptance window |
|---|---|---|---|
| Pellet moisture after drying | ISO 15512:2019 | Desiccant dryer, 65°C, 4 h to 6 h | <0.02% by weight |
| Tensile yield strength | ASTM D638-14 | 23°C, 50% RH, 5 mm/min | Compare to virgin PET-G lot baseline; variation under ±10% |
| Flexural modulus | ISO 178:2019 | 2.0 mm/min, 80 mm × 10 mm × 4 mm specimen | Report lot value; typical unreinforced PET-G near 2.0 GPa |
| Heat deflection temperature | ASTM D648-18 | 0.455 MPa, annealed specimen | ≥65°C preferred; reject continuous-load applications below 60°C |
| Flame classification | UL 94 | 3.0 mm printed slab | HB for bare polymer; final assembly may alter classification |
Marine cabinetry and high-humidity service parts made from this recycled PET-G are printed as flat panels with a 2.0 mm layer height and a 25% infill density, then sealed with a two-component polyurethane clear coat to prevent water staining at the layer lines. The moisture absorption of PET-G remains below 0.3% after 24 h immersion at 23°C according to ASTM D570-98(2018), so dimensional change in a hot shower enclosure is lower than that of unreinforced polyamide printed parts, but the surface must not be continuously submerged. Metal threaded inserts installed with a minimum edge distance of 2.0 × the insert diameter and a pull-out load below 220 N per insert are stable after 1,000 cycles of loading and unloading. Exposure to salt mist per ISO 9227:2022 for 96 h does not mass-corrode the polymer, but aluminum backing frames in direct contact with the printed surface require a nylon washer because galvanic corrosion at the fastener interface can crack the polymer under torque. Ultraviolet exposure is not a primary use case; unpigmented recycled PET-G will yellow and lose tensile elongation after 1,000 h of accelerated weathering per ASTM G154-23 cycle 1, and outdoor installations are restricted to shaded or interior environments.
Custom interior wall panels and facade mockups are generated as large, relatively thin slabs where the dominant defect is not delamination but out-of-plane warp caused by differential cooling across the build plate. A panel sized 1,200 mm × 2,400 mm × 30 mm printed on a heated vacuum table at 75°C with a 4.0 mm nozzle can show edge lift exceeding 8 mm unless the table vacuum is held above −0.6 bar and the first layer is ironed at 235°C with a 0.6 mm overlap. After the tenth layer, the print is paused and the substrate temperature is uniformly reduced to 65°C over 20 min to reduce the thermal gradient between the lower and upper surfaces. The recycled polymer’s melt strength is sufficient for unsupported spans up to 400 mm when printing a 45° arch, but horizontal ceilings larger than that require temporary support posts made from the same material or a water-soluble support filament. On a production-scale machine with a single-screw extruder of 30 mm diameter and 24:1 L/D, melt pressure fluctuations greater than 1.5 MPa caused by inconsistent pellet size from the recycled source produce visible surface banding; installing a melt pump and a 300 µm screen pack reduces the pressure variation to below 0.5 MPa. The panel is machinable, sandable, and paintable with a two-component acrylic-polyurethane; adhesion tests should exceed 2.5 MPa in pull-off per ISO 4624:2016. The fire performance of the bare polymer in a finished interior is governed by the regional building code; where a Class A or B surface spread of flame rating is needed, the printed PET-G alone is insufficient and must be protected with an intumescent coating or non-combustible barrier.
For office furniture hardware prototypes, blending a 4 wt% PETG-compatible masterbatch through a gravimetric feeder on the pellet inlet requires no alteration beyond confirming the melt filter remains below 1.0 MPa pressure drop at 250°C.
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Fused granulate fabrication (FGF) additive manufacturing converts polymer pellets directly into large-format printed structures through a pellet-fed single-screw extruder. The Mitsubishi FGF Recycled PET-G 3D Printing Polymer is supplied in granulate form for this equipment class; regional certifications may list the material as FGF rPET-G or with a formulation-specific suffix rather than a single universal model code. The base polymer is a glycol-modified polyethylene terephthalate copolyester in which the 1,4-cyclohexanedimethanol content suppresses crystallization, thereby reducing curl and delamination when compared with semi-crystalline recycled PET feedstocks. Recycled content is declared as post-industrial or post-consumer material under ISO 14021:2016, with the exact mass fraction stated on the lot certificate when a sustainability claim is made. The nominal pellet dimension for large-format pellet extruders is generally 2–4 mm, measured by sieve analysis according to ISO 4610 or an equivalent procedure. Published lot data for the Mitsubishi FGF rPET-G grade can be limited in some regional markets; the supplier certificate of analysis is authoritative for melt flow rate, moisture, recycled fraction, and color.
Moisture uptake in PET-G feedstocks follows a diffusion-limited path from the pellet surface, but at a granulate dimension of 2–4 mm the practical vulnerability is concentrated in the outer shell. Hydrolysis during plasticization attacks ester linkages, reducing intrinsic viscosity and producing acetaldehyde. For extrusion AM, the feedstock should be dried to a residual moisture below 0.02 wt% (200 ppm) before processing. A desiccant-wheel dryer with an air dew point of −40°C or lower, a hopper temperature of 65–80°C, and a residence time of 4–6 h is common for PET-G extrusion pellets. The upper drying temperature should not exceed 85°C because pellet softening and agglomeration in the hopper can occur before the material reaches the feed throat. Water content is verified by Karl Fischer titration using ISO 15512:2019 or ASTM D6869; the same measurement should be applied to regrind streams and any pellet blend containing recycled fraction.
On a pellet-fed extrusion AM cell, the melt processing window for unfilled PET-G feedstock is typically 230–260°C at the nozzle, with barrel zone temperatures increasing from 220°C near the feed throat to 250°C in the metering section. Build-plate temperature is generally 60–80°C, and enclosed chamber temperatures above 45°C improve interlayer fusion on full-size tools. Screw configurations with an L/D ratio of 20:1 to 30:1 and a compression ratio near 2.5:1 are compatible with 0.8–3.0 mm nozzle diameters. Residence time in the hot zone should remain below 5 min when possible; longer exposure at the upper melt-temperature limit shifts color and broadens molecular weight distribution. Back pressure and screw speed are machine-dependent, but excessive shear above 100 s⁻¹ without melt filtration can generate gel particles in recycled feedstocks that contain residual contamination. Processors using a gravimetric pellet feeder reduce shot-to-shot feed variation, which is critical because recycled granulate can exhibit a wider bulk density range than virgin pellets.
Table 1 is a compiled property envelope from ISO test data for unfilled amorphous PET-G FGF feedstocks. The recycled-grade lot may occupy the lower portion of the range when the recycled fraction is high or when feedstock sorting is less selective. These values are not a certification for the Mitsubishi FGF Recycled PET-G grade; the seller certificate of analysis applies.
| Property | Test standard | Recycled FGF PET-G envelope | Virgin unfilled PET-G envelope |
|---|---|---|---|
| Density | ISO 1183-1:2019 | 1.26–1.28 g/cm³ | 1.26–1.28 g/cm³ |
| Melt volume rate | ISO 1133-1:2022, 250°C, 2.16 kg | 8–15 cm³/10 min | 8–14 cm³/10 min |
| Tensile stress at yield | ISO 527-2:2012 | 45–53 MPa | 48–55 MPa |
| Tensile modulus | ISO 527-2:2012 | 1900–2200 MPa | 1900–2200 MPa |
| Nominal strain at break | ISO 527-2:2012 | 15–30% | 20–35% |
| Flexural modulus | ISO 178:2019 | 1900–2200 MPa | 1900–2200 MPa |
| Charpy notched impact strength | ISO 179-1:2020, 23°C | 6–10 kJ/m² | 8–12 kJ/m² |
| Heat deflection temperature, HDT-A | ISO 75-2:2013, 1.8 MPa | 60–70°C | 60–70°C |
| Glass transition temperature | ISO 11357-2:2020 | 75–80°C | 75–80°C |
| Shore D hardness | ISO 868:2003 | 72–78 | 72–78 |
Solid-state property differences between recycled and virgin PET-G are often smaller than melt-processing differences. Recycled feedstocks may present a wider melt-volume-rate distribution, requiring feed-rate compensation or nozzle-temperature trimming. Tensile and impact data are also orientation-dependent: printed specimens tested in flat and upright orientations can show more than 20% difference in Charpy notched impact under ISO 179-1:2020, so design allowables must be derived from the print orientation used in service.
The amorphous morphology of PET-G provides a measurable advantage in flatness and edge stability on tools exceeding 300 mm in length. Free linear shrinkage of unreinforced PET-G is normally below 0.5% when measured according to ISO 294-4 after molding, and printed parts commonly show lower warpage than glass-fiber-reinforced or semi-crystalline feedstocks. Unlike styrenic feedstocks, the copolyester does not release styrene monomer during melt processing; acetaldehyde and trace glycol-derived compounds may still be generated at high residence time. The recycled variant may exhibit deeper initial color and slightly higher haze than virgin PET-G, but notch sensitivity to alkalis and certain cutting fluids can be similar. The thermal limitation is explicit: PET-G loses load-bearing stiffness above 60–70°C under 1.8 MPa flexural load, so tools for high-temperature autoclave, powder-coat curing, or hot-plate forming should not be produced from this material.
If sealed containers are left open at 23°C and 50% RH, PET-G pellets can regain enough moisture within 24 h to raise residual water above the 0.02 wt% threshold; at 70% RH, the same shift may occur within a single shift. In a pellet-fed extruder with a 25 mm screw and 1.2 mm nozzle, wet feedstock is observed as irregular melt flow, splay on deposited beads, reduced interlayer wetting, and tensile delamination below the expected ISO 527-2:2012 yield stress. Hydrolyzed rPET-G exhibits a higher melt volume rate and lower melt strength; in extreme cases the material foams in the hot zone because water flashes at processing temperatures above 200°C. Batch-to-batch variance on recycled lots can also appear as gel accumulation at the nozzle tip, requiring a screen pack with 300–500 μm mesh openings or a melt filter before the print nozzle. Published data for the Mitsubishi FGF rPET-G grade under uncontrolled-humidity storage are limited; therefore, the drying limit should be treated as a boundary condition for process validation, not as a cosmetic recommendation.
For industrial fixtures, vacuum-forming tools, and robot end-of-arm housings, the choice among pellet-fed ABS, PLA, recycled PET-G, and polycarbonate involves a trade-off between heat resistance, emission profile, and bed adhesion. Recycled PET-G is positioned below polycarbonate in continuous use temperature: polycarbonate grades can withstand 115–125°C under 1.8 MPa ISO 75-2:2013, but polycarbonate requires drying at 120°C for 4 h and melt temperatures of 280–310°C. ABS provides higher HDT near 90–100°C but shows greater warpage and a styrene monomer emission profile during melt processing. PLA prints at lower melt temperatures near 190–220°C but has lower HDT and lower notch impact. Recycled PET-G offers intermediate melting temperature, lower curl than ABS, and greater ductility than PLA. The FGF pellet form also differs from filament-based PET-G because pellet extrusion can deposit at higher throughput on large-format equipment, but it demands tighter feed control: pellet bridging in the hopper or a worn non-return valve causes pressure oscillation that alters bead width and layer compaction.
Sustainability declarations must be separated from property claims. Under ISO 14021:2016, a purchaser-facing assertion of recycled content requires the seller to state whether the fraction is post-consumer, pre-consumer/post-industrial, or a mass-balance allocation. The FGF recycled PET-G product may be offered with a regional ISCC PLUS mass-balance certificate or equivalent, but that certificate does not alter the melt-processing requirements. Regrind from printed reject parts can be reincorporated only after shredding to a granulate size below 4 mm and drying to the same moisture limit. A regrind fraction above 20 wt% can broaden viscosity distribution and raise gel-particle counts, and the acceptable regrind level must be validated on the specific print cell with tensile specimens tested in both flat and upright orientations using ISO 527-2:2012.