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TRANSMARE BIO 35LA-0.001 Injection Molding Biodegradable Polylactic Acid

    • Название продукта: TRANSMARE BIO 35LA-0.001 Injection Molding Biodegradable Polylactic Acid
    • Сайт Factroy: Округ Юду, Ганьчжоу, Цзянси, Китай
    • Запрос цены: admin@ascent-chem.com
    • Производитель: Ascent Petrochem Holdings Co., Limited
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    Спецификации
    Код ТН ВЭД 449843

    Как аккредитованная TRANSMARE BIO 35LA-0.001 фабрика по биологически разлагаемой полимолачной кислоте для литья под впрыском, мы соблюдаем строгие протоколы качества - каждая партия подвергается строгим испытаниям для обеспечения последовательных стандартов эффективности и безопасности.

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    Применение TRANSMARE BIO 35LA-0.001 Биоразрождаемой полимолочной кислоты для литья под впрыском
    In multi-cavity disposable cutlery tooling, 35LA-0.001 is processed only after predrying in a desiccant dryer with a dew point below −40 °C at 80 °C for 4 h. Residual moisture above 0.025 wt% (250 ppm) causes hydrolytic chain scission during plastication; the resulting viscosity drop shifts short-shot boundaries in 16-cavity or 32-cavity tools and produces splay on fork tine tips and knife spine edges. Melt temperature at the nozzle is maintained between 185 °C and 200 °C, and the mold is held at 25 °C to 35 °C with turbulent-flow water circuits to limit cycle time. Injection speed is set from 120 mm/s to 200 mm/s for wall sections of 1.2 mm to 2.0 mm, with screw cushion held at 3 mm to 6 mm. Because unreinforced PLA exhibits low notched impact resistance, thin-wall cutlery designs avoid abrupt transitions; radii below 0.5 mm at the fork tine root can crack on ejection or during flexure in service. Post-mold shrinkage under uncontrolled ambient conditions remains below 0.4% after 24 h unless the part is removed above 45 °C. Food-contact compliance for finished articles is documented under Commission Regulation (EU) No 10/2011 with an overall migration limit of 10 mg/dm², and industrial compostability is assessed under EN 13432:2000/AC:2005 with at least 90% disintegration after 12 weeks. Color concentrates based on PLA-compatible carriers are added at 1.5 wt% to 3 wt%; masterbatches containing hygroscopic carriers must be avoided because they elevate process moisture and produce black specks on cutlery surfaces.

    What Injection Boundaries Limit Thick-Wall Cosmetic Jar Molding?

    When 35LA-0.001 is used for single- and double-wall cosmetic jars with nominal wall thickness of 3 mm to 5 mm, mold temperature becomes the controlling variable. At 25 °C the skin solidifies before the core compresses, leading to sink marks around the neck thread and internal voids; raising the mold to 65 °C to 85 °C slows solidification and increases surface gloss, but cycle time increases by 15 s to 30 s. The processing window narrows to a mold-temperature band of ±5 °C when gloss and dimensional stability must be combined: below 60 °C sink marks increase, and above 90 °C ejection deformation occurs. Pack pressure of 45 MPa to 70 MPa hydraulic is applied for 4 s to 8 s after fill, followed by cooling through B-half channels. The material should be dried to below 200 ppm moisture, and screw rotation should not exceed 100 rpm to limit frictional heat. Because PLA has a crystallization plateau around 100 °C to 120 °C, annealing of thick-walled jars at 90 °C to 110 °C for 30 min to 60 min can raise heat deflection temperature but also increases longitudinal shrinkage from 0.3% to 0.9%, which must be compensated in thread and closure dimensions. Notched Izod impact measured by ISO 180/A remains low; drop tests on carpeted concrete at 0.5 m should be executed on first-article parts because thread shear and wall-step regions are the primary failure sites. The melt is kept at 190 °C to 210 °C, and hot runner manifolds with small shutdown volumes are preferred because prolonged residence above 220 °C for more than 5 min produces acetaldehyde-like off-notes. REACH Regulation (EC) No 1907/2006 and the absence of phthalates are verified via supplier declarations; RoHS 2011/65/EU applies where cosmetic containers include metallic spring inserts. If an immiscible fragrance barrier liner is co-injected, published data for this specific configuration is limited and compatibility must be validated by seal-peel testing and storage at 40 °C for 30 days.For disposable dental impression tray bodies and single-use instrument handles, 35LA-0.001 is molded in cleanroom environments with filtered air complying with ISO 14644-1 Class 8 as a minimum. The melt temperature is held at 185 °C to 205 °C, and mold surfaces are kept at 20 °C to 30 °C to reduce adhesion to polished steel; external mold release is prohibited because residual silicone interferes with subsequent pad printing and assembly. The part design uses 2.0 mm to 3.5 mm nominal wall, with compound curvature to stiffen the tray periphery without introducing molded-in stress. Shrinkage is monitored over 24 h at 23 °C and 50% relative humidity; deviations above 0.5% across the arch length can distort tray fit to dentition models. Because single-use instruments are not terminally sterilized by steam in most lines, heated ethylene oxide at 40 °C to 55 °C is preferred; autoclaving at 121 °C is outside the application window because the heat deflection temperature of unreinforced PLA under 0.45 MPa is insufficient. Biocompatibility data are required under ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2013 for skin sensitization and irritation, even if the part is short-term surface contact. Scrap from rejected dental trays cannot be reground into medical parts unless the percentage of post-industrial regrind is restricted to 5 wt% or less and validated for cleanliness. Production-scale observation indicates that ejector pins below 2 mm diameter can puncture the soft part if ejection is advanced before the core reaches 50 °C.

    When Cold-Brew Capsule Bases Require Compostable Sealing Bosses

    When 35LA-0.001 is injection molded into cold-brew coffee capsule bases, the part is not exposed to espresso brew temperatures of 88 °C to 94 °C; the application is restricted to chilled or ambient immersion below 40 °C. Wall thickness at the sealing boss is designed at 1.0 mm to 1.6 mm, and the gate is positioned opposite the filter support to avoid race-track flow around the central perforation. Melt temperature of 190 °C to 205 °C and mold temperature of 30 °C to 45 °C minimize warpage of the flat sealing flange; warpage above 0.3 mm across a 40 mm diameter flange disrupts ultrasonic weld amplitude and increases leaker rates. Nucleating agents, where used, are added at 0.5 wt% to 1.5 wt% to stabilize dimensional recovery after demolding, but talc above 2 wt% reduces weld-line strength at the injection point. The capsule body and lidding film are tested for compostability under EN 13432:2000/AC:2005, including aerobic biodegradation of at least 90% relative to a reference within 180 days, and disintegration below 2 mm in a 12-week pilot-scale test. Moisture after drying must remain below 180 ppm because residual water in the melt hydrolyzes PLA at these thin sections and reduces burst strength. Cold-brew contact requires sensory testing for off-flavor; storage at 40 °C for 10 days in water is a common screening method, but published data for this specific grade in long-term beverage contact is limited.

    Rigid Educational Building Blocks and Interlocking Clearance Control

    Educational building blocks and shape sorters molded from 35LA-0.001 require dimensional clearance in the 0.05 mm to 0.15 mm range for assembly without cracking. The mold is assembled with cavity-to-cavity variation no greater than 0.03 mm, and cavity pressure sensors are used to switch from injection to pack at reproducible values. Melt temperature is set at 185 °C to 200 °C, with mold temperature at 25 °C to 35 °C; fast cooling produces amorphous parts with lower eventual shrinkage than annealed parts, but mechanical properties remain modest. Tensile strength tested by ISO 527-2:2012 and notched impact by ISO 180/A should be verified for block side walls and snap features; sharp internal corners below 0.5 mm radius act as stress concentrators. Color masterbatches are limited to 2 wt% to 4 wt% and must use carriers that do not depress melt flow rate below the point at which multi-cavity filling balance is lost. Toys must comply with EN 71-3:2019+A1:2021 for migration of 19 elements and, for the United States market, ASTM F963-23 mechanical and chemical requirements; small-part warnings are not required for blocks larger than 31 mm in diameter. Long-term UV exposure causes yellowing and embrittlement, so indoor use is the defined boundary. Batch-to-batch MFR variation greater than 1.5 g/10 min at 210 °C with 2.16 kg has shifted fill time in 8-cavity block molds and created short shots in the corner boss, according to production-scale troubleshooting records.Horticultural seed tray webs, vine clips, and plant identification tags are molded from 35LA-0.001 in single-face tools with edge gates along the runner spine; the melt is held at 180 °C to 200 °C and the mold cooled to 20 °C to 30 °C to permit cycle times below 25 s for 2.0 mm walls. The use of talc at 5 wt% to 10 wt% improves bending stiffness for clip spring force but increases melt viscosity and can shift hole-fill balance in stack molds. Mineral-filled PLA compounds require screw tip check-ring clearance below 0.2 mm to prevent leakage and inconsistent shot weight. Biodegradation is not a service property: under ISO 20200:2023 laboratory-scale composting conditions, samples disintegrate within 12 to 16 weeks, but field soil at 15 °C to 25 °C and low microbial activity will not reliably degrade the parts within one growing season. For nursery use, the primary compliance reference is EN 13432:2000/AC:2005 or ASTM D6400-21, and labeling must distinguish industrial composting from home composting. Recycled regrind from sprue and runners is limited to 20 wt% in thin-walled seedling webs; higher ratios cause visible flow lines and lower melt strength at the edge perimeter. If the clips are used to support branches, service loads must be below 10 N to avoid creep at ambient temperatures above 30 °C.Comparative processing limits consolidated from the above application clusters are shown below.
    Application clusterDrying requirementMelt temperature rangeMold temperature rangeNominal wall thicknessCritical compliance controls
    Disposable cutleryDesiccant dryer, dew point −40 °C, 80 °C / 4 h, residual <250 ppm185–200 °C25–35 °C1.2–2.0 mmEN 13432:2000/AC:2005; (EU) No 10/2011
    Cosmetic jarsDew point −40 °C, 80 °C / 4 h, residual <200 ppm190–210 °C65–85 °C3.0–5.0 mmREACH (EC) No 1907/2006; RoHS 2011/65/EU
    Dental traysCleanroom drying to <200 ppm185–205 °C20–30 °C2.0–3.5 mmISO 10993-5:2009; ISO 10993-10:2013
    Cold-brew capsulesDesiccant dryer, residual <180 ppm190–205 °C30–45 °C1.0–1.6 mmEN 13432:2000/AC:2005
    Building blocksResidual <250 ppm185–200 °C25–35 °CVariable boss thicknessEN 71-3:2019+A1:2021; ASTM F963-23
    Horticultural trays and clipsResidual <250 ppm180–200 °C20–30 °C2.0 mmISO 20200:2023; ASTM D6400-21
    Electronics distribution traysResidual <200 ppm190–210 °C20–35 °C2.0–4.0 mmRoHS 2011/65/EU; ASTM D257-14

    Low-Temperature Electronics Distribution Trays Do Not Permit Solder Contact

    Electronics distribution trays molded from 35LA-0.001 are restricted to ambient and low-temperature component handling; direct exposure to solder reflow temperatures above 180 °C is outside the material capability. Melt temperature is set at 190 °C to 210 °C, and mold temperature at 20 °C to 35 °C produces flat tray pockets with minimal sink. Wall thickness is maintained between 2.0 mm and 4.0 mm to balance rigidity and cycle time. Because unfilled PLA is inherently insulative, static dissipative properties require an anti-static additive; surface resistivity is measured by ASTM D257-14, and static decay time is evaluated by MIL-PRF-81705 where component handling is sensitive. Additive loadings above 2 wt% can reduce melt flow and create flow lines at the gate, so supplier recommendations for the specific lubricant system must be followed. Trace-metal constraints for electronics packaging are governed by RoHS 2011/65/EU; hazardous substance declarations must include lead, cadmium, mercury, hexavalent chromium, PBB, and PBDE. Dimensional inspection after molding at 23 °C and 50% relative humidity should confirm pocket-to-pocket variation below 0.1 mm, because warpage in larger trays amplifies pick-and-place misalignment. Stored trays should not be stacked above 60 °C in closed containers, where creep and deformation can exceed 1% under static load.
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    Более подробное введение

    TRANSMARE BIO 35LA-0.001 is designated as an injection-molding grade of biodegradable polylactic acid (PLA). The alphanumeric suffix 0.001 is not an ISO-defined melt-flow or additive notation; it is a manufacturer-specific identifier that must be read against the lot certificate and safety data sheet. For unfilled PLA injection grades characterized under ISO 527-2, typical values reported in public polymer databases lie in the ranges 3.0–3.5 GPa for tensile modulus, 48–60 MPa for tensile strength, and 2.5–4.0 kJ/m² for notched Izod impact strength under ISO 180/A. Published data for this precise TRANSMARE designation is limited, and these ranges are not a substitute for lot-specific certification.

    Thermal analysis by differential scanning calorimetry under ISO 11357-2 on similar PLA injection grades records a glass transition between 55°C and 60°C and a melting endotherm between 150°C and 170°C, depending on L-lactide optical purity. The melt volume-flow rate for PLA injection grades at 210°C and 2.16 kg under ISO 1133-1 typically falls between 6 cm³/10 min and 15 cm³/10 min, but no value for the 0.001 suffix is assigned without a supplier certificate. Biobased carbon fraction may be measured under ASTM D6866-22 Method B; PLA derived from lactic acid fermentation commonly exceeds 95% biobased carbon, but the exact figure for this grade must be confirmed from the manufacturer. The material should be considered unfilled and non-nucleated unless the supplier documentation explicitly lists additives.

    Material Designation and Classification Under ISO 1043-1

    Under ISO 1043-1, polylactic acid is designated as PLA; the same abbreviation appears in EN ISO 1043-1. The term BIO in the trade name is not an ISO 1043 classification and does not independently certify compostability or biodegradability. A finished article made from this resin may be claimed compostable only when the article has been tested and certified under EN 13432, ASTM D6400-23, or ISO 17088:2021. Those standards contain requirements for disintegration at 12 weeks, biodegradation at 180 days at 58°C for industrial composting, and ecotoxicity limits for heavy metals. Compliance therefore belongs to the finished article and its additives, not to the raw polymer alone.

    Before melt processing, the pellets must be dried in a desiccant dryer with a dew point of -40°C or lower. For PLA injection grades, residual moisture should be reduced below 250 ppm by mass, because hydrolytic chain scission accelerates when moisture exceeds 0.025 wt% at melt temperatures above 190°C. A drying schedule of 80°C for 4 h or 60°C for 8 h is common for unfilled PLA, but ambient relative humidity above 60% can overload oven drying. Moisture content should be verified by Karl Fischer titration or ISO 15512:2019 before startup; values above 300 ppm typically produce splay, lowered molecular weight, and reduced impact resistance in molded parts. Hydrolysis in the barrel is further autocatalyzed by residual lactide, so dried pellets should not be returned to uncovered containers.

    What Limits the Processing Window for Unfilled PLA Injection Grades?

    The upper melt-temperature limit is set by thermal degradation. Published studies on PLA quantify measurable molecular-weight loss after 10–15 min residence at 240°C, with lactide reformation and discoloration. The lower limit is set by incomplete plastication; capillary rheometry data under ISO 11443 for similar PLA grades show pseudoplastic flow with a power-law index near 0.3–0.6 between 100 s⁻¹ and 10,000 s⁻¹. This shear-thinning is less than that of polypropylene, so narrow runners and small gates can generate excessive pressure drop if melt temperature falls below 190°C. The effective melt-temperature window for unfilled PLA is therefore approximately 190–220°C, and deviations of ±5°C around the mid-range alter gate-seal clarity, part mass, and post-mold shrinkage.

    Mold temperature introduces a second conflict. Cold molds at 20–30°C provide fast ejection but suppress crystallization, producing amorphous parts with lower heat-deflection performance. Hot molds at 90–110°C can develop higher crystallinity but extend cooling time and may cause sticking or ejection defects if draft angles are below . Nozzle freeze-off is common when the tool is below 20°C and the runner system has insufficient hot-tip control.

    Injection speed is preferably moderate to high for thin-wall parts, because PLA solidifies quickly enough to freeze off gates before complete packing in slow-fill cycles. Molding trials on conventional hydraulic and electric machines with clamp force from 600 kN to 1,200 kN indicate that gate blush appears when shear rates exceed 10,000 s⁻¹; local shear heating can then push melt temperature above 230°C and promote degradation at the gate interface. A general-purpose screw with L/D ratio 20:1–24:1 and compression ratio 2:1–3:1 is suitable; low-compression screws intended for PVC are not recommended because PLA requires more dispersive mixing for any functional additive masterbatch. Back pressure should be maintained between 0.5 MPa and 1.5 MPa, and screw speed between 100 rpm and 200 rpm. Holding pressure for unfilled PLA is commonly 40–70 MPa, but actual gate-seal time should be determined by part-weight stabilization at the press rather than by a fixed timer.

    Parameter Starting range Reference or equipment
    Residual moisture after drying below 250 ppm ISO 15512:2019, Karl Fischer titration
    Melt temperature 190–220°C closed-loop barrel heaters
    Mold temperature, amorphous 20–30°C water-cooled tool
    Mold temperature, crystallized 90–110°C oil or electric mold heating
    Back pressure 0.5–1.5 MPa hydraulic injection unit
    Screw speed 100–200 rpm general-purpose screw 20:1–24:1 L/D
    Holding pressure 40–70 MPa screw-tip hydraulic pressure
    Nozzle temperature 200–215°C closed-loop nozzle heater

    When Crystallization Is Suppressed by Rapid Tool Cooling

    If the tool surface remains below the glass transition during filling, the molded article is largely amorphous and exhibits heat-deflection behavior governed by ISO 75-2 Method B. Unfilled amorphous PLA typically shows HDT values between 50°C and 60°C at 0.45 MPa, which restricts use in hot-fill, dishwasher, or automotive interior applications. Post-mold annealing at 90–100°C for 30–60 min can increase crystallinity and raise HDT, but the process introduces dimensional change and can warp non-uniform thin-wall parts. Mold shrinkage for amorphous PLA injection grades is typically 0.3–0.5%, but this value changes after annealing. If a part requires tighter dimensional stability, a mineral-filled or nucleated grade is normally used; this product designation should not be compounded with talc or other fillers without supplier confirmation.

    Comparative Mechanical Property Matrix for PLA, ABS, and PP

    Table 2 is a comparison of typical literature values for unfilled PLA injection grades against general-purpose ABS and PP homopolymer. Values are not lot-specific data for TRANSMARE BIO 35LA-0.001; they are provided for material-selection screening and must be replaced with supplier certificate values before tooling or process validation.

    Property Test method Unfilled PLA injection grade ABS general purpose PP homopolymer
    Tensile modulus ISO 527-2 3.0–3.5 GPa 2.0–2.6 GPa 1.3–1.8 GPa
    Tensile yield strength ISO 527-2 48–60 MPa 40–50 MPa 25–35 MPa
    Notched Izod impact strength ISO 180/A 2.5–4.0 kJ/m² 15–25 kJ/m² 5–10 kJ/m²
    HDT at 0.45 MPa ISO 75-2/B 50–60°C 95–100°C 90–110°C
    Elongation at break ISO 527-2 2–10% 5–25% 50–500%

    Compared with petroleum-based ABS and PP, the PLA grade has higher tensile modulus but lower notched impact strength and lower heat-deflection temperature under identical ISO 75-2/B conditions. PLA is sensitive to hydrolytic degradation during processing and service, whereas ABS is susceptible to solvent stress cracking and PP may oxidize under prolonged thermal aging. The functional difference that dominates material selection is end-of-life: PLA articles can biodegrade under industrial composting conditions when certified to EN 13432 or ASTM D6400-23, while ABS and PP do not. Compared with other biodegradable polyesters such as PBAT or starch blends, PLA is stiffer and more brittle; impact modification is required for durable packaging or cutlery that must withstand snap-fit assembly. Compared with PHA, PLA generally has lower elongation at break and higher melt stiffness but a narrower processing window.

    Compostability Certification Requires More Than a Biobased Carbon Label

    Biodegradability and compostability are not equivalent. A PLA injection-molded article may be certified as industrially compostable only after testing under EN 13432 or ASTM D6400-23. Those protocols require ≥90% carbon conversion to CO₂ relative to a cellulose reference within 180 days under controlled composting at 58°C, disintegration below 2 mm after 12 weeks, and ecotoxicity testing of the resulting compost. Home composting conditions are less reproducible; PLA typically does not meet home-compost standards at ambient temperatures because hydrolytic degradation is too slow below 50°C. If the end-use environment lacks industrial composting infrastructure, the article will persist as a rigid plastic waste stream and must not be released to conventional recycling without sorting because PLA contamination can disrupt PET reclaim streams.

    At the end of a production run, PLA should not be left in the barrel. Residual PLA degrades during heat soak and can form carbonaceous deposits and acidic decomposition by-products. Purging with a polypropylene or high-density polyethylene purge grade at 200–220°C is standard; purging with polycarbonate is incompatible because its higher processing temperature accelerates PLA decomposition. The material should be stored in moisture-barrier packaging and not dry-mixed with other biodegradable polyesters such as PBAT without confirmed compatibility, because melting-point differences produce phase separation at the screw. Storage exceeding 12 months or exposure to ambient humidity above 60% requires re-drying and melt-flow verification under ISO 1133-1 before use. Amine-based additives and certain metal stearates can catalyze ester hydrolysis; their use should be avoided unless the masterbatch supplier demonstrates compatibility through melt-flow retention testing.

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