| Код ТН ВЭД | 449843 |
Как аккредитованная TRANSMARE BIO 35LA-0.001 фабрика по биологически разлагаемой полимолачной кислоте для литья под впрыском, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.
| Упаковка | |
| Доставка | |
| Хранение |
| Application cluster | Drying requirement | Melt temperature range | Mold temperature range | Nominal wall thickness | Critical compliance controls |
|---|---|---|---|---|---|
| Disposable cutlery | Desiccant dryer, dew point −40 °C, 80 °C / 4 h, residual <250 ppm | 185–200 °C | 25–35 °C | 1.2–2.0 mm | EN 13432:2000/AC:2005; (EU) No 10/2011 |
| Cosmetic jars | Dew point −40 °C, 80 °C / 4 h, residual <200 ppm | 190–210 °C | 65–85 °C | 3.0–5.0 mm | REACH (EC) No 1907/2006; RoHS 2011/65/EU |
| Dental trays | Cleanroom drying to <200 ppm | 185–205 °C | 20–30 °C | 2.0–3.5 mm | ISO 10993-5:2009; ISO 10993-10:2013 |
| Cold-brew capsules | Desiccant dryer, residual <180 ppm | 190–205 °C | 30–45 °C | 1.0–1.6 mm | EN 13432:2000/AC:2005 |
| Building blocks | Residual <250 ppm | 185–200 °C | 25–35 °C | Variable boss thickness | EN 71-3:2019+A1:2021; ASTM F963-23 |
| Horticultural trays and clips | Residual <250 ppm | 180–200 °C | 20–30 °C | 2.0 mm | ISO 20200:2023; ASTM D6400-21 |
| Electronics distribution trays | Residual <200 ppm | 190–210 °C | 20–35 °C | 2.0–4.0 mm | RoHS 2011/65/EU; ASTM D257-14 |
Конкурентоспособные цены на биоразлагаемую полимолачную кислоту TRANSMARE BIO 35LA-0.001 для литья под впрыском, которые соответствуют вашему бюджету - гибкие условия и индивидуальные котировки для каждого заказа.
Для получения образцов, цен или более подробной информации свяжитесь с нами по адресу +8618136850665 или отправить по почте admin@ascent-chem.com.
Мы ответим вам как можно скорее.
Телефон: +8618136850665
Электронная почта: admin@ascent-chem.com
Гибкие условия оплаты, конкурентоспособные цены, первоклассное обслуживание — обращайтесь прямо сейчас!
TRANSMARE BIO 35LA-0.001 is designated as an injection-molding grade of biodegradable polylactic acid (PLA). The alphanumeric suffix 0.001 is not an ISO-defined melt-flow or additive notation; it is a manufacturer-specific identifier that must be read against the lot certificate and safety data sheet. For unfilled PLA injection grades characterized under ISO 527-2, typical values reported in public polymer databases lie in the ranges 3.0–3.5 GPa for tensile modulus, 48–60 MPa for tensile strength, and 2.5–4.0 kJ/m² for notched Izod impact strength under ISO 180/A. Published data for this precise TRANSMARE designation is limited, and these ranges are not a substitute for lot-specific certification.
Thermal analysis by differential scanning calorimetry under ISO 11357-2 on similar PLA injection grades records a glass transition between 55°C and 60°C and a melting endotherm between 150°C and 170°C, depending on L-lactide optical purity. The melt volume-flow rate for PLA injection grades at 210°C and 2.16 kg under ISO 1133-1 typically falls between 6 cm³/10 min and 15 cm³/10 min, but no value for the 0.001 suffix is assigned without a supplier certificate. Biobased carbon fraction may be measured under ASTM D6866-22 Method B; PLA derived from lactic acid fermentation commonly exceeds 95% biobased carbon, but the exact figure for this grade must be confirmed from the manufacturer. The material should be considered unfilled and non-nucleated unless the supplier documentation explicitly lists additives.
Under ISO 1043-1, polylactic acid is designated as PLA; the same abbreviation appears in EN ISO 1043-1. The term BIO in the trade name is not an ISO 1043 classification and does not independently certify compostability or biodegradability. A finished article made from this resin may be claimed compostable only when the article has been tested and certified under EN 13432, ASTM D6400-23, or ISO 17088:2021. Those standards contain requirements for disintegration at 12 weeks, biodegradation at 180 days at 58°C for industrial composting, and ecotoxicity limits for heavy metals. Compliance therefore belongs to the finished article and its additives, not to the raw polymer alone.
Before melt processing, the pellets must be dried in a desiccant dryer with a dew point of -40°C or lower. For PLA injection grades, residual moisture should be reduced below 250 ppm by mass, because hydrolytic chain scission accelerates when moisture exceeds 0.025 wt% at melt temperatures above 190°C. A drying schedule of 80°C for 4 h or 60°C for 8 h is common for unfilled PLA, but ambient relative humidity above 60% can overload oven drying. Moisture content should be verified by Karl Fischer titration or ISO 15512:2019 before startup; values above 300 ppm typically produce splay, lowered molecular weight, and reduced impact resistance in molded parts. Hydrolysis in the barrel is further autocatalyzed by residual lactide, so dried pellets should not be returned to uncovered containers.
The upper melt-temperature limit is set by thermal degradation. Published studies on PLA quantify measurable molecular-weight loss after 10–15 min residence at 240°C, with lactide reformation and discoloration. The lower limit is set by incomplete plastication; capillary rheometry data under ISO 11443 for similar PLA grades show pseudoplastic flow with a power-law index near 0.3–0.6 between 100 s⁻¹ and 10,000 s⁻¹. This shear-thinning is less than that of polypropylene, so narrow runners and small gates can generate excessive pressure drop if melt temperature falls below 190°C. The effective melt-temperature window for unfilled PLA is therefore approximately 190–220°C, and deviations of ±5°C around the mid-range alter gate-seal clarity, part mass, and post-mold shrinkage.
Mold temperature introduces a second conflict. Cold molds at 20–30°C provide fast ejection but suppress crystallization, producing amorphous parts with lower heat-deflection performance. Hot molds at 90–110°C can develop higher crystallinity but extend cooling time and may cause sticking or ejection defects if draft angles are below 1°. Nozzle freeze-off is common when the tool is below 20°C and the runner system has insufficient hot-tip control.
Injection speed is preferably moderate to high for thin-wall parts, because PLA solidifies quickly enough to freeze off gates before complete packing in slow-fill cycles. Molding trials on conventional hydraulic and electric machines with clamp force from 600 kN to 1,200 kN indicate that gate blush appears when shear rates exceed 10,000 s⁻¹; local shear heating can then push melt temperature above 230°C and promote degradation at the gate interface. A general-purpose screw with L/D ratio 20:1–24:1 and compression ratio 2:1–3:1 is suitable; low-compression screws intended for PVC are not recommended because PLA requires more dispersive mixing for any functional additive masterbatch. Back pressure should be maintained between 0.5 MPa and 1.5 MPa, and screw speed between 100 rpm and 200 rpm. Holding pressure for unfilled PLA is commonly 40–70 MPa, but actual gate-seal time should be determined by part-weight stabilization at the press rather than by a fixed timer.
| Parameter | Starting range | Reference or equipment |
|---|---|---|
| Residual moisture after drying | below 250 ppm | ISO 15512:2019, Karl Fischer titration |
| Melt temperature | 190–220°C | closed-loop barrel heaters |
| Mold temperature, amorphous | 20–30°C | water-cooled tool |
| Mold temperature, crystallized | 90–110°C | oil or electric mold heating |
| Back pressure | 0.5–1.5 MPa | hydraulic injection unit |
| Screw speed | 100–200 rpm | general-purpose screw 20:1–24:1 L/D |
| Holding pressure | 40–70 MPa | screw-tip hydraulic pressure |
| Nozzle temperature | 200–215°C | closed-loop nozzle heater |
If the tool surface remains below the glass transition during filling, the molded article is largely amorphous and exhibits heat-deflection behavior governed by ISO 75-2 Method B. Unfilled amorphous PLA typically shows HDT values between 50°C and 60°C at 0.45 MPa, which restricts use in hot-fill, dishwasher, or automotive interior applications. Post-mold annealing at 90–100°C for 30–60 min can increase crystallinity and raise HDT, but the process introduces dimensional change and can warp non-uniform thin-wall parts. Mold shrinkage for amorphous PLA injection grades is typically 0.3–0.5%, but this value changes after annealing. If a part requires tighter dimensional stability, a mineral-filled or nucleated grade is normally used; this product designation should not be compounded with talc or other fillers without supplier confirmation.
Table 2 is a comparison of typical literature values for unfilled PLA injection grades against general-purpose ABS and PP homopolymer. Values are not lot-specific data for TRANSMARE BIO 35LA-0.001; they are provided for material-selection screening and must be replaced with supplier certificate values before tooling or process validation.
| Property | Test method | Unfilled PLA injection grade | ABS general purpose | PP homopolymer |
|---|---|---|---|---|
| Tensile modulus | ISO 527-2 | 3.0–3.5 GPa | 2.0–2.6 GPa | 1.3–1.8 GPa |
| Tensile yield strength | ISO 527-2 | 48–60 MPa | 40–50 MPa | 25–35 MPa |
| Notched Izod impact strength | ISO 180/A | 2.5–4.0 kJ/m² | 15–25 kJ/m² | 5–10 kJ/m² |
| HDT at 0.45 MPa | ISO 75-2/B | 50–60°C | 95–100°C | 90–110°C |
| Elongation at break | ISO 527-2 | 2–10% | 5–25% | 50–500% |
Compared with petroleum-based ABS and PP, the PLA grade has higher tensile modulus but lower notched impact strength and lower heat-deflection temperature under identical ISO 75-2/B conditions. PLA is sensitive to hydrolytic degradation during processing and service, whereas ABS is susceptible to solvent stress cracking and PP may oxidize under prolonged thermal aging. The functional difference that dominates material selection is end-of-life: PLA articles can biodegrade under industrial composting conditions when certified to EN 13432 or ASTM D6400-23, while ABS and PP do not. Compared with other biodegradable polyesters such as PBAT or starch blends, PLA is stiffer and more brittle; impact modification is required for durable packaging or cutlery that must withstand snap-fit assembly. Compared with PHA, PLA generally has lower elongation at break and higher melt stiffness but a narrower processing window.
Biodegradability and compostability are not equivalent. A PLA injection-molded article may be certified as industrially compostable only after testing under EN 13432 or ASTM D6400-23. Those protocols require ≥90% carbon conversion to CO₂ relative to a cellulose reference within 180 days under controlled composting at 58°C, disintegration below 2 mm after 12 weeks, and ecotoxicity testing of the resulting compost. Home composting conditions are less reproducible; PLA typically does not meet home-compost standards at ambient temperatures because hydrolytic degradation is too slow below 50°C. If the end-use environment lacks industrial composting infrastructure, the article will persist as a rigid plastic waste stream and must not be released to conventional recycling without sorting because PLA contamination can disrupt PET reclaim streams.
At the end of a production run, PLA should not be left in the barrel. Residual PLA degrades during heat soak and can form carbonaceous deposits and acidic decomposition by-products. Purging with a polypropylene or high-density polyethylene purge grade at 200–220°C is standard; purging with polycarbonate is incompatible because its higher processing temperature accelerates PLA decomposition. The material should be stored in moisture-barrier packaging and not dry-mixed with other biodegradable polyesters such as PBAT without confirmed compatibility, because melting-point differences produce phase separation at the screw. Storage exceeding 12 months or exposure to ambient humidity above 60% requires re-drying and melt-flow verification under ISO 1133-1 before use. Amine-based additives and certain metal stearates can catalyze ester hydrolysis; their use should be avoided unless the masterbatch supplier demonstrates compatibility through melt-flow retention testing.