| Код ТН ВЭД | 508082 |
Как аккредитованная фабрика Proto3000 Objet Digital Materials™ DM_9120/9420/9220/9320 для прототипирования резиноподобных полимеров, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
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The Proto3000 Objet Digital Materials DM_9120, DM_9220, DM_9320, and DM_9420 rubber-like prototyping polymer series is handled as an acrylate-functional photopolymer system for PolyJet platforms with digital material mixing. The numerical suffix of the DM_9xxx series corresponds to a graded Shore A sequence, with DM_9120 at the lowest durometer and DM_9420 at the highest among the four materials. Because published data for this specific configuration is limited, each tolerance-critical prototype is validated against ASTM D2240-15e1 Shore A, ISO 37:2017 tensile stress-strain, and ASTM D624-00(2020) tear strength after print conditioning. The materials are characterised before use with 6 mm stacked hardness plaques and 2 mm Type 3 tensile bars printed in the same orientation as the final part; build-to-build hardness drift of 2–4 Shore A points is recorded when the printer wiper blade exceeds 1,200 h service and should be treated as a process-control boundary. Support material is removed with pressurised water at 30–40 bar; sodium hydroxide release baths are used only when the geometry traps internal support cells, and immersion is limited to 30 min at 2% concentration to avoid surface hydrolysis.
In static face-seal prototyping, the DM_9220 material is used at 100% in the sealing bead region, while the clamping land is assigned 100% DM_9320 to resist creep under bolt torque. The transition between the two zones is a digitally dithered boundary 1.2 mm wide, in which the printer alternates voxels on a 50/50 duty cycle over five consecutive layers before stabilising into the land material. Processing is performed on an Objet Connex 350 in High Quality mode at 16 µm layer height with the critical seal face oriented away from support material; this orientation results in a top-side surface roughness target of Ra 0.8–1.6 µm measured to DIN EN ISO 4288. After support removal, the seat is conditioned for 72 h at 23±2°C and 50±10% relative humidity in the dark. The prototype is tested under 25 kPa internal air pressure using a modified ASTM F37-06 leak-rate fixture; the part functions as a form/fit gauge for compression-moulded EPDM gaskets, not as a service-facing seal. Continuous service above 50°C or contact with hot ethylene glycol is outside the operational boundary because the acrylate network softens and compression set increases beyond acceptable limits.
For footwear midsole prototypes, a region-specific material map is used rather than a single Shore A value. A heel strike pad is assigned 100% DM_9420, a forefoot flex zone is assigned 100% DM_9120, and the metatarsal bridge is printed as an alternating voxel dither of 70% DM_9120 and 30% DM_9420 across a transition band 4 mm wide. This assignment strategy is set directly in the PolyJet build preparation software and does not require manual resin blending. The midsole shell is printed with an outer wall thickness of 1.6 mm and an internal lattice beam thickness of 1.1 mm on an Objet 500 in High Speed mode at 30 µm layer height. After support removal with a water-jet station at 30–40 bar, the midsole is conditioned for 72 h in a desiccant cabinet at 30°C and 10% RH before mechanical testing. Because rubber-like PolyJet photopolymers absorb atmospheric moisture, Shore A values measured after 24 h conditioning are typically 3–5 points lower than after desiccation; this shift is material-batch dependent and must be recorded for each build. Energy loss is measured by force-displacement hysteresis loops on an ElectroPuls E3000 at 5 Hz, ±2 mm displacement, and 1,000 preconditioning cycles; the target energy return is above 60% for the heel pad and above 70% for the forefoot zone. Compression set is evaluated per ASTM D395-18 Method B using 13 mm diameter discs cut from the parallel printed pad, with acceptance below 20% after 22 h at 23°C. The terminal printed component is a fit-and-gait evaluation insert limited to 50–60 dry wear cycles; repeated flexing beyond this limit produces surface crazing and irreversible cell-wall collapse in the lattice, particularly at relative humidity above 60%.
Patient-specific cardiac defect replicas used in surgical pathway rehearsal are configured with a two-layer shell and a rigid insert interface. The intimal surface layer is assigned 100% DM_9120 for low Shore A softness; the outer adventitial shell is assigned 100% DM_9320 to provide shape retention during suturing; and the defect rim is a 2 mm annular zone of 40% DM_9320 and 60% DM_9420 by voxel duty cycle, because a harder rim prevents tearing when the surrogate patch is sutured. Print geometry is prepared from DICOM segmentation and hollowed to a wall thickness of 1.4 mm on an Objet Connex 260 in High Quality mode at 16 µm layer height. Internal support material is removed with a water jet at 25 bar; subsequent extraction in a 2% sodium hydroxide bath is limited to 30 min at 21–25°C because prolonged alkaline immersion degrades the elastomeric shell and increases the incidence of microcracking. The cleaned model is stored in a dark, ventilated cabinet at 20–24°C for 48 h before use to allow residual monomer volatiles to dissipate. Biocompatibility evaluation is required when the prototype will be handled by patients or clinical staff; the standard test battery is ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2010 for sensitisation, but the raw DM_9xxx rubber-like grade is supplied as industrial prototyping material and is not automatically certified for mucosal contact or long-term skin exposure. The terminal printed object is a multi-durometer cardiac model with a removable defect insert and suture channels of 0.6 mm diameter; terminal sterilisation is not validated, so application is limited to 24 h intact-skin contact per ISO 10993-1:2020.
| Property | Standard method | Specimen condition | Acceptance/target |
|---|---|---|---|
| Shore A hardness | ASTM D2240-15e1 | 6 mm stacked build, desiccated 72 h | 30–60 by material code and application |
| Tensile strength | ISO 37:2017 Type 3 | 2 mm dumbbell, 50 mm/min | ≥ 1.5 MPa |
| Elongation at break | ISO 37:2017 Type 3 | 2 mm dumbbell | ≥ 45% |
| Tear strength | ASTM D624-00(2020) die C | 2 mm sheet | ≥ 4 kN/m |
| Compression set | ASTM D395-18 Method B | 13 mm disc, 22 h/23°C | ≤ 20% |
| Cytotoxicity | ISO 10993-5:2009 | extract dilution, 24 h contact | pass only if grade certified |
| Flammability | FMVSS 302 | 100 mm x 300 mm, 3.3 mm nominal | ≤ 100 mm/min |
| Drop shock | MIL-STD-810H Method 516.8 | device assembly | 1.2 m, 5 drops/axis |
Because a bench screen showed that a DM_9320 corner specimen exceeded 6 mm lateral deflection under a 500 g static load, the outer shell of a handheld data terminal drop-test bumper is assigned 100% DM_9420, and the inner rigid chassis interface is printed in 100% VeroClear RGD810 with an overlap region of 1.0 mm at each corner. The material assignment ratio at the overlap is controlled by the printer's voxel dither pattern, set to 50% DM_9420 and 50% VeroClear over four layers, which creates a mechanical interlock rather than a molecular interphase. Corner bumper walls are 2.8 mm thick and the internal fillet radius is 4.2 mm; these dimensions are held to ±0.06 mm across a 12-part build on an Objet Connex 500. Drop-test qualification follows MIL-STD-810H Method 516.8 Procedure IV, with 5 drops per axis from 1.2 m onto plywood-backed concrete, while a piezoresistive accelerometer on the device centroid samples at 10 kHz. Tensile behaviour of the digital material is measured according to ASTM D638-14 Type IV at 50 mm/min, with an acceptance tensile strength of not less than 1.8 MPa and elongation at break not less than 40%. Dynamic mechanical analysis is run in tension mode under ISO 6721-1:2019 at 1 Hz and 3°C/min from −40°C to 60°C; published data for this specific DM_9420/VeroClear configuration is limited, so tan δ peak temperature and storage modulus are recorded for each build lot to detect batch-to-batch drift. The terminal printed parts are used as pre-tooling verification aids for silicone injection-moulded bumpers, not as final electronics enclosure compliance components.
For automotive interior trim prototypes requiring flame retardance and scratch resistance, a two-material build is used with DM_9420 as the tactile skin and a rigid Vero-family polymer as the structural core. The skin region is assigned 100% DM_9420 with a thickness of 0.9 mm, and the core region is assigned 100% rigid photopolymer with a thickness of 2.4 mm; the interface is a dithered transition band 0.3 mm wide in which the printer alternates voxels at 60% DM_9420 and 40% rigid polymer for three layers before solidifying the core. The visible skin side is printed at 16 µm High Quality mode, and the back side is printed at 30 µm High Speed mode where the variable-layer slicing capability is available on the platform. Support removal uses a water jet at 30–40 bar; no sodium hydroxide post-treatment is applied because previous builds at 2% NaOH for 30 min showed visible edge whitening in the DM_9420 skin. The surface is then finished with a waterborne polyurethane clear coat at 10–15 µm dry film thickness and cured at 60°C for 2 h. Flammability screening follows FMVSS 302 with a specimen thickness of 3.3 mm and a maximum burn rate acceptance of 100 mm/min; a preliminary uncoated DM_9420 specimen exceeded this target, and the clear coat with flame-retardant additive was required to reach a passing configuration. Scratch resistance is assessed with a crockmeter per ASTM D6279-20 using 10 double rubs under a 50 g load with a white cotton cloth; the visual change is graded against the ISO 105-A02 grey scale and a rating below 4 is rejected. The terminal component is a dashboard trim design-review model with soft-touch haptics and a rigid mounting structure, not a homologation-part substitute.
Mechanically, DM_9220 is selected for low-pressure pneumatic bellows in a soft robotics research cell because the material retains recoverable strain after cyclical flexure when wall thickness is kept below 1.0 mm. The bellow is built with an outer diameter of 12 mm, lobe pitch of 20 mm, and wall thickness of 0.8 mm; the root sections are assigned 100% DM_9320, while the expansion lobes are assigned 100% DM_9220, yielding a longitudinal material ratio of approximately 70% DM_9220 to 30% DM_9320 over the total part volume. No manual resin blending is used; the two material regions are separated by a dithered boundary 2 mm wide with a 50/50 voxel duty cycle. The part is printed vertically on an Objet Connex 260 at 16 µm layer height with sacrificial support material filling the internal chambers. Support removal is performed in a 2% sodium carbonate solution at 30°C for 48 h, followed by a deionized-water flush at 0.3 L/min through the internal passage until the effluent conductivity falls below 10 µS/cm. The cleaned bellow is conditioned at 23±2°C and 45±10% RH for 24 h before pneumatic cycling. Leak integrity is checked at 220 kPa for 20 s after every 1,000 cycles of a 0.5 Hz sinusoidal pressure profile from 0 kPa to 180 kPa; flattening or radial bulging beyond 0.3 mm is recorded as a failure. Tensile properties are tested according to ISO 37:2017 Type 3 with an acceptance elongation at break not less than 50% and tear strength not less than 4 kN/m per ASTM D624-00(2020). Published data for this specific DM_9220/DM_9320 bellows configuration is limited, so each build batch requires sacrificial tensile bars and tear coupons printed at 0.8 mm thickness in the same orientation. The terminal printed artifact is a proof-of-concept pneumatic bending actuator for grasping foam cylinders of 25–40 mm diameter; sustained industrial automation is outside the operational boundary because the acrylate photopolymer network remains susceptible to moisture-driven dimensional drift and fatigue under continuous duty.
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Proto3000 supplies the Objet Digital Materials™ DM_9120/9420/9220/9320 Rubber-like Prototyping Polymer as a UV-curable multi-grade resin system processed on PolyJet material jetting platforms. The four designations refer to rubber-like digital material grades generated by simultaneous jetting and in situ blending of soft and rigid photopolymer precursors. The deposited droplets are roller-planarized and UV-cured, producing dense elastomer parts with a build resolution controlled by the selected mode: 16 μm in glossy mode or 30 μm in matte/high-speed mode. The DM_9120, DM_9420, DM_9220, and DM_9320 grades are used where a rubber-like Shore A response, elongation, and surface detail are required before committing to low-volume silicone, thermoplastic polyurethane, or polyurethane production tooling.
Compared with RTV silicone casting and injection-molded thermoplastic elastomers, the digital material route eliminates cavity machining, reduces the number of process steps for form-and-function prototypes, and permits hardness gradients within one build. However, PolyJet rubber-like photopolymers are not direct replacements for production thermoset or thermoplastic elastomers under continuous service. Elevated temperature, ultraviolet exposure, or aggressive fluid contact can shift the stress-strain response. Validation programs therefore use ASTM D573 or ISO 188 for heat aging, ASTM G154 for UV exposure, and ASTM D543 for chemical compatibility before any production substitution is attempted.
In a homogeneous TangoPlus or TangoBlackPlus build, the entire part is formed from a single Shore A base resin; published TangoPlus data are commonly reported in the Shore A 26–28 range when measured according to ASTM D2240. The DM series is produced by digital blending of soft and rigid Objet base materials, shifting hardness and modulus into intermediate values that are not available as a single homogeneous cartridge. Public documents for DM_9120, DM_9420, DM_9220, and DM_9320 do not always provide full grade-specific mechanical data in a single sheet. Grade-specific hardness, tensile strength at break, elongation at break, and tear resistance values should be obtained from the current manufacturer technical data sheet. Published data for the exact numerical differences between the four suffixes is limited; substituting TangoPlus values or extrapolating from Shore A alone is not valid for design calculations.
The relevant test matrix for elastomer-like photopolymer prototypes is shown in Table 1. Conditioning is performed at 23 ± 2 °C and 50 ± 5 % RH according to ASTM D618 unless otherwise specified. Hardness specimens are stacked or printed to a minimum 6 mm thickness to avoid the substrate effect described in ASTM D2240.
| Property | Reference Method | Notes |
|---|---|---|
| Shore A hardness | ASTM D2240-15 / ISO 7619-1:2010 | Use 6 mm minimum thickness; report indentation time as 1 s or 3 s after initial contact. |
| Tensile stress-strain | ASTM D412-16 or ISO 37:2017 | Crosshead speed 500 mm/min; Die C or Die D geometry must be confirmed with the technical data sheet. |
| Tear resistance | ASTM D624-00(2012) Die C | Record the median tear peak; notch preparation affects results more than Shore A variation. |
| Compression set | ASTM D395-18 Method B | Apply 25 % deflection; test for 22 h at 23 °C or 70 °C depending on service temperature. |
| Density | ASTM D792-20 | Report at 23 °C after conditioning. |
| Water absorption | ASTM D570-22 | Immerse 24 h at 23 °C; moisture from support removal can distort immediate test results. |
| Flammability | UL 94 | Typically HB or no UL classification; verify before electrical or enclosed-system use. |
The mechanical response of the DM grades is not adequately captured by Shore A alone because digital blends can produce different tangent moduli and recovery kinetics at the same durometer value. For tensile testing, ASTM D412-16 applies to rubber-like specimens, while ASTM D638-14 is sometimes used for rigid digital blends. When ASTM D638 is applied to elastomer-like PolyJet materials, the strain rate and necking behavior differ from ASTM D412; data from the two methods should not be mixed on one material certificate.
In a sealing-interface prototype, DM_9120, DM_9420, DM_9220, or DM_9320 may be used to simulate a production gasket with a target Shore A specification. The design should not rely on a single hardness measurement alone. A compression set test is run according to ASTM D395 Method B at 25 % deflection; a 22 h test at 23 °C establishes room-temperature recovery, while a 22 h test at 70 °C detects thermomechanical relaxation. For a flange seal, the part is printed with the sealing bead oriented so that compression load is applied perpendicular to the layer interfaces. Loading parallel to the layer stack increases the risk of delamination-induced leakage. Support material is removed from gland corners with a low-pressure waterjet according to the machine manufacturer protocol, and the part is conditioned before Shore A and thickness verification.
The digital blend can exhibit position-dependent Shore A and elongation if the resin ratio is altered within a build. For validation, tensile specimens should be extracted or printed separately at the same digital material configuration as the final part. ASTM D412-16 defines a crosshead speed of 500 mm/min for rubber specimens, but the specimen geometry must be confirmed against the material technical data sheet because PolyJet photopolymers may use ASTM D638-14 for rigid digital blends. When ASTM D638 is used, Type IV specimens are common for elastomeric plastics, but the resulting strain rate and necking behavior differ from a D412 rubber protocol.
Tear resistance measured under ASTM D624 Die C is sensitive to the printed edge finish and layer orientation. A specimen with the tear notch aligned parallel to the build layers may show a lower tear peak than one with the notch perpendicular to the layers. Compression set under ASTM D395 Method B is more relevant for gaskets and seals than tensile elongation because the retained deflection is directly related to sealing force loss. Table 2 summarizes grade-selection logic for common prototyped elastomer functions.
| Prototyping Requirement | Primary Measurement | Grade Selection Consideration |
|---|---|---|
| Low-pressure seal or gasket | ASTM D395 compression set and Shore A | Select grade with the lowest compression set that still matches the target Shore A; verify recovery after 70 °C aging. |
| Repeated flexing bellows or diaphragm | Tear resistance, ASTM D624 Die C | Higher-modulus grades may tear earlier at a sharp notch; verify crack propagation on the convex side of the folded feature. |
| Overmolding simulation | Hardness ASTM D2240, elongation ASTM D412 | Match production TPE Shore A and note that PolyJet rubber-like grades are not molten thermoplastics; no melt-film adhesion to a rigid substrate exists. |
| Soft-touch grip or overlay | Shore A, surface texture, ASTM D3363 pencil hardness | Matte mode provides coarse surface; glossy mode reduces roughness; verify coating adhesion according to ASTM D3359. |
PolyJet rubber-like parts are anisotropic to a degree that depends on layer thickness, print mode, and the local blend ratio. A cylinder printed with its axis perpendicular to the build tray shows different radial compression stiffness than the same cylinder printed with its axis parallel to the tray. For functional validation, measurements should be made on parts built in the same orientation as the intended service orientation. Waterjet removal of SUP705/SUP706 family support can introduce residual water into the surface; if tensile or hardness testing is performed immediately without conditioning, the mechanical data will not match the manufacturer specifications.
For DM_9120, DM_9420, DM_9220, and DM_9320 parts with wall sections below 1 mm, the UV dose transmitted through the layer stack can vary with pigment and support-material contamination. Dimensional accuracy may shift if parts are not dried after support removal. Moisture uptake in unconditioned samples can plasticize the photopolymer network, lowering Shore A readings and increasing elongation before break. The effect is reversible in some formulations only after 24–48 h of desiccation at 23 °C and 50 % RH or after a controlled air-dry cycle, but no manufacturing decision should rely on uncorrected wet measurements.
In an ergonomic overmolding study, the digital material is jetted over a rigid PolyJet core or onto a machined substrate. The joint is not a melt bond; it forms through photopolymerization and mechanical interlocking. Lap shear strength can be measured according to ASTM D3163 for adhesively bonded plastic joints if the interface is considered adhesive; if the overmolding is a geometric interlock, the limiting failure mode is shear through the elastomer layer rather than the interface. Prototype validation should therefore include both Shore A measurement and destructive peel or shear testing at the exact interface thickness.
Temperature limits and fluid exposure require explicit boundaries. The TangoPlus-derived base resin has a published heat deflection temperature near 45–50 °C under ASTM D648 at 0.45 MPa; DM formulations may shift this envelope but should not be assumed to extend continuous-service temperature significantly without grade-specific data. Continuous exposure to ketones, chlorinated solvents, esters, or high-aromatic fuels can soften or craze acrylate-based photopolymer networks. Chemical resistance testing under ASTM D543 is required before the DM grade is used in fuel-system, brake-system, or aggressive cleaning applications.
Differences from other prototyping materials are clearest in processing and failure behavior. RTV silicone casting produces lower hardness and better high-temperature and tear recovery in many cases, but requires mold fabrication and manual degassing. Thermoplastic elastomer fused deposition provides melt-processable layers with higher elongation but coarser resolution and weaker interlayer fusion. The DM_9120, DM_9420, DM_9220, and DM_9320 materials occupy a middle range: fine PolyJet resolution, digital hardness control, and rubber-like recovery, while remaining bounded by photopolymer aging, moisture sensitivity, and lower tear resistance than many production elastomers.